CN111718548A - Novel wood-plastic composite material - Google Patents

Novel wood-plastic composite material Download PDF

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Publication number
CN111718548A
CN111718548A CN202010797849.1A CN202010797849A CN111718548A CN 111718548 A CN111718548 A CN 111718548A CN 202010797849 A CN202010797849 A CN 202010797849A CN 111718548 A CN111718548 A CN 111718548A
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China
Prior art keywords
parts
plastic composite
composite material
wood
powder
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Pending
Application number
CN202010797849.1A
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Chinese (zh)
Inventor
谢丹峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Dongfeng Wood Plastic Products Co ltd
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Fujian Dongfeng Wood Plastic Products Co ltd
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Application filed by Fujian Dongfeng Wood Plastic Products Co ltd filed Critical Fujian Dongfeng Wood Plastic Products Co ltd
Priority to CN202010797849.1A priority Critical patent/CN111718548A/en
Publication of CN111718548A publication Critical patent/CN111718548A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a novel wood-plastic composite material which comprises the following components in parts by weight: 40-60 parts of PVC powder, 40-60 parts of heavy calcium powder, 10-20 parts of talcum powder, 12-20 parts of wood powder, 1.5-3.5 parts of stabilizer, 3-6 parts of modifier, 0.5-2 parts of acrylate, 0.1-1 part of internal lubricant and 0.2-0.7 part of external lubricant. The novel wood-plastic composite material disclosed by the invention has excellent performances in static bending strength, impact resistance and the like.

Description

Novel wood-plastic composite material
Technical Field
The invention relates to a wood-plastic composite material, in particular to a novel wood-plastic composite material.
Background
The wood-plastic composite material is a novel environment-friendly composite material and has attracted wide attention at home and abroad in recent years. In general, the plate or the section is produced by mixing thermoplastic plastics such as polyethylene, polypropylene and polyvinyl chloride with plant fibers such as wood flour, rice hulls and straws and then carrying out plastic processing technologies such as extrusion, injection molding and mould pressing. The wood-plastic composite material has the advantages of both wood and plastic. The wood-plastic composite material has the appearance similar to natural wood, overcomes the defects, has the advantages of corrosion resistance, moisture resistance, moth prevention, high dimensional stability and the like, has higher hardness than pure plastic, has the processability similar to wood, can be cut and bonded, is fixedly connected by nails or bolts, and can be painted. Therefore, the method has wide application field and can be widely applied to industries such as building materials, furniture, logistics packaging, gardens and the like.
The existing wood-plastic composite material does not achieve very excellent effects in the aspects of bending strength, connection rigidity and the like.
Disclosure of Invention
The invention aims to provide a novel wood-plastic composite material to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
a novel wood-plastic composite material comprises the following components in parts by weight: 40-60 parts of PVC powder, 40-60 parts of heavy calcium powder, 10-20 parts of talcum powder, 12-20 parts of wood powder, 1.5-3.5 parts of stabilizer, 3-6 parts of modifier, 0.5-2 parts of acrylate, 0.1-1 part of internal lubricant and 0.2-0.7 part of external lubricant.
As a further scheme of the invention: the PVC powder is 5-type PVC powder.
As a further scheme of the invention: the fineness of the talcum powder is 500 meshes.
As a further scheme of the invention: the wood powder is obtained by mixing one or more of wood chips, bamboo chips and straws and then crushing and pulverizing.
As a further scheme of the invention: the stabilizer is a lead salt stabilizer.
As a further scheme of the invention: the modifier is maleic anhydride grafted polypropylene or maleic anhydride grafted polyethylene.
As a further scheme of the invention: the inner lubricant is polyethylene wax, and the outer lubricant is stearic acid.
As a further scheme of the invention: the preparation method of the novel wood-plastic composite material comprises the steps of putting the weighed components into a high-speed hot mixer, heating and mixing at the temperature of 115-125 ℃, then sending into a high-speed cold mixer for cold mixing at the temperature of 40-50 ℃, discharging and naturally cooling, putting into a conical double-screw extruder for extrusion and plasticization, cooling and shaping after die forming, cutting and packaging.
Compared with the prior art, the invention has the beneficial effects that: the novel wood-plastic composite material disclosed by the invention has excellent performances in static bending strength, impact resistance and the like.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the first embodiment of the invention, the novel wood-plastic composite material comprises the following components in parts by weight: 45 parts of 5-type PVC powder, 45 parts of coarse whiting powder, 15.5 parts of talcum powder, 18 parts of wood powder, 3 parts of stabilizer, 5 parts of modifier, 2 parts of acrylate, 0.5 part of internal lubricant and 0.4 part of external lubricant, wherein the fineness of the talcum powder is 500 meshes, and the wood powder is obtained by mixing one or more of sawdust, bamboo sawdust and straw and then crushing the mixture into powder; the stabilizer is a lead salt stabilizer, the modifier is maleic anhydride grafted polypropylene or maleic anhydride grafted polyethylene, the internal lubricant is polyethylene wax, and the external lubricant is stearic acid.
In the second embodiment of the invention, the novel wood-plastic composite material comprises the following components in parts by weight: 50 parts of 5-type PVC powder, 50 parts of heavy calcium carbonate powder, 12.5 parts of talcum powder, 12.5 parts of wood powder, 2.5 parts of stabilizer, 5 parts of modifier, 1 part of acrylate, 0.5 part of internal lubricant and 0.4 part of external lubricant, wherein the fineness of the talcum powder is 500 meshes, and the wood powder is obtained by mixing one or more of wood chips, bamboo chips and straws and then crushing the mixture into powder; the stabilizer is a lead salt stabilizer, the modifier is maleic anhydride grafted polypropylene or maleic anhydride grafted polyethylene, the internal lubricant is polyethylene wax, and the external lubricant is stearic acid.
The components of the first embodiment and the second embodiment are respectively put into a high-speed hot mixer, the mixture is heated and mixed at the temperature of 115-125 ℃, then the mixture is sent into a high-speed cold mixer for cold mixing at the temperature of 40-50 ℃, the mixture is discharged and naturally cooled, the mixture is put into a conical double-screw extruder for extrusion and plasticization, the mold is formed and cooled for shaping, and the cutting and packaging are carried out, the static bending strength, the section holding screw force, the maximum breaking force of a connecting angle, the low-temperature drop hammer impact and the thermal resistance in the cross section thickness direction of the test sample are detected according to CB/T8814-2004-unplasticized polyvinyl chloride (PVC-U) section for doors and windows and GB/T17657-2013-artificial board physicochemical property test method for artificial boards and veneer, so as to obtain the detection results shown in the following table 1:
in the context of Table 1, the following examples are,
Figure 577404DEST_PATH_IMAGE001
it can be seen that the above samples all have excellent properties in structural strength, impact resistance, heat insulation and fire resistance.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (8)

1. The novel wood-plastic composite material is characterized in that: the paint comprises the following components in parts by weight: 40-60 parts of PVC powder, 40-60 parts of heavy calcium powder, 10-20 parts of talcum powder, 12-20 parts of wood powder, 1.5-3.5 parts of stabilizer, 3-6 parts of modifier, 0.5-2 parts of acrylate, 0.1-1 part of internal lubricant and 0.2-0.7 part of external lubricant.
2. The novel wood-plastic composite material according to claim 1, characterized in that: the PVC powder is 5-type PVC powder.
3. The novel wood-plastic composite material according to claim 1, characterized in that: the fineness of the talcum powder is 500 meshes.
4. The novel wood-plastic composite material according to claim 1, characterized in that: the wood powder is obtained by mixing one or more of wood chips, bamboo chips and straws and then crushing and pulverizing.
5. The novel wood-plastic composite material according to claim 1, characterized in that: the stabilizer is a lead salt stabilizer.
6. The novel wood-plastic composite material according to claim 1, characterized in that: the modifier is maleic anhydride grafted polypropylene or maleic anhydride grafted polyethylene.
7. The novel wood-plastic composite material according to claim 1, characterized in that: the inner lubricant is polyethylene wax, and the outer lubricant is stearic acid.
8. A novel wood-plastic composite according to any one of claims 1 to 7, characterized in that: the preparation method of the novel wood-plastic composite material comprises the following steps: the components which are weighed and measured are put into a high-speed hot mixer, heated and mixed at the temperature of 115-125 ℃, then sent into a high-speed cold mixer to be cold mixed at the temperature of 40-50 ℃, discharged and naturally cooled, put into a conical double-screw extruder to be extruded and plasticized, and then are cooled and shaped after being molded by a die, cut and packaged.
CN202010797849.1A 2020-08-10 2020-08-10 Novel wood-plastic composite material Pending CN111718548A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010797849.1A CN111718548A (en) 2020-08-10 2020-08-10 Novel wood-plastic composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010797849.1A CN111718548A (en) 2020-08-10 2020-08-10 Novel wood-plastic composite material

Publications (1)

Publication Number Publication Date
CN111718548A true CN111718548A (en) 2020-09-29

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Country Status (1)

Country Link
CN (1) CN111718548A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103122112A (en) * 2013-03-01 2013-05-29 山西峰岩新型建材股份有限公司 PVC (polyvinyl chloride)-based wood plastic and preparation method thereof
US20150267025A1 (en) * 2014-03-21 2015-09-24 Zhejiang Tianzhen Bamboo & Wood Development Co., Ltd. Pvc composite material, foam board, production method and apparatus thereof, and flooring
CN108485102A (en) * 2018-02-13 2018-09-04 南京工业大学 A kind of enhanced polyvinyl chloride wood plastic foam composite material of lignin and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103122112A (en) * 2013-03-01 2013-05-29 山西峰岩新型建材股份有限公司 PVC (polyvinyl chloride)-based wood plastic and preparation method thereof
US20150267025A1 (en) * 2014-03-21 2015-09-24 Zhejiang Tianzhen Bamboo & Wood Development Co., Ltd. Pvc composite material, foam board, production method and apparatus thereof, and flooring
CN108485102A (en) * 2018-02-13 2018-09-04 南京工业大学 A kind of enhanced polyvinyl chloride wood plastic foam composite material of lignin and preparation method thereof

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Application publication date: 20200929