CN111751361A - Device and method for extracting and testing ammonia nitrogen substances in fly ash - Google Patents
Device and method for extracting and testing ammonia nitrogen substances in fly ash Download PDFInfo
- Publication number
- CN111751361A CN111751361A CN202010567894.8A CN202010567894A CN111751361A CN 111751361 A CN111751361 A CN 111751361A CN 202010567894 A CN202010567894 A CN 202010567894A CN 111751361 A CN111751361 A CN 111751361A
- Authority
- CN
- China
- Prior art keywords
- reactor
- fly ash
- absorber
- ammonia
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010881 fly ash Substances 0.000 title claims abstract description 60
- 238000012360 testing method Methods 0.000 title claims abstract description 32
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000000126 substance Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title abstract description 21
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000007788 liquid Substances 0.000 claims abstract description 64
- 239000006096 absorbing agent Substances 0.000 claims abstract description 59
- 238000010521 absorption reaction Methods 0.000 claims abstract description 51
- 239000007789 gas Substances 0.000 claims abstract description 50
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 49
- 238000004448 titration Methods 0.000 claims abstract description 31
- 239000003513 alkali Substances 0.000 claims abstract description 30
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 29
- 238000000605 extraction Methods 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 230000005540 biological transmission Effects 0.000 claims abstract description 11
- 239000007791 liquid phase Substances 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 23
- 239000000523 sample Substances 0.000 claims description 21
- 238000009825 accumulation Methods 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000012086 standard solution Substances 0.000 claims description 9
- 238000003760 magnetic stirring Methods 0.000 claims description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004327 boric acid Substances 0.000 claims description 5
- 239000012295 chemical reaction liquid Substances 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- 238000010998 test method Methods 0.000 claims description 5
- 239000012670 alkaline solution Substances 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- 238000009423 ventilation Methods 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000012496 blank sample Substances 0.000 claims description 3
- 238000004364 calculation method Methods 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 229960000907 methylthioninium chloride Drugs 0.000 claims description 3
- 230000002265 prevention Effects 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000010883 coal ash Substances 0.000 abstract description 4
- 238000010992 reflux Methods 0.000 abstract description 4
- 239000011259 mixed solution Substances 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000004567 concrete Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002585 base Substances 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004255 ion exchange chromatography Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 244000088401 Pyrus pyrifolia Species 0.000 description 1
- 235000001630 Pyrus pyrifolia var culta Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- -1 ammonium ions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
The invention discloses a coal ash ammonia nitrogen substance extraction testing device and a coal ash ammonia nitrogen substance extraction testing method, which comprises a reactor, an anti-splash separator, a condenser pipe, a gas transmission pipeline and an absorber which are sequentially connected, wherein a titration metering unit is arranged below the absorber; the reactor is provided with a sample chamber and an alkali liquor reagent bottle, and the absorber is provided with an absorption liquid reagent bottle; a vent pipeline is arranged between the reactor and the absorber, one end of the vent pipeline extends into the bottom of the reactor, and the other end of the vent pipeline extends into the upper part inside the absorber; the method promotes the ammonium-alkali reaction in the fly ash by adding excessive alkali liquor and heating; the vent pipe continuously blows gas into the reactor, and the mixed solution is stirred for reaction, so that the gas-liquid phase balance of ammonia is broken, and the ammonia gas is promoted to be separated; the vent pipeline and the gas pipeline form circulation reflux between the reactor and the absorber, and the gas is continuously blown in the reactor to separate ammonia gas and is circularly absorbed in the absorber, so that the extraction and the absorption are more sufficient.
Description
Technical Field
The invention relates to the technical field of building material detection, in particular to a device and a method for extracting and testing ammonia nitrogen substances in fly ash.
Background
The fly ash is a byproduct of combustion power generation of a coal-fired power plant, is applied to cement, mortar and concrete products for a long time, plays roles in reducing cost and improving efficiency and improves performance, and is an important cementing material. In recent years, in order to respond to national environmental protection requirements and reduce ammonia nitrogen substances discharged to the atmosphere by enterprises such as thermal power plants and the like, the coal-fired power plants successively carry out denitration modification on units, and in the operation of SCR and SNCR, ammonia is used for treating nitrogen oxides in flue gas and simultaneously causing residues of ammonia nitrogen substances in fly ash, so that the fly ash subjected to denitration modification has the problems of a large amount of bubbles, sharp odor, obviously prolonged or even no coagulation time, concrete volume expansion and even serious expansion, internal porosity, strength reduction and the like in the application process of cement concrete, the deterioration of the performance of the cement concrete is caused, and the quality safety and the construction environment safety of a concrete structure are seriously threatened.
Due to the diversity of chemical forms and physical combination forms of ammonia nitrogen substances in the fly ash, the test of the ammonia nitrogen content of the fly ash has a plurality of difficulties, in particular to the problems of extraction, measurement precision and range applicability of the ammonia nitrogen substances in the fly ash. The currently common methods for extracting and testing ammonia nitrogen substances of the fly ash mainly comprise methods of soaking, suction filtration or centrifugal separation and the like for extracting ammonium ions, a formaldehyde method, a distillation-titration method, a Nassner reagent-spectrophotometer method, a salicylic acid photometer, an ion chromatography and the like. The method of infiltration, suction filtration or centrifugal separation is not sufficient to extract Ca, which is difficult to avoid2+、Mg2+Interference of ions and gels; the formaldehyde method and the distillation-titration method have insufficient precision and cannot meet the test requirement of the fly ash; the accuracy of the method of Nashi reagent-spectrophotometer, salicylic acid photometer, ion chromatography and the like is too high, the test range is narrow, and the method is not suitable for powderAnd testing the ammonia content of the coal ash. In addition, the methods have the problems of low extraction efficiency, complex solution preparation, complex operation and the like in the quantitative test process.
Disclosure of Invention
Aiming at the problems, the invention provides a device and a method for extracting and testing ammonia nitrogen substances in fly ash, which have the characteristics of sufficient extraction and absorption, simple solution preparation, convenient operation, high testing precision, short testing time and the like.
The invention adopts the following technical scheme:
a coal ash ammonia nitrogen substance extraction testing device comprises a reactor, an anti-splash separator, a condenser pipe, a gas transmission pipeline and an absorber which are sequentially connected through a pipeline, wherein a titration metering unit is arranged below the absorber;
the reactor is provided with a sample chamber and an alkali liquor reagent bottle which are communicated with the inside of the reactor through a pipeline, and the absorber is provided with an absorption liquid reagent bottle which is communicated with the inside of the absorber through a pipeline;
a vent pipeline is arranged between the reactor and the absorber, one end of the vent pipeline extends into the bottom of the reactor, and the other end of the vent pipeline extends into the upper part inside the absorber;
the splash-proof separator comprises a hollow spherical cavity, the upper end and the lower end of the cavity are respectively provided with a gas outlet, a gas inlet and a cavity inner part which are communicated, the lower end of the gas outlet extends to the inside of the cavity, the lower end of the gas outlet is provided with a circular arc splash-proof baffle disc for preventing reaction liquid from boiling over to enter a follow-up pipeline and influencing a result, a gas through hole is formed at the joint of the gas outlet and the splash-proof baffle disc, condensed liquid can flow back to the reactor through the gas through hole, a circulating loop which is continuously blown away from and reacts with reflux is formed in the reactor and the splash-proof separator, and ammonia nitrogen substances in the fly ash are fully.
Preferably, the titration metering unit comprises a liquid accumulation bottle, a magnetic stirring device for stirring the liquid accumulation bottle, a color absorption and identification device for identifying a color change judgment end point, a flow meter and a titration solution reagent bottle, wherein a reagent in the titration solution reagent bottle is pumped into the liquid accumulation bottle through a pump, and the consumption of the reagent is metered through the flow meter.
Preferably, a heating element is arranged on the outer side of the reactor, and the heating element is a silica gel heating sheet; and an alkali liquor pump is arranged on a pipeline between the reactor and the alkali liquor reagent bottle and pumps the alkali liquor in the alkali liquor reagent bottle into the reactor.
Preferably, the vent pipeline is provided with a gas pump, and the gas pump pumps the gas in the absorber to the bottom of the reactor, so that a gas circulation loop is formed between the reactor and the absorber.
Preferably, the gas transmission pipeline is provided with a suck-back prevention check valve for preventing liquid in the suck-back absorber at the lower end of the gas transmission pipeline from entering the reactor.
Preferably, the top of the absorber is provided with a pressure release valve, the bottom of the absorber is provided with an absorber liquid discharge valve, and an absorption liquid pump arranged on a pipeline between the absorption liquid reagent bottle and the absorber pumps the absorption liquid in the absorption liquid reagent bottle into the absorber.
A test method for a device for extracting and testing ammonia nitrogen substances from fly ash comprises the following steps:
s1, cleaning by using ammonia-free distilled water, connecting the device, weighing a certain mass of fly ash, filling the fly ash into a sample chamber, adding distilled water for soaking and washing, and entering a reactor to keep the tightness of the device;
s2, firstly pumping the absorption liquid in the absorption liquid reagent bottle into an absorber; pumping excessive alkaline reaction liquid from an alkaline solution reagent bottle into the reactor through an alkaline solution pump to react with the fly ash, and starting a heating element to promote ammonia-alkali reaction and ammonia gas overflow;
s3, starting a gas pump on the vent pipeline to continuously introduce gas into the reactor, breaking the gas-liquid phase balance of ammonia, and promoting the ammonia to be separated;
s4, introducing the ammonia gas blown off from the reactor into the absorption liquid at the bottom of the absorber through a gas pipeline for absorption, re-introducing the ammonia gas which is not absorbed by the absorption liquid into the reactor through the gas pipeline for circulating reaction and absorption, and opening a liquid discharge valve of the absorber after extraction is finished to obtain liquid containing ammonia to be detected;
s5, adding a color indicator into the ammonia-containing solution to be detected, starting a magnetic stirring device (41) for stirring, and dropwise adding a titration reagent with known concentration to a color-changing end point;
s6, calculating the content of ammonia nitrogen substances in the fly ash according to the consumption of the titration reagent, wherein the calculation formula of the ammonia content in the fly ash is as follows:
in the formula, X is the ammonia content of the fly ash, ppm; v2 is the volume of hydrochloric acid standard solution consumed by the test sample, ml; v0 is the volume, ml, of hydrochloric acid standard solution consumed by the measurement of the blank sample; m is the mass of the fly ash sample, g; c is the concentration of the titrated hydrochloric acid standard solution, mol/L.
Preferably, the alkaline reaction solution is sodium hydroxide or potassium hydroxide, the mass concentration is 5-50 wt%, and the mass ratio of the alkaline reaction solution to the fly ash sample is as follows: (5-50): (5-30);
the absorption liquid is boric acid, the mass concentration is 1.5-4 wt%, and the mass ratio of the absorption liquid to the fly ash sample is as follows: (20 to 200) and (5 to 30).
Preferably, the color indicator is a methyl red-methylene blue solution or a methyl red-bromophenol green mixed indicator, the titration reagent is a standard dilute hydrochloric acid or dilute sulfuric acid solution with a known concentration, and the concentration range is 0.001-0.1 mol/L; the ammonia-containing solution to be detected is mainly ammonium borate and excessive boric acid solution, a target product is directly titrated by using strong acid such as dilute hydrochloric acid or dilute sulfuric acid, and the titration of the weak acid and weak base salt of ammonium borate is not influenced by the pH of the titrated product, the concentration and the dosage of the absorption solution, so that interference factors are reduced, and the data stability is improved.
The invention has the beneficial effects that:
1. the method promotes the ammonium-alkali reaction in the fly ash by adding excessive alkali liquor and heating; the vent pipe continuously blows gas into the reactor, and the mixed solution is stirred for reaction, so that the gas-liquid phase balance of ammonia is broken, and the ammonia gas is promoted to be separated; the vent pipeline and the gas pipeline form circulation reflux between the reactor and the absorber, and the reactor is continuously blown with gas to separate ammonia gas, and the absorption process is circulated in the absorber, so that the extraction and the absorption are more sufficient;
2. the method adopts color identification and automatic titration to test the ammonia content of the liquid to be tested, is convenient to operate, and reduces the artificial titration error. The method has the advantages of sufficient extraction and absorption, simple solution preparation, convenient operation, high test precision, short test time, easy realization of automatic design and the like, so the method has strong popularization and application values in the aspect of quick detection of the ammonia content in the fly ash and other building material products.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings of the embodiments will be briefly described below, and it is apparent that the drawings in the following description only relate to some embodiments of the present invention and are not limiting on the present invention.
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a schematic diagram of the structure of a titration cell according to the present invention;
FIG. 3 is a schematic cross-sectional view of a splash separator of the present invention;
FIG. 4 is a schematic circuit diagram of a color recognition device according to the present invention;
shown in the drawings
1-a reactor, 2-a heating element, 3-a ventilation pipeline, 4-a sample chamber, 5-a sample adding valve, 6-an alkali liquor reagent bottle, 7-an alkali liquor pump, 8-an alkali liquor valve and 10-an anti-splash separator;
11-an air pump, 12-a condenser pipe, 13-an anti-suck-back check valve, 14-an air pipeline, 15-an absorber, 16-a pressure release valve, 17-a check valve, 19-an absorption liquid reagent bottle and 20-an absorption liquid pump;
101-splash baffle disc, 102-gas inlet, 103-gas outlet, 104-gas through hole, 105-cavity;
21-absorption liquid valve, 22-absorber drain valve, 23-reactor drain valve, 24-liquid accumulation bottle, 25-magnetic stirring device, 26-titration liquid reagent bottle, 27-flowmeter, 28-color absorption and identification device, and 29-automatic integrated controller.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the drawings of the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the described embodiments of the invention without any inventive step, are within the scope of protection of the invention.
Unless otherwise defined, technical or scientific terms used herein shall have the ordinary meaning as understood by one of ordinary skill in the art to which this disclosure belongs. The use of the word "comprising" or "comprises", and the like, in this disclosure is intended to mean that the elements or items listed before that word, include the elements or items listed after that word, and their equivalents, without excluding other elements or items. "upper", "lower", "left", "right", and the like are used merely to indicate relative positional relationships, and when the absolute position of the object being described is changed, the relative positional relationships may also be changed accordingly.
The invention is further illustrated with reference to the following figures and examples.
As shown in fig. 1 to 4, the device for extracting and testing ammonia nitrogen substances from fly ash comprises a reactor 1, a splash-proof separator 10, a condenser pipe 12, a gas transmission pipeline 14 and an absorber 15 which are sequentially connected through pipelines, wherein a titration metering unit is arranged below the absorber 15;
a sample chamber 4 and an alkali liquor reagent bottle 6 which are arranged on the reactor 1 are communicated with the interior of the reactor 1 through a pipeline, the sample chamber 4 adds the soaked fly ash sample into the reactor 1 through a pipeline and a sample adding valve 5 which is arranged on the pipeline, an alkali liquor pump 7 and an alkali liquor valve 8 are arranged on the pipeline between the reactor 1 and the alkali liquor reagent bottle 6, and the alkali liquor pump 7 pumps the alkali liquor in the alkali liquor reagent bottle 6 into the reactor 1;
the heating element 2 is arranged on the outer side of the reactor 1, the heating element 2 is a silica gel heating sheet, and the heating element 2 can effectively improve the reaction speed of the fly ash and the alkali liquor;
a sealing element is arranged at the joint of the reactor 1 and the splash-proof separator 10 to prevent ammonia gas from escaping;
a reactor drain valve 23 is arranged below the reactor 1, so that liquid can be conveniently drained.
An absorption liquid reagent bottle 19 arranged on the absorber 15 is communicated with the inside of the absorber 15 through a pipeline; an absorption liquid pump 20 arranged on a pipeline between the absorption liquid reagent bottle 19 and the absorber 15 pumps the absorption liquid in the absorption liquid reagent bottle 19 into the absorber 15, a pressure release valve 16 is arranged at the top of the absorber 15, an absorber liquid discharge valve 22 is arranged at the bottom of the absorber 15, and an absorption liquid valve 21 is arranged on a pipeline between the absorption liquid reagent bottle 19 and the absorber 15.
A vent pipeline 3 is arranged between the reactor 1 and the absorber 15, one end of the vent pipeline 3 extends into the bottom of the reactor 1, and the other end of the vent pipeline 3 extends into the upper part of the interior of the absorber 15;
the aeration pipeline 3 is provided with an air pump 11 and a one-way valve 17, the air pump 11 pumps the air in the absorber 15 to the bottom of the reactor 1, so that an air circulation loop is formed between the reactor 1 and the alkali liquor reagent bottle 6, the boiling-over liquid splash-proof backflow and ammonia gas separation are ensured in the blowing-off and heating environment, and the absorption efficiency of the absorber 15 is improved after cooling.
The splash-proof separator 10 comprises a hollow spherical cavity 105, the upper end and the lower end of the cavity 105 are respectively provided with a gas outlet 103 and a gas inlet 102 which are communicated with the interior of the cavity 105, the lower end of the gas outlet 103 extends into the cavity 105, and the lower end of the gas outlet 103 is provided with a circular arc splash-proof baffle disc 101 to prevent reaction liquid from boiling over and entering a subsequent pipeline to influence the result;
the connecting part of the gas outlet 103 and the splash-proof baffle disc 101 is provided with a plurality of gas through holes 104, ammonia gas enters the condenser pipe 12 through the gas through holes 104, boiling reaction liquid and condensed liquid flow back to the reactor 1 through the splash-proof baffle disc, a circulation loop which is continuously blown away and reacts with reflux is formed in the reactor 1 and the splash-proof separator 10, and ammonia nitrogen substances in the fly ash are fully extracted.
The air transmission pipeline 14 is provided with a reverse suction prevention one-way valve 13, and the blown-off ammonia gas is introduced into the bottom of the absorber 15 through the air transmission pipeline 14 after splash-proof backflow, separation and cooling, and forms a circulation loop with the ventilation pipeline 3 under the action of the air pump 11.
The titration metering unit comprises a liquid accumulation bottle 24, a magnetic stirring device 25 for stirring the liquid accumulation bottle 24, a color absorption and identification device 28 for identifying a color change judgment end point, a flowmeter 27 and a titration liquid reagent bottle 26, wherein a parallel lens of a light-permeable source at the bottom of the liquid accumulation bottle 24 is used for allowing a light source to enter one side of the parallel lens and allowing a color to enter the color absorption and identification device 28, and a reagent in the titration liquid reagent bottle 26 is pumped into the liquid accumulation bottle 24 through a pump and is metered by the consumption of the reagent through.
The color absorption and recognition device 28 is a color recognition sensor module integrating a TCS34725 chip and an MCU (model MINI ATMEGA328P-AU) chip, and is IIC or serial communication to directly output RGB values, and the working principle is that after a light source irradiates an object to be detected, the return light detects RGB ratio values through a filter, and recognizes colors according to the RGB ratio values, as shown in fig. 4.
The titration metering unit further comprises an automatic integrated controller 29, the automatic integrated controller 29 is electrically connected with the color absorption and recognition device 28 and the pump through a relay and a magnetic stirring device 25 to control the opening and closing of the automatic integrated controller, the automatic integrated controller can be a PLC controller and comprises a 16-bit or 32-bit MCU chip, a clock circuit, an amplifying circuit, a storage module and the like (in the prior art, the details are not repeated).
A test method for a device for extracting and testing ammonia nitrogen substances from fly ash comprises the following steps:
s1, cleaning by using ammonia-free distilled water, connecting the device, weighing a certain mass of fly ash, filling the fly ash into a sample chamber 4, adding distilled water for soaking and washing, and entering a reactor 1 to keep the tightness of the device;
s2, firstly, adding a boric acid solution with the mass concentration of 1.5-4 wt% into the absorber 15;
then pumping NaOH solution with the mass concentration of 5-50 wt% from an alkali liquor reagent bottle 6 into the reactor 1 through an alkali liquor pump 7 to react with the fly ash, and simultaneously starting a heating element 2 to promote ammonia-alkali reaction and ammonia gas overflow;
s3, starting the heating element 2 on the reactor 1, enabling the gas to enter the absorber 15 through the splash-proof separator 10, the condenser pipe 12 and the gas transmission pipeline 14, starting the gas pump 11 on the ventilation pipeline 3 to continuously introduce the gas into the reactor 1, breaking the gas-liquid phase balance of ammonia, and promoting the separation of ammonia gas;
s4, introducing the ammonia gas blown off from the reactor 1 into the absorption liquid at the bottom of the absorber 15 through the gas pipeline 14 for absorption, introducing the unabsorbed ammonia gas into the reactor 1 through the gas pipeline for circulating reaction and absorption, and opening a liquid discharge valve of the absorber after extraction is finished to obtain liquid containing ammonia to be detected;
setting the extraction time to be 10min, closing the heating element 2 and the air pump 11 after extraction is finished, opening the liquid discharge valve 22 of the absorber, and allowing the liquid containing ammonia to be detected to flow into the liquid accumulation bottle 24;
s5, adding a color indicator into the ammonia-containing solution to be detected, starting the magnetic stirring device 25 to stir, and dropwise adding a titration reagent with known concentration to a color-changing end point;
s6, calculating the content of ammonia nitrogen substances in the fly ash according to the consumption of the titration reagent, wherein the calculation formula of the ammonia content in the fly ash is as follows:
in the formula, X is the ammonia content of the fly ash, ppm; v2 is the volume of hydrochloric acid standard solution consumed by the test sample, ml; v0 is the volume, ml, of hydrochloric acid standard solution consumed by the measurement of the blank sample; m is the mass of the fly ash sample, g; c is the concentration of the titrated hydrochloric acid standard solution, mol/L.
The color indicator is a methyl red-methylene blue solution or a methyl red-bromophenol green mixed indicator, the titration reagent is a standard dilute hydrochloric acid or dilute sulfuric acid solution with known concentration, and the concentration range is 0.001-0.1 mol/L; the ammonia-containing solution to be detected is mainly ammonium borate and excessive boric acid solution, a target product is directly titrated by using strong acid such as dilute hydrochloric acid or dilute sulfuric acid, and the titration of the weak acid and weak base salt of ammonium borate is not influenced by the pH of the titrated product, the concentration and the dosage of the absorption solution, so that interference factors are reduced, and the data stability is improved.
Each group of fly ash samples was measured 3 times, the average was calculated, the Standard Deviation (SD) was used to reflect the degree of dispersion between the parallel groups, and the Relative Standard Deviation (RSD) was used to measure the relative error between the measured and true values, and the results are shown in table 1.
TABLE 1 different denitration fly ash ammonia-containing test parameters
TABLE 2 results of ammonia test of different denitration fly ashes
Although the present invention has been described with reference to a preferred embodiment, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (9)
1. The device for extracting and testing the ammonia nitrogen substances in the fly ash is characterized by comprising a reactor (1), a splash-proof separator (10), a condenser pipe (12), a gas transmission pipeline (14) and an absorber (15) which are sequentially connected, wherein a titration metering unit is arranged below the absorber (15);
a sample chamber (4) and an alkali liquor reagent bottle (6) are arranged on the reactor (1), and an absorption liquid reagent bottle (19) is arranged on the absorber (15);
a vent pipeline (3) is arranged between the reactor (1) and the absorber (15), one end of the vent pipeline (3) extends into the bottom of the reactor (1), and the other end of the vent pipeline extends into the upper part of the interior of the absorber (15);
splash guard separator (10) are including cavity (105), the upper and lower end of cavity (105) is equipped with gas outlet (103) and gas inlet (102) respectively, inside gas outlet (103) extended to cavity (105), the lower tip was equipped with splash guard (101), and gas outlet (103) and splash guard (101)'s junction is equipped with gas through-hole (104).
2. The fly ash ammonia nitrogen substance extraction testing device as claimed in claim 1, wherein the titration metering unit comprises a liquid accumulation bottle (24), a magnetic stirring device (25) for stirring the liquid accumulation bottle (24), a color absorption and identification device (28) for identifying a color change judgment end point, a flow meter (27), and a titration liquid reagent bottle (26), wherein a reagent in the titration liquid reagent bottle (26) is pumped into the liquid accumulation bottle (24) through a pump, and the consumption of the reagent is metered through the flow meter (27).
3. The fly ash ammonia nitrogen substance extraction testing device according to claim 2, wherein a heating element (2) is arranged outside the reactor (1), and the heating element (2) is a silica gel heating sheet; an alkali liquor pump (7) is arranged on a pipeline between the reactor (1) and the alkali liquor reagent bottle (6).
4. The fly ash ammonia nitrogen substance extraction testing device as claimed in claim 3, wherein an air pump (11) is arranged on the ventilation pipeline (3).
5. The fly ash ammonia nitrogen substance extraction and test device as claimed in claim 4, wherein the gas transmission pipeline (14) is provided with a suck-back prevention check valve (13).
6. The fly ash ammonia nitrogen substance extraction testing device as claimed in claim 4, wherein a pressure release valve (16) is arranged at the top of the absorber (15), an absorber liquid discharge valve (22) is arranged at the bottom of the absorber, and an absorption liquid pump (20) is arranged on a pipeline between the absorption liquid reagent bottle (19) and the absorber (15).
7. A fly ash ammonia nitrogen substance extraction test method, which utilizes the fly ash ammonia nitrogen substance extraction test device of any one of claims 1-6, and is characterized by comprising the following steps:
s1, cleaning by using ammonia-free distilled water, connecting the device, weighing a certain mass of fly ash, filling the fly ash into a sample chamber (4), adding distilled water for soaking and washing, and entering a reactor (1) to keep the tightness of the device;
s2, firstly pumping the absorption liquid in the absorption liquid reagent bottle (19) into an absorber (15);
pumping excessive alkaline reaction liquid from an alkaline solution reagent bottle (6) into the reactor (1) through an alkaline solution pump (7) to react with the fly ash, and starting a heating element (2) to promote ammonia-alkali reaction and ammonia overflow;
s3, opening an air pump (11) on the vent pipeline (3) to continuously introduce air into the reactor (1), breaking the gas-liquid phase balance of ammonia, and promoting the ammonia to be separated;
s4, introducing the ammonia gas blown off in the reactor (1) into the absorption liquid at the bottom of the absorber (15) through the gas transmission pipeline (14) for absorption, re-introducing the unabsorbed ammonia gas into the reactor (1), and obtaining ammonia-containing liquid to be detected after extraction is finished;
s5, adding a color indicator into the ammonia-containing solution to be detected, starting a magnetic stirring device (41) for stirring, and dropwise adding a titration reagent with known concentration to a color-changing end point;
s6, calculating the content of ammonia nitrogen substances in the fly ash according to the consumption of the titration reagent, wherein the calculation formula of the ammonia content in the fly ash is as follows:
in the formula, X is the ammonia content of the fly ash, ppm; v2 is the volume of hydrochloric acid standard solution consumed by the test sample, ml; v0 is the volume, ml, of hydrochloric acid standard solution consumed by the measurement of the blank sample; m is the mass of the fly ash sample, g; c is the concentration of the titrated hydrochloric acid standard solution, mol/L.
8. The extraction and test method for ammonia nitrogen substances in fly ash according to claim 7, wherein the alkaline reaction solution is sodium hydroxide or potassium hydroxide, the mass concentration is 5-50 wt%, and the mass ratio of the alkaline reaction solution to the fly ash sample is as follows: (5-50): (5-30);
the absorption liquid is boric acid, the mass concentration is 1.5-4 wt%, and the mass ratio of the absorption liquid to the fly ash sample is as follows: (20 to 200) and (5 to 30).
9. The extraction and test method for ammonia nitrogen substances in fly ash according to claim 7, wherein the color indicator is a methyl red-methylene blue solution or a methyl red-bromophenol green mixed indicator, and the titration reagent is a dilute hydrochloric acid or dilute sulfuric acid solution with a concentration range of 0.001-0.1 mol/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010567894.8A CN111751361A (en) | 2020-06-19 | 2020-06-19 | Device and method for extracting and testing ammonia nitrogen substances in fly ash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010567894.8A CN111751361A (en) | 2020-06-19 | 2020-06-19 | Device and method for extracting and testing ammonia nitrogen substances in fly ash |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111751361A true CN111751361A (en) | 2020-10-09 |
Family
ID=72675251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010567894.8A Pending CN111751361A (en) | 2020-06-19 | 2020-06-19 | Device and method for extracting and testing ammonia nitrogen substances in fly ash |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111751361A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113860803A (en) * | 2021-09-17 | 2021-12-31 | 西安科技大学 | Preparation method and device for controlling ammonia release of fly ash and/or magnesium slag and magnesium slag-based filling paste |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002048435A (en) * | 2000-07-31 | 2002-02-15 | Hitachi Zosen Corp | Absorption type refrigerating machine |
| CN201611342U (en) * | 2010-02-03 | 2010-10-20 | 济南精密科学仪器仪表有限公司 | Automatic sample introduction Kjeldahl nitrogen determination apparatus |
| CN103076320A (en) * | 2012-12-28 | 2013-05-01 | 重庆川仪分析仪器有限公司 | Ammonia nitrogen detector and detection method |
| CN103712981A (en) * | 2013-12-11 | 2014-04-09 | 上海市建筑科学研究院(集团)有限公司 | Method for detecting content of nitrogen in denitrified fly ash |
| CN105021767A (en) * | 2015-07-29 | 2015-11-04 | 江汉大学 | Automatic titrating system |
| CN105424836A (en) * | 2015-11-30 | 2016-03-23 | 国网浙江省电力公司电力科学研究院 | Method for detecting content of ammonia in fly ash |
| CN208275421U (en) * | 2018-03-30 | 2018-12-25 | 安徽益瑞德新材料科技有限公司 | A kind of air inlet buffer-type anti-splash ball |
| CN109358012A (en) * | 2018-11-27 | 2019-02-19 | 成都海兰天澄科技股份有限公司 | A kind of Water quality ammonia nitrogen device for fast detecting and method |
| CN212301341U (en) * | 2020-06-19 | 2021-01-05 | 中建西部建设建材科学研究院有限公司 | Fly ash ammonia nitrogen material draws testing arrangement |
-
2020
- 2020-06-19 CN CN202010567894.8A patent/CN111751361A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002048435A (en) * | 2000-07-31 | 2002-02-15 | Hitachi Zosen Corp | Absorption type refrigerating machine |
| CN201611342U (en) * | 2010-02-03 | 2010-10-20 | 济南精密科学仪器仪表有限公司 | Automatic sample introduction Kjeldahl nitrogen determination apparatus |
| CN103076320A (en) * | 2012-12-28 | 2013-05-01 | 重庆川仪分析仪器有限公司 | Ammonia nitrogen detector and detection method |
| CN103712981A (en) * | 2013-12-11 | 2014-04-09 | 上海市建筑科学研究院(集团)有限公司 | Method for detecting content of nitrogen in denitrified fly ash |
| CN105021767A (en) * | 2015-07-29 | 2015-11-04 | 江汉大学 | Automatic titrating system |
| CN105424836A (en) * | 2015-11-30 | 2016-03-23 | 国网浙江省电力公司电力科学研究院 | Method for detecting content of ammonia in fly ash |
| CN208275421U (en) * | 2018-03-30 | 2018-12-25 | 安徽益瑞德新材料科技有限公司 | A kind of air inlet buffer-type anti-splash ball |
| CN109358012A (en) * | 2018-11-27 | 2019-02-19 | 成都海兰天澄科技股份有限公司 | A kind of Water quality ammonia nitrogen device for fast detecting and method |
| CN212301341U (en) * | 2020-06-19 | 2021-01-05 | 中建西部建设建材科学研究院有限公司 | Fly ash ammonia nitrogen material draws testing arrangement |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113860803A (en) * | 2021-09-17 | 2021-12-31 | 西安科技大学 | Preparation method and device for controlling ammonia release of fly ash and/or magnesium slag and magnesium slag-based filling paste |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN212301341U (en) | Fly ash ammonia nitrogen material draws testing arrangement | |
| CN103344641B (en) | Method for measuring zinc and nickel contents in zinc-nickel alloy electroplating solution | |
| CN105181614B (en) | Sulfur trioxide analytical instrument and method | |
| CN109632408A (en) | SO in a kind of flue gas3Self-operated measuring unit and method | |
| CN100397075C (en) | Hardness indicator composition for water hardness measurement and hardness measuring method | |
| CN111751361A (en) | Device and method for extracting and testing ammonia nitrogen substances in fly ash | |
| CN104977265A (en) | Analyzer and analytical method for soluble sulfides in water sample | |
| CN100422718C (en) | Method for determining sodium chloride content in phosphate using spectrophotometry | |
| CN102095729A (en) | Device for detecting ammonium nitrogen in fertilizer with cold air distillation method and method thereof | |
| CN212301343U (en) | Quantitative test device for ammonia nitrogen substances in fly ash | |
| CN101718706B (en) | Test agent for on-site rapid detection of formaldehyde in air | |
| CN205003004U (en) | Automatic calibration device of coal fired power plant flue gas mercury measuring apparatu | |
| CN111751363A (en) | Quantitative testing device and testing method for ammonia nitrogen substances in fly ash | |
| CN205246422U (en) | Sulfur trioxide's preprocessing device in flue gas | |
| CN212301342U (en) | Test device for rapidly judging ammonia content of fly ash | |
| CN107389673A (en) | A kind of assay method of organic matter hydroxyl value and application | |
| CN106885871A (en) | A kind of assay method of complicated solution middle and high concentration sulfate radical | |
| CN111751362A (en) | Testing device and method for rapidly judging ammonia content of fly ash | |
| CN215985925U (en) | Device for on-line detecting sulfite content of wet desulphurization slurry | |
| CN105301188A (en) | Automatic calibration device of coal-fired power plant flue gas mercury measuring instrument and control method | |
| CN209656382U (en) | SO in a kind of flue gas3Self-operated measuring unit | |
| CN113607879A (en) | Device and method for online detection of sulfite content of wet desulphurization slurry | |
| CN108226435A (en) | COD detection methods and device based on multi-sensor information fusion | |
| CN108341452A (en) | A kind of method that membrane separating process couples removing oxygen in water with chemical deoxidation process | |
| CN217112388U (en) | Non-contact ammonia nitrogen detects automatic reagent feeding system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |