CN111791416A - Preparation method of carbon fiber composite material - Google Patents

Preparation method of carbon fiber composite material Download PDF

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Publication number
CN111791416A
CN111791416A CN202010343373.4A CN202010343373A CN111791416A CN 111791416 A CN111791416 A CN 111791416A CN 202010343373 A CN202010343373 A CN 202010343373A CN 111791416 A CN111791416 A CN 111791416A
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CN
China
Prior art keywords
epoxy
mold
carbon fiber
glue resin
temperature
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Pending
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CN202010343373.4A
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Chinese (zh)
Inventor
麦德坤
曾昭叶
陈艺少
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Dongguan Westward New Material Technology Co ltd
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Dongguan Westward New Material Technology Co ltd
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Priority to CN202010343373.4A priority Critical patent/CN111791416A/en
Publication of CN111791416A publication Critical patent/CN111791416A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/56Compression moulding under special conditions, e.g. vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/56Compression moulding under special conditions, e.g. vacuum
    • B29C2043/561Compression moulding under special conditions, e.g. vacuum under vacuum conditions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

The carbon fiber, the epoxy A glue resin and the epoxy B glue resin are mixed and stirred into a first mixture, then the first mixture is poured into a mold, and the mold is vacuumized; heating the mould to a first temperature, pressurizing and loading the mould to a first pressure, keeping the first temperature and the first pressure for a first time, cooling the mould to a second temperature, keeping the mould at the second temperature and the first pressure for a second time, and taking the cured and molded carbon fiber material out of the mould after cooling; the composite material with the carbon fibers as the matrix and the epoxy resin as the reinforcement can improve the aging resistance, abrasion resistance and impact strength of the carbon fiber composite material, reduce the quality of the carbon fiber composite material, and ensure that the mobile phone shell and the watch shell prepared from the carbon fiber composite material have higher performance and better appearance.

Description

Preparation method of carbon fiber composite material
Technical Field
The application relates to the technical field of carbon fiber material preparation, in particular to a preparation method of a carbon fiber composite material.
Background
With the improvement of the appearance and weight of the mobile phone and the watch, the improvement of the aging resistance, abrasion resistance, impact resistance and modulus of the middle frame of the mobile phone and the shell of the watch is required, and the reduction of the weight of the mobile phone and the watch is also required, which puts higher requirements on the performance of the used materials of the middle frame of the mobile phone and the shell of the watch.
At present, the materials of the middle frame and the watch shell of the mobile phone which are mainly used are metal or plastic, the abrasion resistance and the impact strength of the metal and the plastic are not enough to ensure that the mobile phone is kept in good condition when falling, the ageing resistance of the plastic is poor, and the appearance of the mobile phone or the watch is greatly influenced when the plastic is aged after being used for a period of time.
Disclosure of Invention
In view of the above problems, the present application proposes a method for preparing a carbon fiber composite material to improve the problems of poor aging resistance and abrasion resistance of the above metals and plastics.
In a first aspect, the present application provides a method of making a carbon fiber composite material, the method comprising:
respectively weighing 50-75% of carbon fiber, 30-60% of epoxy A glue resin and 5-10% of epoxy B glue resin in percentage by mass of the total material;
stirring and mixing the weighed carbon fibers, the epoxy A glue resin and the epoxy B glue resin to obtain a first mixture;
heating the mold to a first temperature for preheating;
pouring the first mixture into the mold, and vacuumizing the mold;
maintaining the mold at the first temperature while applying a pressure load to the mold to a first pressure, the first temperature and the first pressure being maintained for a first time;
and cooling the mold to a second temperature, and keeping the mold at the second temperature for a second time to obtain the carbon fiber composite material.
More preferably, the die is pressure loaded and 3% -8% by weight of the first mixture is extruded from the die.
Preferably, the carbon fiber, the epoxy A glue resin and the epoxy B glue resin are poured into a container, and the carbon fiber, the epoxy A glue resin and the epoxy B glue resin are stirred and mixed to obtain a first mixture.
More preferably, the heating the mold to the first temperature for preheating comprises: and uniformly coating the release agent on the surface of the mold, preheating the mold for the first time, and drying and solidifying the release agent on the surface of the mold.
More preferably, the pouring of the first mixture into a mold, the evacuating of the mold comprising: the mold is placed in a vacuum vessel, and the vacuum vessel is evacuated for at least 3 minutes.
More preferably, the first temperature follows the function W1: w1> -300 ℃; this second temperature follows the function W2: w2> -130 ℃.
More preferably, the first time obeys the function T1: t1> -15 min; this second time obeys the function T2: t2> 30 min.
More preferably, the first pressure obeys a function P of 40MPa < P <70 MPa.
Preferably, the step of respectively weighing the carbon fiber, the epoxy A glue resin and the epoxy B glue resin which account for 50-75 percent, 30-60 percent and 5-10 percent of the total mass of the material comprises the step of respectively weighing the carbon fiber, the epoxy A glue resin, the epoxy B glue resin and the metal powder which account for 50-75 percent, 20-40 percent, 5-10 percent and 5-10 percent of the total mass of the material.
Preferably, the step of weighing the carbon fiber accounting for 50-75% of the total mass of the material, the epoxy A glue resin accounting for 30-60% of the total mass of the material and the epoxy B glue resin accounting for 5-10% of the total mass of the material comprises the following steps: respectively weighing 50-75% of carbon fiber, 20-40% of epoxy A glue resin, 5-10% of epoxy B glue resin and 5-10% of color paste.
The carbon fiber, the epoxy A glue resin and the epoxy B glue resin are mixed and stirred into a first mixture, then the first mixture is poured into a mold, and the mold is vacuumized; heating the mould to a first temperature, pressurizing and loading the mould to a first pressure, keeping the first temperature and the first pressure for a first time, cooling the mould to a second temperature, keeping the mould at the second temperature and the first pressure for a second time, and taking the cured and molded carbon fiber material out of the mould after cooling; the composite material with the carbon fibers as the matrix and the epoxy resin as the reinforcement can improve the aging resistance, abrasion resistance and impact strength of the carbon fiber composite material, reduce the quality of the carbon fiber composite material, and ensure that the mobile phone shell and the watch shell prepared from the carbon fiber composite material have higher performance and better appearance.
Drawings
Fig. 1 is a flow chart of a method for preparing a carbon fiber composite material according to an embodiment of the present disclosure;
fig. 2 is a flowchart of a method for preparing a carbon fiber composite material according to an embodiment of the present disclosure.
Detailed Description
The technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
Fig. 1 is a flow chart of a method for preparing a carbon fiber composite material provided in an embodiment of the present application, and referring to fig. 1, the method includes:
101. respectively weighing 50-75% of carbon fiber, 20-40% of epoxy A glue resin and 5-10% of epoxy B glue resin in percentage by mass of the total material.
102. And stirring and mixing the weighed carbon fiber, the epoxy A glue resin and the epoxy B glue resin to obtain a first mixture.
103. Heating the mold to a first temperature for preheating.
104. The first mixture is poured into the mold and the mold is evacuated.
105. The mold is maintained at the first temperature while the mold is pressurized to a first pressure, the first temperature and the first pressure being maintained for a first time.
106. And cooling the mold to a second temperature, and maintaining the mold at the second temperature and the first pressure for a second time to obtain the carbon fiber composite material.
More preferably, the die is pressure loaded and 3% -8% by weight of the first mixture is extruded from the die.
Preferably, the carbon fiber, the epoxy A glue resin and the epoxy B glue resin are poured into a container, and the carbon fiber, the epoxy A glue resin and the epoxy B glue resin are stirred and mixed to obtain a first mixture.
More preferably, the heating the mold to the first temperature for preheating comprises: and uniformly coating the release agent on the surface of the mold, preheating the mold for the first time, and drying and solidifying the release agent on the surface of the mold.
More preferably, the pouring of the first mixture into a mold, the evacuating of the mold comprising: the mold is placed in a vacuum vessel, and the vacuum vessel is evacuated for at least 3 minutes.
More preferably, the first temperature follows the function W1: w1> -300 ℃; this second temperature follows the function W2: w2> -130 ℃.
More preferably, the first time obeys the function T1: t1> -15 min; this second time obeys the function T2: t2> 30 min.
More preferably, the first pressure obeys a function P of 40MPa < P <70 MPa.
Preferably, the step of respectively weighing the carbon fiber, the epoxy A glue resin and the epoxy B glue resin which account for 50-75 percent, 20-40 percent and 5-10 percent of the total mass of the material comprises the step of respectively weighing the carbon fiber, the epoxy A glue resin, the epoxy B glue resin and the metal powder which account for 50-75 percent, 20-40 percent, 5-10 percent and 5-10 percent of the total mass of the material.
Preferably, the step of weighing the carbon fiber accounting for 50-75% of the total mass of the material, the epoxy A glue resin accounting for 20-40% of the total mass of the material and the epoxy B glue resin accounting for 5-10% of the total mass of the material comprises the following steps: respectively weighing 50-75% of carbon fiber, 20-40% of epoxy A glue resin, 5-10% of epoxy B glue resin and 5-10% of color paste.
Fig. 2 is a flowchart of a method for preparing a carbon fiber composite material provided in an embodiment of the present application, and referring to fig. 2, the method includes:
201. respectively weighing 50-75% of carbon fiber, 20-40% of epoxy A glue resin and 5-10% of epoxy B glue resin in percentage by mass of the total material.
And respectively multiplying the mass percentages of the carbon fiber, the epoxy A glue resin and the epoxy B glue resin by the total mass number of the material to obtain the mass numbers of the carbon fiber, the epoxy A glue resin and the epoxy B glue resin, and weighing the carbon fiber, the epoxy A glue resin and the epoxy B glue resin with the corresponding mass numbers. The sum of the mass percentages of the components is 100 percent by adjusting the mixture ratio; for example, 60% by mass of carbon fiber, 30% by mass of epoxy A glue resin and 10% by mass of epoxy B glue resin are weighed; weighing 50% of carbon fiber, 35% of epoxy A glue resin and 15% of epoxy B glue resin by mass; because the carbon fiber has light weight, high strength and good aging resistance, the composite material using the carbon fiber as the matrix also has the advantages of light weight, high strength and good aging resistance.
Preferably, the carbon fiber accounting for 50-75% of the total mass of the material, the epoxy A glue resin accounting for 20-40%, the epoxy B glue resin accounting for 5-10% and the metal powder accounting for 5-10% of the total mass of the material are respectively weighed. The metal powder is added into the ingredients, so that the number and the type of the textures of the carbon fiber composite material for reflecting light can be increased, and the appearance attractiveness of the carbon fiber composite material is improved.
Preferably, the carbon fiber accounting for 50 to 75 percent of the total mass of the material, the epoxy A glue resin accounting for 20 to 40 percent of the total mass of the material, the epoxy B glue resin accounting for 5 to 10 percent of the total mass of the material and the color paste accounting for 5 to 10 percent of the total mass of the material are respectively weighed. The addition of the color paste changes the appearance color of the carbon fiber composite material, and the color of the color paste has various choices, such as red, yellow, blue, green and purple, or mixed colors formed by matching various colors. The color paste is mixed into the first mixture, so that the color of the first mixture is changed, and the appearance attractiveness of the carbon fiber composite material is improved.
202. And pouring the carbon fibers, the epoxy A glue resin and the epoxy B glue resin into a container, and stirring and mixing the carbon fibers, the epoxy A glue resin and the epoxy B glue resin to obtain a first mixture.
The method comprises the steps of pouring weighed carbon fibers, epoxy A glue resin and epoxy B glue resin into a container for mixing and stirring, uniformly mixing the carbon fibers, the epoxy A glue resin and the epoxy B glue resin into a first mixture, for example, stirring the carbon fibers, the epoxy A glue resin and the epoxy B glue resin poured into a glass container by using a stirrer at the rotation speed of 300 revolutions per minute for 3 minutes in a clockwise manner, and then stirring for 3 minutes in a counter-clockwise manner to obtain the uniformly mixed first mixture.
203. Heating the mold to a first temperature for preheating, uniformly coating the mold release agent on the surface of the mold, and keeping the preheating of the mold for a first time until the mold release agent is dried and fixed on the surface of the mold.
Heating the surface of the mold to a first temperature, and uniformly coating a release agent on the surface of the mold, or putting the mold into the release agent for soaking; keeping the mold at a first temperature for a first time, so that the release agent coated on the surface of the mold is dried and solidified on the surface of the mold, and the mold is wrapped by the dried and solidified release agent; the release agent can prevent the material from being stuck in the mould and protect the formed composite material from being completely taken out of the mould. For example, when the mold is used for the first time, the mold is subjected to a release agent coating and dry curing treatment; or the release agent is stripped from the surface of the mold due to long service time, the mold with the surface not covered by the release agent is not covered, and the coating and the drying treatment of the release agent are carried out again.
204. Pouring the first mixture into the mold, placing the mold into a vacuum vessel, and evacuating the vacuum vessel for at least 3 minutes.
Wherein the mold is placed in a closed container, the closed container is vacuumized, a vacuum negative pressure is formed in the closed container, the vacuum negative pressure in the closed container is at least 40Kpa, the mold is placed in the closed container with the vacuum negative pressure for at least 3 minutes, for example, the mold is placed in the vacuum container, the vacuum container is vacuumized, the vacuum negative pressure in the closed container can be 40Kpa, 50Kpa, 60Kpa and 70Kpa, and the duration of the vacuum negative pressure can be 3 minutes, 4 minutes, 8 minutes and 20 minutes.
When the mould is in a vacuum negative pressure state in the closed container, bubbles in the first mixture are discharged into the closed container from the interior of the first mixture when the mould is in the vacuum negative pressure state due to the fact that a steam pocket in the mould is kept in an atmospheric pressure state; as the bubbles in the first mixture are discharged, the density of the first mixture is improved, and the carbon fiber composite material after being cured and molded does not contain bubbles, so that the impact strength of the carbon fiber composite material is improved.
205. The mold is maintained at the first temperature while the mold is pressurized to a first pressure, the first temperature and the first pressure being maintained for a first time.
The epoxy resin B in the first mixture can be subjected to a crosslinking curing reaction with the epoxy resin A at a first temperature, and microscopically, the carbon fibers can be fixed by the crosslinking curing of the two epoxy resins, so that the carbon fibers are prevented from deforming due to impact, the original shape is maintained, the crosslinking curing speed of the epoxy resins is higher at the first temperature, and the crosslinking degree is higher; by applying the first pressure to the mold, the density of the first mixture in the mold is increased, so that the carbon fiber composite material after crosslinking and curing has higher density, the crosslinking of carbon fibers and epoxy resin in the carbon fiber composite material is tighter, and the impact strength of the material is improved; the impact strength and the wear resistance of the carbon fiber composite material are improved by improving the density of the carbon fiber composite material.
More preferably, the first temperature follows the function W1: w1> -300 ℃, the first time obeying the function T1: t1> -15 min. For example, the first temperature may be set at: 300 ℃, 310 ℃, 320 ℃, 330 ℃ and 340 ℃; the first time may be set as: 15min, 20min, 25min, 30min and 35 min.
206. The die is pressurized to a first pressure and a first mixture, 3% -8% by mass of the first mixture, is extruded from the die.
When the first mixture is poured into the mold, the first mixture is poured in an amount larger than the capacity of the mold. After the mold is pressurized and loaded, the upper side and the lower side of the mold are completely closed, 3% -8% of the first mixture in the mold can be extruded from the discharge port of the mold, after the redundant first mixture is extruded from the mold, the inner cavity of the mold is filled with the first mixture, and the formed carbon fiber composite material can have a complete shape.
207. And cooling the mold to a second temperature, and maintaining the mold at the second temperature and the first pressure for a second time to obtain the carbon fiber composite material.
After the epoxy resin in the first mixture reacts at a high temperature, the crosslinking reaction speed is reduced, in order to improve the crosslinking degree of the epoxy resin, the temperature can be reduced and the reaction time can be prolonged, the crosslinking degree of the crosslinking reaction is not enough, and the crosslinking curing reaction needs to be continued; and continuously reacting for a second time at a second temperature, wherein the set second time is longer than the first time, and the second time is set to be long enough, so that the carbon fiber composite material with higher crosslinking degree can be obtained.
More preferably, the second temperature follows the function W2: w2> -130 ℃; this second time obeys the function T2: t2> 30 min. For example, the second temperature may be set to: 130 ℃, 135 ℃, 140 ℃ and 150 ℃; the second time may be set as: 30min, 35min, 40min, 50min, 60 min.
208. And cooling the mold to 25 ℃, simultaneously removing the pressurizing load, taking the cured and molded carbon fiber composite material out of the mold, and then carrying out appearance processing on the carbon fiber composite material.
Wherein the mold is cooled to 25 ℃, for example, the heating function in the closed container is turned off, the mold is naturally cooled to 25 ℃, or the mold is placed in a cooling plate, and the cooling of the mold is accelerated. And cooling the carbon fiber composite material in the mold to 25 ℃ along with the mold, removing the pressurizing load of the mold, opening the mold, and taking out the carbon fiber composite material in the mold. The carbon fiber composite material is also rough in shape or has defects, and the carbon fiber composite material needs to be processed into the required shape.
In summary, the carbon fiber, the epoxy A glue resin and the epoxy B glue resin are mixed into the first mixture, the first mixture is poured into the mold and then vacuumized, so that bubbles in the first mixture are discharged, and the density of the first mixture is improved; heating the mold to a first temperature and applying a first pressure, and maintaining the first temperature and the first pressure for a first time to enable the epoxy resin to be crosslinked and cured; cooling the mold to a second temperature, and maintaining the second temperature and the first pressure for a second time, wherein the second time is longer than the first time, and the sufficient second time can enable the epoxy resin to generate higher crosslinking degree, so that the impact strength of the carbon fiber composite material is improved; and cooling the mold, taking the carbon fiber composite material out of the mold, and carrying out appearance processing on the carbon fiber composite material to obtain the mobile phone middle frame or the watch shell prepared from the carbon fiber material.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solutions of the present application, and not to limit the same; although the present application has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; such modifications and substitutions do not necessarily depart from the spirit and scope of the corresponding technical solutions in the embodiments of the present application.

Claims (10)

1. A method of making a carbon fiber composite, the method comprising:
respectively weighing 50-75% of carbon fiber, 20-40% of epoxy A glue resin and 5-10% of epoxy B glue resin in percentage by mass of the total material;
stirring and mixing the weighed carbon fibers, the epoxy A glue resin and the epoxy B glue resin to obtain a first mixture;
heating the mold to a first temperature for preheating;
pouring the first mixture into the mold, and vacuumizing the mold;
maintaining the mold at the first temperature while applying a pressure load to the mold to a first pressure, the first temperature and the first pressure being maintained for a first time;
and cooling the mold to a second temperature, and keeping the mold at the second temperature and the first pressure for a second time to obtain the carbon fiber composite material.
2. The method of claim 1, wherein the die is pressurized and wherein 3% to 8% by weight of the first mixture is extruded from the die.
3. The method of claim 1, wherein the carbon fibers, epoxy a glue resin and epoxy B glue resin are poured into a container and the carbon fibers, epoxy a glue resin and epoxy B glue resin are mixed with stirring to obtain a first mixture.
4. The method of claim 1, wherein the heating the mold to a first temperature for preheating comprises: and uniformly coating the release agent on the surface of the mold, preheating the mold for the first time, and drying and solidifying the release agent on the surface of the mold.
5. The method of claim 1, wherein the pouring the first mixture into a mold, and evacuating the mold comprises: and putting the mold into a vacuum container, vacuumizing the vacuum container, and continuing vacuumizing for at least 3 minutes.
6. The method of claim 1, wherein the first temperature follows a function W1: w1> -300 ℃; the second temperature obeys the function W2: w2> -130 ℃.
7. The method of claim 1, wherein the first time obeys a function T1: t1> -15 min; said second time obeys the function T2: t2> 30 min.
8. The method of claim 1, wherein the first pressure obeys a function P:40Mpa < P <70 Mpa.
9. The method of claim 1, wherein weighing the carbon fiber, the epoxy A glue resin and the epoxy B glue resin respectively in an amount of 50-75% by weight, 20-40% by weight and 5-10% by weight of the total material comprises weighing the carbon fiber, the epoxy A glue resin, the epoxy B glue resin and the metal powder respectively in an amount of 50-75% by weight, 20-40% by weight, 5-10% by weight and 5-10% by weight of the total material.
10. The method as claimed in claim 1, wherein the step of weighing the carbon fiber, the epoxy A glue resin and the epoxy B glue resin respectively in an amount of 50-75% by weight, 20-40% by weight and 5-10% by weight based on the total weight of the material comprises the steps of: respectively weighing 50-75% of carbon fiber, 20-40% of epoxy A glue resin, 5-10% of epoxy B glue resin and 5-10% of color paste.
CN202010343373.4A 2020-04-27 2020-04-27 Preparation method of carbon fiber composite material Pending CN111791416A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153833A (en) * 2010-09-20 2011-08-17 青岛科技大学 Carbon fiber (powder)/epoxy resin composite material used for rapid prototyping die
CN106247003A (en) * 2016-07-26 2016-12-21 安徽理工大学 A kind of spool and valve pocket friction pair assembly and preparation method thereof
US20190351624A1 (en) * 2018-05-16 2019-11-21 GM Global Technology Operations LLC Systems and processes for repairing fiber-reinforced polymer structures
CN110815619A (en) * 2019-10-09 2020-02-21 安徽众博新材料有限公司 Method for producing epoxy resin-based composite material by using ultrasonic mixing
CN110903607A (en) * 2019-12-10 2020-03-24 西安电子科技大学 Preparation method of electromagnetic shielding composite material based on silver-plated carbon fiber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153833A (en) * 2010-09-20 2011-08-17 青岛科技大学 Carbon fiber (powder)/epoxy resin composite material used for rapid prototyping die
CN106247003A (en) * 2016-07-26 2016-12-21 安徽理工大学 A kind of spool and valve pocket friction pair assembly and preparation method thereof
US20190351624A1 (en) * 2018-05-16 2019-11-21 GM Global Technology Operations LLC Systems and processes for repairing fiber-reinforced polymer structures
CN110815619A (en) * 2019-10-09 2020-02-21 安徽众博新材料有限公司 Method for producing epoxy resin-based composite material by using ultrasonic mixing
CN110903607A (en) * 2019-12-10 2020-03-24 西安电子科技大学 Preparation method of electromagnetic shielding composite material based on silver-plated carbon fiber

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