CN111718695A - Production method of anti-freezing solution for hydraulic support - Google Patents

Production method of anti-freezing solution for hydraulic support Download PDF

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CN111718695A
CN111718695A CN202010726108.4A CN202010726108A CN111718695A CN 111718695 A CN111718695 A CN 111718695A CN 202010726108 A CN202010726108 A CN 202010726108A CN 111718695 A CN111718695 A CN 111718695A
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stock solution
solution
inhibitor
proportion
ethylene glycol
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丁峨
葛敏
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Huaibei Jinling Petrochemical Co ltd
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Huaibei Jinling Petrochemical Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/20Antifreeze additives therefor, e.g. for radiator liquids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083Inorganic acids or salts thereof containing nitrogen nitrites
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046Hydroxy ethers
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/18Containing nitrogen-to-nitrogen bonds, e.g. hydrazine
    • C10M2215/182Azo compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents

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Abstract

The invention discloses a production method of an antifreezing solution for a hydraulic support, which relates to the technical field of antifreezing solution production, and comprises the following steps of S1, preparing deionized water and ethylene glycol, and adding the deionized water, the ethylene glycol and metasilicate into a container in proportion, wherein the adding proportion is 30-50%: 40-60%: 5% -10%, stirring and shaking up, standing for 20 minutes at normal temperature to form primary stock solution; s2, taking out 10ml of the prepared primary stock solution for detecting the pH and the ion concentration of the solution, taking out a certain amount of the primary stock solution, and adding a preservative, a corrosion inhibitor, a scale inhibitor, a pour inhibitor, an odor inhibitor and a thickening inhibitor into the taken-out primary stock solution. According to the invention, the proportion of the glycol to the deionized water is proper, so that the proportion of other reagents added into the antifreeze is low, the manufacturing cost of the product can be reduced, the efficient preparation of the product is facilitated, the freezing point can be reduced, and the market competitiveness of the product is improved.

Description

Production method of anti-freezing solution for hydraulic support
Technical Field
The invention relates to the technical field of antifreeze solution production, in particular to a production method of an antifreeze solution for a hydraulic support.
Background
The antifreeze liquid is called antifreeze coolant, which means coolant with antifreeze function. The antifreeze can prevent the coolant from freezing to burst the radiator and freeze the engine cylinder block or cover when the vehicle is stopped in cold winter.
During production of the existing antifreeze, due to the fact that multiple auxiliary reagents need to be added, the overall production cost of the antifreeze is high, and the antifreeze is not beneficial to production requirements of enterprises.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides a production method of an antifreezing solution for a hydraulic bracket.
In order to achieve the purpose, the invention adopts the following technical scheme:
a production method of anti-freezing solution for a hydraulic support comprises the following steps:
s1, preparing deionized water and ethylene glycol, and adding the deionized water, the ethylene glycol and the metasilicate into a container according to the proportion of 30% -50%: 40-60%: 5% -10%, stirring and shaking up, standing for 20 minutes at normal temperature to form primary stock solution;
s2, taking out 10ml of the prepared primary stock solution for detecting the pH and the ion concentration of the solution, taking out a certain amount of the primary stock solution, and adding a preservative, a corrosion inhibitor, a scale inhibitor, a pour inhibitor, an odor inhibitor and a thickening inhibitor into the taken-out primary stock solution in a proportion of 90%: 2%: 2%: 2%: 2%: 1%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form secondary stock solution;
s3, taking out a certain amount of secondary stock solution, and adding the foam breaking agent, the coloring agent and the sterilization and mildew preventive into the secondary stock solution in proportion, wherein the addition proportion is 95%: 2%: 2%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form three times of stock solution;
and S4, performing pH detection on the third stock solution, and adding a pH regulator into the third stock solution according to the pH until the pH of the third stock solution reaches 7 to form the final antifreezing solution.
Preferably, the preservative is one or more of carbazone, 1, 2-hexanediol and ethylene glycol phenyl ether, the corrosion inhibitor is one or more of borax, phosphate, nitrite, nitrate and molybdate, and the scale inhibitor is one or more of phosphate and chlorate.
Preferably, the foam reducing agent uses one or more of alkyl nonionic surfactants, glycerol ethers, alcohols and silicones.
Preferably, the colorant is selected from one of methyl red, phenol red and methylene blue.
Preferably, the bactericidal mildewcide is sodium benzoate.
Preferably, the PH adjuster is one or more of organic amines, phosphates, and phosphates.
According to the invention, the proportion of the glycol to the deionized water is proper, so that the proportion of other reagents added into the antifreeze is low, the manufacturing cost of the product can be reduced, the efficient preparation of the product is facilitated, the freezing point can be reduced, and the market competitiveness of the product is improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
Example one
A production method of anti-freezing solution for a hydraulic support comprises the following steps:
s1, preparing deionized water and ethylene glycol, and adding the deionized water, the ethylene glycol and the metasilicate into a container in a ratio of 40%: 50%: stirring and shaking up 10 percent, standing for 20 minutes at normal temperature to form primary stock solution;
s2, taking out 10ml of the prepared primary stock solution for detecting the pH and the ion concentration of the solution, taking out a certain amount of the primary stock solution, and adding a preservative, a corrosion inhibitor, a scale inhibitor, a pour inhibitor, an odor inhibitor and a thickening inhibitor into the taken-out primary stock solution in a proportion of 90%: 2%: 2%: 2%: 2%: 1%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form secondary stock solution;
s3, taking out a certain amount of secondary stock solution, and adding the foam breaking agent, the coloring agent and the sterilization and mildew preventive into the secondary stock solution in proportion, wherein the addition proportion is 95%: 2%: 2%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form three times of stock solution;
and S4, performing pH detection on the third stock solution, and adding a pH regulator into the third stock solution according to the pH until the pH of the third stock solution reaches 7 to form the final antifreezing solution.
The preservative is one or more of carbazone, 1, 2-hexanediol and ethylene glycol phenyl ether, the corrosion inhibitor is one or more of borax, phosphate, nitrite, nitrate and molybdate, the scale inhibitor is one or more of phosphate and chlorate, the foam suppressor uses one or more of alkyl nonionic surfactant, one or more of rotary glyceryl ether, alcohol and silicone, the colorant is one of methyl red, phenol red and methylene blue, the sterilization and mildew preventive is sodium benzoate, and the pH regulator is one or more of organic amine, phosphate and phosphate.
Example two
A production method of anti-freezing solution for a hydraulic support comprises the following steps:
s1, preparing deionized water and ethylene glycol, and adding the deionized water, the ethylene glycol and the metasilicate into the container in proportion, wherein the adding proportion is 42%: 52%: 8 percent, stirring and shaking evenly, standing for 20 minutes at normal temperature to form primary stock solution;
s2, taking out 10ml of the prepared primary stock solution for detecting the pH and the ion concentration of the solution, taking out a certain amount of the primary stock solution, and adding a preservative, a corrosion inhibitor, a scale inhibitor, a pour inhibitor, an odor inhibitor and a thickening inhibitor into the taken-out primary stock solution in a proportion of 90%: 2%: 2%: 2%: 2%: 1%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form secondary stock solution;
s3, taking out a certain amount of secondary stock solution, and adding the foam breaking agent, the coloring agent and the sterilization and mildew preventive into the secondary stock solution in proportion, wherein the addition proportion is 95%: 2%: 2%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form three times of stock solution;
and S4, performing pH detection on the third stock solution, and adding a pH regulator into the third stock solution according to the pH until the pH of the third stock solution reaches 7 to form the final antifreezing solution.
The preservative is one or more of carbazone, 1, 2-hexanediol and ethylene glycol phenyl ether, the corrosion inhibitor is one or more of borax, phosphate, nitrite, nitrate and molybdate, the scale inhibitor is one or more of phosphate and chlorate, the foam suppressor uses one or more of alkyl nonionic surfactant, one or more of rotary glyceryl ether, alcohol and silicone, the colorant is one of methyl red, phenol red and methylene blue, the sterilization and mildew preventive is sodium benzoate, and the pH regulator is one or more of organic amine, phosphate and phosphate.
EXAMPLE III
A production method of anti-freezing solution for a hydraulic support comprises the following steps:
s1, preparing deionized water and ethylene glycol, and adding the deionized water, the ethylene glycol and the metasilicate into a container in a ratio of 44%: 55%: 1 percent, stirring and shaking evenly, standing for 20 minutes at normal temperature to form primary stock solution;
s2, taking out 10ml of the prepared primary stock solution for detecting the pH and the ion concentration of the solution, taking out a certain amount of the primary stock solution, and adding a preservative, a corrosion inhibitor, a scale inhibitor, a pour inhibitor, an odor inhibitor and a thickening inhibitor into the taken-out primary stock solution in a proportion of 90%: 2%: 2%: 2%: 2%: 1%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form secondary stock solution;
s3, taking out a certain amount of secondary stock solution, and adding the foam breaking agent, the coloring agent and the sterilization and mildew preventive into the secondary stock solution in proportion, wherein the addition proportion is 95%: 2%: 2%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form three times of stock solution;
and S4, performing pH detection on the third stock solution, and adding a pH regulator into the third stock solution according to the pH until the pH of the third stock solution reaches 7 to form the final antifreezing solution.
The preservative is one or more of carbazone, 1, 2-hexanediol and ethylene glycol phenyl ether, the corrosion inhibitor is one or more of borax, phosphate, nitrite, nitrate and molybdate, the scale inhibitor is one or more of phosphate and chlorate, the foam suppressor uses one or more of alkyl nonionic surfactant, one or more of rotary glyceryl ether, alcohol and silicone, the colorant is one of methyl red, phenol red and methylene blue, the sterilization and mildew preventive is sodium benzoate, and the pH regulator is one or more of organic amine, phosphate and phosphate.
Example four
A production method of anti-freezing solution for a hydraulic support comprises the following steps:
s1, preparing deionized water and ethylene glycol, and adding the deionized water, the ethylene glycol and the metasilicate into the container in proportion, wherein the adding proportion is 37%: 59%: 4 percent, stirring and shaking evenly, standing for 20 minutes at normal temperature to form primary stock solution;
s2, taking out 10ml of the prepared primary stock solution for detecting the pH and the ion concentration of the solution, taking out a certain amount of the primary stock solution, and adding a preservative, a corrosion inhibitor, a scale inhibitor, a pour inhibitor, an odor inhibitor and a thickening inhibitor into the taken-out primary stock solution in a proportion of 90%: 2%: 2%: 2%: 2%: 1%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form secondary stock solution;
s3, taking out a certain amount of secondary stock solution, and adding the foam breaking agent, the coloring agent and the sterilization and mildew preventive into the secondary stock solution in proportion, wherein the addition proportion is 95%: 2%: 2%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form three times of stock solution;
and S4, performing pH detection on the third stock solution, and adding a pH regulator into the third stock solution according to the pH until the pH of the third stock solution reaches 7 to form the final antifreezing solution.
The preservative is one or more of carbazone, 1, 2-hexanediol and ethylene glycol phenyl ether, the corrosion inhibitor is one or more of borax, phosphate, nitrite, nitrate and molybdate, the scale inhibitor is one or more of phosphate and chlorate, the foam suppressor uses one or more of alkyl nonionic surfactant, one or more of rotary glyceryl ether, alcohol and silicone, the colorant is one of methyl red, phenol red and methylene blue, the sterilization and mildew preventive is sodium benzoate, and the pH regulator is one or more of organic amine, phosphate and phosphate.
Different ratios of ethylene glycol to deionized water form different freezing points:
de-ionized water/%) Ethylene glycol/%) Freezing point/. degree.C
40 50 -30℃
42 52 -32℃
44 55 -29℃
37 59 -45℃
In summary, it can be seen from the comparison of the data that the ratio of ethylene glycol to deionized water is 59%: when the concentration is 37%, the freezing point of the antifreeze reaches the maximum, the proportion is the optimal proportion, and the proportion of other reagents added into the antifreeze is low, so that the manufacturing cost of the product can be reduced, and the efficient preparation of the product is facilitated.
The function of adding the foam reducing agent into the antifreeze liquid is as follows: as the automobile engine inevitably vibrates in the running process, air enters the antifreeze solution to generate certain foam. This affects the heat transfer. And a proper amount of defoaming agent is added into the antifreeze, and when the concentration of the defoaming agent reaches a certain amount, a defoaming effect can be achieved. The antifreezing solution is added with a nontoxic water-soluble colorant for the following functions: the addition of the water-soluble colorant facilitates the observation of the pH value change of the antifreeze. If the observed color does not match the indicating color, the antifreezing agent is acidic, and the acidity does not play a role in preventing freezing and rust. The function of adding the sterilization mildew preventive into the antifreeze fluid is as follows: because microorganisms are easy to generate in the process of storing the antifreeze, a small amount of sterilization and mildew-proof agent is required to be added in order to inhibit the growth of the microorganisms and prevent the antifreeze from mildewing and deteriorating, so that the antifreeze is prevented from mildewing in the storage period of 2-3 years. As the PH value of the antifreeze can be reduced and the medium can be changed into acid in the working process, the PH value can be controlled within a certain range by adding the corrosion inhibitor.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (6)

1. A production method of anti-freezing solution for a hydraulic support comprises the following steps:
s1, preparing deionized water and ethylene glycol, and adding the deionized water, the ethylene glycol and the metasilicate into a container according to the proportion of 30% -50%: 40-60%: 5% -10%, stirring and shaking up, standing for 20 minutes at normal temperature to form primary stock solution;
s2, taking out 10ml of the prepared primary stock solution for detecting the pH and the ion concentration of the solution, taking out a certain amount of the primary stock solution, and adding a preservative, a corrosion inhibitor, a scale inhibitor, a pour inhibitor, an odor inhibitor and a thickening inhibitor into the taken-out primary stock solution in a proportion of 90%: 2%: 2%: 2%: 2%: 1%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form secondary stock solution;
s3, taking out a certain amount of secondary stock solution, and adding the foam breaking agent, the coloring agent and the sterilization and mildew preventive into the secondary stock solution in proportion, wherein the addition proportion is 95%: 2%: 2%: 1 percent, stirring and shaking up, standing for 20 minutes at normal temperature to form three times of stock solution;
and S4, performing pH detection on the third stock solution, and adding a pH regulator into the third stock solution according to the pH until the pH of the third stock solution reaches 7 to form the final antifreezing solution.
2. The method for producing antifreeze solution for hydraulic brackets according to claim 1, wherein said preservative is one or more of Kathon, 1, 2-hexanediol and ethylene glycol phenyl ether, said corrosion inhibitor is one or more of borax, phosphate, nitrite, nitrate and molybdate, and said scale inhibitor is one or more of phosphate and chlorate.
3. The method for producing antifreeze solution for hydraulic brackets according to claim 1, wherein said antifoaming agent uses one or more of alkyl nonionic surfactants, rotary glyceryl ethers, alcohols and silicones.
4. The method for producing antifreeze solution for hydraulic brackets according to claim 1, wherein said coloring agent is one selected from the group consisting of methyl red, phenol red and methylene blue.
5. The method for producing the antifreeze solution for hydraulic brackets according to claim 1, wherein said bactericidal and fungicidal agent is selected from sodium benzoate.
6. The method for producing antifreeze solution for hydraulic brackets according to claim 1, wherein said PH adjuster is one or more of organic amines, phosphates and phosphates.
CN202010726108.4A 2020-07-25 2020-07-25 Production method of anti-freezing solution for hydraulic support Pending CN111718695A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115404119A (en) * 2022-08-23 2022-11-29 煤炭科学技术研究院有限公司 Hydraulic support antifreeze fluid composite additive and preparation method and application thereof

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CN101747871A (en) * 2008-12-13 2010-06-23 温晋中 Formula for preparing antifreezing fluid of engine
CN103666389A (en) * 2013-09-30 2014-03-26 安阳化学工业集团有限责任公司 Engine cooling liquid prepared by utilizing coal ethylene glycol waste
CN103666738A (en) * 2013-12-06 2014-03-26 华阳新兴科技(天津)集团有限公司 Environment-friendly hydraulic support antifreeze fluid and preparation method thereof
CN104031620A (en) * 2014-07-02 2014-09-10 宝捷润滑油镇江有限公司 Anti-boiling, anti-scale and anti-freeze solution and preparation method thereof
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