CN111719131A - Production process of variable-thickness steel plate with coating - Google Patents

Production process of variable-thickness steel plate with coating Download PDF

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Publication number
CN111719131A
CN111719131A CN201910219841.4A CN201910219841A CN111719131A CN 111719131 A CN111719131 A CN 111719131A CN 201910219841 A CN201910219841 A CN 201910219841A CN 111719131 A CN111719131 A CN 111719131A
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CN
China
Prior art keywords
thickness
steel coil
variable
continuously variable
cold
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Pending
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CN201910219841.4A
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Chinese (zh)
Inventor
熊斐
李山青
汪义如
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Baoshan Iron and Steel Co Ltd
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Baoshan Iron and Steel Co Ltd
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Priority to CN201910219841.4A priority Critical patent/CN111719131A/en
Publication of CN111719131A publication Critical patent/CN111719131A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • C23C14/562Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks for coating elongated substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/54Controlling or regulating the coating process
    • C23C14/542Controlling the film thickness or evaporation rate

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

The invention discloses a production process of a variable-thickness steel plate with a coating, which comprises the steps of firstly, continuously changing the thickness of a hot-rolled/cold-rolled steel coil with the same thickness to obtain a continuously variable-thickness cold-rolled steel coil, then conveying the continuously variable-thickness cold-rolled steel coil to a continuous vacuum plating unit for vacuum coating to obtain the continuously variable-thickness steel coil with the coating, and finally delivering the continuously variable-thickness steel coil to a user; or the constant-thickness hot-rolled/cold-rolled steel coil is continuously rolled in variable thickness to obtain a continuously variable-thickness cold-rolled steel coil, the continuously variable-thickness cold-rolled steel coil is subjected to heat treatment, the continuously variable-thickness cold-rolled steel coil subjected to heat treatment is sent to a continuous vacuum plating unit for vacuum coating to obtain the continuously variable-thickness steel coil with the coating, and finally the continuously variable-thickness steel coil is delivered to a user. The method can avoid the problems of the prior art and efficiently and economically obtain the variable-thickness steel coil with the coating.

Description

Production process of variable-thickness steel plate with coating
Technical Field
The invention relates to a production technology of a variable-thickness steel plate, in particular to a production process of a variable-thickness steel plate with a coating.
Background
In order to reduce carbon emission, it is required to reduce the weight of an automobile as much as possible while securing strength, and continuously variable thickness steel sheets have been accepted by users due to their unique advantages and are increasingly demanded. For the purpose of corrosion protection, it is necessary to subject the continuously variable thickness steel sheet to a coating treatment. There are several treatment methods at present:
1) coating the coiled strip steel by a hot-dip or electroplating unit:
as in patent publication No. CN103806029A, after the thickness-variable rolling, the strip is subjected to electroplating, after which an alloying treatment is carried out, after which the user is submitted to a forming treatment. In the patent publication No. CN102712961, hot-rolled incoming materials are subjected to unequal-thickness rolling, then recrystallization annealing, electroplating and alloying treatment are carried out.
2) The coated equal-thickness strip steel is subjected to thickness-variable rolling to obtain the strip steel with the coating layer with the variable thickness:
for example, in patent publication No. CN101796210B, hot-rolled strip steel is hot-dip galvanized or hot-dip aluminized, then continuously rolled in variable thickness, and then the sheet material required by the user is cut from the coil as required. In contrast, U.S. Pat. No. US8522586B2 proposes hot-dipping or electroplating of a hot-rolled or cold-rolled incoming material, followed by unequal-thickness rolling and subsequent processing.
3) After the strip steel is cut or blanked, the cut (blanked) steel plate is subjected to single-piece electroplating treatment.
However, the above treatments have their own disadvantages:
firstly, whether electroplating or hot-dip plating is carried out, the requirement of unit control on the thickness uniformity of strip steel is high, namely the distance between an air knife and the strip steel during hot-dip plating directly influences the thickness of a plating layer, and if the thickness of the strip steel changes frequently and the thickness difference is large, the thickness of the plating layer is likely to be uneven; during electroplating, if the lengths of all equal-thickness sections of the strip steel are short and the thickness difference between the equal-thickness sections is large, the conductive roller can frequently jump, and the risk of burning the conductive roller is brought.
Secondly, the method of coating a single steel sheet is inefficient, costly and also affected by the size of the bath.
Furthermore, if the coating is applied and then rolled, the rolling process will damage the surface of the coating, which reduces the corrosion protection effect of the material.
Finally, there is often user feedback that the hydrogen embrittlement probability of the strip coating thickened plate after hot forming is higher than that of a strip coating equal-thickness plate, which is probably caused by the intrusion of hydrogen elements introduced during electroplating and hot-dipping into the strip steel substrate through the coating damaged during rolling.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a production process of a variable-thickness steel plate with a coating, which can avoid the problems of the prior art and efficiently and economically obtain the variable-thickness steel coil with the coating.
In order to achieve the purpose, the invention adopts the following technical scheme:
a production process of a variable-thickness steel plate with a coating comprises the following steps:
firstly, continuously variable-thickness rolling is carried out on an equal-thickness hot-rolled/cold-rolled steel coil to obtain a continuously variable-thickness cold-rolled steel coil, then the continuously variable-thickness cold-rolled steel coil is sent to a continuous vacuum plating unit for vacuum coating to obtain a continuously variable-thickness steel coil with a plating layer, and finally the continuously variable-thickness steel coil is delivered to a user; or
The method comprises the steps of firstly, continuously changing the thickness of a hot-rolled/cold-rolled steel coil with the same thickness to obtain a continuously variable-thickness cold-rolled steel coil, then carrying out heat treatment on the continuously variable-thickness cold-rolled steel coil, then sending the continuously variable-thickness cold-rolled steel coil after the heat treatment to a continuous vacuum plating unit for vacuum coating to obtain the continuously variable-thickness steel coil with a plating layer, and finally delivering the continuously variable-thickness steel coil to a user.
After the continuous variable-thickness steel coil with the coating is obtained, the steel coil can be subjected to a leveling procedure and finally delivered to a user.
The heat treatment is continuous annealing treatment or cover annealing treatment.
The heat treatment is cover annealing treatment, and then a steel coil needs to be leveled.
The continuous vacuum plating unit comprises an inlet vacuum lock, a pretreatment chamber, a vacuum deposition chamber, an outlet preparation chamber and an outlet vacuum lock.
The vacuum deposition chamber uses a physical Vapor deposition (PVD for short) mode, and can be thermal evaporation (resistance, induction heating or electron beam heating) plating or ion plating (cathode arc or magnetron sputtering).
The production process of the steel plate with the coating and with the variable thickness can conveniently solve the production problem of the steel plate with the coating and with the variable thickness, can efficiently obtain the steel coil with the uniform coating and with the variable thickness, and also avoids introducing hydrogen in the coating process and increasing the risk of hydrogen embrittlement. Meanwhile, the invention is not sensitive to the thickness change of the strip steel in the process, can obtain a more uniform coating, adopts the process of rolling first and then coating, prevents the coating from being damaged, and ensures that the strip steel has excellent anti-corrosion performance. In addition, the invention is deposited in a vacuum mode, no extra chemical is added, zero emission can be realized, the invention has great environmental protection advantage, no hydrogen element is introduced in the coating process, and the risk of hydrogen embrittlement in the later period is reduced.
Drawings
FIG. 1 is a flow chart of the production process of the present invention;
FIG. 2 is a schematic view of a continuous variable thickness cold rolled steel coil according to an embodiment of the present invention;
FIG. 3 is a schematic view of a second continuous variable thickness cold rolled steel coil according to an embodiment of the present invention.
Detailed Description
The technical scheme of the invention is further explained by combining the drawings and the embodiment.
Referring to fig. 1, the process for producing a plated variable thickness steel sheet according to the present invention includes:
1) continuously variable-thickness cold-rolled steel coils are obtained by continuously variable-thickness rolling the hot-rolled pickling coils or the cold-rolled steel coils with the same thickness, namely the strip steel has periodic thickness variation in the rolling direction;
2) carrying out heat treatment on the continuously variable-thickness cold-rolled steel coil, wherein the heat treatment mode can be continuous annealing or cover annealing;
3) flattening the steel coil subjected to the cover annealing treatment;
4) sending the flattened continuous variable-thickness steel coil into a continuous vacuum plating unit for vacuum coating (PVD, also called physical vapor deposition) to obtain a continuous variable-thickness steel coil with a plating layer;
5) according to the requirements of users, the continuous variable-thickness steel coil after vacuum plating can be selected to be leveled or uneven and then directly delivered to the users.
The steps are the technological process of producing the coating variable-thickness steel coil, and according to the actual situation, the continuously variable-thickness cold-rolled steel coil which is subjected to heat treatment or the continuously variable-thickness hard-rolled steel coil which is not subjected to heat treatment can be directly selected as the raw material to be sent into a continuous vacuum plating unit for coating treatment.
Example one
A hot rolled pickled coil of 2.2mm thickness of DP590 steel grade was selected and subjected to continuous thickness-variable rolling to obtain a cold rolled hard coil having a set thickness distribution (1.2mm/1.5mm/1.8mm), after rolling the thickness and length dimensions as shown in FIG. 2.
And then introducing the steel coil into a continuous annealing unit for heat treatment. The leveling machines are uniformly arranged in the continuous annealing unit, so that the strip steel subjected to continuous annealing treatment has a good plate shape and can be directly subjected to coating treatment.
The strip steel enters a continuous vacuum plating unit, and can be selected to be leveled or not after passing through an inlet vacuum lock, a pretreatment chamber, a vacuum deposition chamber, an outlet preparation chamber and an outlet vacuum lock, and then is coiled.
Example two
A hot-rolled pickled coil of 2.6mm in thickness of HC340LA steel was selected and subjected to continuous thickness-variable rolling to obtain a cold-rolled hard coil having a set thickness distribution (2.0mm/1.0mm), and the thickness and length dimensions after rolling were as shown in FIG. 3.
Then, the steel coil is placed in a bell type furnace for heat treatment.
After the steel coil is discharged from the furnace, the steel coil is sent into a leveling machine for leveling so as to improve the plate shape and the mechanical property.
The strip steel after being leveled enters a continuous vacuum plating unit, and is selectively leveled or not after passing through an inlet vacuum lock, a pretreatment chamber, a vacuum deposition chamber, an outlet preparation chamber and an outlet vacuum lock, and then is coiled.
In summary, the production process of the steel plate with the coating and the variable thickness adopts a Physical Vapor Deposition (PVD) mode to deposit the coating material on the steel coil with the variable thickness to be coated. Namely, the strip steel with different thicknesses in the longitudinal direction is introduced into a vacuum plating unit, and plating material vapor or ions are deposited on the clean strip steel in a vacuum environment to form a uniform plating layer.
It should be understood by those skilled in the art that the above embodiments are only for illustrating the present invention and are not to be used as a limitation of the present invention, and that changes and modifications to the above described embodiments are within the scope of the claims of the present invention as long as they are within the spirit and scope of the present invention.

Claims (7)

1. The production process of the variable-thickness steel plate with the coating is characterized by comprising the following steps of: comprises that
Firstly, continuously variable-thickness rolling is carried out on an equal-thickness hot-rolled/cold-rolled steel coil to obtain a continuously variable-thickness cold-rolled steel coil, then the continuously variable-thickness cold-rolled steel coil is sent to a continuous vacuum plating unit for vacuum coating to obtain a continuously variable-thickness steel coil with a plating layer, and finally the continuously variable-thickness steel coil is delivered to a user; or
The method comprises the steps of firstly, continuously changing the thickness of a hot-rolled/cold-rolled steel coil with the same thickness to obtain a continuously variable-thickness cold-rolled steel coil, then carrying out heat treatment on the continuously variable-thickness cold-rolled steel coil, then sending the continuously variable-thickness cold-rolled steel coil after the heat treatment to a continuous vacuum plating unit for vacuum coating to obtain the continuously variable-thickness steel coil with a plating layer, and finally delivering the continuously variable-thickness steel coil to a user.
2. The process for producing a coated variable thickness steel sheet as claimed in claim 1, wherein: after the continuous variable-thickness steel coil with the coating is obtained, the steel coil can be subjected to a leveling procedure and finally delivered to a user.
3. The process for producing a coated variable thickness steel sheet as claimed in claim 1, wherein: the heat treatment is continuous annealing treatment or cover annealing treatment.
4. The process for producing a coated variable thickness steel sheet as claimed in claim 3, wherein: the heat treatment is cover annealing treatment, and then a steel coil needs to be leveled.
5. The process for producing a coated variable thickness steel sheet as claimed in claim 1, wherein: the continuous vacuum plating unit comprises an inlet vacuum lock, a pretreatment chamber, a vacuum deposition chamber, an outlet preparation chamber and an outlet vacuum lock.
6. The process for producing a coated variable thickness steel sheet as claimed in claim 5, wherein: the vacuum deposition chamber adopts a physical vapor deposition mode.
7. The process for producing a coated variable thickness steel sheet as claimed in claim 6, wherein: the physical vapor deposition mode is thermal evaporation or ion plating.
CN201910219841.4A 2019-03-22 2019-03-22 Production process of variable-thickness steel plate with coating Pending CN111719131A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114226455A (en) * 2021-12-09 2022-03-25 苏州东宝海星金属材料科技有限公司 Method for controlling thickness of Al-based alloy coating of plate strip

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63171871A (en) * 1987-01-09 1988-07-15 Nisshin Steel Co Ltd Production of high strength steel plated with zinc by vapor deposition
KR20060090804A (en) * 2003-09-05 2006-08-16 산드빅 인터렉츄얼 프로퍼티 에이비 A stainless steel strip coated with aluminium
CN102712961A (en) * 2009-11-03 2012-10-03 沃斯特阿尔派因钢铁有限责任公司 Manufacturing galvannealed sheets by heat-treating electrolytically finished sheets
US20140134450A1 (en) * 2012-11-14 2014-05-15 Muhr Und Bender Kg Method for Manufacturing a Product from a Flexibly Rolled Strip Material
CN105887085A (en) * 2016-04-22 2016-08-24 武汉钢铁股份有限公司 Production method of ultra-thin steel belt plated with precious metal
CN105925775A (en) * 2016-07-08 2016-09-07 武汉钢铁股份有限公司 Production method of corrosion-resistance decorative composite plating steel strip of which thickness is less than or equal to 0.1mm
CN106555144A (en) * 2015-09-30 2017-04-05 宝山钢铁股份有限公司 The hot galvanized layer thickness control system of continuous variable thickness band and method
CN106624651A (en) * 2016-12-27 2017-05-10 宝山钢铁股份有限公司 Variable-thickness proximate matter production method and production line
CN106623421A (en) * 2016-12-27 2017-05-10 上海宝钢型钢有限公司 Continuous production method and line for variable-thickness profile

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63171871A (en) * 1987-01-09 1988-07-15 Nisshin Steel Co Ltd Production of high strength steel plated with zinc by vapor deposition
KR20060090804A (en) * 2003-09-05 2006-08-16 산드빅 인터렉츄얼 프로퍼티 에이비 A stainless steel strip coated with aluminium
CN102712961A (en) * 2009-11-03 2012-10-03 沃斯特阿尔派因钢铁有限责任公司 Manufacturing galvannealed sheets by heat-treating electrolytically finished sheets
US20140134450A1 (en) * 2012-11-14 2014-05-15 Muhr Und Bender Kg Method for Manufacturing a Product from a Flexibly Rolled Strip Material
CN106555144A (en) * 2015-09-30 2017-04-05 宝山钢铁股份有限公司 The hot galvanized layer thickness control system of continuous variable thickness band and method
CN105887085A (en) * 2016-04-22 2016-08-24 武汉钢铁股份有限公司 Production method of ultra-thin steel belt plated with precious metal
CN105925775A (en) * 2016-07-08 2016-09-07 武汉钢铁股份有限公司 Production method of corrosion-resistance decorative composite plating steel strip of which thickness is less than or equal to 0.1mm
CN106624651A (en) * 2016-12-27 2017-05-10 宝山钢铁股份有限公司 Variable-thickness proximate matter production method and production line
CN106623421A (en) * 2016-12-27 2017-05-10 上海宝钢型钢有限公司 Continuous production method and line for variable-thickness profile

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114226455A (en) * 2021-12-09 2022-03-25 苏州东宝海星金属材料科技有限公司 Method for controlling thickness of Al-based alloy coating of plate strip
CN114226455B (en) * 2021-12-09 2024-03-26 苏州东宝海星金属材料科技有限公司 Method for controlling thickness of Al-based alloy coating of strip

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Application publication date: 20200929