CN111675455A - Drying treatment technology for oil-containing sludge - Google Patents

Drying treatment technology for oil-containing sludge Download PDF

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Publication number
CN111675455A
CN111675455A CN202010418495.5A CN202010418495A CN111675455A CN 111675455 A CN111675455 A CN 111675455A CN 202010418495 A CN202010418495 A CN 202010418495A CN 111675455 A CN111675455 A CN 111675455A
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China
Prior art keywords
sludge
oily sludge
drying treatment
oil
treatment technology
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Pending
Application number
CN202010418495.5A
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Chinese (zh)
Inventor
林木茂
丁达明
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Jiangsu Senmao Energy Developments Co ltd
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Jiangsu Senmao Energy Developments Co ltd
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Priority to CN202010418495.5A priority Critical patent/CN111675455A/en
Publication of CN111675455A publication Critical patent/CN111675455A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/13Treatment of sludge; Devices therefor by de-watering, drying or thickening by heating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/143Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/143Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances
    • C02F11/145Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances using calcium compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/148Combined use of inorganic and organic substances, being added in the same treatment step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention belongs to the technical field of sludge treatment, and discloses a drying treatment technology for oil-containing sludge. The drying treatment technology of the oil-containing sludge comprises the following steps: crushing sludge, crushing oily sludge by a sorting runner, filtering the sludge by using a sieve plate, and repeatedly crushing and sieving large solid matters under the sieve; the oily sludge is circularly crushed for a plurality of times until the oily sludge passes through the sieve plate; and step two, demulsifying the oily sludge, adding a demulsifier into the oily sludge crushed in the step one, and continuously stirring and mixing. This mummification processing technology of oiliness mud carries out many times broken filtration to mud, can the content of greatly reduced large granule filth, makes abundant preparation for subsequent improvement step, avoids the insufficient condition of improvement to this processing technology simplifies the processing procedure, easy operation, and the input cost is low, is fit for extensive popularization.

Description

Drying treatment technology for oil-containing sludge
Technical Field
The invention relates to the technical field of sludge treatment, in particular to a drying treatment technology of oil-containing sludge.
Background
The oily (hydrocarbon-containing) sludge is huge in volume, if the oily (hydrocarbon-containing) sludge is directly discharged without treatment, not only a large amount of cultivated land is occupied, but also the surrounding soil, water and air are polluted, along with the generation of malodorous gases, the sludge contains a large amount of pathogenic bacteria, parasites (eggs), heavy metals such as copper, zinc, chromium, mercury and the like, salts, toxic substances with malodor such as benzene series, phenols, polychlorinated biphenyl, dioxin, anthracene, pyrene and the like, and refractory toxic substances such as radioactive nuclide and the like. The land filling can cause serious pollution to underground water and serious damage to natural original ecology such as grain crops, trees, vegetation and the like.
The oily sludge usually has a large amount of large-particle dirt, and the existence of the large-particle dirt seriously affects the drying treatment of the oily sludge, for example, in the improvement process, because the existence of large particles, the mixing of a modifying agent and the dirt is difficult to realize, and the improvement effect is affected, so how to realize high-efficiency sludge drying treatment is a problem which needs to be solved urgently.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides a drying treatment technology for oil-containing sludge, which can efficiently carry out drying treatment on sludge and repeatedly and greatly improve the sludge modification effect.
The invention provides the following technical scheme: the drying treatment technology of the oily sludge comprises the following steps:
step one, carrying out crushing treatment on sludge,
the separation runner is used for crushing the oily sludge, the sieve plate is used for filtering the sludge, and large solid matters under the sieve are repeatedly crushed and sieved; the oily sludge is circularly crushed for a plurality of times until the oily sludge passes through the sieve plate.
Step two, demulsifying the oil-containing sludge,
and (3) adding a demulsifier into the oily sludge crushed in the step one, continuously stirring and mixing, introducing the oily sludge into a sedimentation tank after demulsification is finished, adding a coagulant for sedimentation, and discharging the upper-layer waste oil and accumulated water to obtain bottom sludge after sedimentation is finished.
Step three, carrying out purification treatment on the oily sludge,
measuring the water content of sludge to be treated of the oil-containing sludge, preparing a modifying agent according to the parts by weight, conveying the oil-containing sludge into a drying tank, stirring the sludge, adding the modifying agent according to the proportion of 1:4 while stirring, heating the drying tank, and keeping the temperature of the drying tank between 200 ℃ and 250 ℃.
And step four, sampling the sludge in the step three, stopping heating when the water content is less than or equal to 5 percent and the oil content is less than or equal to 0.5 percent, and introducing the dried sludge into a granulator to be processed into sludge granules.
And (5) finishing drying treatment.
Preferably, the addition amount of the demulsifier is 20-60 g/L, and the demulsification time is 12-25 minutes.
Preferably, the demulsifier adopts calcium chloride or polymeric aluminum ferric sulfate.
Preferably, the modifier comprises 70 parts of curing agent, 40 parts of calorific value regulator, 5 parts of alkaline activator, 4 parts of oil absorbent, 22 parts of surfactant, 15 parts of moisture regulator and 15 parts of deodorant.
Preferably, the oil absorbent component is one or more of modified zeolite, modified diatomite, modified straw fiber, sodium lignosulfonate and calcium lignosulfonate, and the alkali activator is one or more of sodium carbonate, sodium hydroxide, potassium carbonate, alum and potassium nitrate.
Preferably, the moisture regulator is one or more of zeolite, diatomite or activated carbon powder, and the deodorant is one or more of wood vinegar or plant polyphenol.
Preferably, the surfactant is one or more of sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether, sodium carboxymethylcellulose or propylene glycol methyl ether acetate.
Preferably, the coagulant is aluminum polysilicate, ferric polysilicate or aluminum polysilicate ferric, the addition amount of the coagulant is 20-40mg/L, the stirring time is 10-30min, and the precipitation time is 30-60 min.
By adopting the technical scheme, the invention has the beneficial effects that:
this mummification processing technology of oiliness mud carries out many times broken filtration to mud, can the content of greatly reduced large granule filth, makes abundant preparation for subsequent improvement step, avoids the insufficient condition of improvement to this processing technology simplifies the processing procedure, easy operation, and the input cost is low, is fit for extensive popularization.
Detailed Description
The technical solution of the present invention will be described in detail below with reference to specific examples.
A drying treatment technology of oily sludge comprises the following steps:
step one, carrying out crushing treatment on sludge,
the separation runner is used for crushing the oily sludge, the sieve plate is used for filtering the sludge, and large solid matters under the sieve are repeatedly crushed and sieved; the oily sludge is circularly crushed for a plurality of times until the oily sludge passes through the sieve plate.
Step two, demulsifying the oil-containing sludge,
and (3) adding a demulsifier into the oily sludge crushed in the step one, continuously stirring and mixing, introducing the oily sludge into a sedimentation tank after demulsification is finished, adding a coagulant for sedimentation, and discharging the upper-layer waste oil and accumulated water to obtain bottom sludge after sedimentation is finished.
Step three, carrying out purification treatment on the oily sludge,
measuring the water content of sludge to be treated of the oil-containing sludge, preparing a modifying agent according to the parts by weight, conveying the oil-containing sludge into a drying tank, stirring the sludge, adding the modifying agent according to the proportion of 1:4 while stirring, heating the drying tank, and keeping the temperature of the drying tank between 200 ℃ and 250 ℃.
And step four, sampling the sludge in the step three, stopping heating when the water content is less than or equal to 5 percent and the oil content is less than or equal to 0.5 percent, and introducing the dried sludge into a granulator to be processed into sludge granules.
And (5) finishing drying treatment.
The addition amount of the demulsifier is 20-60 g/L, and the demulsification time is 12-25 minutes.
The demulsifier adopts calcium chloride or polymeric aluminum ferric sulfate.
The modifier comprises 70 parts of curing agent, 40 parts of heat value regulator, 5 parts of alkaline activator, 4 parts of oil absorbent, 22 parts of surfactant, 15 parts of moisture regulator and 15 parts of deodorant.
The oil absorbent is one or more of modified zeolite, modified diatomite, modified straw fiber, sodium lignosulfonate or calcium lignosulfonate, and the alkali activator is one or more of sodium carbonate, sodium hydroxide, potassium carbonate, alum or potassium nitrate.
The moisture regulator is one or more of zeolite, diatomaceous earth or activated carbon powder, and the deodorant is one or more of wood vinegar liquid or plant polyphenol.
The surfactant is one or more of sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether, sodium carboxymethylcellulose or propylene glycol methyl ether acetate.
The coagulant is aluminum polysilicate, ferric polysilicate or aluminum ferric polysilicate, the addition amount of the coagulant is 20-40mg/L, the stirring time is 10-30min, and the precipitation time is 30-60 min.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (8)

1. A drying treatment technology of oily sludge is characterized in that: the drying treatment technology comprises the following steps:
step one, carrying out crushing treatment on sludge,
the separation runner is used for crushing the oily sludge, the sieve plate is used for filtering the sludge, and large solid matters under the sieve are repeatedly crushed and sieved; the oily sludge is circularly crushed for a plurality of times until the oily sludge passes through the sieve plate;
step two, demulsifying the oil-containing sludge,
adding a demulsifier into the crushed oily sludge obtained in the step one, continuously stirring and mixing, introducing the oily sludge into a sedimentation tank after demulsification is completed, adding a coagulant for sedimentation, and discharging upper-layer waste oil and accumulated water to obtain bottom sludge after sedimentation is completed;
step three, carrying out purification treatment on the oily sludge,
measuring the water content of sludge to be treated of the oil-containing sludge, preparing a modifying agent according to the parts by weight, conveying the oil-containing sludge into a drying tank, stirring the sludge, adding the modifying agent according to the proportion of 1:4 while stirring, heating the drying tank, and keeping the temperature of the drying tank between 200 ℃ and 250 ℃.
Step four, sampling the sludge in the step three, stopping heating when the water content is less than or equal to 5 percent and the oil content is less than or equal to 0.5 percent, and introducing the sludge which is dried into a granulator to be processed into sludge particles;
and (5) finishing drying treatment.
2. The drying treatment technology of the oily sludge according to claim 1, which is characterized in that: the addition amount of the demulsifier is 20-60 g/L, and the demulsification time is 12-25 minutes.
3. The drying treatment technology of the oily sludge according to claim 1, which is characterized in that: the demulsifier adopts calcium chloride or polymeric aluminum ferric sulfate.
4. The drying treatment technology of the oily sludge according to claim 1, which is characterized in that: the modifier comprises 70 parts of a curing agent, 40 parts of a heat value regulator, 5 parts of an alkaline activator, 4 parts of an oil absorbent, 22 parts of a surfactant, 15 parts of a moisture regulator and 15 parts of a deodorant.
5. The drying treatment technology of the oily sludge according to claim 4, which is characterized in that: the oil absorbent is prepared by compounding one or more of modified zeolite, modified diatomite, modified straw fiber, sodium lignosulfonate and calcium lignosulfonate, and the alkali activator is one or more of sodium carbonate, sodium hydroxide, potassium carbonate, alum and potassium nitrate.
6. The drying treatment technology of the oily sludge according to claim 4, which is characterized in that: the moisture regulator is one or more of zeolite, diatomite or activated carbon powder, and the deodorant is one or more of wood vinegar or plant polyphenol.
7. The drying treatment technology of the oily sludge according to claim 4, which is characterized in that: the surfactant is one or more of sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether, sodium carboxymethylcellulose or propylene glycol methyl ether acetate.
8. The drying treatment technology of the oily sludge according to claim 1, which is characterized in that: the coagulant is aluminum polysilicate, ferric polysilicate or aluminum ferric polysilicate, the addition amount of the coagulant is 20-40mg/L, the stirring time is 10-30min, and the precipitation time is 30-60 min.
CN202010418495.5A 2020-05-18 2020-05-18 Drying treatment technology for oil-containing sludge Pending CN111675455A (en)

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Application Number Priority Date Filing Date Title
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CN111675455A true CN111675455A (en) 2020-09-18

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114128592A (en) * 2021-12-02 2022-03-04 青岛润森生态建设工程有限公司 Soil matrix for mountain restoration and preparation method and application thereof
CN115072907A (en) * 2022-07-22 2022-09-20 天津开放大学 Trace sediment treatment method for industrial oily wastewater
CN115583780A (en) * 2022-10-13 2023-01-10 山东京阳科技股份有限公司 Oily sludge treatment method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630545A (en) * 2017-02-06 2017-05-10 天津市环境保护技术开发中心设计所 Drying treatment method of oil-containing sludge
CN107162359A (en) * 2017-05-31 2017-09-15 北京朗清源节能环保科技有限公司 Process for treating oil-containing sludge
WO2020029653A1 (en) * 2018-08-04 2020-02-13 盘锦宁泰能源科技有限公司 Intelligent oil sludge treatment apparatus and treatment process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630545A (en) * 2017-02-06 2017-05-10 天津市环境保护技术开发中心设计所 Drying treatment method of oil-containing sludge
CN107162359A (en) * 2017-05-31 2017-09-15 北京朗清源节能环保科技有限公司 Process for treating oil-containing sludge
WO2020029653A1 (en) * 2018-08-04 2020-02-13 盘锦宁泰能源科技有限公司 Intelligent oil sludge treatment apparatus and treatment process

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114128592A (en) * 2021-12-02 2022-03-04 青岛润森生态建设工程有限公司 Soil matrix for mountain restoration and preparation method and application thereof
CN114128592B (en) * 2021-12-02 2022-10-25 青岛润森生态环境科技有限公司 Soil matrix for mountain restoration and preparation method and application thereof
CN115072907A (en) * 2022-07-22 2022-09-20 天津开放大学 Trace sediment treatment method for industrial oily wastewater
CN115583780A (en) * 2022-10-13 2023-01-10 山东京阳科技股份有限公司 Oily sludge treatment method

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