CN111746072A - Lightweight composite multilayer glass - Google Patents
Lightweight composite multilayer glass Download PDFInfo
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- CN111746072A CN111746072A CN202010744429.7A CN202010744429A CN111746072A CN 111746072 A CN111746072 A CN 111746072A CN 202010744429 A CN202010744429 A CN 202010744429A CN 111746072 A CN111746072 A CN 111746072A
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- 239000011521 glass Substances 0.000 title claims abstract description 103
- 239000002131 composite material Substances 0.000 title claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 65
- 239000011347 resin Substances 0.000 claims abstract description 65
- 230000001681 protective effect Effects 0.000 claims abstract description 25
- 239000004417 polycarbonate Substances 0.000 claims abstract description 14
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 13
- 239000005341 toughened glass Substances 0.000 claims abstract description 12
- 238000001746 injection moulding Methods 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 10
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 131
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 10
- 230000004888 barrier function Effects 0.000 claims description 10
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 10
- 239000012790 adhesive layer Substances 0.000 claims description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 9
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 9
- 230000000903 blocking effect Effects 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000005266 casting Methods 0.000 claims description 6
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- -1 polyethylene terephthalate Polymers 0.000 claims description 5
- 238000013329 compounding Methods 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000005340 laminated glass Substances 0.000 abstract description 9
- 238000005336 cracking Methods 0.000 abstract description 4
- 239000000243 solution Substances 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract 1
- 229920002799 BoPET Polymers 0.000 description 5
- 239000011162 core material Substances 0.000 description 4
- 229920006255 plastic film Polymers 0.000 description 4
- 239000002985 plastic film Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 229920005992 thermoplastic resin Polymers 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- QZRLETONGKUVFA-UHFFFAOYSA-N [K].[Cs] Chemical compound [K].[Cs] QZRLETONGKUVFA-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/718—Weight, e.g. weight per square meter
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a lightweight composite multilayer glass, which comprises a layered structure of a glass layer and a resin layer, and at least comprises the following components from outside to inside: an outer inorganic glass layer, toughened glass with the thickness of 0.1mm-1.6 mm; an intermediate resin layer which is a transparent resin material layer; an inner protective film which is a thermoplastic film with scratch resistance and is compounded with the middle resin layer. The invention also provides a method for injection molding the lightweight composite multilayer glass. The invention provides a scheme for replacing traditional inorganic toughened glass and inorganic laminated glass, which has the advantages that: the weight of the glass is lighter than that of the traditional inorganic glass; the anti-cracking performance of the glass is superior to that of the traditional inorganic glass; better manufacturability and manufacturability than the polycarbonate + hardened coating solution while retaining the lightweight characteristics of the polycarbonate solution.
Description
Technical Field
The invention relates to lightweight composite multilayer glass.
Background
Inorganic glass has high light transmittance but is fragile, and the requirements on the performance of the glass are improved along with the improvement of the functional requirements.
Application No.: 01266987.3 discloses a novel ultra-thin bulletproof glass, which is formed by sequentially bonding glass with the thickness of 6-12 mm, a polycarbonate film with the thickness of 0.5-2 mm and a polycarbonate plate with the thickness of 2-5 mm at high temperature and high pressure. The other side of the glass is provided with a PET film with the thickness of 0.1-0.4 mm, and the PET film is directly bonded at normal temperature and normal pressure. The bulletproof glass avoids the compounding of multiple layers of glass, thereby simplifying the structure, reducing the production cost, and improving the bulletproof reliability of the glass by sticking the PET film on the outer side of the glass.
Application No.: 200780026719.0A window system having solar control properties includes: a substrate having a first side and a second side; a first plasma layer adjacent to a first side of the substrate; a first weathering layer between the first side of the substrate and the plasma layer; and a solar control system positioned between the first side of the substrate and the weathering layer.
Application No.: 200780050453.3 are used in a multifunctional glazing panel for a motor vehicle window assembly. The glazing panel includes a plastic film having a functional layer, a base layer of a polymeric material, and a tie layer between the plastic film and the base layer. Providing an abrasion resistant layer on the plastic film protects the plastic film and the base layer from damage due to abrasion.
Application No.: 200880109500.1 relates to a lightweight transparent armor laminate comprising a borosilicate glass layer, a transparent glass ceramic layer, and a polymeric spall layer of polycarbonate and/or polymethyl methacrylate. The layers are bonded together by a polyurethane and/or polyvinyl butyral interlayer film.
Application No.: 201720551890.4 discloses a novel bulletproof and smash-proof glass, which comprises three same transparent glass bulletproof plates glued together in turn by glass films; transparent glass bulletproof plate from top to bottom includes: the laminated glass comprises a toughened glass layer, a cesium-potassium glass composite layer, a PC (polycarbonate) plate layer and a polycarbonate plate, wherein the layers are glued together by a glass film. The utility model discloses a shellproof prevents pounding glass has the characteristics that thickness is little, light in weight, with low costs, and shellproof effect is high, can prevent effectively that the bullet from passing glass, can prevent effectively simultaneously that the glass piece from causing secondary damage to the human body, and the shellproof protection of three-layer, bending strength can reach 600 + 1100MPa, can bear 79 formula submachine-gun and shoot in succession at 15 meters distance and do not wear, concrete very good guard action.
Application No.: 201780063934.1A laminated glass (10) is provided with: a core 11 including a resin plate 12, and a first glass sheet 13a and a second glass sheet 13b laminated on both surfaces of the core 11 via adhesive layers 15a and 15 b. The first glass sheet 13a and the second glass sheet 13b are each thinner than the core 11. A resin cover plate 14 is laminated on the outer surface of the first glass sheet 13a via an adhesive layer 15 c. This makes it possible to suppress local damage due to collision of a flying object while reducing the weight. The thickness of each of the first glass sheet 13a and the second glass sheet 13b is preferably 1/5 or less of the thickness of the core material 11.
Application No.: 201780091519.7A flexible ultra-thin glass with high contact resistance relates to an ultra-thin chemical toughened glass product with the thickness less than or equal to 0.4 mm. To improve the resistance to sharp object impact, the glass article has a break height (given in mm) greater than 50 times the thickness (t) of the glass article (t given in mm). Further, the glass article has a break bend radius (given in mm) that is less than 100000 times the thickness (t) of the glass article (t given in mm) divided by a value of a surface compressive stress (in MPa) measured at the first surface.
Application No.: 201910975854.4 the present invention relates to the field of glass products, particularly to glass for mounting on automobiles, and specifically provides a heat-insulating laminated glass for automobiles and a manufacturing method thereof. The heat-insulating laminated glass for the automobile comprises an outer glass plate, a heat-insulating interlayer and an inner glass plate, wherein the heat-insulating interlayer comprises a first thermoplastic resin film, an infrared reflection film and a second thermoplastic resin film which are sequentially laminated, the infrared reflection film comprises at least two resin films laminated together, the difference between the refractive indexes of the two adjacent resin films is greater than or equal to 0.05, and the softening point temperature of the infrared reflection film is at least three times greater than the softening point temperature of the first thermoplastic resin film and the second thermoplastic resin film. The invention can avoid the heat insulation intermediate layers from softening and extruding mutually at the same time, eliminates the appearance defects of ripples or pits and the like, ensures the appearance quality of the laminated glass, does not block electromagnetic wave signals from passing through, and ensures the communication and other additional functions in the vehicle.
Disclosure of Invention
The invention aims to: the lightweight composite multilayer glass is lighter than the traditional inorganic glass; the anti-cracking performance of the glass is superior to that of the traditional inorganic glass.
Yet another object of the present invention is to: provided is a method for producing the lightweight composite multilayer glass.
The purpose of the invention is realized by the following scheme: a lightweight composite multiple layer glass, comprising a layered structure of a glass layer and a resin layer, comprising at least from outside to inside:
an outer inorganic glass layer, toughened glass with the thickness of 0.1mm-1.6 mm;
an intermediate resin layer which is a transparent resin material layer;
an inner protective film which is a thermoplastic film with scratch resistance and is compounded with the middle resin layer.
The invention has light weight, is anti-fragmentation, is easy to form and has light weight compared with the traditional inorganic glass; the anti-cracking performance of the glass is superior to that of the traditional inorganic glass.
On the basis of the scheme, the middle resin layer is made of polycarbonate or polymethyl methacrylate, and can also be made of other alternative materials.
On the basis of the scheme, the protective film is at least a polyethylene terephthalate (PET) film or a Thermoplastic Polyurethane (TPU) film, and is compounded with the middle resin layer into a whole through the bonding layer.
Furthermore, a transparent UV barrier layer is arranged between the inorganic glass layer and the middle resin layer.
Furthermore, the inorganic glass layer and the intermediate resin layer are directly compounded or compounded through a bonding layer.
The invention also provides a preparation method of the light composite multilayer glass, which comprises the following steps:
step one, forming a resin layer on an outer inorganic glass layer by casting or injection molding;
and step two, compounding the protective film with the resin layer through the bonding layer.
Further, in the first step, a UV blocking layer is deposited on the surface of the inorganic glass layer by spraying or magnetron sputtering, and then a resin layer is cast or injection molded on the surface of the inorganic glass layer with the UV blocking layer. Injection molding is preferred.
Further, depositing a transparent UV barrier layer on the surface of the outer inorganic glass layer in a spraying or magnetron sputtering mode;
step two, preparing an intermediate resin layer sheet by casting or injection molding;
and step three, selecting a protective film, stacking the inorganic glass layer, the intermediate resin layer and the adhesive layer among the protective film in sequence, and performing hot press molding.
The invention provides a scheme for replacing traditional inorganic toughened glass and inorganic laminated glass, which has the advantages that: the weight of the glass is lighter than that of the traditional inorganic glass; the anti-cracking performance of the glass is superior to that of the traditional inorganic glass; better manufacturability and manufacturability than the polycarbonate + hardened coating solution while retaining the lightweight characteristics of the polycarbonate solution.
Drawings
FIG. 1 is a schematic structural view of example 1;
FIG. 2 is a schematic structural view of example 2;
FIG. 3 is a schematic structural diagram of embodiment 3;
the reference numbers in the figures illustrate:
1-inorganic glass layer; 2-intermediate resin layer; 3-protective film;
4-UV blocking layer;
5-a bonding layer between the inorganic glass layer and the intermediate resin layer;
6-adhesive layer between protective film and intermediate resin layer.
Detailed Description
Example 1
A lightweight glass structure, as shown in FIG. 1, comprises, from the outside to the inside:
the outer inorganic glass layer 1 is toughened glass with the thickness of 0.1mm-1.6mm, and can be physically toughened or chemically toughened;
a transparent UV barrier layer 4 for blocking the aging action of ultraviolet rays on the intermediate resin layer 2;
an intermediate resin layer 2 made of a transparent resin material including any one of polycarbonate and polymethyl methacrylate;
an adhesive layer 6 between the protective film and the intermediate resin layer;
an inner protective film 3 for improving the scratch resistance of the intermediate resin layer, and is made of polyethylene terephthalate film (PET film) or thermoplastic polyurethane film (TPU film).
The preparation method comprises the following steps:
depositing a UV barrier layer 4 on the surface of the outer inorganic glass layer 1 in a spraying or magnetron sputtering mode;
step two, forming an intermediate resin layer 2 on the UV barrier layer of the glass treated in the step one by injection molding of a layer of resin;
and step three, selecting finished films such as a PET protective film with good light transmittance, and attaching the protective film on the middle resin layer 2 through the bonding layer to obtain the lightweight composite multilayer glass.
Example 2
A lightweight glass structure, as shown in FIG. 2, comprises, from the outside to the inside:
an outer inorganic glass layer 1 is toughened glass with the thickness of 0.1mm-1.6 mm;
a transparent UV barrier layer 4 for blocking ultraviolet rays from aging the intermediate resin layer 2;
an intermediate resin layer 2, which is a transparent resin material layer, optionally including: polycarbonate, polymethyl methacrylate and other materials are combined with the transparent UV barrier layer 4 through an adhesive layer 5 between the inorganic glass layer and the middle resin layer;
an inner protective film 3 for improving the scratch resistance of the middle resin layer, which can be made of thermoplastic material including polyethylene terephthalate (PET) and Thermoplastic Polyurethane (TPU), and is compounded with the middle resin layer 2 into a whole through a bonding layer 6 between the protective film and the middle resin layer.
This example was prepared as follows:
depositing a transparent UV barrier layer 4 on the surface of the outer inorganic glass layer 1 in a spraying or magnetron sputtering mode;
step two, preparing an intermediate resin layer 2 sheet by casting or injection molding;
and thirdly, selecting a finished protective film, stacking the outer inorganic glass layer 1 with the transparent UV barrier layer 4, the bonding layer 5 between the inorganic glass layer and the middle resin layer, the middle resin layer 2, the bonding layer 6 between the protective film and the middle resin layer and the protective film 3 in sequence, and performing hot press molding to obtain the lightweight composite multilayer glass capable of replacing the traditional inorganic toughened glass and the inorganic laminated glass.
Example 3
A lightweight glass structure, as shown in FIG. 3, comprises, from the outside to the inside:
an outer inorganic glass layer 1 is toughened glass with the thickness of 0.1mm-1.6 mm;
an intermediate resin layer 2, which is a transparent resin material layer and can be made of polycarbonate, polymethyl methacrylate and the like;
an inner protective film 3 for improving the scratch resistance of the middle resin layer, which comprises a polyethylene terephthalate film (PET film), a thermoplastic polyurethane film (TPU film) or a film material prepared from other thermoplastic materials, and is compounded with the middle resin layer 2 through a bonding layer.
The preparation method comprises the following steps:
step one, forming a resin layer on an outer inorganic glass layer 1 by casting or injection molding to form an intermediate resin layer 2;
and secondly, selecting a proper finished product protective film 3, and compounding the protective film and the middle resin layer through the bonding layer 6 between the protective film and the middle resin layer 2 to obtain the lightweight composite multilayer glass capable of replacing the traditional inorganic toughened glass and the inorganic laminated glass.
Claims (9)
1. The utility model provides a compound multiple glazing of lightweight, includes the lamellar structure of glass layer, resin layer which characterized in that: comprising at least from the outside to the inside:
an outer inorganic glass layer, toughened glass with the thickness of 0.1mm-1.6 mm;
an intermediate resin layer which is a transparent resin material layer;
an inner protective film which is a thermoplastic film with scratch resistance and is compounded with the middle resin layer.
2. The lightweight composite multiple layer glass according to claim 1, wherein said intermediate resin layer is polycarbonate or polymethyl methacrylate.
3. The lightweight composite multiple layer glass according to claim 1 or 2, wherein the protective film is at least a polyethylene terephthalate (PET) film or a Thermoplastic Polyurethane (TPU) film, and is integrally laminated with the intermediate resin layer through an adhesive layer.
4. The lightweight composite multiple layer glass according to claim 1 or 2, wherein a transparent UV blocking layer is provided between said inorganic glass layer and said intermediate resin layer.
5. The lightweight composite multiple layer glass according to claim 4, wherein said inorganic glass layer and said intermediate resin layer are directly laminated or laminated via an adhesive layer.
6. A method of making a lightweight composite multiple layer glass according to any one of claims 1 to 5, comprising the steps of:
step one, forming a resin layer on an outer inorganic glass layer by casting or injection molding;
and step two, compounding the protective film with the resin layer through the bonding layer.
7. The method for producing a lightweight composite multiple layer glass according to claim 6, wherein: in the first step, a resin layer is formed through injection molding.
8. The method for producing a lightweight composite multilayer glass according to claim 6 or 7, characterized in that:
in the first step, the UV blocking layer is deposited on the surface of the inorganic glass layer in a spraying or magnetron sputtering mode, and then a resin layer is cast or injection molded on the surface of the inorganic glass layer with the UV blocking layer.
9. The method for producing a lightweight composite multiple layer glass according to claim 8, wherein:
depositing a transparent UV barrier layer on the surface of the outer inorganic glass layer in a spraying or magnetron sputtering mode;
step two, preparing an intermediate resin layer sheet by casting or injection molding;
and step three, selecting a protective film, stacking the inorganic glass layer, the intermediate resin layer and the adhesive layer among the protective film in sequence, and performing hot press molding.
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CN1341083A (en) * | 1999-01-11 | 2002-03-20 | 肖特显示玻璃有限责任公司 | Thin glass film matrix coated with polymer |
EP1577084A1 (en) * | 2004-03-19 | 2005-09-21 | KRD Coatings GmbH | Laminated plastic glazing for vehicles |
CN103496225A (en) * | 2013-09-06 | 2014-01-08 | 天津广源新材料科技有限公司 | High-strength light-weight weather-proof type bulletproof glass |
CN104553207A (en) * | 2014-12-12 | 2015-04-29 | 中国航空工业集团公司北京航空材料研究院 | Safety glass capable of preventing splashing during breaking |
US20160354996A1 (en) * | 2015-06-03 | 2016-12-08 | Precision Glass Bending Corporation | Bent, veneer-encapsulated heat-treated safety glass panels and methods of manufacture |
CN108394149A (en) * | 2018-04-28 | 2018-08-14 | 四川大硅特玻科技有限公司 | A kind of composite intelligent dimming glass |
CN209974634U (en) * | 2019-02-25 | 2020-01-21 | 东莞市银泰玻璃有限公司 | Anti-ultraviolet sandwich glass structure |
CN212266908U (en) * | 2020-07-29 | 2021-01-01 | 上海暨奕智能科技有限公司 | Lightweight composite multilayer glass |
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