CN111647390A - Temperature-controlled cooling mother liquor, preparation method and application thereof - Google Patents
Temperature-controlled cooling mother liquor, preparation method and application thereof Download PDFInfo
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Abstract
The invention provides a temperature-controlled cooling mother liquor, which is formed by mixing a first part of mixed liquor and a second part of mixed liquor; the first part of mixed liquid comprises sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate, triethanolamine and deionized purified water; the second part of mixed solution comprises N-methyl pyrrolidone, allyl glycidyl ether, antelope methyl cellulose, graphene oxide dispersion liquid, nitrate and gold chloride. The invention has the beneficial effects that: the invention can quickly cool and radiate, when the temperature is low, the temperature can be quickly raised, so that the temperature of the engine is kept in a uniform and stable state, thereby leading the engine to be more fully combusted, and really achieving the purposes of saving oil, increasing power and reducing emission.
Description
Technical Field
The invention belongs to the cooling field of common machines or engines, and particularly relates to a temperature-controlled cooling mother liquor and a preparation method thereof.
Background
The temperature-controlled cooling liquid is widely used in the fields of engineering machinery, automobiles, ships and the like.
The performance characteristics of the temperature-control cooling liquid are different according to different production raw materials, and the conventional temperature-control cooling liquid is divided into ethanol type, glycerol type, glycol type, dimethyl sulfoxide type and other types, but most products in the market are glycol type. The conventional temperature-controlled cooling liquid as a cooling medium of an engine cooling system has many advantages over water in that the freezing point is low, and the freezing of a water tank and a cylinder block can be avoided at low temperature. The freezing point of water is 0 ℃, and the freezing point of the anti-freezing solution can reach below-60 ℃, so the anti-freezing solution is named.
The traditional conventional temperature control cooling liquid only has an antifreezing effect, the temperature is unstable and uneven, the water channel can be blocked by scale for a long time, and the abrasion is increased.
Disclosure of Invention
The invention overcomes the defects in the prior art, and aims at providing a temperature-controlled cooling mother liquor, and also aims at providing a preparation method of the temperature-controlled cooling mother liquor and applying the mother liquor.
The purpose of the invention is realized by the following technical scheme.
A temperature-controlled cooling mother liquor comprises a first part of mixed liquor and a second part of mixed liquor;
the first part of mixed solution comprises sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate, triethanolamine and deionized purified water;
the second part of mixed solution comprises N-methyl pyrrolidone, allyl glycidyl ether, antelope methyl cellulose, graphene oxide dispersion liquid, nitrate and gold chloride.
Preferably, the first part of mixed solution comprises the following components in parts by weight: 0.3-1 part of cane sugar, 0.08-0.7 part of sodium benzoate, 0.1-0.7 part of calcium chloride, 0.08-0.5 part of benzotriazole, 0.03-0.1 part of sodium molybdate, 0.03-0.09 part of triethanolamine and 5.5-13 parts of deionized purified water.
In any of the above schemes, preferably, the first part of the mixed solution comprises the following components in parts by weight: 0.5-0.8 part of cane sugar, 0.1-0.5 part of sodium benzoate, 0.3-0.5 part of calcium chloride, 0.1-0.3 part of benzotriazole, 0.05-0.08 part of sodium molybdate, 0.05-0.07 part of triethanolamine and 7.5-11 parts of deionized purified water.
In any of the above schemes, preferably, the second part of the mixed solution comprises the following components in parts by weight: 0.01-0.07 part of N-methylpyrrolidone, 0.01-0.08 part of allyl glycidyl ether, 0.01-0.07 part of antelope methyl cellulose, 0.003-0.009 part of graphene oxide dispersion liquid, 0.001-0.007 part of nitrate and 0.001-0.005 part of gold chloride.
In any of the above schemes, preferably, the second part of the mixed solution comprises the following components in parts by weight: 0.02-0.05 part of N-methylpyrrolidone, 0.02-0.06 part of allyl glycidyl ether, 0.01-0.05 part of antelope methyl cellulose, 0.005-0.007 part of graphene oxide dispersion liquid, 0.002-0.005 part of nitrate and 0.001-0.003 part of gold chloride.
The preparation method of any temperature-controlled cooling mother liquor comprises the following steps in sequence:
firstly, mixing sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate and triethanolamine according to a ratio, adding deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, mixing N-methyl pyrrolidone and allyl glycidyl ether according to a ratio, mixing graphene oxide dispersion liquid and nitrate and gold chloride according to a ratio, completely mixing the two mixtures, and adding antelope methyl cellulose to form a second part of mixed liquid;
thirdly, heating the second part of mixed solution to 80-100 ℃, then placing and warming to natural temperature, and repeating heating and warming for 3 times within 48 h;
and step four, mixing the first part of mixed liquor obtained in the step one with the second part of mixed liquor obtained in the step three to obtain mother liquor.
Preferably, in the first step, the first part of mixed solution comprises the following components in parts by weight: 0.5-0.8 part of cane sugar, 0.1-0.5 part of sodium benzoate, 0.3-0.5 part of calcium chloride, 0.1-0.3 part of benzotriazole, 0.05-0.08 part of sodium molybdate, 0.05-0.07 part of triethanolamine and 7.5-11 parts of deionized purified water.
In any of the above schemes, preferably, in the second step, the second part of the mixed solution comprises the following components in parts by weight: 0.02-0.05 part of N-methylpyrrolidone, 0.02-0.06 part of allyl glycidyl ether, 0.01-0.05 part of antelope methyl cellulose, 0.005-0.007 part of graphene oxide dispersion liquid, 0.002-0.005 part of nitrate and 0.001-0.003 part of gold chloride.
The application of any temperature-controlled cooling mother liquor is characterized in that the mother liquor is applied to the fields of engineering machinery, automobiles, ships and water system cooling engines.
The invention has the beneficial effects that:
the technical scheme of the invention can clean the water channel and prevent the generation of scale;
the temperature rise is fast, the heat preservation is good, the heat dissipation is fast, the engine can be controlled at the optimal working temperature, the working efficiency of the engine is improved, and the inconvenience caused by overhigh or overlow temperature of the engine is solved;
the toner can be added, is nontoxic, harmless and odorless, and does not affect the environment.
The technical scheme of the invention can rapidly cool and radiate, and when the temperature is low, the temperature can be rapidly raised, so that the temperature of the engine is kept in a uniform and stable state, the engine can be more fully combusted, and the aims of saving oil, increasing power and reducing emission are really achieved.
Detailed Description
The technical solution of the present invention is further illustrated by the following specific examples.
Composition of temp. -controlled cooling mother liquor
The mother liquor is cooled at controlled temperature and comprises a first part of mixed liquor and a second part of mixed liquor;
the first part of mixed solution comprises sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate, triethanolamine and deionized purified water;
the second part of mixed solution comprises N-methyl pyrrolidone, allyl glycidyl ether, antelope methyl cellulose, graphene oxide dispersion liquid, nitrate and gold chloride.
The first part of mixed liquid is prepared by mixing sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate and triethanolamine; this first part mixed liquid has played the guard action to the engine, and it is effectual to prevent corrosion, wherein:
the cane sugar plays a role in metal protection;
sodium benzoate is used as antiseptic;
calcium chloride, benzotriazole, sodium molybdate and triethanolamine are used as a resistance removing agent for removing water scale in the engine.
The second part of mixed solution is prepared by mixing N-methyl pyrrolidone, allyl glycidyl ether, antelope methyl cellulose, graphene oxide dispersion liquid, nitrate and gold chloride. The second part of mixed solution is subjected to chemical reaction, and the heat accumulation of metal:
the antelope methylcellulose is used as a lubricant and a cleaning agent and is combined with calcium chloride to clean a water channel and prevent the generation of scale;
n-methyl pyrrolidone, diluted propyl glycidyl ether and sucrose are added into calcium chloride to generate a saturated chemical reaction, and the temperature is rapidly raised under the stirring of a water pump of an engine, so that the hot start time of the engine is greatly reduced;
the graphene oxide dispersion liquid has the advantages of fast heat dissipation, high circulation speed and instant heat removal;
the nitrate dissolves the gold chloride, and the heat accumulation is rapid;
the quantity of ions in the deionized purified water can be manually controlled, physical and chemical indexes such as resistivity, solubility, corrosivity, viruses and bacteria and the like can be well controlled, and because the deionized water is used in the invention, parameters in the technical scheme are closer to ideal data, and the quality of the obtained energy-saving environment-friendly antifreezing solution is easier to control.
Second, temperature-controlled cooling mother liquor preparation method
The preparation method of the temperature-controlled cooling mother liquor comprises the following steps in sequence:
firstly, mixing sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate and triethanolamine, adding deionized purified water, and heating to dissolve to form a first part of mixed solution;
step two, mixing N-methyl pyrrolidone and allyl glycidyl ether, mixing graphene oxide dispersion liquid and nitrate with gold chloride, then completely mixing the two mixtures, and adding antelope methyl cellulose to form a second part of mixed liquid;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature, wherein the natural temperature is 18-24 ℃, and repeatedly heating and heating for 3 times within 48 hours;
and step four, mixing the mixed liquor obtained in the step one with the mixed liquor obtained in the step three to obtain mother liquor.
And thirdly, preparing the anti-freezing cooling liquid for the water system cooling engine by using the temperature-controlled cooling mother liquid.
The method for preparing the anti-freezing cooling liquid for the water system cooling engine by using the temperature-controlled cooling mother liquid comprises the following steps in sequence:
firstly, mixing sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate and triethanolamine, adding deionized purified water, and heating to dissolve to form a first part of mixed solution;
step two, mixing N-methyl pyrrolidone and allyl glycidyl ether, mixing graphene oxide dispersion liquid and nitrate with gold chloride, then completely mixing the two mixtures, and adding antelope methyl cellulose to obtain a second part of mixed liquid;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature, wherein the natural temperature is 18-24 ℃, and repeatedly heating and heating for 3 times within 48 hours;
fourthly, mixing the first part of mixture with the second part of mixed solution obtained in the third step to obtain mother liquor;
and fifthly, adding the existing cooling antifreeze solution into the fourth step to form a final antifreeze coolant product. The existing cooling antifreeze is preferably: propylene glycol antifreeze, ethylene glycol antifreeze, diethylene glycol-water antifreeze and engine oil.
Taking the propylene glycol antifreeze solution containing the temperature-controlled cooling mother liquor prepared by the method as an example, the propylene glycol antifreeze solution containing the temperature-controlled cooling mother liquor prepared by the method comprises a first mixed solution part, a second mixed solution part and the propylene glycol antifreeze solution, wherein the addition amount of the propylene glycol antifreeze solution is 2-7% of the total amount of the first mixed solution part and the second mixed solution part.
Example 1
The mother solution-propylene glycol antifreeze solution comprises a first part of mixed solution, a second part of mixed solution and propylene glycol antifreeze solution which are mixed, wherein the addition amount of the propylene glycol antifreeze solution is 2 percent of the total amount of the first part of mixed solution and the second part of mixed solution, the propylene glycol antifreeze solution is formed by mixing propylene glycol and deionized purified water, and the pH value of the temperature-control, energy-saving and environment-friendly antifreeze cooling solution is between 7 and 8;
the first part of mixed solution is prepared by mixing the following components in parts by weight: 0.3 part of cane sugar, 0.08 part of sodium benzoate, 0.1 part of calcium chloride, 0.08 part of benzotriazole, 0.03 part of sodium molybdate, 0.03 part of triethanolamine and 5.5 parts of deionized purified water;
the second part of mixed solution is prepared by mixing the following components in parts by weight: 0.01 part of N-methylpyrrolidone, 0.01 part of allyl glycidyl ether, 0.01 part of antelope methyl cellulose, 0.003 part of graphene oxide dispersion liquid, 0.001 part of nitrate and 0.001 part of gold chloride.
A process for preparing a mother liquor-propylene glycol antifreeze solution comprising the steps of:
firstly, mixing 0.3 part of cane sugar, 0.08 part of sodium benzoate, 0.1 part of calcium chloride, 0.08 part of benzotriazole, 0.03 part of sodium molybdate and 0.03 part of triethanolamine, adding 5.5 parts of deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, respectively mixing 0.01 part of N-methyl pyrrolidone and 0.01 part of allyl glycidyl ether, mixing 0.003 part of graphene oxide dispersion liquid, 0.001 part of nitrate and 0.001 part of gold chloride, then completely mixing the two mixtures, and then adding 0.01 part of antelope methyl cellulose to obtain a second part of mixed solution;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature of 18-24 ℃, and repeating heating and heating for 3 times within 48 h;
fourthly, mixing the first part of mixed liquor with the second part of mixed liquor obtained in the third step to obtain mother liquor;
and fifthly, adding propylene glycol antifreeze solution into the mother solution obtained in the fourth step to obtain the temperature-controlled energy-saving environment-friendly antifreeze cooling liquid.
Further, adding a toner into the temperature-control energy-saving environment-friendly anti-freezing cooling liquid obtained in the fifth step.
Example 2
The mother solution-propylene glycol antifreeze solution comprises a first part of mixed solution, a second part of mixed solution and propylene glycol antifreeze solution which are mixed, wherein the addition amount of the propylene glycol antifreeze solution is 3 percent of the total amount of the first part of mixed solution and the second part of mixed solution, the propylene glycol antifreeze solution is formed by mixing propylene glycol and deionized purified water, and the pH value of the temperature-control, energy-saving and environment-friendly antifreeze cooling solution is between 7 and 8;
the first part of mixed solution is prepared by mixing the following components in parts by weight: 0.4 part of cane sugar, 0.1 part of sodium benzoate, 0.2 part of calcium chloride, 0.1 part of benzotriazole, 0.04 part of sodium molybdate, 0.04 part of triethanolamine and 7.5 parts of deionized purified water.
The second part of mixed solution is prepared by mixing the following components in parts by weight: 0.02 part of N-methyl pyrrolidone, 0.02 part of allyl glycidyl ether, 0.02 part of antelope methyl cellulose, 0.004 part of graphene oxide dispersion liquid, 0.002 part of nitrate and 0.002 part of gold chloride.
A process for preparing a mother liquor-propylene glycol antifreeze solution comprising the steps of:
firstly, mixing 0.4 part of cane sugar, 0.1 part of sodium benzoate, 0.2 part of calcium chloride, 0.1 part of benzotriazole, 0.04 part of sodium molybdate and 0.04 part of triethanolamine, adding 7.5 parts of deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, respectively mixing 0.02 part of N-methyl pyrrolidone and 0.02 part of allyl glycidyl ether, mixing 0.004 part of graphene oxide dispersion liquid, 0.002 part of nitrate and 0.002 part of gold chloride, then completely mixing the two mixtures, and then adding 0.02 part of antelope methyl cellulose to obtain a second part of mixed solution;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature of 18-24 ℃, and repeating heating and heating for 3 times within 48 h;
fourthly, mixing the first part of mixed liquor with the second part of mixed liquor obtained in the third step to obtain mother liquor;
and fifthly, adding propylene glycol antifreeze solution into the mother solution obtained in the fourth step to obtain the temperature-controlled energy-saving environment-friendly antifreeze cooling liquid.
Example 3
The mother solution-propylene glycol antifreeze solution comprises a first part of mixed solution, a second part of mixed solution and propylene glycol antifreeze solution which are mixed, wherein the addition amount of the propylene glycol antifreeze solution is 4 percent of the total amount of the first part of mixed solution and the second part of mixed solution, the propylene glycol antifreeze solution is formed by mixing propylene glycol and deionized purified water, and the pH value of the temperature-control, energy-saving and environment-friendly antifreeze cooling solution is between 7 and 8;
the first part of mixed solution is prepared by mixing the following components in parts by weight: 0.5 part of cane sugar, 0.3 part of sodium benzoate, 0.3 part of calcium chloride, 0.2 part of benzotriazole, 0.05 part of sodium molybdate, 0.05 part of triethanolamine and 8.5 parts of deionized purified water.
The second part of mixed solution is prepared by mixing the following components in parts by weight: 0.03 part of N-methylpyrrolidone, 0.03 part of allyl glycidyl ether, 0.03 part of antelope methyl cellulose, 0.005 part of graphene oxide dispersion liquid, 0.003 part of nitrate and 0.0025 part of gold chloride.
A process for preparing a mother liquor-propylene glycol antifreeze solution comprising the steps of:
firstly, mixing 0.5 part of cane sugar, 0.3 part of sodium benzoate, 0.3 part of calcium chloride, 0.2 part of benzotriazole, 0.05 part of sodium molybdate and 0.05 part of triethanolamine, adding 8.5 parts of deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, respectively mixing 0.03 part of N-methyl pyrrolidone and 0.03 part of allyl glycidyl ether, mixing 0.005 part of graphene oxide dispersion liquid, 0.003 part of nitrate and 0.0025 part of gold chloride, then completely mixing the two mixtures, and then adding 0.03 part of antelope methyl cellulose to obtain a second part of mixed solution;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature of 18-24 ℃, and repeating the heating and heating for 3 times within 48h to obtain a second part of mixed liquor;
fourthly, mixing the first part of mixed liquor with the second part of mixed liquor obtained in the third step to obtain mother liquor;
and fifthly, adding propylene glycol antifreeze solution into the mother solution obtained in the fourth step to obtain the temperature-controlled energy-saving environment-friendly antifreeze cooling liquid.
Further, adding a toner into the temperature-control energy-saving environment-friendly anti-freezing cooling liquid obtained in the fifth step.
Example 4
The mother solution-propylene glycol antifreeze solution comprises a first part of mixed solution, a second part of mixed solution and propylene glycol antifreeze solution which are mixed, wherein the addition amount of the propylene glycol antifreeze solution is 5 percent of the total amount of the first part of mixed solution and the second part of mixed solution, the propylene glycol antifreeze solution is formed by mixing propylene glycol and deionized purified water, and the pH value of the temperature-control, energy-saving and environment-friendly antifreeze cooling solution is between 7 and 8;
the first part of mixed solution is prepared by mixing the following components in parts by weight: 0.6 part of cane sugar, 0.4 part of sodium benzoate, 0.4 part of calcium chloride, 0.3 part of benzotriazole, 0.06 part of sodium molybdate, 0.06 part of triethanolamine and 9 parts of deionized purified water.
The second part of mixed solution is prepared by mixing the following components in parts by weight: 0.04 part of N-methylpyrrolidone, 0.04 part of allyl glycidyl ether, 0.04 part of antelope methyl cellulose, 0.006 part of graphene oxide dispersion liquid, 0.004 part of nitrate and 0.003 part of gold chloride.
A process for preparing a mother liquor-propylene glycol antifreeze solution comprising the steps of:
firstly, mixing 0.6 part of cane sugar, 0.4 part of sodium benzoate, 0.4 part of calcium chloride, 0.3 part of benzotriazole, 0.06 part of sodium molybdate and 0.06 part of triethanolamine, adding 9 parts of deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, respectively mixing 0.04 parts of N-methylpyrrolidone and 0.04 parts of allyl glycidyl ether, mixing 0.006 part of graphene oxide dispersion liquid, 0.004 part of nitrate and 0.003 part of gold chloride, then completely mixing the two mixtures, and adding 0.04 part of antelope methyl cellulose to obtain a second part of mixed solution;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature of 18-24 ℃, and repeating the heating and heating for 3 times within 48h to obtain a second part of mixed liquor;
fourthly, mixing the first part of mixed liquor with the second part of mixed liquor obtained in the third step to obtain mother liquor;
and fifthly, adding propylene glycol antifreeze solution into the mother solution obtained in the fourth step to obtain the temperature-controlled energy-saving environment-friendly antifreeze cooling liquid.
Example 5
The mother solution-propylene glycol antifreeze solution comprises a first part of mixed solution, a second part of mixed solution and propylene glycol antifreeze solution which are mixed, wherein the addition amount of the propylene glycol antifreeze solution is 6 percent of the total amount of the first part of mixed solution and the second part of mixed solution, the propylene glycol antifreeze solution is formed by mixing propylene glycol and deionized purified water, and the pH value of the temperature-control, energy-saving and environment-friendly antifreeze cooling solution is between 7 and 8;
the first part of mixed solution is prepared by mixing the following components in parts by weight: 0.7 part of cane sugar, 0.5 part of sodium benzoate, 0.5 part of calcium chloride, 0.35 part of benzotriazole, 0.07 part of sodium molybdate, 0.07 part of triethanolamine and 10 parts of deionized purified water.
The second part of mixed solution is prepared by mixing the following components in parts by weight: 0.05 part of N-methylpyrrolidone, 0.05 part of allyl glycidyl ether, 0.05 part of antelope methyl cellulose, 0.007 part of graphene oxide dispersion liquid, 0.005 part of nitrate and 0.004 part of gold chloride.
A process for preparing a mother liquor-propylene glycol antifreeze solution comprising the steps of:
firstly, mixing 0.7 part of cane sugar, 0.5 part of sodium benzoate, 0.5 part of calcium chloride, 0.35 part of benzotriazole, 0.07 part of sodium molybdate and 0.07 part of triethanolamine, adding 10 parts of deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, respectively mixing 0.05 part of N-methyl pyrrolidone and 0.05 part of allyl glycidyl ether, mixing 0.007 part of graphene oxide dispersion liquid, 0.005 part of nitrate and 0.004 part of gold chloride, then completely mixing the two mixtures, and then adding 0.05 part of antelope methyl cellulose to obtain a second part of mixed solution;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature of 18-24 ℃, and repeating the heating and heating for 3 times within 48h to obtain a second part of mixed liquor;
fourthly, mixing the first part of mixed liquor with the second part of mixed liquor obtained in the third step to obtain mother liquor;
and fifthly, adding propylene glycol antifreeze solution into the mother solution obtained in the fourth step to obtain the temperature-controlled energy-saving environment-friendly antifreeze cooling liquid.
Example 6
The mother solution-propylene glycol antifreezing solution is formed by mixing a first part of mixed solution, a second part of mixed solution and propylene glycol antifreezing solution, wherein the addition amount of the propylene glycol antifreezing solution is 6.5% of the total amount of the first part of mixed solution and the second part of mixed solution, the propylene glycol antifreezing solution is formed by mixing propylene glycol and deionized purified water, and the pH value of the temperature-control, energy-saving and environment-friendly antifreezing cooling solution is between 7 and 8;
the first part of mixed solution is prepared by mixing the following components in parts by weight: 0.8 part of cane sugar, 0.6 part of sodium benzoate, 0.6 part of calcium chloride, 0.4 part of benzotriazole, 0.08 part of sodium molybdate, 0.08 part of triethanolamine and 11 parts of deionized purified water.
The second part of mixed solution is prepared by mixing the following components in parts by weight: 0.06 part of N-methylpyrrolidone, 0.06 part of allyl glycidyl ether, 0.06 part of antelope methyl cellulose, 0.008 part of graphene oxide dispersion liquid, 0.006 part of nitrate and 0.0045 part of gold chloride.
A process for preparing a mother liquor-propylene glycol antifreeze solution comprising the steps of:
firstly, mixing 0.8 part of cane sugar, 0.6 part of sodium benzoate, 0.6 part of calcium chloride, 0.4 part of benzotriazole, 0.08 part of sodium molybdate and 0.08 part of triethanolamine, adding 11 parts of deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, respectively mixing 0.06 part of N-methyl pyrrolidone and 0.06 part of allyl glycidyl ether, mixing 0.008 part of graphene oxide dispersion liquid, 0.006 part of nitrate and 0.0045 part of gold chloride, then completely mixing the two mixtures, and then adding 0.06 part of antelope methyl cellulose to obtain a second part of mixed solution;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature of 18-24 ℃, and repeating the heating and heating for 3 times within 48h to obtain a second part of mixed liquor;
fourthly, mixing the first part of mixed liquor with the second part of mixed liquor obtained in the third step to obtain mother liquor;
and fifthly, adding propylene glycol antifreeze solution into the mother solution obtained in the fourth step to obtain the temperature-controlled energy-saving environment-friendly antifreeze cooling liquid.
Example 7
The mother solution-propylene glycol antifreeze solution comprises a first part of mixed solution, a second part of mixed solution and propylene glycol antifreeze solution which are mixed, wherein the addition amount of the propylene glycol antifreeze solution is 7 percent of the total amount of the first part of mixed solution and the second part of mixed solution, the propylene glycol antifreeze solution is formed by mixing propylene glycol and deionized purified water, and the pH value of the temperature-control, energy-saving and environment-friendly antifreeze cooling solution is between 7 and 8;
the first part of mixed solution is prepared by mixing the following components in parts by weight: 1 part of cane sugar, 0.7 part of sodium benzoate, 0.7 part of calcium chloride, 0.5 part of benzotriazole, 0.1 part of sodium molybdate, 0.09 part of triethanolamine and 13 parts of deionized purified water.
The second part of mixed solution is prepared by mixing the following components in parts by weight: 0.07 part of N-methylpyrrolidone, 0.08 part of allyl glycidyl ether, 0.07 part of antelope methyl cellulose, 0.009 part of graphene oxide dispersion liquid, 0.007 part of nitrate and 0.005 part of gold chloride.
A process for preparing a mother liquor-propylene glycol antifreeze solution comprising the steps of:
firstly, mixing 1 part of sucrose, 0.7 part of sodium benzoate, 0.7 part of calcium chloride, 0.5 part of benzotriazole, 0.1 part of sodium molybdate and 0.09 part of triethanolamine, adding 13 parts of deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, respectively mixing 0.07 part of N-methylpyrrolidone and 0.08 part of allyl glycidyl ether, mixing 0.009 part of graphene oxide dispersion liquid, 0.007 part of nitrate and 0.005 part of gold chloride, then completely mixing the two mixtures, and then adding 0.07 part of antelope methyl cellulose to obtain a second part of mixed liquid;
thirdly, heating the mixture obtained in the second step to 80-100 ℃, then placing and heating to natural temperature of 18-24 ℃, and repeating the heating and heating for 3 times within 48h to obtain a second part of mixed liquor;
fourthly, mixing the first part of mixed liquor with the second part of mixed liquor obtained in the third step to obtain mother liquor;
and fifthly, adding propylene glycol antifreeze solution into the mother solution obtained in the fourth step to obtain the temperature-controlled energy-saving environment-friendly antifreeze cooling liquid.
And (3) comparison test:
the ratio of each component of the experimental group 1 is as follows:
first part of mixed liquid: 0.05 part of cane sugar, 0.001 part of sodium benzoate, 0.001 part of calcium chloride, 0.001 part of benzotriazole, 0.001 part of sodium molybdate, 0.001 part of triethanolamine and 4 parts of deionized purified water;
the second part of mixed solution: 0.0001 part of N-methylpyrrolidone, 0.0001 part of allyl glycidyl ether, 0.0001 part of antelope methyl cellulose, 0.001 part of graphene oxide dispersion, 0.0001 part of nitrate and 0.0001 part of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 0.2 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
The ratio of each component of the experimental group 2 is as follows:
first part of mixed liquid: 0.1 part of cane sugar, 0.005 part of sodium benzoate, 0.005 part of calcium chloride, 0.005 part of benzotriazole, 0.005 part of sodium molybdate, 0.005 part of triethanolamine and 4.5 parts of deionized purified water;
the second part of mixed solution: 0.0005 parts of N-methylpyrrolidone, 0.0005 parts of allyl glycidyl ether, 0.0005 parts of antelope methyl cellulose, 0.0015 parts of graphene oxide dispersion, 0.0003 parts of nitrate and 0.0003 parts of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 0.8 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
The ratio of each component of the experimental group 3 is as follows:
first part of mixed liquid: 0.25 part of cane sugar, 0.01 part of sodium benzoate, 0.01 part of calcium chloride, 0.01 part of benzotriazole, 0.01 part of sodium molybdate, 0.01 part of triethanolamine and 5 parts of deionized purified water;
the second part of mixed solution: 0.001 part of N-methylpyrrolidone, 0.001 part of allyl glycidyl ether, 0.001 part of antelope methyl cellulose, 0.002 part of graphene oxide dispersion, 0.0005 part of nitrate and 0.0005 part of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 1.2 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
The ratio of each component of the experimental group 4 is as follows:
first part of mixed liquid: 0.028 parts of cane sugar, 0.07 part of sodium benzoate, 0.08 part of calcium chloride, 0.07 part of benzotriazole, 0.025 part of sodium molybdate, 0.025 part of triethanolamine and 5.4 parts of deionized purified water;
the second part of mixed solution: 0.008 parts of N-methylpyrrolidone, 0.008 parts of allyl glycidyl ether, 0.008 parts of antelope methyl cellulose, 0.0028 parts of graphene oxide dispersion, 0.0008 parts of nitrate and 0.0008 parts of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 1.8 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
The ratio of each component of the experimental group 5 is as follows:
first part of mixed liquid: 1.08 parts of sucrose, 0.75 part of sodium benzoate, 0.75 part of calcium chloride, 0.55 part of benzotriazole, 0.15 part of sodium molybdate, 0.1 part of triethanolamine and 13.3 parts of deionized purified water;
the second part of mixed solution: 0.075 part of N-methylpyrrolidone, 0.085 part of allyl glycidyl ether, 0.075 part of antelope methyl cellulose, 0.0095 part of graphene oxide dispersion, 0.0072 part of nitrate and 0.0052 part of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 7.2 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
The ratio of each component of the experimental group 6 is as follows:
first part of mixed liquid: 1.5 parts of sucrose, 0.9 part of sodium benzoate, 0.9 part of calcium chloride, 0.8 part of benzotriazole, 0.3 part of sodium molybdate, 0.2 part of triethanolamine and 14 parts of deionized purified water;
the second part of mixed solution: 0.09 part of N-methylpyrrolidone, 0.1 part of allyl glycidyl ether, 0.09 part of antelope methyl cellulose, 0.01 part of graphene oxide dispersion liquid, 0.009 part of nitrate and 0.009 part of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 8 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
Experiment group 7 the ratio of each component is as follows:
first part of mixed liquid: 2.5 parts of sucrose, 1.5 parts of sodium benzoate, 1.5 parts of calcium chloride, 1.5 parts of benzotriazole, 0.4 part of sodium molybdate, 0.4 part of triethanolamine and 14.5 parts of deionized purified water;
the second part of mixed solution: 0.1 part of N-methylpyrrolidone, 0.2 part of allyl glycidyl ether, 0.1 part of antelope methyl cellulose, 0.05 part of graphene oxide dispersion liquid, 0.01 part of nitrate and 0.01 part of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 8.5 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
The ratio of each component of the experimental group 8 is as follows:
first part of mixed liquid: 3 parts of sucrose, 2.5 parts of sodium benzoate, 2.5 parts of calcium chloride, 3 parts of benzotriazole, 0.5 part of sodium molybdate, 0.5 part of triethanolamine and 15.5 parts of deionized purified water;
the second part of mixed solution: 0.5 part of N-methylpyrrolidone, 0.4 part of allyl glycidyl ether, 0.5 part of antelope methyl cellulose, 1 part of graphene oxide dispersion liquid, 0.09 part of nitrate and 0.09 part of gold chloride;
the addition amount of the propylene glycol antifreezing solution is 9 percent of the total amount of the first part of mixed solution and the second part of mixed solution.
Test verification:
indexes which can represent that the antifreeze solution of the embodiment has good energy-saving and environment-friendly effects include temperature rise time, heat dissipation time and heat preservation time. The temperature rise index refers to the temperature rise time of the cooling liquid under the condition that the engine runs the water pump and is stirred during the dynamic state; the heat dissipation index means that when the working temperature of the engine exceeds the optimal working temperature, the cooling liquid takes away redundant heat so that the engine is at the optimal working temperature; the warm-keeping index is the time taken for the coolant to decrease from the operating temperature to the ambient temperature in the engine-off state.
TABLE 1 temperature rise, heat dissipation, and holding times for this example and comparative tests
As can be seen from Table 1, the mother liquor-propylene glycol antifreeze solutions in the embodiments 1 to 7 have the best component value range, and have the effects of fast temperature rise, fast heat dissipation and good heat preservation, thereby realizing the effects of energy conservation and environmental protection.
For the test result with fast temperature rise, the test temperature rises from the ambient temperature to 80 ℃. In examples 1-7, the time for the coolant to warm up from ambient temperature to 80 degrees was very fast, in the range of 2.1-2.7min, i.e. not more than 3min, with the engine operating. The cooling liquid of the application is heated up so fast because N-methyl pyrrolidone, diluted propyl glycidyl ether, antelope methyl cellulose, graphene oxide dispersion liquid, nitrate and gold chloride are added into calcium chloride to generate a saturated chemical reaction, and the temperature is rapidly raised under the stirring of a water pump of an engine, so that the hot start time of the engine is greatly reduced. However, the contents of calcium chloride, N-methyl pyrrolidone, diluted propyl glycidyl ether, antelope methyl cellulose, graphene oxide dispersion, nitrate, and gold chloride are within the range of the present application, higher or lower than the range of the present application, and still the expected effects of the present application are not achieved, and if the contents of the components are not within the numerical range of the present application, the temperature rise time is within the range of 6.5 to 8.4min, that is, not lower than 6 min.
For the test result of fast heat dissipation, the test temperature is from 90 degrees to 85 degrees. In the present application, under the working condition of the engine, the time for the cooling liquid to dissipate heat from 90 degrees to 85 degrees is very fast and is in the range of 7.9-8.8s, namely not more than 10 s. The cooling liquid has the advantages that the cooling liquid is fast in heat dissipation, because the calcium chloride is added with the N-methyl pyrrolidone, the dilute propyl glycidyl ether, the antelope methyl cellulose, the graphene oxide dispersion liquid, the nitrate and the gold chloride, the calcium chloride is added with the N-methyl pyrrolidone, the dilute propyl glycidyl ether and the cane sugar, a saturated chemical reaction is generated, the temperature is rapidly raised under the stirring of a water pump of an engine, and the hot start time of the engine is greatly reduced; the graphene oxide dispersion liquid has the advantages of fast heat dissipation, high circulation speed and instant heat removal; the nitrate dissolves the gold chloride, and the heat accumulation is fast; and the content range of each component must be in the range of the present application to achieve the effect expected by the present application, and if the content of the component is not in the numerical range of the present application, the heat dissipation time is in the range of 2.8-4.1min, that is, not less than 2.5 min.
And (3) aiming at the test result with good heat preservation, performing stepwise measurement on the heat preservation time from 90 degrees to 80 degrees, the heat preservation time from 80 degrees to 70 degrees, the heat preservation time from 70 degrees to 50 degrees, the heat preservation time from 50 degrees to 30 degrees and the heat preservation time from 30 degrees to 0 degrees. In the application, under the condition that the engine is static and is not interfered by external factors (such as parking, water pump non-operation, no stirring and the like), the heat preservation time of the cooling liquid from 90 degrees to 80 degrees, the heat preservation time from 80 degrees to 70 degrees, the heat preservation time from 70 degrees to 50 degrees, the heat preservation time from 50 degrees to 30 degrees and the heat preservation time from 30 degrees to 0 degrees are not less than 8h in total. The cooling liquid has a very good heat preservation effect, namely long heat preservation time, and has the effect brought by the combination of the calcium chloride antifreeze and the alcohol antifreeze, because the N-methyl pyrrolidone, the dilute propyl glycidyl ether and the sucrose react with other substances to form a heat preservation film under static conditions without the interference of external factors (such as parking, water pump non-working, no stirring and the like), and the heat preservation effect is achieved. And the content range of each component must be in the range of the present application to achieve the effect expected by the present application, and if the content of the component is not in the numerical range of the present application, the holding time from 90 degrees to 0 degrees is not more than 1 hour, and the holding time is very short.
Description of the drawings: various chemical reagents used in the embodiment of the invention and the comparative test are purchased from Beijing chemical reagent company, the test environment is the same, and the test environment and the test conditions are the same. In this example and comparative experiments, propylene glycol antifreeze is taken as an example, and the test results are shown in Table 1, while ethylene glycol antifreeze, diethylene glycol-water antifreeze and engine oil are taken as examples, and the test results are substantially the same as in Table 1. Meanwhile, the propylene glycol antifreeze, the ethylene glycol antifreeze, the diethylene glycol-water antifreeze and the engine oil are tested, the test items are as shown in the table 1, but in the case of not adding the mother solution, the temperature rise time of the propylene glycol antifreeze, the ethylene glycol antifreeze, the diethylene glycol-water antifreeze and the engine oil is 5-10% slower than that of each group in the table 1, the heat dissipation time of the propylene glycol antifreeze, the ethylene glycol antifreeze, the diethylene glycol-water antifreeze and the engine oil is 5-8% slower than that of each group in the table 1, and the heat preservation time of the propylene glycol antifreeze, the ethylene glycol antifreeze, the diethylene glycol-water antifreeze and the engine oil is 6-10% shorter than that of each group in the table 1.
The seven embodiments of the present invention have been described in detail, but the description is only for the preferred embodiments of the present invention and should not be construed as limiting the scope of the present invention. All equivalent changes and modifications made within the scope of the present invention shall fall within the scope of the present invention.
Claims (9)
1. A temperature-controlled cooling mother liquor is characterized in that: comprises a first part of mixed liquor and a second part of mixed liquor;
the first part of mixed solution comprises sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate, triethanolamine and deionized purified water;
the second part of mixed solution comprises N-methyl pyrrolidone, allyl glycidyl ether, antelope methyl cellulose, graphene oxide dispersion liquid, nitrate and gold chloride.
2. The temperature-controlled cooling mother liquor according to claim 1, characterized in that: the first part of mixed solution comprises the following components in parts by weight: 0.3-1 part of cane sugar, 0.08-0.7 part of sodium benzoate, 0.1-0.7 part of calcium chloride, 0.08-0.5 part of benzotriazole, 0.03-0.1 part of sodium molybdate, 0.03-0.09 part of triethanolamine and 5.5-13 parts of deionized purified water.
3. The temperature-controlled cooling mother liquor according to claim 2, characterized in that: the first part of mixed solution comprises the following components in parts by weight: 0.5-0.8 part of cane sugar, 0.1-0.5 part of sodium benzoate, 0.3-0.5 part of calcium chloride, 0.1-0.3 part of benzotriazole, 0.05-0.08 part of sodium molybdate, 0.05-0.07 part of triethanolamine and 7.5-11 parts of deionized purified water.
4. The temperature-controlled cooling mother liquor according to claim 1, characterized in that: the second part of mixed solution comprises the following components in parts by weight: 0.01-0.07 part of N-methylpyrrolidone, 0.01-0.08 part of allyl glycidyl ether, 0.01-0.07 part of antelope methyl cellulose, 0.003-0.009 part of graphene oxide dispersion liquid, 0.001-0.007 part of nitrate and 0.001-0.005 part of gold chloride.
5. The temperature-controlled cooling mother liquor according to claim 4, characterized in that: the second part of mixed solution comprises the following components in parts by weight: 0.02-0.05 part of N-methylpyrrolidone, 0.02-0.06 part of allyl glycidyl ether, 0.01-0.05 part of antelope methyl cellulose, 0.005-0.007 part of graphene oxide dispersion liquid, 0.002-0.005 part of nitrate and 0.001-0.003 part of gold chloride.
6. A process for the preparation of a temperature-controlled cooled mother liquor according to any one of claims 1 to 5, characterized in that: comprises the following steps in sequence:
firstly, mixing sucrose, sodium benzoate, calcium chloride, benzotriazole, sodium molybdate and triethanolamine according to a ratio, adding deionized purified water, and heating to dissolve to form a first part of mixed solution;
secondly, mixing N-methyl pyrrolidone and allyl glycidyl ether according to a ratio, mixing graphene oxide dispersion liquid and nitrate and gold chloride according to a ratio, completely mixing the two mixtures, and adding antelope methyl cellulose to form a second part of mixed liquid;
thirdly, heating the second part of mixed solution to 80-100 ℃, then placing and warming to natural temperature, and repeating heating and warming for 3 times within 48 h;
and step four, mixing the first part of mixed liquor obtained in the step one with the second part of mixed liquor obtained in the step three to obtain mother liquor.
7. The method for preparing temperature-controlled cooling mother liquor according to claim 6, characterized in that: in the first step, the first part of mixed solution comprises the following components in parts by weight: 0.5-0.8 part of cane sugar, 0.1-0.5 part of sodium benzoate, 0.3-0.5 part of calcium chloride, 0.1-0.3 part of benzotriazole, 0.05-0.08 part of sodium molybdate, 0.05-0.07 part of triethanolamine and 7.5-11 parts of deionized purified water.
8. The method for preparing temperature-controlled cooling mother liquor according to claim 6, characterized in that: in the second step, the second part of mixed solution comprises the following components in parts by weight: 0.02-0.05 part of N-methylpyrrolidone, 0.02-0.06 part of allyl glycidyl ether, 0.01-0.05 part of antelope methyl cellulose, 0.005-0.007 part of graphene oxide dispersion liquid, 0.002-0.005 part of nitrate and 0.001-0.003 part of gold chloride.
9. Use of a temperature-controlled cooling mother liquor according to any one of claims 1 to 5, characterized in that: the mother solution is applied to the fields of engineering machinery, automobiles, ships and water system cooling engines.
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| CN112760083A (en) * | 2020-06-17 | 2021-05-07 | 北京龙轩行科技有限公司 | Temperature-control energy-saving environment-friendly anti-freezing cooling liquid and preparation method thereof |
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Application publication date: 20200911 |