CN111778112B - Antifouling and dustproof quick-drying cleaning agent composition - Google Patents
Antifouling and dustproof quick-drying cleaning agent composition Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
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- C08G77/38—Polysiloxanes modified by chemical after-treatment
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- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/02—Anionic compounds
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- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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Abstract
The invention relates to an antifouling and dustproof quick-drying cleaning agent composition which comprises the following components in parts by weight: AEO 91-3 parts; 1-4 parts of APG; 5-15 parts of modified polysiloxane; 2.5-6 parts of an anionic surfactant; 1.5-3 parts of 2-tridecyloxyethanol, wherein the modified polysiloxane is a product prepared by condensation reaction of hydrogen-containing silicone oil and poly-polyol monomethyl ether. The composition is a low-toxicity, green and environment-friendly composition, and does not contain any insoluble solid particulate matter; can quickly form a film on the hard surface of kitchenware facilities, and has the effects of excellent quick-drying effect, decontamination effect, lasting anti-fouling performance and the like.
Description
Technical Field
The invention belongs to the field of cleaning agents, and particularly relates to an antifouling and dustproof quick-drying cleaning agent composition.
Background
Chinese food culture is mainly used for frying dishes, and the frying dishes are supplemented with seasoning means such as heavy oil, heavy salt and the like, and are particularly represented by provinces such as Hunan, Sichuan and the like. The long-term application of heavy oil and heavy salt and other cooking modes can cause heavy oil stains to be attached to hard surfaces of kitchen appliances, such as smoke exhaust ventilators, cooking benches and other facilities, and outer walls, wall surfaces, glass and the like of related household appliances in a kitchen. Although the cleaning can be carried out by using a detergent and the like, the removal of the greasy dirt on the hard surface of the facility is only temporary, the cleaned facility does not have the capability of continuously preventing the greasy dirt, or the persistence of the greasy dirt prevention is poor, so that the greasy dirt can be easily attached to the hard surface again, and the cleaning times and the workload are increased; especially in the season of low temperature, the attached oil stains can be solidified in a short time if not cleaned in time, thereby bringing difficulty to thorough cleaning.
CN107245255A, CN107383949A, CN107236454A and other patents disclose preparation methods of hard surface hydrophobing agents, the main mechanism of which is to form a layer of hydrophobic film on the hard surface, which can effectively prevent the accumulation of oil stains, and the main component of the agent is organic polysilane. However, the above technical solutions do not combine the cleaning and grease proofing properties into one. CN105368171A, CN108300597A and other patents disclose an antifouling detergent, which mentions that the composition has the beneficial effect of preventing the reattachment of oil stains after cleaning, thereby providing antifouling persistence on hard surfaces, however, the main functional substance in the composition is polytetrafluoroethylene micropowder with particle size of micron grade, such as 20 μm. Moreover, the polytetrafluoroethylene particles are relatively high in manufacturing cost, are insoluble in water, are inert solid particles, introduce new impurities to kitchen-related facilities, and are inconvenient to clean subsequently; and the adhesion of polytetrafluoroethylene on a hard surface is poor, so that the oil stain resistance continuity is low.
Therefore, there is a need to find a more suitable composition which has excellent water solubility, and which has excellent effects of quick-drying and durability of stain-proofing on hard surfaces of kitchenware and the like.
Disclosure of Invention
The invention discloses an antifouling and dustproof quick-drying cleaning agent composition which can form a film on a hard surface, has an oil-repellent and antifouling effect, does not leave dot/strip dirt after cleaning, does not generate liquid drops during washing, has an excellent quick-drying effect, and is shiny twice after cleaning. The cleaning efficiency and the secondary pollution resistance are improved, and meanwhile, the cleaning and maintenance period and the service life are prolonged. Has obvious environmental protection effects of saving cost, saving water, reducing the use of chemical substances and discharging sewage. In addition, all the components are water-soluble, can be effectively dissolved in water, and can not leave any solid particles on the hard surface, so that the cleaning is more convenient and labor-saving.
The invention is realized by the following technical means:
an antifouling and dustproof quick-drying cleaning agent composition comprises the following components in parts by weight:
wherein, the modified polysiloxane is a product prepared by condensation reaction of hydrogen-containing silicone oil and polyatomic alcohol monomethyl ether.
Further, the hydrogen content of the hydrogen-containing silicone oil is selected from 0.18 wt%, 0.36 wt% or 0.75 wt%.
Further, the poly-polyol monomethyl ether is selected from one or two of poly-ethylene glycol monomethyl ether or polypropylene glycol monomethyl ether.
Furthermore, the ethoxy number of the polyethylene glycol monomethyl ether is 5-15, and the propoxy number of the polypropylene glycol monomethyl ether is 3-10.
Further, the anionic surfactant is selected from one or more of DOWFAX 2A1, LAS, AES and MES.
Further, the preparation method of the modified polysiloxane comprises the following steps:
dissolving hydrogen-containing silicone oil and polyatomic alcohol monomethyl ether in an organic solvent, and carrying out reflux reaction for 8-15h under the protection of nitrogen in a zinc acetate catalytic system; the solvent was removed by distillation under the reduced pressure, and the product was purified by column chromatography.
Further, the molar ratio of the hydrogen-containing silicone oil to the poly-polyol monomethyl ether is 1:1-1: 3.
Further, the organic solvent is selected from toluene, tetrahydrofuran, DMF, chlorobenzene or dichlorobenzene.
Furthermore, the adding amount of the zinc acetate is 0.1 to 0.3 weight percent of the hydrogen-containing silicone oil.
Further, the antifouling and dustproof quick-drying cleaning agent composition also comprises triethanolamine, alcohols and water.
The invention has the following beneficial effects:
1. the addition of the modified polysiloxane polymer enables the modified polysiloxane polymer and the surfactant in the composition to have a good synergistic effect, particularly with the nonionic surfactants AEO9 and APG in the composition, which is characterized in that: the EO/PO chain segment in the modified polysiloxane has good compatibility with the EO chain segment of AEO9 and the alkyl of APG, therefore, the chain segments are extremely easy to be entangled together, so that the modified polysiloxane polymer is easier to disperse in the composition along with the nonionic surfactant, the phenomenon that the polymer is not uniformly dispersed in the composition due to polymer agglomeration is avoided, so that during the cleaning of hard surfaces in kitchen appliances with the composition of the invention and subsequent drying, so that the hydrophilic film formed by the composition on the hard surface of the kitchen facility is uniform and compact, the hydrophilic film is effectively prevented from being difficult to form, or uneven after formation, thereby reducing the residue of surfactant, dirt and other viscous substances on the fiber surface, having excellent quick-drying effect, decontamination effect and secondary pollution resistance, and simultaneously prolonging the cleaning and maintenance period and the service life.
In particular, it has been unexpectedly found that when the modified polysiloxane contains both EO and PO segment structures in its molecular structure, and the EO or PO branches grafted on the modified polysiloxane have a length within a certain range (e.g., EO number is 5-15, PO number is 3-10), the oil repellency of the composition is better maintained, probably because the branch lengths of the modified polysiloxane and those of AEO9 and APG are more closely matched, thereby facilitating the entanglement of the branches.
2. The specific surfactants in the invention have excellent synergistic effect, so that the efficacy of each material is exerted to the maximum, the decontamination capability of the final product is excellent, and the decontamination effect is very ideal.
3. All the components in the composition are common, green and environment-friendly, and low-toxicity components, so that no obvious side effect is generated on a human body after long-term use or trace intake; and does not contain any insoluble solid particulate matter, and does not need to be cleaned for the second time after use.
Drawings
FIG. 1 is a graph comparing the effect of the quick drying test for example 3 (top) and comparative example 1 (bottom);
FIG. 2 is a graph comparing the effectiveness of the soil release tests of example 3 (top) and comparative example 1 (bottom);
fig. 3 is a graph comparing the effects of the dust control test of example 3 (top) and comparative example 1 (bottom).
Detailed Description
The present invention is further illustrated by the following specific examples, which are not intended to limit the invention in any way. The starting materials described in the examples of the present invention are commercially available and, unless otherwise specified, the starting materials and methods employed are those conventional in the art.
Wherein, the HLB value of AEO9 used in the invention is 13-14, the pH value of the nonionic surfactant AEO-9 is 5-7, and the surfactant is purchased from the Dow chemistry;
the HLB value of the APG is 12-14, and the APG is purchased from Shanghai daily chemical and is of APG1214 type;
the used 2-tridecyloxyethanol has a kinetic viscosity of 85-95mPa.s, a pH of 6.5-7.514.5-15.5, and is available from Basff and is TO-7;
among the used anionic surfactants, DOWFAX 2A1 has HLB value of 14.5-15.5, is purchased from Dow chemical, and other anionic surfactants are common commercially available surfactants;
the hydrogen-containing silicone oil is purchased from chemical engineering Limited company of sea in Jiangxi province, and the hydrogen content is 0.18 wt%, 0.36 wt% or 0.75 wt% respectively;
the hydrogen-containing silicone oil is a mixture, so the number average molecular weight can be roughly estimated, and the related estimation method adopts a nuclear magnetic method (the specific method is referred to in the literature)1H NMR measurement of hydrogen content and molecular weight of hydrogen-containing silicone oil, Frankia styracifolia, etc., Spectroscopy laboratory, 2011,28,1287), and the value of the estimated number average molecular weight is calculated as 5000;
the polyethylene glycol monomethyl ether and polypropylene glycol monomethyl ether series products are purchased from Shanghai Riyi chemical company Limited;
the zinc acetate used was purchased from Teng chemical industries, West division, Luoyang.
Preparation example 1
The modified polysiloxane 1 was prepared as follows: 1mmol of hydrogen-containing silicone oil (hydrogen content: 0.18 wt%) and 1mmol of polyethylene glycol monomethyl ether (average number of EO is 5) were dissolved in 50ml of toluene, and then 0.1 wt% of zinc acetate of hydrogen-containing silicone oil was added as a catalyst, and reacted under reflux for 8 hours, followed by distillation under reduced pressure to remove the solvent, and the residue was passed through a silica gel column (mobile phase: petroleum ether: dichloromethane ═ 1:1, v/v), and the product was collected to give modified polysiloxane 1 in a yield of 91.2%.
Preparation example 2
The modified polysiloxane 2 was prepared as follows: 1mmol of hydrogen-containing silicone oil (hydrogen content: 0.18 wt%) and 3mmol of polypropylene glycol monomethyl ether (average number of PO: 3) were dissolved in 50ml of DMF, and then 0.3 wt% of zinc acetate of hydrogen-containing silicone oil was added as a catalyst, and reacted under reflux for 15 hours, followed by distillation under reduced pressure to remove the solvent, and the residue was passed through a silica gel column (mobile phase: petroleum ether: dichloromethane ═ 1:1, v/v), and the product was collected to obtain modified polysiloxane 2 in a yield of 92.6%.
Preparation example 3
The modified polysiloxane 3 was prepared as follows: 1mmol of hydrogen-containing silicone oil (hydrogen content: 0.18 wt%) and 1mmol of polyethylene glycol monomethyl ether (average number of EO is 5) and 1mmol of polypropylene glycol monomethyl ether (average number of PO is 3) were dissolved in 50ml of DMF, and then 0.2 wt% of zinc acetate of hydrogen-containing silicone oil was added as a catalyst, and reacted under reflux for 10 hours, followed by distillation under reduced pressure to remove the solvent, and the residue was passed through a silica gel column (mobile phase: petroleum ether: dichloromethane ═ 1:1, v/v), and the product was collected to obtain modified polysiloxane 3 in a yield of 92.0%.
Preparation example 4
The modified polysiloxane 4 was prepared as follows: 1mmol of hydrogen-containing silicone oil (hydrogen content: 0.75 wt%), 1mmol of polyethylene glycol monomethyl ether (average number of EO is 15) and 1mmol of polypropylene glycol monomethyl ether (average number of PO is 10) were dissolved in 50ml of DMF, and then 0.2 wt% of zinc acetate of hydrogen-containing silicone oil was added as a catalyst, and the mixture was reacted under reflux for 10 hours, followed by distillation under reduced pressure to remove the solvent, and the residue was passed through a silica gel column (mobile phase: petroleum ether: dichloromethane: 1, v/v), and the product was collected to obtain modified polysiloxane 4 in a yield of 90.3%.
Preparation example 5
The modified polysiloxane 5 was prepared as follows: 1mmol of hydrogen-containing silicone oil (hydrogen content: 0.36 wt%) and 1mmol of polyethylene glycol monomethyl ether (average number of EO is 3) were dissolved in 50ml of toluene, and then 0.1 wt% of zinc acetate of hydrogen-containing silicone oil was added as a catalyst, and reacted under reflux for 8 hours, followed by distillation under reduced pressure to remove the solvent, and the residue was passed through a silica gel column (mobile phase: petroleum ether: dichloromethane ═ 1:1, v/v), and the product was collected to obtain modified polysiloxane 5 with a yield of 91.7%.
Preparation example 6
The modified polysiloxane 6 was prepared as follows: 1mmol of hydrogen-containing silicone oil (hydrogen content: 0.36 wt%) and 3mmol of polypropylene glycol monomethyl ether (average number of PO is 20) were dissolved in 50ml of DMF, and then 0.3 wt% of zinc acetate of hydrogen-containing silicone oil was added as a catalyst, and reacted under reflux for 15 hours, followed by distillation under reduced pressure to remove the solvent, and the residue was passed through a silica gel column (mobile phase: petroleum ether: dichloromethane ═ 1:1, v/v), and the product was collected to give modified polysiloxane 6 in a yield of 93.0%.
Example 1
An antifouling and dustproof quick-drying cleaning agent composition 1 comprises the following components in parts by weight:
the preparation method of the antifouling and dustproof quick-drying cleaning agent composition 1 comprises the following steps: the components are mixed in a reaction kettle according to the parts by weight, stirred uniformly at normal temperature, and then discharged from the bottom of the kettle to obtain a product.
Example 2
An antifouling and dustproof quick-drying cleaning agent composition 2 comprises the following components in parts by weight:
the preparation method of the antifouling and dustproof quick-drying cleaning agent composition 2 comprises the following steps: the components are mixed in a reaction kettle according to the parts by weight, stirred uniformly at normal temperature, and then discharged from the bottom of the kettle to obtain a product.
Example 3
An antifouling and dustproof quick-drying cleaning agent composition 3 comprises the following components in parts by weight:
the preparation method of the antifouling and dustproof quick-drying cleaning agent composition 3 comprises the following steps: the components are mixed in a reaction kettle according to the parts by weight, stirred uniformly at normal temperature, and then discharged from the bottom of the kettle to obtain a product.
Example 4
An antifouling and dustproof quick-drying cleaning agent composition 4 comprises the following components in parts by weight:
the preparation method of the antifouling and dustproof quick-drying cleaning agent composition 4 comprises the following steps: the components are mixed in a reaction kettle according to the parts by weight, stirred uniformly at normal temperature, and then discharged from the bottom of the kettle to obtain a product.
Example 5
The antifouling and dustproof quick-drying detergent composition 5 in example 5 is identical to the antifouling and dustproof quick-drying detergent composition 1 in example 1 in component types, component parts by mass and preparation method, and the only difference is that the antifouling and dustproof quick-drying detergent composition 5 adopts modified polysiloxane 5 instead of the modified polysiloxane 1.
Example 6
The antifouling and dustproof quick-drying detergent composition 6 in example 6 is identical to the antifouling and dustproof quick-drying detergent composition 1 in example 1 in component types, component parts by mass and preparation method, and the only difference is that the antifouling and dustproof quick-drying detergent composition 6 adopts modified polysiloxane 6 instead of modified polysiloxane 1.
Comparative example 1
The antifouling and dustproof quick-drying detergent composition 7 in the comparative example 1 is identical to the antifouling and dustproof quick-drying detergent composition 1 in the example 1 in component type, component parts by mass and preparation method, and the only difference is that the antifouling and dustproof quick-drying detergent composition 7 does not contain the modified polysiloxane 1.
Comparative example 2
The antifouling and dustproof quick-drying detergent composition 8 in comparative example 2 was identical to the antifouling and dustproof quick-drying detergent composition 1 in example 1 in the component kinds, component parts by mass and preparation method, and the only difference was that the antifouling and dustproof quick-drying detergent composition 8 did not contain 1 part by mass of AEO9 and 1 part by mass of APG, but the antifouling and dustproof quick-drying detergent composition contained 4.5 parts by mass of 2-tridecyloxyethanol in total.
Test example
Toxic components of the antifouling and dustproof quick-drying cleaning agent compositions 1 to 8 were measured, and the test was carried out according to the method described in ROHS Directive 2011/65/EU.
The test results obtained are shown in table 1.
TABLE 1 toxic component test results for stain and dust repellent quick-drying cleaner compositions 1-8
As can be seen from the results in Table 1, no toxic substance was detected in any of the antifouling and dustproof quick-drying detergent compositions 1 to 8, and the detergent compositions meet the ROHS Directive2011/65/EU standard.
Then, the quick-drying effect, the decontamination effect and the dustproof effect of the antifouling and dustproof quick-drying cleaning agent compositions 1 to 8 are compared.
The test method of the quick-drying effect comprises the following steps:
the apparatus used was: glass sheets (size: 30X 30 cm).
The specific testing steps are as follows:
1: the glass sheet was thoroughly cleaned and dried with deionized water and then 10ml of the test product was evenly spread on the glass which was placed upright.
2: distilled water was sprayed onto the glass surface for 10 seconds and the time to water run dry on the glass was recorded.
The antifouling effect test method comprises the following steps:
the apparatus and equipment used: black ceramic tile (size: 15cm x 15cm), spraying equipment, beaker, measuring cylinder and stirrer;
the fouling used: preparation of high lime hardness Water (9.86g of MgSO41L of distilled water, 82g of CaCl2) Adding 10g of yellow mud into the mixture, and uniformly mixing the mixture for later use.
The specific testing steps are as follows:
1: 10g of the test product is uniformly sprayed on a black ceramic tile vertical to the air, washed by water and vertically drained.
2: the black tiles were weighed, recorded as M1, sprayed evenly with 10ml of the dirt used, and then dried.
3: the weight of the black dirt-coated tile was weighed and recorded as M2.
4: the tile was rinsed with water for 10 seconds and the black tile was weighed again and recorded as M3.
The stain removal rate is (M2-M3)/(M2-M1) × 100%, and the greater the stain removal rate, the better the stain-proofing effect.
The test method of the dustproof effect comprises the following steps:
the apparatus and equipment used: black ceramic tile (size: 15cm x 15cm)
Dust used: picking and mixing of common household dusts from vacuum cleaners
The specific testing steps are as follows:
1: 10.00g of the test product was sprayed onto black tiles, waited for complete drying, and weighed as M1.
2: 10.00g of dust was scattered over the horizontal black tile until complete coverage.
3: the black tile was placed vertically at a height of 10cm from the table, allowed to fall vertically in a free-fall motion onto the table, and then weighed again as M2.
The dust-proofing ratio was (M1+10.00-M2)/10.00 × 100%, and the larger the dust-proofing ratio, the better the dust-proofing effect.
The results obtained are shown in Table 2.
TABLE 2 quick drying, stain removal and dust control effects of antifouling and dust control quick drying detergent compositions 1-8
| Water flow dry time(s) | Decontamination ratio (%) | Dust percentage (%) | |
| Composition 1 | 4.1 | 98.17 | 82 |
| Composition 2 | 4.3 | 99.16 | 85 |
| Composition 3 | 3.5 | 99.35 | 92 |
| Composition 4 | 3.6 | 99.25 | 90 |
| Composition 5 | 4.9 | 97.19 | 75 |
| Composition 6 | 5.3 | 93.27 | 72 |
| Composition 7 | 24.6 | 84.43 | 35 |
| Composition 8 | 6.5 | 94.23 | 61 |
Table 2 it can be seen that the data for examples 1-6 are more desirable than for comparative examples 1-2 in terms of technical effect. Figures 1-3 show graphs comparing the effects of the quick-dry test, stain release test, and dust test of example 3 and comparative example 1. It can be seen that example 3 has a more significant sensory advantage in quick drying, stain removal and dust control than comparative example 1.
The above data fully illustrate the advantages of the antifouling and dustproof quick-drying detergent compositions provided by the present invention over comparative examples 1-2.
Claims (6)
1. The quick-drying detergent composition for preventing fouling and dust is characterized by comprising the following components in parts by weight:
wherein, the modified polysiloxane is a product prepared by condensation reaction of hydrogen-containing silicone oil and poly-polyhydric alcohol monomethyl ether;
the poly-polyol monomethyl ether is selected from one or two of poly-ethylene glycol monomethyl ether or polypropylene glycol monomethyl ether;
the preparation method of the modified polysiloxane comprises the following steps:
dissolving hydrogen-containing silicone oil and polyatomic alcohol monomethyl ether in an organic solvent, and carrying out reflux reaction for 8-15h under the protection of nitrogen in a zinc acetate catalytic system; distilling under reduced pressure to remove the solvent, and purifying by a column to obtain a product;
the molar ratio of the hydrogen-containing silicone oil to the poly-polyol monomethyl ether is 1:1-1: 3;
the addition amount of the zinc acetate is 0.1-0.3 wt% of the hydrogen-containing silicone oil.
2. The antifouling and dustproof quick-drying detergent composition as claimed in claim 1, wherein the hydrogen content of the hydrogen-containing silicone oil is selected from 0.18 wt%, 0.36 wt% or 0.75 wt%.
3. The antifouling and dustproof quick-drying detergent composition as claimed in claim 1, wherein the number of ethoxy groups in the polyethylene glycol monomethyl ether is 5 to 15, and the number of propoxy groups in the polypropylene glycol monomethyl ether is 3 to 10.
4. The antifouling and dustproof quick-drying detergent composition as claimed in claim 1, wherein the anionic surfactant is one or more selected from DOWFAX 2A1, LAS, AES and MES.
5. The quick-drying detergent composition for preventing fouling and dust according to claim 1, wherein the organic solvent is selected from toluene, tetrahydrofuran, DMF, chlorobenzene or dichlorobenzene.
6. The antifouling and dustproof quick-drying detergent composition as claimed in claim 1, wherein the antifouling and dustproof quick-drying detergent composition further comprises triethanolamine, alcohols and water.
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85102801A (en) * | 1985-04-01 | 1987-04-08 | 吉林省化学纤维技术研究所 | Water-repellent artificial fur |
| CN1847381A (en) * | 2006-04-30 | 2006-10-18 | 北京市航天焊接材料厂 | Green multifunctional detergent and its prepn process |
| CN101475731A (en) * | 2009-01-06 | 2009-07-08 | 中国科学院广州化学研究所 | Epoxy resin composite material added with modified polysiloxane and preparation thereof |
| CN102115533A (en) * | 2009-12-30 | 2011-07-06 | 上海杰事杰新材料(集团)股份有限公司 | Low-temperature-resistant polyester elastomer with mixed soft segment and preparation method thereof |
| CN103160847A (en) * | 2013-04-03 | 2013-06-19 | 东莞市剑鑫电子材料有限公司 | Aluminum zinc cleaning agent |
| CN105733832A (en) * | 2016-01-26 | 2016-07-06 | 池州汉诺威机电设备科技有限公司 | Deoiling detergent and preparation method thereof |
| CN106702394A (en) * | 2016-12-26 | 2017-05-24 | 东莞市华畅机电科技有限公司 | Anti-bacteria cleaning agent and preparation method thereof |
| CN107312177A (en) * | 2017-08-02 | 2017-11-03 | 王琪宇 | A kind of preparation method of cutting fluid polyether modified silicon oil processed |
| CN110078925A (en) * | 2019-05-05 | 2019-08-02 | 河北科技大学 | A kind of preparation method of high polymerization degree Si-O-C type block polyether modified silicon oil |
| WO2020064467A1 (en) * | 2018-09-26 | 2020-04-02 | Firmenich Sa | Powder detergent composition |
-
2020
- 2020-07-02 CN CN202010633883.5A patent/CN111778112B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85102801A (en) * | 1985-04-01 | 1987-04-08 | 吉林省化学纤维技术研究所 | Water-repellent artificial fur |
| CN1847381A (en) * | 2006-04-30 | 2006-10-18 | 北京市航天焊接材料厂 | Green multifunctional detergent and its prepn process |
| CN101475731A (en) * | 2009-01-06 | 2009-07-08 | 中国科学院广州化学研究所 | Epoxy resin composite material added with modified polysiloxane and preparation thereof |
| CN102115533A (en) * | 2009-12-30 | 2011-07-06 | 上海杰事杰新材料(集团)股份有限公司 | Low-temperature-resistant polyester elastomer with mixed soft segment and preparation method thereof |
| CN103160847A (en) * | 2013-04-03 | 2013-06-19 | 东莞市剑鑫电子材料有限公司 | Aluminum zinc cleaning agent |
| CN105733832A (en) * | 2016-01-26 | 2016-07-06 | 池州汉诺威机电设备科技有限公司 | Deoiling detergent and preparation method thereof |
| CN106702394A (en) * | 2016-12-26 | 2017-05-24 | 东莞市华畅机电科技有限公司 | Anti-bacteria cleaning agent and preparation method thereof |
| CN107312177A (en) * | 2017-08-02 | 2017-11-03 | 王琪宇 | A kind of preparation method of cutting fluid polyether modified silicon oil processed |
| WO2020064467A1 (en) * | 2018-09-26 | 2020-04-02 | Firmenich Sa | Powder detergent composition |
| CN110078925A (en) * | 2019-05-05 | 2019-08-02 | 河北科技大学 | A kind of preparation method of high polymerization degree Si-O-C type block polyether modified silicon oil |
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