CN111793430A - Antibacterial composite heat-insulating environment-friendly coating - Google Patents
Antibacterial composite heat-insulating environment-friendly coating Download PDFInfo
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- CN111793430A CN111793430A CN202010785039.4A CN202010785039A CN111793430A CN 111793430 A CN111793430 A CN 111793430A CN 202010785039 A CN202010785039 A CN 202010785039A CN 111793430 A CN111793430 A CN 111793430A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/262—Alkali metal carbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides an antibacterial composite heat-insulating environment-friendly coating which comprises a biological modified acrylic resin emulsion, a water-based modified organic silicon resin emulsion, nano silicon dioxide, modified polysiloxane, glass fiber, modified polysiloxane, a hydrophobic active agent, an antibacterial agent and emulsified silicone oil. The environment-friendly material has the advantages of good antibacterial effect, capability of solving the problem of environmental pollution caused by the use of an organic solvent by adopting water as the solvent, small weather resistance, stain resistance and surface friction resistance, scratch resistance, scrubbing resistance and long service life, and can not generate the problems of foaming, cracking, whitening and even delamination and the like after long-term use.
Description
Technical Field
The invention relates to an environment-friendly coating, in particular to an antibacterial composite heat-insulating environment-friendly coating, and belongs to the field of environmental protection.
Background
In recent years, with the national importance on environmental pollution, people can select more cautious interior decorative coatings, and pay more attention to the problems of environmental protection, no pollution and the like. Energy problems become bottlenecks which restrict economic development of various countries, and at present, about one third of energy consumption is in the field of buildings or equipment, so that the countries pay high attention to searching and formulating effective energy-saving heat preservation methods. Under the background, the development of heat-insulating coatings is one of the important measures for energy conservation and heat preservation. The common coating has simple production process, convenient and flexible construction, low heat conductivity coefficient of the heat-insulating material and obvious heat-insulating effect, but is inconvenient for construction, and if the advantages of the two are combined to prepare the heat-insulating coating which can play the characteristics of the two when coated on a substrate.
The nanometer technology and the nanometer raw materials are applied to the coating, and the heat preservation and heat insulation property, the water resistance and the mildew resistance of the coating can be improved by utilizing the nanometer effects of zero convection and the like. The patent CN87102864 adopts the raw materials which are mainly fibrous materials of hydrous magnesium aluminum silicate, and also has the method of adding nanometer components to improve the quality of the coating, for example, the patent CN 03118030.2 adopts pure acrylic emulsion as a base material, and nanometer zinc oxide, silicon oxide, titanium oxide and the like are added, although the coating has better washing resistance and antibacterial self-cleaning function, the heat insulation effect is poorer, and the production process is more complicated. The coating invented by patent CN92112722.7 is a composite heat insulation coating which is compounded by adding fiber materials, mineral aggregates, fillers and a plurality of chemical additives by a specific process, the raw materials are in micron or millimeter level, the grinding is needed, and the production process is complex. Therefore, how to provide a coating with better heat insulation and heat preservation effects is a problem to be solved urgently.
Disclosure of Invention
The invention aims to provide an antibacterial composite heat-insulating environment-friendly coating to overcome the defects in the prior art.
The invention provides an antibacterial composite heat-insulating environment-friendly coating which comprises a biological modified acrylic resin emulsion, a water-based modified organic silicon resin emulsion, nano silicon dioxide, modified polysiloxane, glass fiber, modified polysiloxane, a hydrophobic active agent, an antibacterial agent and emulsified silicone oil.
Optionally, the biological modified acrylic resin emulsion biological modifying group is selected from at least one of amino or hydroxyl.
Alternatively, the amino group is selected from at least one of an aliphatic amino group, an alicyclic amino group, and an aromatic amino group.
Alternatively, the hydroxyl group is selected from at least one of an aliphatic hydroxyl group, an alicyclic hydroxyl group, and an aromatic hydroxyl group.
Optionally, the bio-modified acrylic resin emulsion is selected from linear copolymer emulsions.
Optionally, the aqueous modified silicone resin emulsion contains at least one hydroxyl group.
Optionally, the nano silicon dioxide is spherical, and the particle diameter is 100-500 nm.
Optionally, the upper limit of the diameter of the nano silica particles is selected from 120nm, 150nm, 200nm, 250nm, 300nm, 350nm, 400nm, 450nm and 500 nm; the lower limit of the diameter of the nano silicon dioxide particles is selected from 100nm, 120nm, 150nm, 200nm, 250nm, 300nm, 350nm, 400nm and 450 nm.
Optionally, the glass fibers are selected from at least one of E-glass and C-glass.
Optionally, the modified polysiloxane is selected from a fluoro-modified siloxane.
Optionally, the hydrophobic active agent is selected from at least one of a metal oxide, a hydroxide, and a basic carbonate.
Optionally, the antimicrobial agent is selected from inorganic antimicrobial agents.
Optionally, the organic antibacterial agent is selected from at least one of zinc oxide, copper oxide, ammonium dihydrogen phosphate and lithium carbonate.
Optionally, the environment-friendly coating also comprises water; the environment-friendly coating comprises the following components in percentage by weight: 5-10 parts of biological modified acrylic resin emulsion, 10-15 parts of water modified organic silicon resin emulsion, 10-15 parts of nano silicon dioxide, 3-5 parts of modified polysiloxane, 10-15 parts of glass fiber, 5-10 parts of modified polysiloxane, 3-5 parts of hydrophobic active agent, 3-5 parts of antibacterial agent, 3-10 parts of emulsified silicone oil and the balance of water, wherein the total content of the components is 100%.
In one embodiment, the environment-friendly coating comprises the following components in percentage by weight: 10 parts of biological modified acrylic resin emulsion, 15 parts of water-modified organic silicon resin emulsion, 10 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 10 parts of glass fiber, 10 parts of modified polysiloxane, 5 parts of hydrophobic active agent, 5 parts of antibacterial agent, 10 parts of emulsified silicone oil and 20 parts of water.
Compared with the prior art, the invention has the advantages that:
the antibacterial composite heat-insulation environment-friendly coating provided by the application has a good antibacterial effect, adopts water as a solvent, solves the problem of environmental pollution caused by the use of an organic solvent, has the advantages of small weather resistance, stain resistance and surface friction resistance coefficient, scratch resistance, scrubbing resistance and long service life, and can not generate the problems of foaming, cracking, whitening and even delamination after long-term use.
Detailed Description
In view of the deficiencies in the prior art, the inventors of the present invention have made extensive studies and extensive practices to provide technical solutions of the present invention. The technical solution, its implementation and principles, etc. will be further explained as follows.
The invention provides an antibacterial composite heat-insulating environment-friendly coating which comprises a biological modified acrylic resin emulsion, a water-based modified organic silicon resin emulsion, nano silicon dioxide, modified polysiloxane, glass fiber, modified polysiloxane, a hydrophobic active agent, an antibacterial agent and emulsified silicone oil.
Optionally, the biological modified acrylic resin emulsion biological modifying group is selected from at least one of amino or hydroxyl.
Alternatively, the amino group is selected from at least one of an aliphatic amino group, an alicyclic amino group, and an aromatic amino group.
Alternatively, the hydroxyl group is selected from at least one of an aliphatic hydroxyl group, an alicyclic hydroxyl group, and an aromatic hydroxyl group.
Optionally, the bio-modified acrylic resin emulsion is selected from linear copolymer emulsions.
Optionally, the aqueous modified silicone resin emulsion contains at least one hydroxyl group.
Optionally, the nano silicon dioxide is spherical, and the particle diameter is 100-500 nm.
Optionally, the upper limit of the diameter of the nano silica particles is selected from 120nm, 150nm, 200nm, 250nm, 300nm, 350nm, 400nm, 450nm and 500 nm; the lower limit of the diameter of the nano silicon dioxide particles is selected from 100nm, 120nm, 150nm, 200nm, 250nm, 300nm, 350nm, 400nm and 450 nm.
Optionally, the glass fibers are selected from at least one of E-glass and C-glass.
Optionally, the modified polysiloxane is selected from a fluoro-modified siloxane.
Optionally, the hydrophobic active agent is selected from at least one of a metal oxide, a hydroxide, and a basic carbonate.
Optionally, the antimicrobial agent is selected from inorganic antimicrobial agents.
Optionally, the organic antibacterial agent is selected from at least one of zinc oxide, copper oxide, ammonium dihydrogen phosphate and lithium carbonate.
Optionally, the environment-friendly coating also comprises water; the environment-friendly coating comprises the following components in percentage by weight: 5-10 parts of biological modified acrylic resin emulsion, 10-15 parts of water modified organic silicon resin emulsion, 10-15 parts of nano silicon dioxide, 3-5 parts of modified polysiloxane, 10-15 parts of glass fiber, 5-10 parts of modified polysiloxane, 3-5 parts of hydrophobic active agent, 3-5 parts of antibacterial agent, 3-10 parts of emulsified silicone oil and the balance of water, wherein the total content of the components is 100%.
In one embodiment, the environment-friendly coating comprises the following components in percentage by weight: 10 parts of biological modified acrylic resin emulsion, 15 parts of water-modified organic silicon resin emulsion, 10 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 10 parts of glass fiber, 10 parts of modified polysiloxane, 5 parts of hydrophobic active agent, 5 parts of antibacterial agent, 10 parts of emulsified silicone oil and 20 parts of water.
The technical solution of the present invention is further explained below with reference to several examples.
Example 1
The preparation of the antibacterial composite heat-insulating environment-friendly coating comprises the following steps:
5 parts of biological modified acrylic resin emulsion, 15 parts of water-modified organic silicon resin emulsion, 15 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 15 parts of glass fiber, 10 parts of modified polysiloxane, 5 parts of hydrophobic active agent, 5 parts of antibacterial agent, 10 parts of emulsified silicone oil and the balance of components are water, wherein the total content of the components is 100%, and the prepared antibacterial composite heat-insulating environment-friendly coating is recorded as sample # 1.
Example 2
10 parts of biological modified acrylic resin emulsion, 15 parts of water-based modified organic silicon resin emulsion, 10 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 10 parts of glass fiber, 10 parts of modified polysiloxane, 5 parts of hydrophobic active agent, 5 parts of antibacterial agent, 10 parts of emulsified silicone oil and 20 parts of water, and the prepared antibacterial composite heat-insulating environment-friendly coating is recorded as sample # 2.
Example 3
8 parts of biological modified acrylic resin emulsion, 12 parts of water-modified organic silicon resin emulsion, 15 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 15 parts of glass fiber, 10 parts of modified polysiloxane, 5 parts of hydrophobic active agent, 5 parts of antibacterial agent, 5 parts of emulsified silicone oil and the balance of components are water, wherein the total content of the components is 100%, and the prepared antibacterial composite heat-insulating environment-friendly coating is recorded as sample # 3.
Example 4
8 parts of biological modified acrylic resin emulsion, 12 parts of water-modified organic silicon resin emulsion, 15 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 10 parts of glass fiber, 15 parts of modified polysiloxane, 3 parts of hydrophobic active agent, 3 parts of antibacterial agent, 5 parts of emulsified silicone oil and the balance of components are water, wherein the total content of the components is 100%, and the prepared antibacterial composite heat-insulating environment-friendly coating is recorded as sample # 4.
Example 5
8 parts of biological modified acrylic resin emulsion, 12 parts of water-modified organic silicon resin emulsion, 15 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 10 parts of glass fiber, 15 parts of modified polysiloxane, 3 parts of hydrophobic active agent, 4 parts of antibacterial agent, 4 parts of emulsified silicone oil and the balance of components are water, wherein the total content of the components is 100%, and the prepared antibacterial composite heat-insulating environment-friendly coating is recorded as sample # 5.
It should be understood that the above-mentioned embodiments are merely illustrative of the technical concepts and features of the present invention, which are intended to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and therefore, the protection scope of the present invention is not limited thereby. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.
Claims (10)
1. The antibacterial composite heat-insulating environment-friendly coating is characterized by comprising a biological modified acrylic resin emulsion, a water-based modified organic silicon resin emulsion, nano silicon dioxide, modified polysiloxane, glass fiber, modified polysiloxane, a hydrophobic active agent, an antibacterial agent and emulsified silicone oil.
2. The environment-friendly paint according to claim 1, wherein the biological modification group of the biological modified acrylic resin emulsion is selected from at least one of amino or hydroxyl,
preferably, the amino group is selected from at least one of an aliphatic amino group, an alicyclic amino group, and an aromatic amino group;
preferably, the hydroxyl group is selected from at least one of an aliphatic hydroxyl group, an alicyclic hydroxyl group and an aromatic hydroxyl group.
Preferably, the bio-modified acrylic resin emulsion is selected from linear copolymer emulsions.
3. The environment-friendly paint according to claim 1, wherein the aqueous modified silicone resin emulsion contains at least one hydroxyl group.
4. The environment-friendly coating as claimed in claim 1, wherein the nano silica is spherical and has a particle diameter of 100 to 500 nm.
5. The environmentally friendly coating of claim 1, wherein the glass fiber is selected from at least one of E-glass and C-glass.
6. The environmentally friendly coating of claim 1, wherein the modified polysiloxane is selected from a fluorine modified siloxane.
7. The environmentally friendly coating of claim 1, wherein the hydrophobic active agent is selected from at least one of a metal oxide, a hydroxide, and a basic carbonate.
8. The environmentally friendly coating of claim 1, wherein the antimicrobial agent is selected from the group consisting of inorganic antimicrobial agents;
preferably, the organic antibacterial agent is at least one selected from the group consisting of zinc oxide, copper oxide, ammonium dihydrogen phosphate, and lithium carbonate.
9. The environment-friendly paint according to claim 1, further comprising water; preferably, the environment-friendly coating comprises the following components in percentage by weight: 5-10 parts of biological modified acrylic resin emulsion, 10-15 parts of water modified organic silicon resin emulsion, 10-15 parts of nano silicon dioxide, 3-5 parts of modified polysiloxane, 10-15 parts of glass fiber, 5-10 parts of modified polysiloxane, 3-5 parts of hydrophobic active agent, 3-5 parts of antibacterial agent, 3-10 parts of emulsified silicone oil and the balance of water, wherein the total content of the components is 100%.
10. The environment-friendly coating as claimed in claim 1, wherein the environment-friendly coating comprises the following components in percentage by weight: 10 parts of biological modified acrylic resin emulsion, 15 parts of water-modified organic silicon resin emulsion, 10 parts of nano silicon dioxide, 5 parts of modified polysiloxane, 10 parts of glass fiber, 10 parts of modified polysiloxane, 5 parts of hydrophobic active agent, 5 parts of antibacterial agent, 10 parts of emulsified silicone oil and 20 parts of water.
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2020
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