CN111621193A - Safe and environment-friendly plant oil-based book and periodical printing ink and preparation method thereof - Google Patents
Safe and environment-friendly plant oil-based book and periodical printing ink and preparation method thereof Download PDFInfo
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- CN111621193A CN111621193A CN202010635574.1A CN202010635574A CN111621193A CN 111621193 A CN111621193 A CN 111621193A CN 202010635574 A CN202010635574 A CN 202010635574A CN 111621193 A CN111621193 A CN 111621193A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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Abstract
The invention discloses safe and environment-friendly plant oil-based book and periodical ink and a preparation method thereof, and relates to the technical field of printing ink. The invention prepares modified soybean oil by using soybean oil and tung oil under the catalysis of zinc oxide and anthraquinone, then coats cetyl trimethyl ammonium bromide on the surface of nano spherical ferric oxide, and places the nano spherical ferric oxide into ethyl orthosilicate ethanol solution, after stirring and reacting, obtains pretreatment additive, prepares additive blank after the pretreatment additive is acid-etched, mixes the additive blank with ethyl acetate, freezes and dries to prepare additive, finally mixes the modified soybean oil with rosin modified phenolic resin, adds additive, organic pigment, paraffin and auxiliary agent, stirs and mixes, and obtains safe and environment-friendly plant-based book and periodical ink. The safe and environment-friendly plant-based book and periodical printing ink prepared by the invention has the advantages of higher drying rate and lower VOC content.
Description
Technical Field
The invention relates to the technical field of printing ink, in particular to safe and environment-friendly vegetable oil-based book and periodical ink and a preparation method thereof.
Background
The environment is always a problem of great attention in the world, and the requirement on environmental protection is continuously improved in the domestic printing and packaging industry under the current situation of rising green and environmental protection. As an industry having a certain influence on the environment, attention is also paid to its own behavior, and the industry is involved in the environmental protection. The ink is one of raw materials of printed products, and also starts the green and environment-friendly way of the ink, and various types of environment-friendly ink are produced at the same time. The adoption of the environment-friendly ink gradually becomes a fashion of the printing industry and also becomes a mode for improving the competitiveness of printing enterprises.
The "ink aroma" commonly heard by people is the smell of PAH (polycyclic aromatic hydrocarbon) contained in the traditional ink, which is a volatile solvent and is diffused in the air, and VOC (volatile organic compounds) contained in the ink can not only increase air pollution, but also cause harm to human bodies. Although most of the solvent is eliminated after the ink is dried, part of the solvent is remained, a student textbook reads for a long time, and the inhaled gas affects the central nervous system of the brain and poses a threat to health of books printed by the ink.
Moreover, the pigment particles in the ink are fine and have strong adsorption capacity, and the ink contains heavy metal elements such as lead, chromium, cadmium, mercury and the like, and has certain toxicity. Their discharge not only causes damage to the natural environment but also causes chronic poisoning of the human body. Especially, the consequences are more unreasonable after the student and the child are in close contact with each other.
The green printing is a printing mode which does not damage the ecological environment, does not threaten the human health and saves energy and resources. Developing green printing has profound significance to the environment, human health and resources. Recently, the printing of green teaching materials proposed by the nation has more special significance as the primary measure for promoting the development of green printing. Children are in the stage of young growth, and the phenomena of book licking, book gnawing and random eating after book turning are very common, so the probability of benzene series injury is far higher than that of adults. The teaching materials are mainly used by middle and primary school students, and the teaching materials are used as learning tools of the students and are required to be contacted every day. Many students are used to reading while eating, touch the teaching material with the hands, contact food again, like this, can lead to the teaching material printing in-process, and a large amount of non-environmental protection material that uses gets into the human body along with food, causes certain poison to the health, for child's health, therefore our research direction is to let plant oil base textbook and periodical printing ink replace traditional offset printing ink.
For the existing printing ink, high efficiency and high selectivity are pursued, and the product is pursued to be green in the reaction process, and the green environment-friendly product promotes the reaction rate of chemical products to be high; the method has the advantages of less by-products, low energy consumption, reduction of raw materials, low toxicity or no toxicity of reaction conditions, reaction media and generated products, and great significance in solving the environmental pollution.
Disclosure of Invention
The invention aims to provide safe and environment-friendly plant oil-based book and periodical printing ink and a preparation method thereof, so as to solve the problems in the background art.
In order to achieve the purpose, the invention provides the following technical scheme:
the safe and environment-friendly vegetable oil-based book and periodical printing ink is characterized by mainly comprising the following raw material components in parts by weight: 13-18 parts of organic pigment, 20-40 parts of modified soybean oil, 7-12 parts of rosin modified phenolic resin, 2-3 parts of paraffin and 3.5-5.5 parts of auxiliary agent.
The safe and environment-friendly vegetable oil-based book and periodical ink is characterized by further comprising the following raw material components in parts by weight: 5.5-8.5 parts of additive.
Preferably, the modified soybean oil is prepared from soybean oil and tung oil under the catalysis of zinc oxide and anthraquinone.
Preferably, the additive is formed by mixing modified silicon dioxide and ethyl acetate, wherein the modified silicon dioxide is prepared from tetraethoxysilane, spherical nano ferric oxide and hexadecyl trimethyl ammonium bromide.
As optimization, the safe and environment-friendly vegetable oil-based book and periodical ink mainly comprises the following raw material components in parts by weight: 15 parts of organic pigment, 32 parts of modified soybean oil, 12 parts of rosin modified phenolic resin, 3 parts of paraffin, 5 parts of auxiliary agent and 7 parts of additive.
As optimization, the preparation method of the safe and environment-friendly vegetable oil-based book and periodical ink mainly comprises the following preparation steps:
(1) mixing soybean oil and tung oil, adding a mixed catalyst, and reacting at high temperature and high pressure to obtain modified soybean oil;
(2) mixing and dispersing nano spherical ferric oxide and water, adding hexadecyl trimethyl ammonium bromide, adjusting the pH value, adding ethyl orthosilicate ethanol solution, stirring for reaction, filtering to obtain a pretreatment additive blank, etching the pretreatment additive blank by acid liquor, filtering, washing and drying to obtain a pretreatment additive, mixing the pretreatment additive with ethyl acetate, filtering, and freeze-drying to obtain an additive;
(3) mixing the modified soybean oil obtained in the step (1) with rosin modified phenolic resin, adding the additive obtained in the step (2), organic pigment, paraffin and auxiliary agent, and stirring and mixing to obtain safe and environment-friendly plant-based book and periodical ink;
(4) and (4) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (3).
As optimization, the preparation method of the safe and environment-friendly vegetable oil-based book and periodical ink mainly comprises the following preparation steps:
(1) mixing soybean oil and tung oil in a mass ratio of 1:9 in a flask, adding a mixed catalyst which is 0.04 times of the mass of the materials in the flask into the flask, and reacting for 120min at the temperature of 310 ℃ and the pressure of 4MPa to obtain modified soybean oil;
(2) mixing and dispersing nano spherical ferric oxide and water according to the mass ratio of 1:100 in a beaker, adding hexadecyl trimethyl ammonium bromide which is 1-4 times of the mass of the nano spherical ferric oxide into the beaker, adjusting the pH value in the flask to 10, adding 20% ethyl orthosilicate ethanol solution by mass fraction into the flask, stirring and reacting for 20 hours at the temperature of 35 ℃, filtering to obtain a pretreatment additive blank, mixing the pretreatment additive blank and 0.1% hydrochloric acid solution by mass fraction according to the mass ratio of 1:15, stirring and etching for 4 hours, filtering to obtain a filter cake, washing the filter cake with deionized water for 5-8 times, drying for 3 hours at the temperature of 65 ℃ to obtain a pretreatment additive, mixing the pretreatment additive and ethyl acetate according to the mass ratio of 1:15, mixing and soaking for 12 hours, filtering to obtain an additive blank, freeze-drying the additive blank to obtain an additive;
(3) mixing the modified soybean oil obtained in the step (1) and rosin modified phenolic resin in a stirrer according to a mass ratio of 8:3, adding 7/32 times of the additive obtained in the step (2) in mass of the modified soybean oil, 15/32 times of organic pigment in mass of the modified soybean oil, 3/32 times of paraffin in mass of the modified soybean oil and 5/32 times of auxiliary agent in mass of the modified soybean oil into the stirrer, and stirring and mixing for 60min under the conditions that the temperature is 20 ℃ and the rotating speed is 320r/min to obtain the safe and environment-friendly plant-based book and periodical ink;
(4) and (4) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (3).
Preferably, the mixed catalyst in the step (1) is obtained by mixing anthraquinone and zinc oxide according to the mass ratio of 1: 1.
Optimally, the preparation method of the nano spherical ferric trioxide in the step (2) comprises the steps of adding 2-10% by mass of ferric trichloride solution into a three-necked bottle containing a condenser, stirring and reacting for 72 hours at the temperature of 100 ℃, then carrying out centrifugal separation, filtering, and removing liquid to obtain the nano spherical ferric trioxide.
Preferably, the organic pigment in the step (3) is any one or more of lithol rubine 5700, lithol rubine 5701, benzidine yellow pigment 1278, phthalocyanine blue 7631, phthalocyanine blue 153, carbon black 303, carbon black 505 and titanium dioxide; the auxiliary agent is any one of an anti-emulsifier, a drying agent, an antioxidant or a dispersing agent.
Compared with the prior art, the invention has the beneficial effects that:
according to the invention, the modified soybean oil is used when the safe and environment-friendly vegetable oil-based book and periodical printing ink is prepared, and the additive is added into the product, firstly, after the soybean oil is modified, the bonding effect of the vegetable oil-based bonding material can reach the bonding effect of the mineral oil bonding material, so that the content of the mineral oil in the product is reduced, the VOC (volatile organic compound) release amount of the product is reduced, and the environmental protection performance of the product is improved; secondly, the additive added into the product is a porous silicon dioxide vesicle structure containing ethyl acetate inside, after the additive is added into the product, the ethyl acetate can be released in the product curing process, so that the vegetable oil inside the product is taken away, the drying rate of the product is further improved, and the additive gradually becomes the porous silicon dioxide vesicle structure along with the consumption of the ethyl acetate, so that the VOC can be adsorbed, the release of the vegetable oil inside the product is improved, the drying rate of the product is further improved, and the VOC release amount of the product is reduced.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
For more clear explanation, the method provided by the present invention is illustrated in detail by the following examples, and the method for testing each index of the safe and environment-friendly vegetable oil-based book ink manufactured in the following examples is as follows:
drying rate: the safe and environment-friendly vegetable oil-based book ink obtained in each example and each comparative example was coated on paper in the same thickness, and the drying time was measured.
VOC measurement: and (3) separating the VOC of the safe and environment-friendly vegetable oil-based book and periodical printing ink obtained in each embodiment and comparative example by using a gas chromatography technology, selecting a sample injection mode according to the type of the compound, qualitatively identifying the resin oil to be detected, quantifying by using an internal standard method according to the peak area, and calculating to obtain the content of the VOC. .
Example 1
A safe and environment-friendly vegetable oil-based book and periodical printing ink mainly comprises the following components in parts by weight: 15 parts of organic pigment, 32 parts of modified soybean oil, 12 parts of rosin modified phenolic resin, 3 parts of paraffin, 5 parts of auxiliary agent and 7 parts of additive.
A preparation method of safe and environment-friendly plant oil-based book and periodical ink mainly comprises the following preparation steps:
(1) mixing soybean oil and tung oil in a mass ratio of 1:9 in a flask, adding a mixed catalyst which is 0.04 times of the mass of the materials in the flask into the flask, and reacting for 120min at the temperature of 310 ℃ and the pressure of 4MPa to obtain modified soybean oil;
(2) mixing and dispersing nano spherical ferric oxide and water according to the mass ratio of 1:100 in a beaker, adding hexadecyl trimethyl ammonium bromide which is 4 times of the mass of the nano spherical ferric oxide into the beaker, adjusting the pH value in the flask to 10, adding 20 mass percent ethyl orthosilicate ethanol solution into the flask, stirring and reacting for 20 hours at the temperature of 35 ℃, filtering to obtain a blank of a pretreatment additive, mixing the blank of the pretreatment additive and 0.1 mass percent hydrochloric acid solution according to the mass ratio of 1:15, stirring and etching for 4 hours, filtering to obtain a filter cake, washing the filter cake with deionized water for 6 times, drying for 3 hours at the temperature of 65 ℃ to obtain the pretreatment additive, mixing the pretreatment additive and ethyl acetate according to the mass ratio of 1:15, mixing and soaking for 12 hours, filtering to obtain a blank of the additive, freezing and drying the blank of the additive, obtaining an additive;
(3) mixing the modified soybean oil obtained in the step (1) and rosin modified phenolic resin in a stirrer according to a mass ratio of 8:3, adding 7/32 times of the additive obtained in the step (2) in mass of the modified soybean oil, 15/32 times of organic pigment in mass of the modified soybean oil, 3/32 times of paraffin in mass of the modified soybean oil and 5/32 times of auxiliary agent in mass of the modified soybean oil into the stirrer, and stirring and mixing for 60min under the conditions that the temperature is 20 ℃ and the rotating speed is 320r/min to obtain the safe and environment-friendly plant-based book and periodical ink;
(4) and (4) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (3).
Preferably, the mixed catalyst in the step (1) is obtained by mixing anthraquinone and zinc oxide according to the mass ratio of 1: 1.
Optimally, the preparation method of the nano spherical ferric trioxide in the step (2) comprises the steps of adding 8% by mass of ferric trichloride solution into a three-necked bottle containing a condenser, stirring and reacting for 72 hours at the temperature of 100 ℃, then carrying out centrifugal separation, filtering, and removing liquid to obtain the nano spherical ferric trioxide.
Preferably, the organic pigment in the step (3) is carbon black 303; the auxiliary agent is an anti-emulsifier.
Example 2
A safe and environment-friendly vegetable oil-based book and periodical printing ink mainly comprises the following components in parts by weight: 15 parts of organic pigment, 32 parts of soybean oil, 12 parts of rosin modified phenolic resin, 3 parts of paraffin, 5 parts of auxiliary agent and 7 parts of additive.
A preparation method of safe and environment-friendly plant oil-based book and periodical ink mainly comprises the following preparation steps:
(1) mixing and dispersing nano spherical ferric oxide and water according to the mass ratio of 1:100 in a beaker, adding hexadecyl trimethyl ammonium bromide which is 4 times of the mass of the nano spherical ferric oxide into the beaker, adjusting the pH value in the flask to 10, adding 20 mass percent ethyl orthosilicate ethanol solution into the flask, stirring and reacting for 20 hours at the temperature of 35 ℃, filtering to obtain a blank of a pretreatment additive, mixing the blank of the pretreatment additive and 0.1 mass percent hydrochloric acid solution according to the mass ratio of 1:15, stirring and etching for 4 hours, filtering to obtain a filter cake, washing the filter cake with deionized water for 6 times, drying for 3 hours at the temperature of 65 ℃ to obtain the pretreatment additive, mixing the pretreatment additive and ethyl acetate according to the mass ratio of 1:15, mixing and soaking for 12 hours, filtering to obtain a blank of the additive, freezing and drying the blank of the additive, obtaining an additive;
(2) mixing soybean oil and rosin modified phenolic resin in a stirrer according to the mass ratio of 8:3, adding 7/32 times of the additive obtained in the step (2), 15/32 times of organic pigment, 3/32 times of paraffin and 5/32 times of auxiliary agent into the stirrer, and stirring and mixing for 60min at the temperature of 20 ℃ and the rotating speed of 320r/min to obtain the safe and environment-friendly plant-based book and periodical ink;
(3) and (3) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (2).
Optimally, the preparation method of the nano spherical ferric trioxide in the step (1) comprises the steps of adding 8% by mass of ferric trichloride solution into a three-necked bottle containing a condenser, stirring and reacting for 72 hours at the temperature of 100 ℃, then carrying out centrifugal separation, filtering, and removing liquid to obtain the nano spherical ferric trioxide.
Preferably, the organic pigment in the step (2) is carbon black 303; the auxiliary agent is an anti-emulsifier.
Example 3
A safe and environment-friendly vegetable oil-based book and periodical printing ink mainly comprises the following components in parts by weight: 15 parts of organic pigment, 32 parts of modified soybean oil, 12 parts of rosin modified phenolic resin, 3 parts of paraffin and 5 parts of auxiliary agent.
A preparation method of safe and environment-friendly plant oil-based book and periodical ink mainly comprises the following preparation steps:
(1) mixing soybean oil and tung oil in a mass ratio of 1:9 in a flask, adding a mixed catalyst which is 0.04 times of the mass of the materials in the flask into the flask, and reacting for 120min at the temperature of 310 ℃ and the pressure of 4MPa to obtain modified soybean oil;
(2) mixing the modified soybean oil obtained in the step (1) and rosin modified phenolic resin in a stirrer according to a mass ratio of 8:3, adding an organic pigment which is 15/32 times the mass of the modified soybean oil, paraffin which is 3/32 times the mass of the modified soybean oil and an auxiliary agent which is 5/32 times the mass of the modified soybean oil into the stirrer, and stirring and mixing for 60min under the conditions that the temperature is 20 ℃ and the rotating speed is 320r/min to obtain the safe and environment-friendly plant-based book and periodical ink;
(3) and (3) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (2).
Preferably, the mixed catalyst in the step (1) is obtained by mixing anthraquinone and zinc oxide according to the mass ratio of 1: 1.
Preferably, the organic pigment in the step (2) is carbon black 303; the auxiliary agent is an anti-emulsifier.
Comparative example
A safe and environment-friendly vegetable oil-based book and periodical printing ink mainly comprises the following components in parts by weight: 15 parts of organic pigment, 32 parts of soybean oil, 12 parts of rosin modified phenolic resin, 3 parts of paraffin and 5 parts of auxiliary agent.
A preparation method of safe and environment-friendly plant oil-based book and periodical ink mainly comprises the following preparation steps:
(1) mixing soybean oil and rosin modified phenolic resin in a mixer according to the mass ratio of 8:3, adding 15/32 times of organic pigment, 3/32 times of paraffin and 5/32 times of auxiliary agent into the mixer, and stirring and mixing for 60min at the temperature of 20 ℃ and the rotating speed of 320r/min to obtain the safe and environment-friendly plant-based book and periodical ink;
(2) and (2) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (1).
Preferably, the organic pigment in the step (2) is carbon black 303; the auxiliary agent is an anti-emulsifier.
Examples of effects
Table 1 below gives the results of performance analysis of the safe and environment-friendly vegetable oil-based book ink using examples 1 to 3 of the present invention and comparative example.
TABLE 1
From the comparison of the experimental data of example 1 and the comparative example in table 1, it can be found that the use of the modified soybean oil and the addition of the additive in the preparation of the safe and environment-friendly vegetable oil-based book and periodical ink can effectively increase the drying rate of the product and reduce the VOC content of the product.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Claims (10)
1. The safe and environment-friendly vegetable oil-based book and periodical printing ink is characterized by mainly comprising the following raw material components in parts by weight: 13-18 parts of organic pigment, 20-40 parts of modified soybean oil, 7-12 parts of rosin modified phenolic resin, 2-3 parts of paraffin and 3.5-5.5 parts of auxiliary agent.
2. The safe and environment-friendly plant oil-based book and periodical ink according to claim 1, further comprising the following raw material components in parts by weight: 5.5-8.5 parts of additive.
3. The safe and environment-friendly vegetable oil-based book and periodical ink as claimed in claim 2, wherein the modified soybean oil is prepared from soybean oil and tung oil under catalysis of zinc oxide and anthraquinone.
4. The safe and environment-friendly plant oil-based book and periodical ink as claimed in claim 3, wherein the additive is prepared by mixing modified silica and ethyl acetate, and the modified silica is prepared by tetraethoxysilane, nano-sphere ferric oxide and cetyl trimethyl ammonium bromide.
5. The safe and environment-friendly plant oil-based book and periodical ink according to claim 4, wherein the safe and environment-friendly plant oil-based book and periodical ink mainly comprises the following raw material components in parts by weight: 15 parts of organic pigment, 32 parts of modified soybean oil, 12 parts of rosin modified phenolic resin, 3 parts of paraffin, 5 parts of auxiliary agent and 7 parts of additive.
6. A preparation method of safe and environment-friendly vegetable oil-based book and periodical printing ink is characterized by mainly comprising the following preparation steps:
(1) mixing soybean oil and tung oil, adding a mixed catalyst, and reacting at high temperature and high pressure to obtain modified soybean oil;
(2) mixing and dispersing nano spherical ferric oxide and water, adding hexadecyl trimethyl ammonium bromide, adjusting the pH value, adding ethyl orthosilicate ethanol solution, stirring for reaction, filtering to obtain a pretreatment additive blank, etching the pretreatment additive blank by acid liquor, filtering, washing and drying to obtain a pretreatment additive, mixing the pretreatment additive with ethyl acetate, filtering, and freeze-drying to obtain an additive;
(3) mixing the modified soybean oil obtained in the step (1) with rosin modified phenolic resin, adding the additive obtained in the step (2), organic pigment, paraffin and auxiliary agent, and stirring and mixing to obtain safe and environment-friendly plant-based book and periodical ink;
(4) and (4) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (3).
7. The preparation method of the safe and environment-friendly vegetable oil-based book and periodical ink according to claim 6, which mainly comprises the following preparation steps:
(1) mixing soybean oil and tung oil in a mass ratio of 1:9 in a flask, adding a mixed catalyst which is 0.04 times of the mass of the materials in the flask into the flask, and reacting for 120min at the temperature of 310 ℃ and the pressure of 4MPa to obtain modified soybean oil;
(2) mixing and dispersing nano spherical ferric oxide and water according to the mass ratio of 1:100 in a beaker, adding hexadecyl trimethyl ammonium bromide which is 1-4 times of the mass of the nano spherical ferric oxide into the beaker, adjusting the pH value in the flask to 10, adding 20% ethyl orthosilicate ethanol solution by mass fraction into the flask, stirring and reacting for 20 hours at the temperature of 35 ℃, filtering to obtain a pretreatment additive blank, mixing the pretreatment additive blank and 0.1% hydrochloric acid solution by mass fraction according to the mass ratio of 1:15, stirring and etching for 4 hours, filtering to obtain a filter cake, washing the filter cake with deionized water for 5-8 times, drying for 3 hours at the temperature of 65 ℃ to obtain a pretreatment additive, mixing the pretreatment additive and ethyl acetate according to the mass ratio of 1:15, mixing and soaking for 12 hours, filtering to obtain an additive blank, freeze-drying the additive blank to obtain an additive;
(3) mixing the modified soybean oil obtained in the step (1) and rosin modified phenolic resin in a stirrer according to a mass ratio of 8:3, adding 7/32 times of the additive obtained in the step (2) in mass of the modified soybean oil, 15/32 times of organic pigment in mass of the modified soybean oil, 3/32 times of paraffin in mass of the modified soybean oil and 5/32 times of auxiliary agent in mass of the modified soybean oil into the stirrer, and stirring and mixing for 60min under the conditions that the temperature is 20 ℃ and the rotating speed is 320r/min to obtain the safe and environment-friendly plant-based book and periodical ink;
(4) and (4) carrying out index detection on the safe and environment-friendly plant-based book and periodical printing ink obtained in the step (3).
8. The preparation method of the safe and environment-friendly plant oil-based book and periodical ink according to claim 6, wherein the mixed catalyst in the step (1) is prepared by mixing anthraquinone and zinc oxide according to a mass ratio of 1: 1.
9. The preparation method of the safe and environment-friendly plant oil-based book and periodical ink according to claim 6, wherein the preparation method of the nano spherical ferric oxide in the step (2) comprises the steps of adding a ferric trichloride solution with a mass fraction of 2-10% into a three-necked bottle containing a condenser, stirring and reacting for 72 hours at 100 ℃, centrifuging and separating, filtering, and removing liquid to obtain the nano spherical ferric oxide.
10. The preparation method of the safe and environment-friendly vegetable oil-based book and periodical ink as claimed in claim 6, wherein in the step (3), the organic pigment is any one or more of lithol rubine 5700, lithol rubine 5701, benzidine yellow pigment 1278, phthalo blue 7631, phthalo blue 153, carbon black 303, carbon black 505 and titanium dioxide; the auxiliary agent is any one of an anti-emulsifier, a drying agent, an antioxidant or a dispersing agent.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN117326597A (en) * | 2023-08-30 | 2024-01-02 | 宁波爱诗化妆品有限公司 | Method for regulating and controlling size of nano iron oxide yellow, nano iron oxide yellow and application thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0465473A (en) * | 1990-07-06 | 1992-03-02 | Toyo Ink Mfg Co Ltd | Printing ink |
| JP2005154703A (en) * | 2003-11-21 | 2005-06-16 | Hitachi Kasei Polymer Co Ltd | Resin varnish for printing ink and method for producing the same |
| CN101090018A (en) * | 2007-04-30 | 2007-12-19 | 吉林大学 | Silica-magnetic composite micropartical and its preparation method |
| CN102533389A (en) * | 2011-12-05 | 2012-07-04 | 华北电力大学 | Method for applying mesocellular silica hollow sphere iron-based oxygen carrier |
| CN102786834A (en) * | 2012-08-23 | 2012-11-21 | 福建省宁化县利丰化工有限公司 | Plant-oil-based printing ink vehicle and preparation method thereof |
| CN105176027A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Low-VOC environmentally-friendly high-quality automobile interior trim part material and preparation method thereof |
| CN105802325A (en) * | 2014-12-30 | 2016-07-27 | 天津天女化工集团股份有限公司 | Plant oil-based offset lithographic printing ink formula and preparation method thereof |
| CN110128863A (en) * | 2019-03-29 | 2019-08-16 | 中山市博海精细化工有限公司 | A kind of coating and preparation method thereof with organic matter suction-operated |
-
2020
- 2020-07-03 CN CN202010635574.1A patent/CN111621193A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0465473A (en) * | 1990-07-06 | 1992-03-02 | Toyo Ink Mfg Co Ltd | Printing ink |
| JP2005154703A (en) * | 2003-11-21 | 2005-06-16 | Hitachi Kasei Polymer Co Ltd | Resin varnish for printing ink and method for producing the same |
| CN101090018A (en) * | 2007-04-30 | 2007-12-19 | 吉林大学 | Silica-magnetic composite micropartical and its preparation method |
| CN102533389A (en) * | 2011-12-05 | 2012-07-04 | 华北电力大学 | Method for applying mesocellular silica hollow sphere iron-based oxygen carrier |
| CN102786834A (en) * | 2012-08-23 | 2012-11-21 | 福建省宁化县利丰化工有限公司 | Plant-oil-based printing ink vehicle and preparation method thereof |
| CN105802325A (en) * | 2014-12-30 | 2016-07-27 | 天津天女化工集团股份有限公司 | Plant oil-based offset lithographic printing ink formula and preparation method thereof |
| CN105176027A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Low-VOC environmentally-friendly high-quality automobile interior trim part material and preparation method thereof |
| CN110128863A (en) * | 2019-03-29 | 2019-08-16 | 中山市博海精细化工有限公司 | A kind of coating and preparation method thereof with organic matter suction-operated |
Non-Patent Citations (1)
| Title |
|---|
| 凌云星: "《实用油墨技术指南》", 30 November 2017 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117326597A (en) * | 2023-08-30 | 2024-01-02 | 宁波爱诗化妆品有限公司 | Method for regulating and controlling size of nano iron oxide yellow, nano iron oxide yellow and application thereof |
| CN117326597B (en) * | 2023-08-30 | 2024-05-24 | 宁波爱诗化妆品有限公司 | Method for regulating and controlling size of nano iron oxide yellow, nano iron oxide yellow and application thereof |
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