CN111744482A - High specific surface nickel loaded active carbon material - Google Patents
High specific surface nickel loaded active carbon material Download PDFInfo
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- CN111744482A CN111744482A CN202010834216.3A CN202010834216A CN111744482A CN 111744482 A CN111744482 A CN 111744482A CN 202010834216 A CN202010834216 A CN 202010834216A CN 111744482 A CN111744482 A CN 111744482A
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- activated carbon
- specific surface
- carbon material
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- catalyst
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 13
- 239000003575 carbonaceous material Substances 0.000 title description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 89
- 239000000463 material Substances 0.000 claims abstract description 24
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims abstract description 13
- 239000011976 maleic acid Substances 0.000 claims abstract description 8
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 8
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000003054 catalyst Substances 0.000 abstract description 29
- 229910052751 metal Inorganic materials 0.000 abstract description 12
- 239000002184 metal Substances 0.000 abstract description 12
- 229910052799 carbon Inorganic materials 0.000 abstract description 10
- 230000003197 catalytic effect Effects 0.000 abstract description 6
- 239000002028 Biomass Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 239000003208 petroleum Substances 0.000 abstract description 5
- 238000000197 pyrolysis Methods 0.000 abstract description 4
- 239000011148 porous material Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000009396 hybridization Methods 0.000 description 4
- 239000011363 dried mixture Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention relates to the field of activated carbon materials, in particular to a nickel-loaded activated carbon material with a high specific surface. The activated carbon material comprises the following raw materials in parts by weight: 20-40 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and NiCl20.2-4 parts of solution; the concentration of the NiCl2 solution was 130 g/l. The catalyst has a large specific surface area, so that the metal catalyst can be well dispersed, the exposure of active sites of the catalyst is increased, and the catalytic efficiency is improved; the activated carbon material is stable in itself and acts as a catalystThe carrier is more effective in evaluating the intrinsic activity of the metal catalyst. The carbon source of the activated carbon is wide, and biomass, petroleum processed products and the like which mainly contain carbon elements can be prepared into the activated carbon through pyrolysis.
Description
Technical Field
The invention relates to the field of activated carbon materials, in particular to a nickel-loaded activated carbon material with a high specific surface.
Background
With the gradual decrease of fossil fuels and the increase of environmental crisis, the production of clean hydrogen by electrochemical hydrogen evolution becomes an important alternative to fossil energy. Currently, small commercial catalyst materials are predominantly noble metal-based materials, such as Pt-based materials. Commercial use on a large scale is limited due to scarcity and high cost of precious metals. At present, a metal catalyst with low cost is urgently needed to be found to replace a noble metal catalyst, so that the cost is reduced, and the large-scale commercial production can be realized. However, the pure metal catalyst generally has poor metal particle dispersibility, which results in low catalytic activity, and the supported catalyst can well solve the problem. However, the selection of the carrier is more demanding and requires the following properties: the catalyst has the advantages of excellent conductivity, good corrosion resistance, capability of effectively improving the dispersion condition of the catalyst, and the like.
The earth reserves of carbon elements are rich, and sp exists in carbon compounds2Hybridization, sp3Hybridization, sp2And sp3Hybridization, and the like. The activated carbon is sp bonded by C ═ C2Hybridization to sp of C-C bond3The hybrid structure coexists to form a space skeleton form, and the surface area and the pore volume are directly related to the carbon structure, so that the preparation of the activated carbon material directly influences the physical and chemical properties of the activated carbon. The active carbon porous material has a large specific surface area, so that the metal catalyst can be well dispersed, the exposure of active sites of the catalyst is increased, and the catalytic efficiency is improved; the activated carbon material is stable, and can be used as a catalyst carrier to effectively evaluate the intrinsic activity of the metal catalyst. The carbon source of the activated carbon is wide, and biomass, petroleum processed products and the like which mainly contain carbon elements can be prepared into the activated carbon through pyrolysis. The biomass activated carbon has complex components and high difficulty in raw material pretreatment, so that an activated carbon catalyst with stable and efficient performance is difficult to prepare, and the environment pollution is serious when the petroleum processed products are used for preparing the activated carbon, so that the existing activated carbon cannot be used as an ideal activated carbon supported catalyst material.
Disclosure of Invention
In order to solve the technical problems described in the background art, the invention provides the nickel-loaded activated carbon material with the high specific surface area, and the nickel-loaded activated carbon material has the advantages that the metal catalyst can be well dispersed due to the large specific surface area, the exposure of the active sites of the catalyst is increased, and the catalytic efficiency is improved; the activated carbon material is stable, and can be used as a catalyst carrier to effectively evaluate the intrinsic activity of the metal catalyst. The carbon source of the activated carbon is wide, and biomass, petroleum processed products and the like which mainly contain carbon elements can be prepared into the activated carbon through pyrolysis.
The technical scheme adopted by the invention for solving the technical problems is as follows:
the high specific surface nickel-loaded activated carbon material comprises the following raw materials in parts by weight:
20-40 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and NiCl20.2-4 parts of solution;
the concentration of the NiCl2 solution was 130 g/l.
Specifically, 30-40 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and NiCl20.3-4 parts of solution.
The invention has the beneficial effects that: the invention provides a high specific surface nickel loaded activated carbon material, which has a large specific surface area, so that a metal catalyst can be well dispersed, the exposure of active sites of the catalyst is increased, and the catalytic efficiency is improved; the activated carbon material is stable, and can be used as a catalyst carrier to effectively evaluate the intrinsic activity of the metal catalyst. The carbon source of the activated carbon is wide, and biomass, petroleum processed products and the like which mainly contain carbon elements can be prepared into the activated carbon through pyrolysis.
Detailed Description
The first embodiment is as follows:
a. 20 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and 0.2 part of NiCl2The solution was put into an oil bath pan at 200 ℃ for 2 hours. NiCl2The concentration of the solution was 130 g/l.
b. Taking out the mixture in an oil bath pan, drying the mixture, putting the dried mixture in a tube furnace, and pyrolyzing the mixture for 40 minutes at 800 ℃ in a nitrogen atmosphere to obtain a product; the flow rate of nitrogen is 300 mL/min; the heating rate of the tube furnace was 50 ℃/min.
c. And (4) washing the product for three days until the washing liquid of the product is neutral, and taking out and drying to obtain the activated carbon.
The specific surface area of the high specific surface nickel-loaded activated carbon material is 832 (m)2/g-1) Total pore volume of 0.41 (cm)3/g-1) The pore volume of the micropores was 0.22 (cm)3/g-1) The proportion of the mesopore volume to the total pore volume was 0.46, and the average pore diameter was 4.36 (nm).
Example two:
a. 40 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and 4 parts of NiCl2The solution was put into an oil bath pan at 200 ℃ for 2 hours. NiCl2The concentration of the solution was 130 g/l.
b. Taking out the mixture in an oil bath pan, drying the mixture, putting the dried mixture in a tube furnace, and pyrolyzing the mixture for 40 minutes at 800 ℃ in a nitrogen atmosphere to obtain a product; the flow rate of nitrogen is 300 mL/min; the heating rate of the tube furnace was 50 ℃/min.
c. And (4) washing the product for three days until the washing liquid of the product is neutral, and taking out and drying to obtain the activated carbon.
The specific surface area of the high specific surface nickel-loaded activated carbon material is 830 (m)2/g-1) Total pore volume of 0.39 (cm)3/g-1) The pore volume of the micropores was 0.19 (cm)3/g-1) The proportion of the mesopore volume to the total pore volume was 0.44, and the average pore diameter was 4.22 (nm).
Example three:
a. 30 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and 0.3 part of NiCl2The solution was put into an oil bath pan at 200 ℃ for 2 hours. NiCl2The concentration of the solution was 130 g/l.
b. Taking out the mixture in an oil bath pan, drying the mixture, putting the dried mixture in a tube furnace, and pyrolyzing the mixture for 40 minutes at 800 ℃ in a nitrogen atmosphere to obtain a product; the flow rate of nitrogen is 300 mL/min; the heating rate of the tube furnace was 50 ℃/min.
c. And (4) washing the product for three days until the washing liquid of the product is neutral, and taking out and drying to obtain the activated carbon.
The specific surface area of the high specific surface nickel-loaded activated carbon material is 835 (m)2/g-1) Total pore volume of 0.44 (cm)3/g-1) The pore volume of the micropores was 0.25 (cm)3/g-1) The proportion of the mesopore volume in the total pore volume was 0.49, and the average pore diameter was 4.50 (nm).
The high-specific-surface nickel-loaded activated carbon material has a large specific surface area, so that a metal catalyst can be well dispersed, the exposure of active sites of the catalyst is increased, and the catalytic efficiency is improved; the activated carbon material is stable, and can be used as a catalyst carrier to effectively evaluate the intrinsic activity of the metal catalyst.
In light of the foregoing description of the preferred embodiment of the present invention, many modifications and variations will be apparent to those skilled in the art without departing from the spirit and scope of the invention. The technical scope of the present invention is not limited to the content of the specification, and must be determined according to the scope of the claims.
Claims (2)
1. The high specific surface nickel-loaded activated carbon material is characterized by comprising the following raw materials in parts by weight:
20-40 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and 0.2-4 parts of NiCl2 solution;
the concentration of the NiCl2 solution was 130 g/l.
2. The high specific surface nickel-supported activated carbon material as claimed in claim 1, wherein 30-40 parts of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt and NiCl are added20.3-4 parts of solution.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2020107340974 | 2020-07-27 | ||
| CN202010734097 | 2020-07-27 |
Publications (1)
| Publication Number | Publication Date |
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| CN111744482A true CN111744482A (en) | 2020-10-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202010834216.3A Withdrawn CN111744482A (en) | 2020-07-27 | 2020-08-19 | High specific surface nickel loaded active carbon material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113877527A (en) * | 2021-10-13 | 2022-01-04 | 江苏众志新禹环境科技有限公司 | Nickel loaded activated carbon material |
-
2020
- 2020-08-19 CN CN202010834216.3A patent/CN111744482A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113877527A (en) * | 2021-10-13 | 2022-01-04 | 江苏众志新禹环境科技有限公司 | Nickel loaded activated carbon material |
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Application publication date: 20201009 |