CN111717889A - Portable hydrogen production device and method for generating hydrogen by using same - Google Patents

Portable hydrogen production device and method for generating hydrogen by using same Download PDF

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Publication number
CN111717889A
CN111717889A CN202010611352.6A CN202010611352A CN111717889A CN 111717889 A CN111717889 A CN 111717889A CN 202010611352 A CN202010611352 A CN 202010611352A CN 111717889 A CN111717889 A CN 111717889A
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hydrogen
reactor
bag
water
bottle
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CN202010611352.6A
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Chinese (zh)
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何珍宝
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Wuhan Baoying Puji Technology Co ltd
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Wuhan Baoying Puji Technology Co ltd
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Priority to CN202010611352.6A priority Critical patent/CN111717889A/en
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention discloses a portable hydrogen production device, which relates to a hydrogen production technology and comprises a reactor, a cleaner, an absorption filter, a hydrogen bag and an atomization bottle, wherein the reactor, the cleaner, the absorption filter, the hydrogen bag and the atomization bottle are all connected through pipelines, the reactor is connected with a first water inlet pipe, the atomization bottle is connected with a hydrogen receiving pipe, the first water inlet pipe is provided with a valve, and the pipelines between the absorption filter and the hydrogen bag and the pipelines between the hydrogen bag and the atomization bottle are all provided with valves. The device disclosed by the invention can prepare clean hydrogen with humidity, and the quality of the hydrogen is ensured.

Description

Portable hydrogen production device and method for generating hydrogen by using same
Technical Field
The invention relates to a hydrogen production technology, in particular to a portable hydrogen production device and a method for generating hydrogen by using the portable hydrogen production device.
Background
The working principle of the oxyhydrogen atomizer is mainly under the combined action of an electrolytic bath system and an ultrasonic atomization system. After the AC voltage is converted into the DC voltage by the switching power supply, the DC voltage is added to two electrodes of an electrolytic cell system, and the pure water generates an electrolytic effect under the action of an electric field generated by the DC voltage and a small amount of food-grade catalyst (food base) to generate H and O, so that the water is decomposed into hydrogen and oxygen. The molecular hydrogen has extremely small molecular volume, can quickly permeate and diffuse to the whole body, can penetrate various physiological barriers and cell membranes, enters cell nuclei and removes malignant active oxygen which cannot be eliminated by common means. The hydrogen can be changed into water to be utilized by human body after eliminating the malignant active oxygen, the normal functions of other benign active oxygen and biological molecules can not be influenced, and the important biological molecules and cells which are easy to be damaged by oxidation injury are perfectly protected. However, the existing hydrogen absorption machine is a hydrogen-oxygen atomizer, which generates hydrogen-oxygen mixed gas by electrolyzing water, and the water electrolysis is accompanied by the generation of ozone, and the ozone is harmful to human body; in addition, the oxyhydrogen atomizer is bulky and expensive, needs to be connected with a fixed power supply, is very inconvenient to move, and also limits the application range and crowds of the oxyhydrogen atomizer.
Disclosure of Invention
The technical problem to be solved by the present invention is to provide a portable hydrogen production apparatus and a method for generating hydrogen using the same to solve the problems mentioned in the background above.
In order to solve the technical problems, the technical scheme of the invention is as follows:
the utility model provides a portable hydrogen plant, includes reactor, purger, absorption filter, hydrogen bag and atomizer bottle, wherein reactor, purger, absorption filter, hydrogen bag and atomizer bottle all pass through the pipe connection the reactor is connected with first inlet tube be connected with on the atomizer bottle and connect and inhale the hydrogen pipe be provided with the valve on the first inlet tube absorb pipeline and hydrogen bag between filter and the hydrogen bag with pipeline between the atomizer bottle all is provided with the valve.
Preferably, the atomization bottle is further connected with a second water inlet pipe and a second water outlet pipe, and valves are also arranged on the second water inlet pipe and the second water outlet pipe.
Preferably, a pump body is arranged on a pipeline of the atomization bottle between the hydrogen bags.
Preferably, a liquid level control valve is arranged on the atomizing bottle.
Preferably, the reactor is further provided with a water outlet.
A method of generating hydrogen using a portable hydrogen plant, comprising the steps of:
s1, installing the portable hydrogen production device;
s2, evacuating the air in the reactor and the cleaner;
s3, preparing hydrogen in the reactor;
s4, purifying the hydrogen, and storing the purified hydrogen into the hydrogen bag;
and S5, conveying the hydrogen bag in the step S4 into an atomization bottle through a pipeline, and discharging the hydrogen bag through a hydrogen receiving and absorbing pipe.
Preferably, the specific process of step S3 is as follows: hydrogen production agent and water source are added into the reactor, and hydrogen is generated through the reaction of the hydrogen production agent and the water.
By adopting the technical scheme, namely the scheme of the hydrogen production device, the hydrogen bag and the atomizer, the hydrogen can be produced at any time and any place to absorb hydrogen, and the hydrogen production agent is adopted to react to produce the hydrogen, so that the generation of ozone is avoided, and the absorbed hydrogen is safer and healthier. The hydrogen production device of the device consists of a reactor, a cleaner and a filter, wherein the hydrogen production agent is arranged in the reactor, the hydrogen production agent reacts with water to generate hydrogen after water is added into a water inlet pipe, and the hydrogen is cleaned by the cleaner and then removed from redundant water by an absorption filter to form clean hydrogen with proper humidity, and the hydrogen is suitable for hydrogen absorption. In order to avoid the fluctuation of the hydrogen production speed of the hydrogen production device and influence on the hydrogen absorption quality, the hydrogen bag is arranged as a buffer, when the hydrogen production amount is large, hydrogen is stored in the hydrogen bag, when the hydrogen production amount is small, the hydrogen is supplemented by the hydrogen bag, and therefore the quality of gas absorption is ensured.
Drawings
FIG. 1 is a schematic diagram of the structure of a portable hydrogen production device.
In the figure, 1-a reactor, 2-a cleaner, 3-an absorption filter, 4-a hydrogen bag, 5-an atomization bottle, 6-a first water inlet pipe, 7-a second water inlet pipe, 8-a hydrogen absorption pipe, 9-a water outlet pipe, 10-a pump body and 11-a liquid level control valve.
Detailed Description
The following further describes embodiments of the present invention with reference to the drawings. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
The utility model provides a portable hydrogen plant, including reactor 1, purger 2, absorb filter 3, hydrogen bag 4 and atomizer bottle 5, wherein reactor 1, purger 2, absorb filter 3, hydrogen bag 4 and atomizer bottle 5 all connect gradually through the pipeline, be connected with first inlet tube 6 at reactor 1, be connected with on atomizer bottle 5 and connect and inhale hydrogen pipe 8, be provided with the valve on first inlet tube 6, pipeline between absorption filter 3 and hydrogen bag 4 and the pipeline between hydrogen bag 4 and atomizer bottle 5 all are provided with the valve, wherein be provided with the pump body 10 on the pipeline between hydrogen bag 4 and atomizer bottle 5 and improve hydrogen transportation efficiency, and be provided with liquid level control valve 11 on atomizer bottle 5, come according to the liquid level of atomizer bottle 5.
In a possible embodiment, the hydrogen is produced by first disconnecting the absorption filter 3 from the pipe connected to the hydrogen bag 4, it being understood that the pipe connection can be detached and installed, which is the prior art and is not explained much here, by injecting water into the reactor 1 after disconnecting the absorption filter 3 from the pipe, see fig. 1, the pipe is arranged at the upper end of the reactor 1, so that the water will enter the cleaning device 2 through the pipe after the reactor 1 is full of water until the water fills the cleaning device 2 and flows into the absorption filter 3, which is the evacuation process, and then connecting the absorption filter 3 with the hydrogen bag 4 through the pipe, and then discharging the water inside the reactor 1, then adding the hydrogen production agent and the water into the reactor 1, producing hydrogen by the reaction of the hydrogen production agent and the water, the hydrogen enters the hydrogen bag 4 through the cleaning device 2 and the absorption filter 3, then introduce gas into the atomization bottle 5 through the pump body 10, inhale hydrogen through connecing hydrogen absorption pipe 8 at last, in the whole process, owing to adopt the hydrogen manufacturing agent for whole device can be anytime and anywhere prepared hydrogen and inhale hydrogen, owing to adopt the hydrogen manufacturing agent reaction to produce hydrogen, consequently avoided the production of ozone, make inspiratory hydrogen safer healthy. This device comprises reactor 1, purger 2 and absorption filter 3, and the hydrogen manufacturing agent is arranged in reactor 1, and first inlet tube 6 adds water back, and the hydrogen manufacturing agent reacts with water and generates hydrogen, after the purger 2 washs, absorbs filter 3 again, just becomes clean hydrogen that has humidity, and this hydrogen just is fit for hydrogen absorption. In order to avoid the fluctuation of the hydrogen production speed of the hydrogen production device and influence on the hydrogen absorption quality, the hydrogen bag 4 is arranged as a buffer, when the hydrogen production amount is large, hydrogen is stored in the hydrogen bag 4, and when the hydrogen production amount is small, hydrogen is supplemented by the hydrogen bag 4, so that the gas absorption quality is ensured.
In another possible embodiment, the hydrogen and hydrogen-rich water are produced simultaneously by first disconnecting the absorption filter 3 from the pipe connected to the hydrogen bag 4, it should be understood that the pipe connection can be disassembled and assembled, which is the prior art and is not explained much, after disconnecting the absorption filter 3 from the pipe, by injecting water into the reactor 1, see fig. 1, the pipe is arranged at the upper end of the reactor 1, so that the water will enter the cleaning device 2 through the pipe after the reactor 1 is full of water, until the water fills the cleaning device 2 and flows into the absorption filter 3, which belongs to the emptying process, then connecting the absorption filter 3 with the hydrogen bag 4 through the pipe, then discharging the water in the reactor 1, then adding the hydrogen production agent and the hydrogen production water into the reactor 1, and producing hydrogen through the reaction of the hydrogen production agent and the water, hydrogen passes through purger 2 and absorption filter 3 and enters into hydrogen bag 4 in, then introduces gas into atomizing bottle 5 through the pump body 10, inhales hydrogen through connecing at last and inhales hydrogen pipe 8, and in the whole process, owing to adopt the hydrogen manufacturing agent for whole device can be anytime and anywhere prepared hydrogen and inhale hydrogen, owing to adopt the hydrogen manufacturing agent reaction to produce hydrogen, consequently avoided the production of ozone, feasible inspiratory hydrogen is safer healthy. The device consists of a reactor 1, a cleaner 2 and an absorption filter 3, wherein a hydrogen production agent is arranged in the reactor 1, after water is added into the first water inlet pipe 6, the hydrogen production agent reacts with the water to generate hydrogen, the hydrogen becomes clean and humid hydrogen after being cleaned by the cleaner 2 and passing through the absorption filter 3, the atomizing bottle 5 is also connected with a second water inlet pipe 7 and a water outlet pipe 9, the second water inlet pipe 7 and the water outlet pipe 9 are also provided with valves, so that water can be added into the atomizing bottle 5 through the second water inlet pipe 7, and the amount of the fed water is controlled through the level control valve 11, see figure 1, when hydrogen enters the atomizing bottle 5 through the pump body 10, bubbles can be formed with water in the atomizing bottle 5, the design can enable the hydrogen to be fully dissolved in the water, when the hydrogen passes through the water, hydrogen rich water can be produced, which can be discharged through the outlet pipe 9.
In the whole device, it is understood that the hydrogen production agents adopted are calcium magnesium simple substance, calcium magnesium alloy and mixture of calcium magnesium simple substance, calcium magnesium alloy and solid acid, and the calcium magnesium alloy and the solid acid mainly have displacement reaction and acid-base neutralization reaction with water. Taking the mixture of calcium-magnesium alloy and citric acid as an example, the main reaction is as follows:
Ca+2H2O→Ca(OH)2+H2(1)
Mg+2H2O→Mg(OH)2+H2(2)
2C6H8O7+3Mg(OH)2→Mg3(C6H8O7)2+3H2O (3)
2C6H8O7+3Ca(OH)2→Ca3(C6H8O7)2+3H2O (4)
and the inside of the absorption filter 3 is mainly filtered by using an activated carbon adsorbent. Hydrogen is fully mixed with water in an atomization bottle in a bubbling mode, and the concentration of the generated hydrogen-rich water is close to or even exceeds the saturation concentration of the hydrogen in the water along with some nano bubbles; at normal temperature and pressure, the saturated concentration of hydrogen in water is about 0.8 mol/ton water, which is equivalent to dozens of hydrogen molecules in million water molecules.
The invention also provides a method for generating hydrogen by using the portable hydrogen production device, which comprises the following steps:
s1, installing the portable hydrogen production device;
s2, evacuating the air in the reactor 1 and the cleaner 2;
s3, preparing hydrogen in the reactor 1, namely adding a hydrogen production agent and water into the reactor 1, reacting the hydrogen production agent with the water to generate hydrogen, and feeding the hydrogen generated after reaction into an absorption filter 3;
s4, purifying the hydrogen by the absorption filter 3, and storing the purified hydrogen into the hydrogen bag 4;
and S5, conveying the hydrogen bag 4 in the step S4 into the atomizing bottle 5 through a pipeline, and discharging the hydrogen bag through the hydrogen receiving and absorbing pipe 8.
Preferably, the specific process of step S3 is as follows: hydrogen production agent and water source are added into the reactor 1, and hydrogen is generated through the reaction of the hydrogen production agent and water.
The embodiments of the present invention have been described in detail with reference to the accompanying drawings, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.

Claims (7)

1. A portable hydrogen production device is characterized in that: including reactor (1), purger (2), absorption filter (3), hydrogen bag (4) and atomizer bottle (5), wherein reactor (1), purger (2), absorption filter (3), hydrogen bag (4) and atomizer bottle (5) all are through the pipe connection reactor (1) is connected with first inlet tube (6) be connected with on atomizer bottle (5) and connect and inhale hydrogen pipe (8) be provided with the valve on first inlet tube (6) pipeline and hydrogen bag (4) between absorption filter (3) and hydrogen bag (4) and pipeline between atomizer bottle (5) all are provided with the valve.
2. The portable hydrogen production apparatus according to claim 1, wherein: still be connected with second inlet tube (7) and outlet pipe (9) on atomizing bottle (5) second inlet tube (7) and outlet pipe (9) are last also to be provided with the valve.
3. The portable hydrogen production apparatus according to claim 2, wherein: a pump body (10) is arranged on the pipeline of the atomizing bottle (5) between the hydrogen bags (4).
4. The portable hydrogen production apparatus according to claim 3, wherein: the atomizing bottle (5) is provided with a liquid level control valve (11).
5. The portable hydrogen production apparatus according to claim 4, wherein: the reactor (1) is also provided with a water outlet.
6. A method of generating hydrogen using the portable hydrogen generation apparatus of any of claims 1 to 5, wherein: the method comprises the following steps:
s1, installing the portable hydrogen production device as claimed in any one of claims 1-5;
s2, evacuating the air in the reactor (1) and the cleaner (2);
s3, preparing hydrogen in the reactor (1);
s4, purifying the hydrogen and storing the purified hydrogen into the hydrogen bag (4);
s5, conveying the hydrogen bag (4) in the step S4 into an atomizing bottle (5) through a pipeline, and discharging the hydrogen bag through a hydrogen receiving and absorbing pipe (8).
7. The method of generating hydrogen gas of claim 6, wherein: the specific process of step S3 is as follows: hydrogen production agent and water source are added into the reactor (1), and hydrogen is generated through the reaction of the hydrogen production agent and water.
CN202010611352.6A 2020-06-29 2020-06-29 Portable hydrogen production device and method for generating hydrogen by using same Pending CN111717889A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5956970A (en) * 1996-06-04 1999-09-28 The Kansai Electric Power Company, Inc. Hydrogen purify improving method and the apparatus for the same
CN102167285A (en) * 2011-03-02 2011-08-31 上海师范大学 Portable, safe and controllable hydrolysis hydrogen-producing device
CN206285286U (en) * 2016-04-19 2017-06-30 友荃科技实业股份有限公司 Hydrogen-oxygen molecule atomising device
WO2017149684A1 (en) * 2016-03-01 2017-09-08 株式会社グレイトチレン Wet high-concentration hydrogen-mixed-gas respiration system
CN110526210A (en) * 2019-08-23 2019-12-03 浙江高成绿能科技有限公司 A kind of controllable chemical hydrogen making reaction device
CN210711766U (en) * 2019-11-22 2020-06-09 深圳氢盈健康科技有限责任公司 Portable hydrogen machine
CN212334584U (en) * 2020-06-29 2021-01-12 武汉宝盈普济科技有限公司 Portable hydrogen production device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5956970A (en) * 1996-06-04 1999-09-28 The Kansai Electric Power Company, Inc. Hydrogen purify improving method and the apparatus for the same
CN102167285A (en) * 2011-03-02 2011-08-31 上海师范大学 Portable, safe and controllable hydrolysis hydrogen-producing device
WO2017149684A1 (en) * 2016-03-01 2017-09-08 株式会社グレイトチレン Wet high-concentration hydrogen-mixed-gas respiration system
CN206285286U (en) * 2016-04-19 2017-06-30 友荃科技实业股份有限公司 Hydrogen-oxygen molecule atomising device
CN110526210A (en) * 2019-08-23 2019-12-03 浙江高成绿能科技有限公司 A kind of controllable chemical hydrogen making reaction device
CN210711766U (en) * 2019-11-22 2020-06-09 深圳氢盈健康科技有限责任公司 Portable hydrogen machine
CN212334584U (en) * 2020-06-29 2021-01-12 武汉宝盈普济科技有限公司 Portable hydrogen production device

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