CN111661819A - Hydrogen production machine gas mixture conversion combustion system - Google Patents

Hydrogen production machine gas mixture conversion combustion system Download PDF

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Publication number
CN111661819A
CN111661819A CN202010483266.1A CN202010483266A CN111661819A CN 111661819 A CN111661819 A CN 111661819A CN 202010483266 A CN202010483266 A CN 202010483266A CN 111661819 A CN111661819 A CN 111661819A
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hydrogen
chamber
combustion
reaction chamber
combustion chamber
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CN202010483266.1A
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陈伟明
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C13/00Apparatus in which combustion takes place in the presence of catalytic material
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0822Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217Alcohols
    • C01B2203/1223Methanol

Abstract

The invention discloses a mixed gas conversion combustion system of a hydrogen production machine, wherein a combustion chamber is arranged in a host machine and is coaxially arranged with the host machine, a burner sleeve and a flame guide cylinder are horizontally arranged at the upper and lower positions of the combustion chamber, a steam pipe is vertically arranged in a jacket of the combustion chamber and penetrates through a water jacket and a catalytic reaction chamber, the top of the catalytic reaction chamber is provided with a hydrogen accumulation output layer, one side of the catalytic reaction chamber is provided with a hydrogen outlet, the bottom of the combustion chamber is provided with an air inlet combustion-supporting structure and a hydrogen inlet channel, the radiant heat of the combustion chamber is used as a heat source to provide a heated reaction condition for a methanol-water mixed solution and a catalyst in the water jacket, solution steam enters three layers of catalytic reaction chambers through the steam pipe to be converted into combustible hydrogen and methane, the converted hydrogen enters the combustion chamber to be combusted, the mixed solution and the catalyst are kept at working temperature as, the reaction can be continuously cycled to provide the converted hydrogen for combustion by the burner fuel.

Description

Hydrogen production machine gas mixture conversion combustion system
Technical Field
The invention relates to the technical field, in particular to a mixed gas conversion combustion system of a hydrogen production machine.
Background
The industrial production needs a large amount of consumed energy, most of the energy is petrochemical fuel, 70 percent of the energy consumption comes from industry at present, hydrogen energy has high heat value and is clean and environment-friendly, the hydrogen energy can be used as novel energy to replace the petrochemical fuel, in addition, the reforming of methanol and steam is a reaction technology for preparing hydrogen, and the component after the conversion reaction is H2、CO、CO2、CH4The calorific value of hydrogen is up to 142351KJ/kg, which is the highest among all petrochemical fuels, chemical fuels and biological fuels, and in the prior art, methanol and water vaporCO in components after reforming hydrogen production reaction2Occupies 1/4 content, CO2Is a carbon-oxygen compound, has inactive chemical property and high thermal stability, and can not be combusted, so how to utilize CO occupying 1/4 content2Making it a combustible gas, which is also a problem that technicians in the related field need to solve urgently.
Disclosure of Invention
In order to solve the technical problems, the technical scheme provided by the invention is as follows: a hydrogen production machine mixed gas conversion combustion system comprises a host, a combustion chamber, a hydrogen storage buffer tank, a water jacket, a catalytic reaction chamber, a plurality of steam pipes, a flame guide cylinder, a burner sleeve and an air inlet combustion-supporting structure, wherein the combustion chamber is arranged inside the host and is coaxially arranged with the host, a cavity jacket between the inner wall of the host and the outer wall of the combustion chamber is divided into the water jacket, the catalytic reaction chamber and a reaction gas chamber from top to bottom, the burner sleeve and the flame guide cylinder are horizontally arranged at the upper position and the lower position of the combustion chamber, one end of the burner sleeve is communicated with the combustion chamber and is used for placing a combustion burner, the other end of the burner sleeve penetrates through the catalytic reaction chamber and is communicated with the outside, one end of each of the plurality of steam pipes is vertically arranged in the jacket of the combustion chamber and penetrates through the water jacket and the catalytic reaction chamber, one end of each steam, the catalytic reaction chamber is characterized in that the top of the catalytic reaction chamber is provided with a hydrogen gathering output layer, one side of the catalytic reaction chamber is provided with a hydrogen outlet, and the bottom of the combustion chamber is provided with an air inlet combustion-supporting structure and a hydrogen inlet channel.
As an improvement, the catalytic reaction chamber sequentially comprises a lower layer reaction chamber, a middle layer reaction chamber and an upper layer reaction chamber from bottom to top, wherein a methanol-steam reforming hydrogen production catalyst is arranged in the lower layer reaction chamber, a CO-steam conversion reaction catalyst is arranged in the middle layer reaction chamber, and a CO is arranged in the upper layer reaction chamber2-a hydromethanation reaction catalyst.
As an improvement, a methanol-water mixed solution is filled in the water jacket, and the mass ratio of methanol to water is 2:8 or 3: 7.
As an improvement, the air inlet combustion-supporting structure comprises an air storage disc arranged at the lower part of the combustion chamber, the bottom of the combustion chamber is communicated with the air storage disc through a cyclone air channel, and an air inlet pipe is arranged at one end of the air storage disc.
As an improvement, an interlayer sealing partition plate is arranged between the top of the catalytic reaction chamber and the bottom of the water jacket, and a breathable porous partition plate is arranged between the bottom of the catalytic reaction chamber and the gas chamber.
As an improvement, the mixed gas of the conversion reaction of the catalytic reaction chamber enters a hydrogen storage buffer tank from a hydrogen outlet through a hydrogen guide pipe, is compressed and then is introduced into the combustion chamber from a hydrogen conveying pipe and a hydrogen inlet channel.
As an improvement, the outer side of the part of the flame guide cylinder extending out of the main machine is provided with a cooling outer cylinder.
As an improvement, the realization method comprises the following steps:
(1) placing methanol-water mixed solution in the water jacket, placing methanol-steam reforming hydrogen production catalyst in the lower layer reaction chamber, placing CO-steam conversion reaction catalyst in the middle layer reaction chamber, placing CO in the upper layer reaction chamber2-a hydromethanation reaction catalyst, each layer being separated by a porous partition;
(2) placing fuel in a combustion chamber for mixed combustion, generating expansion pressure in the combustion chamber to force combustion flame out of a flame guide cylinder, using the expansion pressure as a heat source and enabling the temperature of the chamber wall of the combustion chamber to form a high-temperature reaction heat source;
(3) the methanol-water mixed solution in the water jacket and the catalysts in the catalytic reaction chamber are subjected to radiant heat of the chamber wall, the methanol-water mixed solution forms mixed solution steam, the mixed solution steam enters the catalytic reaction chamber through a steam pipe multi-pipe, and the mixed solution steam is converted into hydrogen and methane through the three layers of reaction chambers;
(4) the reacted hydrogen and methane enter the combustion chamber through the hydrogen outlet, the hydrogen guide pipe, the hydrogen storage buffer tank, the hydrogen conveying pipe and the hydrogen inlet channel to be combusted.
After adopting the structure, the invention has the following advantages: the radiant heat of the combustion chamber is used as a heat source to provide heating reaction conditions for a methanol-water mixed solution and a catalyst in the water jacket, solution steam enters the three layers of catalytic reaction chambers through the steam pipe and is converted into combustible hydrogen and methane gas, the converted hydrogen enters the combustion chamber for combustion, the solution and the catalyst are kept at working temperature by using the heat source, and the converted hydrogen can be provided by continuous circular reaction under the condition of continuously supplementing the amount of the mixed solution in the water jacket so as to be combusted by using the burner fuel.
Drawings
FIG. 1 is a schematic diagram of the internal structure of a mixed gas-converting combustion system of a hydrogen generator according to the present invention.
FIG. 2 is a schematic diagram of the internal side structure of the mixed gas reforming combustion system of the hydrogen generator.
FIG. 3 is a schematic top view of a mixed gas-shift combustion system of a hydrogen generator of the present invention.
As shown in the figure: 1. the device comprises a main machine, 1.1 parts of a water jacket, 1.2 parts of a catalytic reaction chamber, 1.2a parts of a lower layer reaction chamber, 1.2b parts of a middle layer reaction chamber, 1.2c parts of an upper layer reaction chamber, 1.3 parts of a reaction gas chamber, 2 parts of a combustion chamber, 3 parts of a steam pipe multi-pipe, 4 parts of a flame guide cylinder, 5 parts of a combustion nozzle sleeve, 6 parts of a hydrogen outlet, 7 parts of a hydrogen storage buffer tank, 8 parts of an air storage disc, 9 parts of a cyclone air duct, 10 parts of an air inlet pipe, 11 parts of an interlayer partition plate, 12 parts of a breathable porous partition plate, 13 parts of a cooling outer cylinder, 14 parts of a hydrogen inlet channel, 15 parts of a hydrogen guide pipe, 16.
Detailed Description
With the attached drawing, the mixed gas conversion combustion system of the hydrogen production machine comprises a main machine 1, a combustion chamber 2, a water jacket 1.1, a catalytic reaction chamber 1.2, a steam pipe multi-pipe 3, a flame guide cylinder 4, a burner tip sleeve 5, a hydrogen storage buffer tank 7 and an air inlet combustion-supporting structure, wherein the combustion chamber 2 is arranged in the main machine 1 and is coaxially arranged with the main machine 1, a cavity jacket between the inner wall of the main machine 1 and the outer wall of the combustion chamber 2 is divided into the water jacket 1.1, the catalytic reaction chamber 1.2 and a reaction gas chamber 1.3 from top to bottom, the burner tip sleeve 5 and the flame guide cylinder 4 are horizontally arranged at the upper and lower positions of the combustion chamber 2, one end of the burner tip sleeve 5 is communicated with the combustion chamber 2 for placing a burner tip, the other end of the burner tip sleeve passes through the catalytic reaction chamber 1.2 to be communicated with the outside, one end of the flame guide cylinder 4 is communicated with the combustion chamber 2, the other end of the flame guide cylinder 4 passes through the water, one end of the catalytic reaction chamber extends into the reaction gas chamber 1.3, the other end of the catalytic reaction chamber extends into the top of the water jacket 1.1, the top of the catalytic reaction chamber 1.2 is provided with a hydrogen accumulation output layer, one side of the catalytic reaction chamber is provided with a hydrogen outlet 6, and the bottom of the combustion chamber 2 is provided with an air inlet combustion-supporting structure and a hydrogen inlet channel 14.
As a preferred embodiment of this embodiment, the catalytic reaction chamber 1.2 comprises a lower reaction chamber 1.2a, a middle reaction chamber 1.2b and an upper reaction chamber 1.2c from bottom to top in sequence, the lower reaction chamber 1.2a contains a catalyst for hydrogen production by methanol-steam reforming, the middle reaction chamber 1.2b contains a catalyst for CO-steam shift reaction, and the upper reaction chamber 1.2c contains CO2-a hydromethanation reaction catalyst.
As a preferred embodiment of the embodiment, the water jacket 1.1 is filled with a methanol-water mixed solution, and the mass ratio of methanol to water is 2:8 or 3: 7.
As a preferred embodiment of this embodiment, the air intake combustion-supporting structure includes an air storage disk 8 disposed at a lower portion of the combustion chamber 2, the bottom of the combustion chamber 2 is communicated with the air storage disk 8 through a cyclone duct 9, and an air inlet pipe 10 is disposed at one end of the air storage disk 8.
As the preferred embodiment of this embodiment, a partition wall 11 is arranged between the top of the catalytic reaction chamber 1.2 and the bottom of the water jacket 1.1, and a gas-permeable porous partition wall 12 is arranged between the bottom of the catalytic reaction chamber 1.2 and the gas 1.3.
As the preferred embodiment of this embodiment, the mixture gas of the conversion reaction in the catalytic reaction chamber 1.2 enters the hydrogen storage buffer tank 7 from the hydrogen outlet 6 through the hydrogen guide pipe 15, is compressed and then is introduced into the combustion chamber 2 from the hydrogen conveying pipe 16 and the hydrogen inlet channel 14.
As a preferred embodiment of the embodiment, the outer side of the part of the flame guide cylinder 4 extending out of the main machine 1 is provided with a cooling outer cylinder 13.
As a preferred embodiment of the present embodiment, the implementation method comprises the following steps:
(1) placing methanol-water mixed solution in the water jacket 1.1, placing methanol-steam reforming hydrogen production catalyst in the lower layer reaction chamber 1.2a, placing CO-steam conversion reaction catalyst in the middle layer reaction chamber 1.2b, and placing CO in the upper layer reaction chamber 1.2c2Catalysts for hydromethanation, with one layer eachSeparating by a porous separator;
(2) placing fuel in the combustion chamber 1.2 for mixed combustion, so that expansion pressure is generated in the combustion chamber 1.2 to force combustion flame out of the flame guide cylinder 4 to serve as a heat source, and the temperature of the chamber wall of the combustion chamber 1.2 forms a high-temperature reaction heat source;
(3) the methanol-water mixed solution in the water jacket 1.1 and each catalyst in the catalytic reaction chamber 1.2 are subjected to the radiation heat of the chamber wall, the methanol-water mixed solution forms mixed solution steam, the mixed solution steam enters the catalytic reaction chamber 1.2 through a steam pipe multi-pipe 3 and is converted into hydrogen and methane through the three layers of reaction chambers;
(4) the reacted hydrogen and methane enter the combustion chamber 2 for combustion through the hydrogen outlet 6, the hydrogen guide pipe 15, the hydrogen storage buffer tank 7, the hydrogen conveying pipe 16 and the hydrogen inlet channel 14, the combustion of the hydrogen in the combustion chamber 2 enables the combustion chamber 2 to keep high temperature, and the hydrogen can be continuously circularly reacted to provide converted hydrogen for the combustion of the fuel of the combustor under the condition of continuously supplementing the amount of the mixed solution in the water jacket.
The present invention and its embodiments have been described above, and the description is not intended to be limiting, and the drawings are only one embodiment of the present invention, and the actual structure is not limited thereto. In summary, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (8)

1. A mixed gas conversion combustion system of a hydrogen production machine is characterized by comprising a host, a combustion chamber, a hydrogen storage buffer tank, a water jacket, a catalytic reaction chamber, a plurality of steam pipes, a flame guide cylinder, a burner sleeve and an air inlet combustion-supporting structure, wherein the combustion chamber is arranged inside the host and is coaxially arranged with the host, a cavity jacket between the inner wall of the host and the outer wall of the combustion chamber is divided into the water jacket, the catalytic reaction chamber and a reaction gas chamber from top to bottom, the burner sleeve and the flame guide cylinder are horizontally arranged at the upper and lower positions of the combustion chamber, one end of the burner sleeve is communicated with the combustion chamber and is used for placing a combustion burner, the other end of the burner sleeve is communicated with the outside through the catalytic reaction chamber, one end of the flame guide cylinder is communicated with the combustion chamber, the other end of the plurality of steam pipes is vertically arranged in the combustion chamber and passes through the water, the other end of the catalytic reaction chamber extends into the top of the water jacket, a hydrogen gathering output layer is arranged at the top of the catalytic reaction chamber, a hydrogen outlet is formed in one side of the catalytic reaction chamber, and an air inlet combustion-supporting structure and a hydrogen inlet channel are arranged at the bottom of the combustion chamber.
2. The system of claim 1, wherein the catalytic reaction chamber comprises a lower reaction chamber, a middle reaction chamber and an upper reaction chamber from bottom to top, the lower reaction chamber contains a catalyst for hydrogen production by methanol-steam reforming, the middle reaction chamber contains a catalyst for CO-steam conversion, and the upper reaction chamber contains a catalyst for CO-steam conversion2-a hydromethanation reaction catalyst.
3. The system for converting and combusting mixed gas of hydrogen generator as claimed in claim 1, wherein the water jacket is filled with methanol-water mixed solution, and the mass ratio of methanol to water is 2:8 or 3: 7.
4. The system for converting and combusting mixed gas of a hydrogen generator as claimed in claim 1, wherein the air intake combustion-supporting structure comprises an air storage disc arranged at the lower part of the combustion chamber, the bottom of the combustion chamber is communicated with the air storage disc through a cyclone air duct, and an air inlet pipe is arranged at one end of the air storage disc.
5. The system for converting and combusting mixed gas of a hydrogen generator as claimed in claim 1, wherein a partition plate is arranged between the top of the catalytic reaction chamber and the bottom of the water jacket for sealing, and a gas-permeable porous partition plate is arranged between the bottom of the catalytic reaction chamber and the gas chamber.
6. The system of claim 1, wherein the mixed gas from the catalytic reaction chamber enters the hydrogen storage buffer tank from the hydrogen outlet through the hydrogen guide tube, is compressed, and is introduced into the combustion chamber from the hydrogen delivery tube and the hydrogen inlet channel.
7. The system for converting and burning the mixed gas of the hydrogen generator as claimed in claim 1, wherein the outer side of the part of the flame guide cylinder extending out of the main unit is provided with a cooling outer cylinder.
8. The system for converting and burning the mixed gas of the hydrogen generator as claimed in claim 1, wherein the method comprises the following steps:
(1) placing methanol-water mixed solution in the water jacket, placing methanol-steam reforming hydrogen production catalyst in the lower layer reaction chamber, placing CO-steam conversion reaction catalyst in the middle layer reaction chamber, placing CO in the upper layer reaction chamber2-a hydromethanation reaction catalyst, each layer being separated by a porous partition;
(2) placing fuel in a combustion chamber for mixed combustion, generating expansion pressure in the combustion chamber to force combustion flame out of a flame guide cylinder, using the expansion pressure as a heat source and enabling the temperature of the chamber wall of the combustion chamber to form a high-temperature reaction heat source;
(3) the methanol-water mixed solution in the water jacket and the catalysts in the catalytic reaction chamber are subjected to radiant heat of the chamber wall, the methanol-water mixed solution forms mixed solution steam, the mixed solution steam enters the catalytic reaction chamber through a steam pipe multi-pipe, and the mixed solution steam is converted into hydrogen and methane through the three layers of reaction chambers;
(4) the reacted hydrogen and methane enter the combustion chamber through the hydrogen outlet, the hydrogen guide pipe, the hydrogen storage buffer tank, the hydrogen conveying pipe and the hydrogen inlet channel to be combusted.
CN202010483266.1A 2020-06-01 2020-06-01 Hydrogen production machine gas mixture conversion combustion system Pending CN111661819A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112340698A (en) * 2020-10-29 2021-02-09 广州汤姆逊电气有限公司 Reaction device for preparing hydrogen fuel by high-temperature catalytic cracking of methane
CN113432125A (en) * 2021-07-15 2021-09-24 山西新源煤化燃料有限公司 White oil hydrogen-mixed combustion burner device

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JP2000281312A (en) * 1999-03-31 2000-10-10 Sanyo Electric Co Ltd Reforming device for fuel cell
US20040223908A1 (en) * 2001-11-07 2004-11-11 Holladay Jamelyn D. Microcombustors, microreformers, and methods involving combusting or reforming fluids
CN106145036A (en) * 2016-08-25 2016-11-23 晋城市阿邦迪能源有限公司 Methanation reaction purifies the methanol steam reforming device of CO
CN106365118A (en) * 2016-11-15 2017-02-01 晋城市阿邦迪能源有限公司 Methyl alcohol reforming reactor with CO purifying and temperature monitoring function
CN106883084A (en) * 2017-03-07 2017-06-23 王亚壮 A kind of method and system of new synthesizing methane
CN207227004U (en) * 2017-08-24 2018-04-13 中海石油气电集团有限责任公司 A kind of combustion gas hydrogen manufacturing integrated reaction device suitable for small Miniature domestic
CN109911849A (en) * 2019-03-29 2019-06-21 摩氢科技有限公司 Self-heat-supply reforming reaction device and hydrogen making machine suitable for hydrogen making machine
CN110562918A (en) * 2019-09-11 2019-12-13 张家港氢云新能源研究院有限公司 Integrated reforming hydrogen production device

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000281312A (en) * 1999-03-31 2000-10-10 Sanyo Electric Co Ltd Reforming device for fuel cell
US20040223908A1 (en) * 2001-11-07 2004-11-11 Holladay Jamelyn D. Microcombustors, microreformers, and methods involving combusting or reforming fluids
CN106145036A (en) * 2016-08-25 2016-11-23 晋城市阿邦迪能源有限公司 Methanation reaction purifies the methanol steam reforming device of CO
CN106365118A (en) * 2016-11-15 2017-02-01 晋城市阿邦迪能源有限公司 Methyl alcohol reforming reactor with CO purifying and temperature monitoring function
CN106883084A (en) * 2017-03-07 2017-06-23 王亚壮 A kind of method and system of new synthesizing methane
CN207227004U (en) * 2017-08-24 2018-04-13 中海石油气电集团有限责任公司 A kind of combustion gas hydrogen manufacturing integrated reaction device suitable for small Miniature domestic
CN109911849A (en) * 2019-03-29 2019-06-21 摩氢科技有限公司 Self-heat-supply reforming reaction device and hydrogen making machine suitable for hydrogen making machine
CN110562918A (en) * 2019-09-11 2019-12-13 张家港氢云新能源研究院有限公司 Integrated reforming hydrogen production device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112340698A (en) * 2020-10-29 2021-02-09 广州汤姆逊电气有限公司 Reaction device for preparing hydrogen fuel by high-temperature catalytic cracking of methane
CN112340698B (en) * 2020-10-29 2023-05-05 广州汤姆逊电气有限公司 Reaction device for preparing hydrogen fuel by high-temperature catalytic cracking of methane
CN113432125A (en) * 2021-07-15 2021-09-24 山西新源煤化燃料有限公司 White oil hydrogen-mixed combustion burner device

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