CN111674491A - Aluminum shell for vehicle - Google Patents

Aluminum shell for vehicle Download PDF

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Publication number
CN111674491A
CN111674491A CN202010399898.XA CN202010399898A CN111674491A CN 111674491 A CN111674491 A CN 111674491A CN 202010399898 A CN202010399898 A CN 202010399898A CN 111674491 A CN111674491 A CN 111674491A
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CN
China
Prior art keywords
aluminum
shell
vehicle
automobile
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010399898.XA
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Chinese (zh)
Inventor
华吉
华胜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Jisheng Casting Co ltd
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Ningbo Jisheng Casting Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN202010399898.XA priority Critical patent/CN111674491A/en
Publication of CN111674491A publication Critical patent/CN111674491A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B62LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
    • B62DMOTOR VEHICLES; TRAILERS
    • B62D63/00Motor vehicles or trailers not otherwise provided for
    • B62D63/02Motor vehicles
    • B62D63/04Component parts or accessories
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/54Electroplating: Baths therefor from solutions of metals not provided for in groups C25D3/04 - C25D3/50
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Transportation (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The invention belongs to the field of vehicle machinery, and particularly relates to a vehicle aluminum shell and a preparation method thereof. The aluminum shell for the vehicle is prepared from aluminum alloy, wherein the aluminum alloy comprises, by weight, 18-21% of Si, 0.11-0.14% of Fe0.11, 0.005-0.007% of Cu0.005-0.007% of Mg0.03-0.05% of Mn0.002-0.004%, 0.005-0.007% of Zn0.02-0.04% of Ti0.02-0.04% of Cr0.05-0.07% of the balance Al, the preparation method comprises the steps of weighing and smelting according to the proportion, standing for 10-20 min after all raw materials are melted, adding Al-P alloy, cooling to 740-750 ℃, preserving heat for 30-40 min, finally casting and molding, and machining to obtain the aluminum shell for the vehicle. The prepared aluminum alloy shell has good wear resistance and corrosion resistance, and the service life of the whole automobile shell is prolonged.

Description

Aluminum shell for vehicle
Technical Field
The invention belongs to the field of vehicle machinery, and particularly relates to a vehicle aluminum shell and a preparation method thereof.
Background
The aluminum alloy has low density, high strength, good plasticity, excellent conductivity, heat conductivity and corrosion resistance. Aluminum alloys are the most widely used non-ferrous structural materials in industry and are used in a large number of applications in the aerospace, automotive, mechanical manufacturing, marine, aluminum alloy and chemical industries. Pure aluminum has a low density of about 1/3 that is iron, a low melting point of 660 ℃, and a face-centered cubic structure, so that the pure aluminum has high plasticity and is easy to process, various sections and plates can be manufactured, the aluminum alloy has good corrosion resistance, but the pure aluminum has low strength and is not suitable for being used as a structural material, and through long-term production practices and scientific experiments, people gradually add alloy elements and apply a heat treatment method to strengthen aluminum to obtain various aluminum alloys with different properties. The alloy formed by adding certain elements can have higher strength while keeping the advantages of light weight of pure aluminum and the like, so that the specific strength is superior to that of a plurality of alloy steels, the alloy becomes an ideal structural material and is widely applied to the aspects of mechanical manufacturing, transportation machinery, power machinery, aviation industry and the like, the airframe, the skin, the air compressor and the like of an airplane are usually made of the aluminum alloy to reduce the dead weight, the aluminum alloy is adopted to replace the welding of a steel plate material, and the structural weight can be reduced by more than 50%.
The aluminum case for a vehicle is a case of a vehicle body and is required to be wear-resistant and corrosion-resistant, and therefore, the surface requirement for the problem is high.
Disclosure of Invention
In order to solve the above problems, the present invention provides an aluminum case for a vehicle and a method for manufacturing the same.
The scheme provided by the invention is as follows:
the aluminum shell for the vehicle is prepared from aluminum alloy, wherein the aluminum alloy comprises, by weight, 18-21% of Si, 0.11-0.14% of Fe0.005-0.007% of Cu0.005-0.007% of Mg0.03-0.05% of Mn0.002-0.004%, 0.005-0.007% of Zn0.02-0.04% of Ti0.05-0.07% of Cr0.05-0.07% of Al, and the balance of Al.
A vehicle aluminum shell is prepared by the steps of adding Al, Fe, Cu, Mg, Zn, Ti, Cr, Al-Si and Al-Mn alloys weighed in proportion into a smelting device for smelting, standing for 10-20 min after all raw materials are melted, adding the Al-P alloy, cooling to 740-750 ℃, preserving heat for 30-40 min, casting and molding molten liquid, and machining into the vehicle aluminum shell.
Further, the smelting temperature is 770-790 ℃.
Further, after the machining of the automobile aluminum shell is completed, surface treatment is carried out.
Further, the surface treatment step is as follows:
(1) cleaning the surface of the casting body by using acetone and water in sequence;
(2) polishing the surface by using 300-mesh and 1000-mesh abrasive paper respectively, and then cleaning by using distilled water;
(3) and putting the casting body into electrolyte for electroplating, wherein the temperature of the electrolyte is kept at 25-30 ℃.
Further, the electrolyte is Na2O·nSiO2,(NaPO3)6,Na2WO4The mixed melt of (1), wherein Na2O·nSiO2Concentration 5g/L, (NaPO)3)6Concentration 5g/L, Na2WO4The concentration was 2 g/L.
Further, the electrolysis process is carried out at a current density of 9-10A/dm 2, a duty ratio of 19-21% and a time of 40-50 min.
The invention has the advantages that: the prepared aluminum alloy shell has good wear resistance and corrosion resistance, and the service life of the whole automobile shell is prolonged.
Detailed Description
Example 1
The automobile aluminum shell is prepared from aluminum alloy, wherein the aluminum alloy comprises, by weight, 18% of Si, 0.11% of Fe0.005% of Cu0.005%, 0.03% of Mg0.03%, 0.002% of Mn0.005%, 0.02% of Ti0.05% of Cr0.05%, and the balance of Al. The raw materials weighed according to the proportion are added into a smelting device for smelting, after the raw materials are completely melted at the smelting temperature of 770 ℃, the mixture is kept stand for 10min, Al-P alloy is added, the temperature is reduced to 740 ℃, the temperature is kept for 30min, finally, the melt is cast and molded, machined into an aluminum shell for a vehicle, and then surface treatment is carried out.
(1) Cleaning the surface of the casting body by using acetone and water in sequence;
(2) polishing the surface by using 300-mesh and 1000-mesh abrasive paper respectively, and then cleaning by using distilled water;
(3) putting the casting body into electrolyte for electroplating, wherein the temperature of the electrolyte is kept at 25 ℃, and the electrolyte is Na 2O-nSiO2,(NaPO3)6,Na2WO4The mixed melt of (1), wherein Na2O·nSiO2Concentration 5g/L, (NaPO)3)6Concentration 5g/L, Na2WO4The concentration is 2g/L, and the current density is 9A/dm2The duty ratio is 19%, and the time is 40 min.
Example 2
The aluminum shell for the vehicle is prepared from aluminum alloy, wherein the aluminum alloy comprises, by weight, Si 21%, Fe0.14%, Cu0.007%, Mg0.05%, Mn0.004%, Zn0.007%, Ti0.04%, Cr0.07%, and the balance of Al. The raw materials weighed according to the proportion are added into a smelting device for smelting, after the raw materials are completely melted at the smelting temperature of 790 ℃, the mixture is kept stand for 20min, Al-P alloy is added, the temperature is reduced to 750 ℃, the temperature is kept for 40min, finally, the melt is cast and molded, the mixture is machined into an aluminum shell for a vehicle, and then surface treatment is carried out.
(4) Cleaning the surface of the casting body by using acetone and water in sequence;
(5) polishing the surface by using 300-mesh and 1000-mesh abrasive paper respectively, and then cleaning by using distilled water;
(6) putting the casting body into electrolyte for electroplating, wherein the temperature of the electrolyte is kept at 30 ℃, and the electrolyte is Na 2O-nSiO2,(NaPO3)6,Na2WO4The mixed melt of (1), wherein Na2O·nSiO2Concentration 5g/L, (NaPO)3)6Concentration 5g/L, Na2WO4The concentration is 2g/L, and the current density is 10A/dm2The duty ratio is 21% and the time is 50 min.
Example 3
The automobile aluminum shell is prepared from aluminum alloy, wherein the aluminum alloy comprises, by weight, 20% of Si, 0.13% of Fe0.005-0.007% of Cu, 0.04% of Mg0.04% of Mn, 0.003% of Zn0.005% of Ti, 0.03% of Cr0.06% of Cr, and the balance of Al. The raw materials weighed according to the proportion are added into a smelting device for smelting, the smelting temperature is 780 ℃, after the raw materials are completely melted, the mixture is kept stand for 15min, Al-P alloy is added, the temperature is reduced to 745 ℃, the temperature is kept for 35min, finally, the melt is cast and molded, the aluminum shell for the vehicle is machined, and then the surface treatment is carried out.
(7) Cleaning the surface of the casting body by using acetone and water in sequence;
(8) polishing the surface by using 300-mesh and 1000-mesh abrasive paper respectively, and then cleaning by using distilled water;
(9) putting the casting body into electrolyte for electroplating, wherein the temperature of the electrolyte is kept at 28 ℃, and the electrolyte is Na 2O-nSiO2,(NaPO3)6,Na2WO4The mixed melt of (1), wherein Na2O·nSiO2Concentration 5g/L, (NaPO)3)6Concentration 5g/L, Na2WO4The concentration is 2g/L, and the current density is 9.5A/dm2The duty cycle is 20% and the time is 45 min.
Comparative example 1
The comparative example differs from example 1 in that the aluminum alloy is a normal aluminum alloy.
Comparative example 2
The comparative example differs from example 1 in that no Al — P alloy was added during melting.
Comparative example 3
The comparative example differs from example 1 in that no surface treatment is performed.
Through performance tests, the aluminum alloy prepared in the embodiment has better wear resistance and corrosion resistance.
Finally, it should be noted that the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to examples, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, which should be covered by the claims of the present invention.

Claims (7)

1. The utility model provides an automobile-used aluminium casing which characterized in that: the aluminum shell is prepared from aluminum alloy, and the aluminum alloy comprises, by weight, 18-21% of Si, 0.11-0.14% of Fe0.005-0.007% of Cu0.005-0.007% of Mg0.03-0.05% of Mn0.002-0.004%, 0.005-0.007% of Zn0.02-0.04% of Ti0.05-0.07% of Cr0.05-0.07% of Al, and the balance of Al.
2. The utility model provides an automobile-used aluminium casing which characterized in that: the preparation method of the automobile aluminum shell comprises the steps of adding Al, Fe, Cu, Mg, Zn, Ti, Cr, Al-Si and Al-Mn alloys weighed in proportion into a smelting device for smelting, standing for 10-20 min after all raw materials are melted, adding the Al-P alloy, cooling to 740-750 ℃, preserving heat for 30-40 min, casting and molding the melt, and machining the aluminum shell for the automobile.
3. The aluminum case for a vehicle according to claim 2, characterized in that: the smelting temperature is 770-790 ℃.
4. The aluminum case for a vehicle according to claim 2, characterized in that: and after the machining of the automobile aluminum shell is finished, performing surface treatment.
5. The aluminum case for a vehicle according to claim 2, characterized in that: the surface treatment comprises the following steps:
(1) cleaning the surface of the casting body by using acetone and water in sequence;
(2) polishing the surface by using 300-mesh and 1000-mesh abrasive paper respectively, and then cleaning by using distilled water;
(3) and putting the casting body into electrolyte for electroplating, wherein the temperature of the electrolyte is kept at 25-30 ℃.
6. The aluminum case for a vehicle according to claim 5, wherein: the electrolyte is Na2O·nSiO2,(NaPO3)6,Na2WO4The mixed melt of (1), wherein Na2O·nSiO2Concentration 5g/L, (NaPO)3)6Concentration 5g/L, Na2WO4The concentration was 2 g/L.
7. The aluminum case for a vehicle according to claim 5, wherein: the electrolysis process is carried out at a current density of 9-10A/dm2The duty ratio is 19-21%, and the time is 40-50 min.
CN202010399898.XA 2020-05-12 2020-05-12 Aluminum shell for vehicle Pending CN111674491A (en)

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Application Number Priority Date Filing Date Title
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506069A (en) * 1993-10-14 1996-04-09 Ovonic Battery Company, Inc. Electrochemical hydrogen storage alloys and batteries fabricated from Mg containing base alloys
CN1793436A (en) * 2005-11-25 2006-06-28 湖南大学 Process for directly electroplating on surface of aluminium or aluminium alloy
CN101270494A (en) * 2008-05-08 2008-09-24 重庆大学 Galvano-chemistry preparation method for metallic face protection ceramic film
CN101629251A (en) * 2008-07-16 2010-01-20 贵州红林机械有限公司 Method for smelting high-silicon aluminum alloy
JP2015021184A (en) * 2013-07-24 2015-02-02 株式会社ブリヂストン Method of manufacturing metal wire for reinforcement of rubber article, metal wire for reinforcement of rubber article, pneumatic tire using the same and apparatus for manufacturing metal wire for reinforcement of rubber article
CN109402699A (en) * 2018-11-01 2019-03-01 中国科学院兰州化学物理研究所 A kind of aluminum alloy surface acid resistance corrosion function ceramic membrane preparation process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506069A (en) * 1993-10-14 1996-04-09 Ovonic Battery Company, Inc. Electrochemical hydrogen storage alloys and batteries fabricated from Mg containing base alloys
CN1793436A (en) * 2005-11-25 2006-06-28 湖南大学 Process for directly electroplating on surface of aluminium or aluminium alloy
CN101270494A (en) * 2008-05-08 2008-09-24 重庆大学 Galvano-chemistry preparation method for metallic face protection ceramic film
CN101629251A (en) * 2008-07-16 2010-01-20 贵州红林机械有限公司 Method for smelting high-silicon aluminum alloy
JP2015021184A (en) * 2013-07-24 2015-02-02 株式会社ブリヂストン Method of manufacturing metal wire for reinforcement of rubber article, metal wire for reinforcement of rubber article, pneumatic tire using the same and apparatus for manufacturing metal wire for reinforcement of rubber article
CN109402699A (en) * 2018-11-01 2019-03-01 中国科学院兰州化学物理研究所 A kind of aluminum alloy surface acid resistance corrosion function ceramic membrane preparation process

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