CN111634983A - Solar swimming pool purifier - Google Patents

Solar swimming pool purifier Download PDF

Info

Publication number
CN111634983A
CN111634983A CN202010628633.2A CN202010628633A CN111634983A CN 111634983 A CN111634983 A CN 111634983A CN 202010628633 A CN202010628633 A CN 202010628633A CN 111634983 A CN111634983 A CN 111634983A
Authority
CN
China
Prior art keywords
anode
copper
silver
swimming pool
solar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010628633.2A
Other languages
Chinese (zh)
Inventor
陈董明
董之立
陈海波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Libang Solar Water Heater Co ltd
Original Assignee
Shanghai Libang Solar Water Heater Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Libang Solar Water Heater Co ltd filed Critical Shanghai Libang Solar Water Heater Co ltd
Priority to CN202010628633.2A priority Critical patent/CN111634983A/en
Publication of CN111634983A publication Critical patent/CN111634983A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S10/00PV power plants; Combinations of PV energy systems with other systems for the generation of electric power
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/42Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a solar swimming pool purifier, which comprises an anode, a cathode and an electric loop device, wherein the anode is a mixed base of copper and silver, the cathode is stainless steel, the electric loop device comprises a solar panel and a circuit, the electric loop device is connected with an electrolysis unit and provides current, the anode comprises an anode copper bar, a round hole with an extension line passing through the center of the cross section of the anode copper bar is arranged on the circumferential surface of the anode copper bar, an anode silver column is embedded in the round hole, and the outer end surface of the anode silver column is matched with the circumferential surface of the anode copper bar. The water purifier is particularly suitable for water purification of outdoor swimming pools, generates electricity through the solar photovoltaic panel, releases underwater anode ions, has a simple structure, breaks through the bottleneck of a manufacturing process, increases the contact time of a water source and an electrolysis unit by the circumferential open electrolysis area of the water purifier, and increases the efficiency under the same treatment amount; the method solves the difficult problem of unmixing silver and copper in process, and also solves the problem of standardization and proportional adjustment of silver and copper proportion in practice.

Description

Solar swimming pool purifier
Technical Field
The invention belongs to the technical field of liquid purification devices, and particularly relates to a solar swimming pool purifier device for purifying swimming pool water.
Background
The swimming pool is a pool for people to do various activities such as competitive swimming, body building, swimming, recreation, rehabilitation, medical treatment and the like in water. The quality of the water quality is very important for ensuring the health of the swimmers. Namely, the requirement that the pool water can not cause discomfort to the swimmer and can not cause certain sanitary injury. Meanwhile, the quality of water quality is also one of effective means for attracting swimmers, and the economic benefit of operators is concerned.
Generally, chlorine powder, chlorine tablets, chlorine particles and the like are added to disinfect swimming pool water to keep water quality, when chlorine is added into a swimming pool, the chlorine is slowly volatilized into air, when the concentration of the air is within a normal range, no problem exists, excessive addition is caused, the volatilized chlorine has serious harm to human bodies, and eyes, noses, throats, upper respiratory tracts and the like are stimulated. Chronic poisoning is caused by long-term inhalation of low-concentration chlorine, and the main symptoms are rhinitis, chronic bronchitis, emphysema and cirrhosis of liver. People who are chlorine-sensitive can develop dermatitis or eczema when exposed to higher concentrations of chlorine. Has harmful effect on plant, and has corrosive effect on metal products and buildings.
In the prior art, many attempts have been made to utilize the sterilization and disinfection effects of electrolytic copper ions and electrolytic silver ions, for example, patent application No. 96198586.0 entitled liquid disinfection device discloses that copper and silver act together on an anode for further disinfection and disinfection, but in this technology, anode copper and anode silver are two separate sets of electrolysis units, and the ratio of the two electrolysis units is not required, so that the dosage proportion of copper ions and silver ions for electrolysis needs to be adjusted separately for troublesome adjustment operations such as current and catalyst, and the device designed according to the technical scheme of the patent has a complex structure and is expensive in manufacturing cost and maintenance cost, and therefore, the device cannot be adapted to the market.
Disclosure of Invention
The invention aims to provide a solar swimming pool purifier device for purifying swimming pool water, which aims to conveniently adjust the dissolution ratio of an anode copper rod and an anode silver column in unit time from the aspect of structure so as to conveniently adjust and release the precipitation content of copper ions and anions aiming at different water areas and water quality.
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides a solar energy swimming pool clarifier, including positive pole, negative pole and electric loop device, the positive pole is the mixed base of copper and silver, the negative pole is the stainless steel, electric loop device includes solar panel and circuit, electric loop device is connected with the electrolysis unit, provide electric current, the positive pole includes the positive pole bar copper, set up the round hole that the extension line passes through positive pole bar copper cross section center on the periphery of positive pole bar copper, positive pole silver post is put into to the embedded formula of round hole, the outer terminal surface of positive pole silver post agrees with the periphery of positive pole bar copper.
Preferably, the number of the round holes is 2 to 10, and the round holes are uniformly distributed on the anode copper rod.
Preferably, the anode silver column is in a pluggable arrangement and is used for adjusting the electrolysis proportion of the anode copper bar and the anode silver column.
Preferably, the electrolysis proportion of the cross sections of the anode copper rod and the anode silver column is 2-5 per mill.
Preferably, the mass ratio of the anode copper rod to the anode silver column is 2.2-6 ‰
Preferably, the release content of copper ions is 0.7-1.0mg/l and the release content of silver ions is 0.001-0.01mg/l during electrolysis.
Preferably, the cathode is a stainless steel spring, the diameter of the stainless steel spring is larger than that of the anode copper bar, and the stainless steel spring is sleeved on the periphery of the anode copper bar.
Preferably, the stainless steel spring is sleeved with the filter screen device.
Preferably, the solar water heater further comprises a shell, a solar panel is laid on the upper top surface of the shell, and the lower bottom surface of the shell is connected with the filter screen device.
Compared with the prior art, the invention has the beneficial effects that: the water purifier device is particularly suitable for water purification of outdoor swimming pools, generates electricity through the solar photovoltaic panel, releases underwater anode ions, has a simple structure, breaks through the bottleneck of a manufacturing process, is placed in the water inlet of the swimming pool and a circumference open type electrolysis area, increases the contact time of a water source and an electrolysis unit, and increases the efficiency under the same treatment amount; the circumference of the anode copper bar is provided with a round hole, an extension line of which passes through the center of the cross section of the anode copper bar, the anode silver column is embedded in the round hole, and the outer end face of the anode silver column is matched with the circumference of the anode copper bar, so that the technical difficulty that the silver and the copper are not mixed is solved technically, the problem that the silver and the copper proportion can be standardized and proportionally adjusted is also solved practically, and the electrolytic proportion is not limited to be adjusted only in a current adjusting mode.
Drawings
FIG. 1 is a schematic structural diagram of the present embodiment;
FIG. 2 is a schematic diagram of the mixed base structure of the anode copper rod and the anode silver column in this embodiment;
in the figure: 1. solar panel, 2, positive pole bar copper, 3, round hole, 4, positive pole silver post, 5, stainless steel spring, 6, filter screen device, 7, casing.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1 and 2, this embodiment illustrates a specific structure of a solar swimming pool purifier to illustrate the technical solution of the present invention, which includes an anode, a cathode and an electric circuit device, wherein the anode is a mixed base of copper and silver, the cathode is stainless steel, the electric circuit device includes a solar panel 1 and a circuit, the electric circuit device is connected with an electrolysis unit to provide current, the anode includes an anode copper rod 2, the anode copper rod 2 has a diameter of 25mm, a length of 105mm, and a weight of 0.45 kg. Set up round hole 3 that the extension line passes through 2 cross section centers of positive pole bar copper on the periphery of positive pole bar copper 2, round hole 3 evenly distributed on positive pole bar copper 2, 3 tops of positive pole bar copper and the round hole 3 embedded 4 positive pole silver posts 4 of putting into of opposition both sides of each 35mm position in bottom at a distance, positive pole silver post 4 diameter 3mm, length 6mm. silver post net weight 0.48g, the outer terminal surface of positive pole silver post 4 agrees with the periphery of positive pole bar copper 2. The diameter of the round hole 3 is slightly larger than that of the anode silver column 4, so that the anode silver column 4 can be plugged and pulled, and the electrolysis proportion of the anode copper bar 2 and the anode silver column 4 can be adjusted.
In this embodiment:
the cross-sectional area of the anode copper rod 2 is 25 × pi × 105 mm-8242.5 mm2
Electrolytic area of 4 anodic silver columns 4:
Figure BDA0002567583450000041
the transverse electrolysis proportion of the anode copper rod 2 and the anode silver column 4 is as follows:
Figure BDA0002567583450000042
the anode copper rod 2 comprises the following components in percentage by mass:
Figure BDA0002567583450000043
the anode silver column 4 comprises the following components in percentage by mass:
Figure BDA0002567583450000044
the mass ratio of the anode copper rod 2 to the anode silver column 4 is as follows:
Figure BDA0002567583450000045
under the conditions of the transverse electrolysis proportion and the mass proportion of the anode copper rod 2 and the anode silver column 4, the release content of copper ions is 0.7-1.0mg/l and the release content of silver ions is 0.001-0.01mg/l in the electrolysis process, thereby achieving the optimal parameter setting and the optimal water quality sterilization and disinfection effects of the swimming pool water purifier.
The negative pole is stainless steel spring 5, and stainless steel spring 5 diameter is greater than the diameter of positive pole bar copper 2 to the periphery of cover locating positive pole bar copper 2. The stainless steel spring 5 is sleeved with a filter screen device 6. Still include casing 7, solar panel 1 is laid to casing 7 upper surface, and filter screen device 6 is connected to casing 7 lower bottom surface.
It should be noted that the invention can also be connected by matching with a microprocessor controller, a current steering regulation switch and a copper and silver ion monitoring instrument, and the matching electrode is stimulated by accurate micro current to release copper ions to the optimum purification effect range with the content of 0.7-1.0mg/l and silver ions to the content of 0.001-0.01 mg/l. A portion of the copper and silver ions flow into the swimming pool via the water, their release is controlled by a microprocessor controller, and a copper and silver ion monitoring instrument is used to measure the copper and silver ion content in the water.
The operation mode of the embodiment is as follows:
the water in the pool is taken from a water source and pumped into the dirt filter through the water pump, then flows through the electrode processing box, copper ions are released into the water by the electrodes, and positive valence and copper and silver ions have flocculation effect. The water with flocculated matter flows through a quartz sand cylinder, and the flocculated matter is precipitated and filtered. The filtered water without impurities flows through the silver electrode treatment box, silver ions are released into the water by the electrodes, and then the purified water with copper and silver ions flows into the swimming pool.
Flocculation is caused by flocculation of metal ions in mineral salts by adding water-soluble mineral salts in the conventional chemical water purification method, but the anions in the mineral salts change the ecological balance of water, such as pH. The electronic physical water purification method is a flocculation process generated by copper ions released by the electrodes, so that anions such as nitrogen, sulfur and the like do not exist in water, and the balance of water quality is not changed.
The flocculation process is described as follows:
the direct current is connected into the electrode, copper ions are generated at the cathode of the electrode, and the intensity of the current determines the release amount of the ions. The positive and negative of the action power supply are changed intermittently, so that the two ends of the electrode are uniformly worn and the electrode at one end is prevented from being calcium-bonded. The part of the released copper ions exceeding the copper solubility product of water and hydroxide anions generated by the positive electrode act to generate copper hydroxide (Cu (OH)2), the copper hydroxide is not dissolved in water, impurities in the water are flocculated in the precipitation process, and therefore large flocculated substances are generated and can be filtered by a quartz sand cylinder. When the quartz sand cylinder is used, the filtration rate is 35m3 per hour per square meter, and the flocculate can not only be retained on the surface layer of the quartz sand, but also permeate into the sand layer and be retained layer by layer. Therefore very importantly adopt high jar in order guaranteeing the filter effect, husky jar undersize, and the flocculation thing can not arouse the muddy of pond water by effectual filtration, and porous filter screen device can play the effect that improves the filter effect in the short time, nevertheless through certain time filter effect can be because the accumulation of flocculation thing and greatly influenced. The different parameters determining the electrolysis, flocculation and filtration effect must be determined in a comprehensive manner to ensure the best overall effect, i.e. a clear water quality with the highest bactericidal activity. The sterilizing capability can be obtained by determining the proper copper content, silver content and copper-silver ratio according to the quality of the water source. The copper and silver ions required to ensure sufficient bactericidal activity and to maintain the water in the tank clean and hygienic are low, approximately 0.7-1.0mg/l copper ions and 0.001-0.01mg/l silver ions, at concentrations such that the water retains its organic character: no smell and smell. Different from the common traditional water purification method (such as chlorine, oxygen and the like), the content of metal ions is not easy to change in water, and the stability of the concentration of the metal ions is not influenced by physical parameters such as temperature and illumination. And the bactericidal performance of the copper silver ions is not influenced by nitrogen in water.
The bactericidal action of the copper silver ion water purification method is based on the combination of positively charged copper silver ions and cell walls of microorganisms with negative charges to form electrostatic bonds, the formation of the electrostatic bonds changes the permeability of the cell walls, and the normal intake of nutrients of the microorganisms is damaged, so that the bactericidal action is achieved. Also, once copper and silver ions have entered algal cells, they attack sulfur-containing amino acids in the cellular proteins, so that photosynthesis does not proceed normally, and the algal cells are thereby killed. The dead cells are filtered through flocculation effect generated by the combination of copper ions and hydroxide anions in water and sand jars
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (9)

1. The utility model provides a solar energy swimming pool clarifier which characterized in that: including positive pole, negative pole and electric circuit device, the positive pole is the mixed base of copper and silver, the negative pole is the stainless steel, electric circuit device includes solar panel (1) and circuit, electric circuit device is connected with the electrolysis unit, provides the electric current, the positive pole includes positive pole bar copper (2), it passes through to set up the extension line on the periphery of positive pole bar copper (2) round hole (3) at positive pole bar copper (2) cross section center, positive pole silver post (4) are put into to embedded formula in round hole (3), the outer terminal surface of positive pole silver post (4) with the periphery of positive pole bar copper (2) agrees with.
2. The solar swimming pool purifier of claim 1, wherein: the number of the round holes (3) is 2-10, and the round holes are uniformly distributed on the anode copper rod (2).
3. A solar swimming pool purifier according to claim 1 or 2, wherein: the anode silver post (4) is pluggable and arranged and used for adjusting the electrolysis proportion of the anode copper bar (2) and the anode silver post (4).
4. The solar swimming pool purifier of claim 1, wherein: the electrolysis proportion of the cross sections of the anode copper rod (2) and the anode silver column (4) is 2-5 per mill.
5. The solar swimming pool purifier of claim 1, wherein: the mass proportion of the anode copper rod (2) and the anode silver column (4) is 2.2-6 per mill.
6. The solar swimming pool purifier of claim 1, wherein: the release content of copper ions is 0.7-1.0mg/l and the release content of silver ions is 0.001-0.01mg/l in the electrolytic process.
7. The solar swimming pool purifier of claim 1, wherein: the cathode is a stainless steel spring (5), and the diameter of the stainless steel spring (5) is larger than that of the anode copper rod (2) and is sleeved on the periphery of the anode copper rod (2).
8. The solar swimming pool purifier of claim 1, wherein: and a filter screen device (6) is sleeved on the periphery of the stainless steel spring (5).
9. The solar swimming pool purifier of claim 1, wherein: still include casing (7), the top surface lays on casing (7) solar panel (1), bottom surface is connected under casing (7) filter screen device (6).
CN202010628633.2A 2020-07-02 2020-07-02 Solar swimming pool purifier Pending CN111634983A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010628633.2A CN111634983A (en) 2020-07-02 2020-07-02 Solar swimming pool purifier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010628633.2A CN111634983A (en) 2020-07-02 2020-07-02 Solar swimming pool purifier

Publications (1)

Publication Number Publication Date
CN111634983A true CN111634983A (en) 2020-09-08

Family

ID=72326160

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010628633.2A Pending CN111634983A (en) 2020-07-02 2020-07-02 Solar swimming pool purifier

Country Status (1)

Country Link
CN (1) CN111634983A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113321274A (en) * 2021-07-01 2021-08-31 宁波市思虎电子科技有限公司 Solar copper ion generator, electrode inverting method and electrode depletion judging method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1202875A (en) * 1995-11-28 1998-12-23 澳斯特克有限公司 Liquid sterilisation apparatus
JP3773520B1 (en) * 2004-09-21 2006-05-10 有限会社 富山エンジニア Fixed electric water purifier
CN202808444U (en) * 2012-09-14 2013-03-20 陈春华 Solar energy water quality treater
CN109095666A (en) * 2018-09-25 2018-12-28 河南国康实业有限公司 Copper silver ion type swimming pool water treatment engineering equipment
CN208540658U (en) * 2018-07-25 2019-02-26 李凯 Silver copper ion generator and sterilizer with the silver copper ion generator
CN212832970U (en) * 2020-07-02 2021-03-30 上海力帮太阳能热水器有限公司 Solar swimming pool purifier

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1202875A (en) * 1995-11-28 1998-12-23 澳斯特克有限公司 Liquid sterilisation apparatus
JP3773520B1 (en) * 2004-09-21 2006-05-10 有限会社 富山エンジニア Fixed electric water purifier
CN202808444U (en) * 2012-09-14 2013-03-20 陈春华 Solar energy water quality treater
CN208540658U (en) * 2018-07-25 2019-02-26 李凯 Silver copper ion generator and sterilizer with the silver copper ion generator
CN109095666A (en) * 2018-09-25 2018-12-28 河南国康实业有限公司 Copper silver ion type swimming pool water treatment engineering equipment
CN212832970U (en) * 2020-07-02 2021-03-30 上海力帮太阳能热水器有限公司 Solar swimming pool purifier

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113321274A (en) * 2021-07-01 2021-08-31 宁波市思虎电子科技有限公司 Solar copper ion generator, electrode inverting method and electrode depletion judging method

Similar Documents

Publication Publication Date Title
KR101379274B1 (en) Apparatus for water containing nitric oxide having sterilizing function
EP0128782A1 (en) Water purification apparatus
CN203373234U (en) Multifunctional total-effect direct-drinking water system
US20090008267A1 (en) Process and method for the removal of arsenic from water
CN102497915A (en) Sealing-type water purifier and water-purifying method for producing electrolyzed hydrogen-containing pure cold and hot water and preventing contamination caused by microorganisms and foreign contaminants
DK2663530T3 (en) Water treatment
CN212832970U (en) Solar swimming pool purifier
CN101704564A (en) Device and method for purifying and sterilizing swimming pool water
CN111634983A (en) Solar swimming pool purifier
JPWO2001060751A1 (en) Coagulant manufacturing apparatus and water purification apparatus using the same
JP2014224646A (en) Outdoor unit auxiliary cooling system
CN201605182U (en) Device for purifying and sterilizing swimming pool water
CN202936282U (en) Water processing and circulating system for swimming pool
CN107140769A (en) A kind of Novel cooling tower circular water treating system
CN2663403Y (en) Tandem type electrolyzer
CA3068385C (en) Water treatment device
CN102923881B (en) Seawater circulating filtration and disinfection system for seawater swimming pool and seawater circulating filtration and disinfection method therefor
KR20130040627A (en) Apparatus for producing reducing water by electrolysis
CN2504260Y (en) Water purifier
CN2215482Y (en) Drinkable unboiled alkalinous ion water treating device
CN212127829U (en) Reverse osmosis concentrate electrolytic recovery device
CN101857333B (en) Six-conversion health active water
CN201445661U (en) Electrolytic apparatus for sterilizing swimming pool
CN201729737U (en) Treated nourishing active water processing equipment
CN207418351U (en) A kind of clear device of adjustable type dirt bacterium

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination