CN111663345B - Washing-free reactive dye printing treatment liquid and application thereof - Google Patents
Washing-free reactive dye printing treatment liquid and application thereof Download PDFInfo
- Publication number
- CN111663345B CN111663345B CN202010436428.6A CN202010436428A CN111663345B CN 111663345 B CN111663345 B CN 111663345B CN 202010436428 A CN202010436428 A CN 202010436428A CN 111663345 B CN111663345 B CN 111663345B
- Authority
- CN
- China
- Prior art keywords
- cross
- water
- linking agent
- washing
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6424—Compounds containing isocyanate or isothiocyanate groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6493—Carbodiimides (=N=C=N=)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The invention relates to a washing-free reactive dye printing treatment liquid which comprises the following components in parts by mass based on the total weight of the liquid: aqueous crosslinking agent: 1% -15%, water-based polyester emulsion: 20 to 70 percent of water, and the balance of water. The invention also discloses application of the washing-free reactive dye printing treating fluid in transfer printing of fabrics. The washing-free reactive dye printing treatment solution can enhance the crosslinking fixation degree of the dye and the fiber, and meanwhile, after the fabric treated by the treatment solution is printed, the fabric hand feeling is not influenced, the utilization rate of the dye in the transfer printing process is improved, and the discharge of printing and dyeing wastewater in actual production is reduced.
Description
Technical Field
The invention relates to the technical field of transfer printing, in particular to a washing-free reactive dye printing treatment liquid and application thereof.
Background
The fabric transfer-printed by the reactive dye has more surface flooding and poor color fastness before washing; the color fastness is improved after washing, but a large amount of printing and dyeing wastewater is generated. Therefore, the method for printing the washing-free reactive dye has important significance, so that the dye utilization rate of the fabric in the transfer printing process is improved, and the printing and dyeing wastewater discharge is reduced.
CN03819480.5 discloses a method for dyeing or printing cellulose-containing fibre materials using disperse dyes, which comprises treating the fibre materials with an aqueous composition comprising a water-soluble or water-dispersible polyester resin and a water-soluble or water-dispersible acrylate binder. The method takes the disperse dye as the coloring agent, is more suitable for dyeing and printing fabrics containing synthetic fibers, and has weaker binding capacity to cellulose fibers. CN201610326578.5 discloses a water-based colored layer coating for a transfer film, which is composed of the following raw materials in parts by mass: styrene maleic anhydride copolymer resin aqueous solution: 20-60, polyacrylic resin aqueous solution: 20-50, water-based reinforcing resin: 3-10, water-based crosslinking agent: 0-3, water-based wetting and leveling agent: 0-1, water-based defoamer: 0-1, PH adjuster: 0-1, deionized water: 0-30. The preparation process of the water-based colored layer coating for the transfer film is relatively complicated.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide the washing-free reactive dye printing treatment liquid and the application thereof.
The invention aims to provide a washing-free reactive dye printing treatment solution which comprises the following components in parts by mass based on the total weight of the treatment solution: aqueous crosslinking agent: 1% -15%, water-based polyester emulsion: 20 to 70 percent of water, and the balance of water.
Further, the washing-free reactive dye printing treatment liquid consists of the following components in percentage by mass: 1-15% of water-based cross-linking agent, 20-55% of water-based polyester emulsion and the balance of water. The water-based cross-linking agent has the function of enabling the reactive dye which is not fixed on the fiber to be cross-linked and fixed on the fiber in the printing treatment process, so that more dye is combined with the fiber. The aqueous polyester emulsion has the function of improving the dyeing definition of the fabric, because the viscosity of the aqueous polyester emulsion is high, and the bleeding degree of the printing is reduced in the drying process after the fabric is dyed, so that the dyeing definition is improved.
Further, the aqueous crosslinking agent includes one or more of a diimine type crosslinking agent, an aziridine type crosslinking agent, an isocyanate type crosslinking agent, and an oxazoline type crosslinking agent.
Further, the diimine-type crosslinking agent is a carbodiimide crosslinking agent.
Further, the aziridine crosslinking agent is selected from the group consisting of crosslinking agents XR-2500.
Further, the isocyanate type cross-linking agent is selected from one or more of cross-linking agent XC-227, cross-linking agent SD-235, cross-linking agent HD-8036, cross-linking agent ACURE355, cross-linking agent Bayer-305 and Bayer-2655.
Further, the oxazoline crosslinking agent is selected from one or more of a crosslinking agent XH-500, a crosslinking agent WS-500 and a crosslinking agent XR-5510.
Further, the aqueous polyester comprises an aqueous polyurethane emulsion and/or an emulsion of an aqueous polyacrylate.
In the invention, the average grain diameter of the water-based polyester emulsion is less than 200 nm; viscosity is 1-50 mP.s. The aqueous polyester emulsion with the characteristic parameters can improve the printing definition to the maximum extent.
The second purpose of the invention is to disclose the application of the washing-free reactive dye printing treating fluid in the invention in the transfer printing of fabrics, wherein the fabrics are fabrics with reactive dyes capable of being dyed.
The third purpose of the invention is to disclose a washing-free reactive dye printing method of fabric, which comprises the following steps:
(1) padding the fabric by using the washing-free reactive dye printing treatment solution, wherein the padding rate is 65-85%, and after padding treatment, drying the fabric for 30-60 s at 60-100 ℃; the fabric is a fabric which can be dyed by reactive dye;
(2) and (3) attaching the transfer printing paper to the surface of the fabric treated in the step (1), and pressing and ironing for 2-5 min at the temperature of 160-190 ℃ to finish the transfer printing process.
Further, in the step (1), the padding process is a one-padding two-padding method.
By the transfer printing method, the dye on the transfer printing paper is attached to the fabric, and the crosslinking fixation of the dye and the fiber is enhanced by the water-based polymer in the washing-free reactive dye printing treatment liquid padded on the fabric in the step (1), so that the color fastness is improved.
In the invention, the fabric which can be treated by the washing-free reactive dye printing treatment solution is a fabric which can be dyed by a reactive dye, and the fabric comprises a fabric containing cellulose fibers, regenerated cellulose fibers, protein fibers, nylon 56 or nylon 66 or a hydrophilic fabric.
By the scheme, the invention at least has the following advantages:
the washing-free reactive dye printing treatment solution consists of a water-based cross-linking agent and a water-based polyester emulsion, and reactive dyes which are not fixed on fibers are cross-linked and fixed on the fibers by using water-based macromolecules so that more dyes are combined with the fibers.
The invention also discloses a washing-free reactive dye printing method for the fabric, which is simple and rapid. When the method is used for transfer printing of the fabric, the obtained fabric has high fastness to washing, rubbing, perspiration and light, and all the fastnesses conform to GB/T3921-: standard for xenon arc.
The foregoing is a summary of the present invention, and in order to provide a clear understanding of the technical means of the present invention and to be implemented in accordance with the present specification, the following is a preferred embodiment of the present invention and is described in detail below.
Detailed Description
The following examples are given to further illustrate the embodiments of the present invention. The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
Unless otherwise specified, the fabrics in the following examples are all cotton fabrics.
Example 1
The embodiment provides a washing-free reactive dye printing treatment fluid which comprises the following components in percentage by weight based on the total weight of the fluid: oxazoline type crosslinking agent: 10%, aqueous polyurethane emulsion: 50 percent of water, and the balance of water. Wherein the oxazoline crosslinking agent is a crosslinking agent XH-500, and the average particle diameter of the aqueous polyurethane emulsion is 95 nm; viscosity 5.3mP · s.
The preparation method of the washing-free reactive dye printing treating fluid comprises the following steps:
according to the weight percentage of the treatment fluid, 10 percent of cross-linking agent XH-500 is diluted by equivalent deionized water, is evenly stirred and is added into 50 percent of waterborne polyurethane emulsion to supplement water to 100 percent.
The embodiment also provides a method for printing the cotton fabric by using the washing-free reactive dye treatment solution, which comprises the following steps:
(1) padding treatment fluid: the washing-free reactive dye printing treatment solution is adopted to carry out one-soaking and two-rolling on the fabric, the rolling residual rate is 75%, after the padding is finished, the fabric is dried for 30s at 100 ℃, and the transfer printing is carried out immediately.
(2) Transfer printing: at normal temperature, the transfer printing substrate is attached to the surface of the cotton fabric, and then the cotton fabric is pressed and ironed for 3min at 180 ℃ by using a pyrograph machine.
Example 2
The embodiment provides a washing-free reactive dye printing treatment fluid which comprises the following components in percentage by weight based on the total weight of the fluid: isocyanate crosslinking agent: 5%, aqueous polyacrylate emulsion: 50 percent of water, and the balance of water. Wherein the isocyanate crosslinking agent is a crosslinking agent SD-235, and the average particle size of the water-based polyacrylate emulsion is 90 nm; viscosity 6.1 mPs. The preparation method of the washing-free reactive dye printing treating fluid comprises the following steps:
according to the weight percentage of the treatment fluid, 5 percent of cross-linking agent SD-235 is diluted by equivalent deionized water, is evenly stirred and is added into 50 percent of water-based polyacrylate emulsion to supplement water to 100 percent.
The washing-free reactive dye treatment solution of the embodiment is used for carrying out washing-free reactive dye printing on cotton fabrics according to the method of the embodiment 1.
Example 3
The embodiment provides a washing-free reactive dye printing treatment fluid which comprises the following components in percentage by weight based on the total weight of the fluid: aziridine crosslinking agent XR-2500: 5%, oxazoline-type crosslinking agent XR-5510: 5 percent, water-based polyurethane emulsion: 50 percent of water, and the balance of water. Wherein the average particle size of the aqueous polyurethane emulsion is 95 nm; viscosity 5.3mP · s.
The preparation method of the washing-free reactive dye printing treating fluid comprises the following steps:
according to the weight percentage of the treatment fluid, 5 percent of aziridine crosslinking agent XR-2500 and 5 percent of oxazoline crosslinking agent XR-5510 are respectively diluted by equivalent deionized water, stirred evenly and added into 50 percent of waterborne polyurethane emulsion to supplement water to 100 percent.
The washing-free reactive dye treatment solution of the embodiment is used for carrying out washing-free reactive dye printing on cotton fabrics according to the method of the embodiment 1.
Example 4
The embodiment provides a washing-free reactive dye printing treatment fluid which comprises the following components in percentage by weight based on the total weight of the fluid: aziridine crosslinking agent XR-2500: 3 percent, water-based polyurethane emulsion: 50 percent of water, and the balance of water. Wherein the average particle size of the aqueous polyurethane emulsion is 95 nm; viscosity 5.3mP · s.
The preparation method of the washing-free reactive dye printing treating fluid comprises the following steps:
according to the weight percentage of the treatment fluid, 3 percent of cross-linking agent XR-2500 is diluted by 10 percent of deionized water, the mixture is evenly stirred and then added into 50 percent of waterborne polyurethane emulsion to supplement water to 100 percent.
The washing-free reactive dye treatment solution of the embodiment is used for carrying out washing-free reactive dye printing on cotton fabrics according to the method of the embodiment 1.
Comparative example 1
The comparative example provides a treatment fluid comprising the following components in weight percent: aqueous polyurethane emulsion: 50 percent of water, and the balance of water.
Transfer printing of cotton fabric was carried out according to the method of example 1 using the above treatment solution.
Comparative example 2
The cotton fabric which is not treated by the printing treatment fluid is directly subjected to transfer printing. The transfer printing substrate is directly attached to the surface of the cotton fabric at normal temperature, and then the cotton fabric is pressed and ironed for 3min at 180 ℃ by using a pyrograph machine.
Comparative example 3
The comparative example provides a treatment fluid comprising the following components in weight percent: aqueous polyurethane thickener: 10 percent of water, and the balance of water.
Transfer printing of cotton fabric was carried out according to the method of example 1 using the above treatment solution.
After transfer printing, the cotton fabrics obtained in the above examples and comparative examples were subjected to various fastness tests, and the results are shown in table 1. The result shows that all the fastnesses of the cotton fabric all conform to GB/T3921-: xenon arc (Xeon arc). The comparative examples are not as fast as the invention.
TABLE 1 fastness test results of fabrics
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, it should be noted that, for those skilled in the art, many modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.
Claims (8)
1. A washing-free reactive dye printing method of fabric is characterized by comprising the following steps:
(1) padding the fabric before the transfer by adopting a washing-free reactive dye printing treatment solution, wherein the padding rate is 65-85%, and after padding treatment, drying the fabric for 30-60 s at 60-100 ℃; the fabric is a fabric which can be dyed by reactive dye;
(2) attaching transfer printing paper to the surface of the fabric treated in the step (1), and pressing and ironing the fabric for 2-5 min at the temperature of 160-190 ℃ to finish the transfer printing process;
the washing-free reactive dye printing treatment liquid is composed of the following components in parts by mass based on the total weight of the liquid: aqueous crosslinking agent: 1% -15%, water-based polyester emulsion: 20 to 70 percent of water, and the balance of water.
2. The printing method of the washing-free reactive dye according to claim 1, characterized by comprising the following components in parts by mass based on the total weight of the printing method: 1-15% of water-based cross-linking agent, 20-55% of water-based polyester emulsion and the balance of water.
3. The method for printing washing-free reactive dye according to claim 1, wherein the water-based cross-linking agent comprises one or more of a diimine cross-linking agent, an aziridine cross-linking agent, an isocyanate cross-linking agent and an oxazoline cross-linking agent.
4. The process for printing with wash-free reactive dyes according to claim 3 characterized in that the diimine type cross-linking agent is selected from carbodiimide cross-linking agents.
5. The process for printing wash-free reactive dyes according to claim 3, characterized in that the aziridine crosslinking agent is selected from the group of crosslinking agents XR-2500.
6. The printing method of the washing-free reactive dye according to claim 3, characterized in that the isocyanate type cross-linking agent is selected from one or more of cross-linking agent XC-227, cross-linking agent SD-235, cross-linking agent HD-8036, cross-linking agent ACURE355, cross-linking agent Bayer-305 and Bayer-2655.
7. The printing method of the washing-free reactive dye according to claim 3, wherein the oxazoline-type cross-linking agent is selected from one or more of a cross-linking agent XH-500, a cross-linking agent WS-500 and a cross-linking agent XR-5510.
8. The method for printing washing-free reactive dyes according to claim 1, characterized in that the water-based polyester comprises a water-based polyurethane emulsion and/or a water-based polyacrylate emulsion.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010436428.6A CN111663345B (en) | 2020-05-21 | 2020-05-21 | Washing-free reactive dye printing treatment liquid and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010436428.6A CN111663345B (en) | 2020-05-21 | 2020-05-21 | Washing-free reactive dye printing treatment liquid and application thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111663345A CN111663345A (en) | 2020-09-15 |
CN111663345B true CN111663345B (en) | 2021-11-23 |
Family
ID=72384221
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010436428.6A Active CN111663345B (en) | 2020-05-21 | 2020-05-21 | Washing-free reactive dye printing treatment liquid and application thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111663345B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112941939B (en) * | 2021-02-04 | 2022-09-20 | 杭州晨宇布业织造有限公司 | Fabric shaping process and fabric |
CN112832044A (en) * | 2021-02-25 | 2021-05-25 | 苏州大学 | Washing-free transfer printing process for transfer printing of glass fiber fabric |
CN112832045A (en) * | 2021-02-25 | 2021-05-25 | 苏州大学 | Washing-free transfer printing paste and preparation method and application thereof |
CN112941934A (en) * | 2021-03-02 | 2021-06-11 | 苏州大学 | Transfer printing paper modified paste and dry heat transfer printing process of nylon 56/cotton interwoven fabric |
CN113201949A (en) * | 2021-05-07 | 2021-08-03 | 江苏华佳丝绸股份有限公司 | Color-changing real silk fabric and processing method thereof |
CN113481738A (en) * | 2021-07-22 | 2021-10-08 | 江苏华佳丝绸股份有限公司 | Soft color-changing real silk fabric and processing method thereof |
JP2023034579A (en) * | 2021-08-31 | 2023-03-13 | セイコーエプソン株式会社 | Treatment liquid composition for dye printing, composition set, printing method, and inkjet printing method |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5281182A (en) * | 1975-12-27 | 1977-07-07 | Toyo Boseki | Transfer printing method of cellulosic products |
DE2926512A1 (en) * | 1979-06-30 | 1981-01-22 | Rotta Gmbh & Co Dr | METHOD FOR COMBINING DYEING AND / OR PRINTING AND FINISHING ALL OR PARTLY OF TEXTILES EXISTING FROM CELLULOSE FIBERS |
WO2004016849A1 (en) * | 2002-08-12 | 2004-02-26 | Ciba Specialty Chemicals Holding Inc. | Method of dyeing or printing cellulose-containing fibre materials using disperse dyes |
KR101634267B1 (en) * | 2016-02-04 | 2016-07-08 | (주)제라원 | Surface treatment agent for sublimation-disperse dye ink transfer printing of natural fiber yarn, the method for making surface treatment agent and natural fiber yarn printed matter by using the method for sublimation-disperse dye ink transfer printing |
-
2020
- 2020-05-21 CN CN202010436428.6A patent/CN111663345B/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN111663345A (en) | 2020-09-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111663345B (en) | Washing-free reactive dye printing treatment liquid and application thereof | |
JP4579966B2 (en) | Coloring composition | |
US6080687A (en) | Method of dyeing anionic materials with pigment colors having a net cationic charge using a padding process | |
WO2014063028A1 (en) | Process for coloring textile materials | |
US20030079302A1 (en) | Fiber-reactive polymeric dyes | |
JPH11315485A (en) | Printing and printed woven fabric | |
CN100482884C (en) | Surface modifier for transfer printing with dispersive cotton fabric dye and its pre-treatment method | |
CN110777549B (en) | Microcapsule slow-release cross-linking agent mucilage and preparation method and application thereof | |
CA1295438C (en) | Textile printing and dyeing | |
CN111519450A (en) | Alkali-free pretreatment slurry for wet transfer printing of wool fabric and printing process | |
Teli | Advances in the dyeing and printing of silk | |
CN105603781B (en) | A kind of preparation method of modified acrylate emulsion and the application in pigment printing | |
Yang et al. | Cotton fabric inkjet printing with acid dyes | |
WO2018163966A1 (en) | Ink, ink jet textile printing method, ink cartridge, ink jet printer, and colored cloth | |
CN105040465B (en) | Dyeing of Superfine Polyester Fibre coating dye liquor and the method for improving Dyeing of Superfine Polyester Fibre color depth | |
CN108642920B (en) | Washing-resistant and anti-falling fabric printing process | |
Gutjahr et al. | Direct print coloration | |
JP2000054277A (en) | Improvement in ozone stability of dyed or undyed polyamide-containing material | |
CN110423553A (en) | A kind of thermal transfer metal zip fastener strap coating solution, thermal transfer metal zip fastener and preparation method thereof | |
JPS63120182A (en) | Coloration of fabric fiber | |
CN113563512B (en) | Anti-rewetting dispersant for reactive dye and preparation method thereof | |
CN110016103B (en) | Modified carboxymethyl starch polymer and preparation method and application thereof | |
CN109914130B (en) | Antistatic pretreatment solution for digital ink-jet printing of terylene and application thereof | |
KR102418421B1 (en) | Surface treatment composition for improving printability of cellulose materials | |
CN109403083B (en) | Reactive ink-jet printing dye mixture and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |