CN111793418A - Powder coating for metal corrosion prevention and preparation method and application method thereof - Google Patents

Powder coating for metal corrosion prevention and preparation method and application method thereof Download PDF

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Publication number
CN111793418A
CN111793418A CN202010771599.4A CN202010771599A CN111793418A CN 111793418 A CN111793418 A CN 111793418A CN 202010771599 A CN202010771599 A CN 202010771599A CN 111793418 A CN111793418 A CN 111793418A
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powder coating
powder
corrosion prevention
resin
metal corrosion
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夏连心
方志望
朱满子
李时雨
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Hunan Lianxin Technology Co Ltd
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Hunan Lianxin Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B05D1/06Applying particulate materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00Epoxy polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2508/00Polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
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  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a powder coating for metal corrosion prevention, a preparation method and an application method thereof, wherein the powder coating comprises the following raw materials in parts by weight: 30-45 parts of unsaturated polyester resin, 25-35 parts of bisphenol A epoxy resin, 3-8 parts of graphene powder, 12-18 parts of curing agent, 3-6 parts of flatting agent and 0.5-0.9 part of benzoin. The powder coating is applied to a metal plate, a compact coating is formed after the powder coating is cured, the compactness is high, the anti-permeability is strong, the metal can be prevented from being corroded, and the service life of the metal is greatly prolonged; and the adhesive property is excellent and the impact resistance is good.

Description

Powder coating for metal corrosion prevention and preparation method and application method thereof
Technical Field
The invention relates to the technical field of powder coatings, in particular to a powder coating for metal corrosion resistance, and a preparation method and an application method thereof.
Background
Powder coatings represent a rapidly growing area in the overall coating technology. Because the VOC emission is almost zero, the rapid development of the VOC is driven by the environmental protection requirement. The requirements of global and Chinese environmental protection laws and regulations are more and more strict, and the development of the environmental protection powder coating industry is effectively promoted.
Metals which are exposed to air for a long time, in contact with oxygen and water vapor, are rapidly oxidized, i.e., rusted, and their strength and other properties are greatly reduced, for example, metallic iron. The existing powder coating is used for corrosion prevention of metal, but after the existing powder coating is sprayed, oxygen and water vapor in the air can still contact with the metal through micropores due to poor compactness of a coating layer, so that the metal is oxidized. Once the metal of the inner layer is oxidized, the coating of the outer layer is stripped, and a chain reaction is formed until the coating is completely stripped and the metal is completely oxidized.
Disclosure of Invention
In view of the above, the invention provides a powder coating for metal corrosion prevention, and a preparation method and an application method thereof.
A powder coating for metal corrosion prevention comprises the following raw materials in parts by weight:
Figure BDA0002616833520000011
Figure BDA0002616833520000021
preferably, the raw materials comprise the following components in parts by weight:
Figure BDA0002616833520000022
preferably, the unsaturated polyester resin is polymerized by styrene, acrylate and vinyl acetate.
Preferably, the bisphenol A epoxy resin has a molecular weight of 4000-6000.
Preferably, the particle size of the graphene powder is 400-600 meshes.
Preferably, the curing agent is a tertiary amine or imidazole curing agent.
Preferably, the leveling agent is one of polydimethylsiloxane, polyether polyester modified organic siloxane and alkyl modified organic siloxane.
A preparation method of a powder coating for metal corrosion prevention comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 100-200 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a flatting agent, benzoin and mixed resin into a high-speed mixer, and mixing at the temperature of 40-60 ℃ and the rotating speed of 500-800r/min for 10-20min to obtain a mixed material;
adding the mixed material into a double-screw extruder with the rotating speed of 200-;
and cooling the melt, and crushing to 250-mesh and 300-mesh to obtain the powder coating.
Preferably, the method is as follows:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 120-180 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a leveling agent, benzoin and mixed resin into a high-speed mixer, and mixing for 14-18min at the temperature of 44-52 ℃ and the rotating speed of 550-750r/min to obtain a mixed material;
adding the mixed material into a double-screw extruder with the rotating speed of 220-;
and cooling the melt, and crushing to 270-290 meshes to obtain the powder coating.
A method for applying powder coating for metal corrosion prevention comprises the following steps:
sieving the powder coating by a 200-300-mesh sieve;
spraying the powder coating on the surface-treated metal plate by an electrostatic spray gun, wherein the thickness of the coating film is 90-110 mu m, and fully curing at the temperature of 210 ℃/8-12min by 190-.
The invention provides a powder coating for metal corrosion prevention, a preparation method and an application method thereof, the powder coating is applied to a metal plate, a compact coating is formed after the powder coating is cured, the compactness is high, the anti-permeability is strong, the metal can be subjected to corrosion prevention, and the service life of the metal is greatly prolonged; and the adhesive property is excellent and the impact resistance is good.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It will be understood that the terms "comprises" and/or "comprising," when used in this specification and the appended claims, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
It should be further understood that the term "and/or" as used in this specification and the appended claims refers to and includes any and all possible combinations of one or more of the associated listed items.
A powder coating for metal corrosion prevention comprises the following raw materials in parts by weight:
Figure BDA0002616833520000041
the unsaturated polyester resin is polymerized by styrene, acrylic ester and vinyl acetate; the molecular weight of the bisphenol A epoxy resin is 4000-6000; the particle size of the graphene powder is 400-mesh and 600-mesh; the curing agent is tertiary amine or imidazole curing agent; the leveling agent is one of polydimethylsiloxane, polyether polyester modified organic siloxane and alkyl modified organic siloxane.
A preparation method of a powder coating for metal corrosion prevention comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 100-200 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a flatting agent, benzoin and mixed resin into a high-speed mixer, and mixing at the temperature of 40-60 ℃ and the rotating speed of 500-800r/min for 10-20min to obtain a mixed material;
adding the mixed material into a double-screw extruder with the rotating speed of 200-;
and cooling the melt, and crushing to 250-mesh and 300-mesh to obtain the powder coating.
A method for applying powder coating for metal corrosion prevention comprises the following steps:
sieving the powder coating by a 200-300-mesh sieve;
spraying the powder coating on the surface-treated metal plate by an electrostatic spray gun, wherein the thickness of the coating film is 90-110 mu m, and fully curing at the temperature of 210 ℃/8-12min by 190-.
Detailed description of the preferred embodiment 1
A powder coating for metal corrosion prevention comprises the following raw materials in parts by weight:
Figure BDA0002616833520000051
the unsaturated polyester resin is polymerized by styrene, acrylic ester and vinyl acetate; the molecular weight of the bisphenol A epoxy resin is 4000-; the particle size of the graphene powder is 600 meshes; the curing agent is a tertiary amine curing agent; the leveling agent is polydimethylsiloxane.
A preparation method of a powder coating for metal corrosion prevention comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 100 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a leveling agent, benzoin and mixed resin into a high-speed mixer, and mixing for 20min at the temperature of 40 ℃ and the rotating speed of 800r/min to obtain a mixed material;
adding the mixed materials into a double-screw extruder with the rotating speed of 200r/min, wherein the temperature of a cavity of the extruder is 100 ℃, the temperature of a discharge port is 125 ℃, and performing melt extrusion;
and cooling the melt, and crushing to 250 meshes to obtain the powder coating.
A method for applying powder coating for metal corrosion prevention comprises the following steps:
sieving the powder coating with a 200-mesh sieve;
and spraying the powder coating on the surface-treated metal plate by using an electrostatic spray gun, wherein the thickness of the coating film is 90 mu m, and fully curing at 190 ℃/12min to obtain the powder coating.
Specific example 2
A powder coating for metal corrosion prevention comprises the following raw materials in parts by weight:
Figure BDA0002616833520000061
the unsaturated polyester resin is polymerized by styrene, acrylic ester and vinyl acetate; the molecular weight of the bisphenol A epoxy resin is 5000-; the particle size of the graphene powder is 400 meshes; the curing agent is imidazole curing agent; the leveling agent is polyether polyester modified organic siloxane.
A preparation method of a powder coating for metal corrosion prevention comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 200 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a leveling agent, benzoin and mixed resin into a high-speed mixer, and mixing at the temperature of 60 ℃ and the rotating speed of 500r/min for 10min to obtain a mixed material;
adding the mixed materials into a double-screw extruder with the rotating speed of 300r/min, wherein the temperature of a cavity of the extruder is 120 ℃, the temperature of a discharge port is 115 ℃, and performing melt extrusion;
the melt was cooled and then pulverized to 300 mesh to obtain a powder coating.
A method for applying powder coating for metal corrosion prevention comprises the following steps:
sieving the powder coating with a 300-mesh sieve;
and spraying the powder coating on the surface-treated metal plate by using an electrostatic spray gun, wherein the thickness of a paint film is 110 mu m, and fully curing at the temperature of 210 ℃/8min to obtain the powder coating.
Specific example 3
A powder coating for metal corrosion prevention comprises the following raw materials in parts by weight:
Figure BDA0002616833520000071
the unsaturated polyester resin is polymerized by styrene, acrylic ester and vinyl acetate; the molecular weight of the bisphenol A epoxy resin is 4500-5500; the particle size of the graphene powder is 500 meshes; the curing agent is a tertiary amine curing agent; the leveling agent is alkyl modified organic siloxane.
A preparation method of a powder coating for metal corrosion prevention comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 120 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a leveling agent, benzoin and mixed resin into a high-speed mixer, and mixing for 14min at the temperature of 44 ℃ and the rotating speed of 750r/min to obtain a mixed material;
adding the mixed materials into a double-screw extruder with the rotating speed of 220r/min, wherein the temperature of a cavity of the extruder is 105 ℃, the temperature of a discharge hole is 118 ℃, and performing melt extrusion;
the melt was cooled and then pulverized to 290 mesh to obtain a powder coating.
A method for applying powder coating for metal corrosion prevention comprises the following steps:
sieving the powder coating with a 300-mesh sieve;
and spraying the powder coating on the surface-treated metal plate by using an electrostatic spray gun, wherein the thickness of the coating film is 90 mu m, and fully curing at 190 ℃/9min to obtain the powder coating.
Specific example 4
A powder coating for metal corrosion prevention comprises the following raw materials in parts by weight:
Figure BDA0002616833520000081
the unsaturated polyester resin is polymerized by styrene, acrylic ester and vinyl acetate; the molecular weight of the bisphenol A epoxy resin is 4000-; the particle size of the graphene powder is 550 meshes; the curing agent is imidazole curing agent; the leveling agent is polyether polyester modified organic siloxane.
A preparation method of a powder coating for metal corrosion prevention comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 120 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a leveling agent, benzoin and mixed resin into a high-speed mixer, and mixing for 18min at the temperature of 52 ℃ and the rotating speed of 550r/min to obtain a mixed material;
adding the mixed materials into a double-screw extruder with the rotating speed of 270r/min, wherein the temperature of a cavity of the extruder is 115 ℃, the temperature of a discharge port is 122 ℃, and performing melt extrusion;
the melt was cooled and then pulverized to 270 mesh to obtain a powder coating.
A method for applying powder coating for metal corrosion prevention comprises the following steps:
sieving the powder coating with a 280-mesh sieve;
and spraying the powder coating on the surface-treated metal plate by using an electrostatic spray gun, wherein the thickness of a paint film is 100 mu m, and fully curing at 195 ℃/10min to obtain the powder coating.
Specific example 5
A powder coating for metal corrosion prevention comprises the following raw materials in parts by weight:
Figure BDA0002616833520000091
the unsaturated polyester resin is polymerized by styrene, acrylic ester and vinyl acetate; the molecular weight of the bisphenol A epoxy resin is 4500-; the particle size of the graphene powder is 450 meshes; the curing agent is imidazole curing agent; the leveling agent is polyether polyester modified organic siloxane.
A preparation method of a powder coating for metal corrosion prevention comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 160 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a leveling agent, benzoin and mixed resin into a high-speed mixer, and mixing at the temperature of 48 ℃ and the rotating speed of 650r/min for 16min to obtain a mixed material;
adding the mixed materials into a double-screw extruder with the rotating speed of 250r/min, wherein the temperature of a cavity of the extruder is 110 ℃, the temperature of a discharge hole is 120 ℃, and performing melt extrusion;
the melt was cooled and then pulverized to 280 mesh to obtain a powder coating.
A method for applying powder coating for metal corrosion prevention comprises the following steps:
sieving the powder coating with a 250-mesh sieve;
and spraying the powder coating on the surface-treated metal plate by using an electrostatic spray gun, wherein the thickness of the coating film is 105 mu m, and fully curing at 200 ℃/11min to obtain the powder coating.
The powder coatings of the specific examples 1 to 5 were applied to metal sheets, and chloride permeability, adhesion, impact resistance and salt spray resistance were tested with a commercially available "new double material" metal anticorrosive powder coating (comparative example 1) according to the following test methods: chloride permeability (GB/T25826-2010), adhesion (ISO2409-2007), impact resistance (GB/T1732-93), salt spray resistance (GB/T17771-1991, 1000h), test results are as follows:
Figure BDA0002616833520000101
as can be seen from the above table: compared with the powder coating of the comparative example 1, the powder coatings of the specific examples 1 to 5 have the permeability of 0 in chloride permeability, mainly because the compactness of the coating is high and the permeability resistance is high, and compared with the existing comparative example 1, the powder coating has the advantages of high permeability, adhesion, impact resistance and salt spray resistance.
The steps in the method of the embodiment of the invention can be sequentially adjusted, combined and deleted according to actual needs.
The present invention has been described in detail, and the principle and embodiments of the present invention are explained by applying specific examples, which are only used to help understanding the method and the core idea of the present invention; meanwhile, for a person skilled in the art, according to the idea of the present invention, there may be variations in the specific embodiments and the application scope, and in summary, the content of the present specification should not be construed as a limitation to the present invention.
It is clear to those skilled in the art that, for convenience and brevity of description, the specific working processes of the above-described systems and units may refer to the corresponding processes in the foregoing method embodiments, and are not described herein again.

Claims (10)

1. The powder coating for metal corrosion prevention is characterized by comprising the following raw materials in parts by weight:
Figure FDA0002616833510000011
2. the powder coating of claim 1, wherein the raw materials comprise, by weight:
Figure FDA0002616833510000012
3. a powder coating according to any one of claims 1-2, wherein the unsaturated polyester resin is polymerized from styrene, acrylates and vinyl acetate.
4. The powder coating of any one of claims 1-2, wherein the bisphenol a epoxy resin has a molecular weight of 4000-.
5. The powder coating as claimed in any one of claims 1-2, wherein the particle size of the graphene powder is 400-600 mesh.
6. The powder coating according to any one of claims 1-2, wherein the curing agent is a tertiary amine or imidazole curing agent.
7. The powder coating according to any one of claims 1-2, wherein the leveling agent is one of polydimethylsiloxane, polyether polyester modified organosiloxane, and alkyl modified organosiloxane.
8. A preparation method of powder coating for metal corrosion prevention is characterized by comprising the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 100-200 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a flatting agent, benzoin and mixed resin into a high-speed mixer, and mixing at the temperature of 40-60 ℃ and the rotating speed of 500-800r/min for 10-20min to obtain a mixed material;
adding the mixed material into a double-screw extruder with the rotating speed of 200-;
and cooling the melt, and crushing to 250-mesh and 300-mesh to obtain the powder coating.
9. The method for preparing the compound of claim 8, wherein the method comprises the following steps:
crushing unsaturated polyester resin and bisphenol A epoxy resin to 120-180 meshes to obtain mixed resin;
adding graphene powder, a curing agent, a leveling agent, benzoin and mixed resin into a high-speed mixer, and mixing for 14-18min at the temperature of 44-52 ℃ and the rotating speed of 550-750r/min to obtain a mixed material;
adding the mixed material into a double-screw extruder with the rotating speed of 220-;
and cooling the melt, and crushing to 270-290 meshes to obtain the powder coating.
10. An application method of a powder coating for metal corrosion prevention is characterized by comprising the following steps:
sieving the powder coating by a 200-300-mesh sieve;
spraying the powder coating on the surface-treated metal plate by an electrostatic spray gun, wherein the thickness of the coating film is 90-110 mu m, and fully curing at the temperature of 210 ℃/8-12min by 190-.
CN202010771599.4A 2020-08-04 2020-08-04 Powder coating for metal corrosion prevention and preparation method and application method thereof Withdrawn CN111793418A (en)

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CN113861806A (en) * 2021-11-05 2021-12-31 浙江双金粉末涂料有限公司 Low-temperature curing epoxy anticorrosive powder coating and preparation method thereof
CN114231067A (en) * 2021-12-28 2022-03-25 厦门国丽静电粉末有限公司 Powder coating with good insulating property and preparation method thereof

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CN113861806A (en) * 2021-11-05 2021-12-31 浙江双金粉末涂料有限公司 Low-temperature curing epoxy anticorrosive powder coating and preparation method thereof
CN114231067A (en) * 2021-12-28 2022-03-25 厦门国丽静电粉末有限公司 Powder coating with good insulating property and preparation method thereof

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Application publication date: 20201020