CN111603394A - Method for integrally 3D printing of polyether-ether-ketone oral restoration bodies with different colors - Google Patents

Method for integrally 3D printing of polyether-ether-ketone oral restoration bodies with different colors Download PDF

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Publication number
CN111603394A
CN111603394A CN202010422800.8A CN202010422800A CN111603394A CN 111603394 A CN111603394 A CN 111603394A CN 202010422800 A CN202010422800 A CN 202010422800A CN 111603394 A CN111603394 A CN 111603394A
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printing
color
prosthesis
ether
ketone
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CN111603394B (en
Inventor
吴国锋
李涤尘
陆伟
丁玲
杨春成
陈晞
王阳涛
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Shaanxi Jugao-Am Technology Co ltd
NANJING STOMATOLOGICAL HOSPITAL
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Shaanxi Jugao-Am Technology Co ltd
NANJING STOMATOLOGICAL HOSPITAL
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/891Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/802Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/802Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics
    • A61K6/813Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics comprising iron oxide
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/802Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics
    • A61K6/816Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics comprising titanium oxide
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/802Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics
    • A61K6/818Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics comprising zirconium oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • B33Y70/10Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing

Abstract

The invention discloses a method for integrally printing polyether-ether-ketone oral restorations with different colors in a 3D mode, which comprises the following steps of: s1: acquiring the upper jaw and the lower jaw of a patient, acquiring digital three-dimensional model data of the upper jaw and the lower jaw of the patient, and acquiring occlusion relation of upper and lower dentitions and personalized tooth colors and gum colors of the patient; s2: based on the three-dimensional data in S1, designing the digital dental prosthesis and adjusting the occlusion contact relation between the digital dental prosthesis and the jaw teeth to obtain a three-dimensional data model of the final prosthesis; s3: separating the three-dimensional data model tooth and the gum part of the prosthesis according to the difference between the tooth color and the gum color to obtain the printing data of different parts of the dental prosthesis and importing the printing data into 3D printing equipment; s4: and respectively determining the colors (tooth color and gum color) of all parts of the prosthesis, respectively proportioning, conveying to two printing heads of the integrated 3D printing equipment, and integrally printing to obtain the final oral prosthesis real object.

Description

Method for integrally 3D printing of polyether-ether-ketone oral restoration bodies with different colors
Technical Field
The invention relates to the technical field of oral cavity restoration bodies, in particular to a method for manufacturing polyether-ether-ketone oral cavity restoration bodies with different colors through integrated 3D printing.
Background
The clinical selection of the traditional oral cavity repairing material is still limited to the old three types (resin, metal and ceramic), and the three materials have the limitations and cannot meet the clinical requirements. The color of the resin is close to that of natural teeth, the aesthetic property is good, but the resin material has low hardness, is easy to age, is easy to abrade natural teeth of the jaw, has the problems of micro-leakage and the like, and is less and less in clinical application though continuous material improvement; the metal material has the advantages of high strength, corrosion resistance, good fatigue resistance and the like, but has the defects of unattractive color, high hardness (easy to wear and tear to natural teeth of the jaw) and the like; in recent years, patients have better aesthetic requirements, and some patients reject the selection of metal materials (factors such as sensitivity to metal odor, metal allergy and negative influence of metal on nuclear magnetic resonance examination), so that the nonmetallic oral cavity repairing material is becoming the mainstream of clinical material selection.
The current ceramic is the most representative inorganic non-metallic repair material, and has the advantages of beautiful color and good biocompatibility, and the defects of great brittleness, easy damage and high price, so that the clinical indications of the ceramic are greatly limited (for example, the ceramic cannot be used for repairing removable dentures); at present, the ceramic materials which are commonly used clinically are mainly glass ceramic and zirconium dioxide ceramic materials, but the hardness and the elastic modulus of the ceramic materials are far greater than those of natural teeth, the ceramic materials are easy to abrade the natural teeth of the jaw, and the clinical effect of the prosthesis is influenced by the overweight of the prosthesis.
Polyetheretherketone (PEEK) is a special engineering plastic with excellent properties such as high temperature resistance, self-lubrication, processed performance and high mechanical strength, and can be manufactured and processed into various mechanical parts; the PEEK material has the following performance advantages: compared with resin materials, the high-strength wear-resistant and wear-resistant composite material has good strength, and is durable and wear-resistant and ageing-resistant; compared with metal materials, the material has the advantages of large space for improving aesthetic properties, excellent biocompatibility and semi-radiation resistance; compared with ceramic materials, the material toughness is far better than that of ceramics, the weight is lighter and the cost is lower; the PEEK material is limited to be prepared into a monochromatic restoration in the field of oral restoration, the processing technology only comprises the processes of milling, injection molding and the like, 3D printing of the PEEK for preparing the oral restoration is not reported clinically, the appearance color of the existing pure PEEK material is light brown, the existing pure PEEK material is not suitable for directly preparing the oral restoration, and the color of the existing pure PEEK material needs to be improved so as to meet the clinical requirement of oral aesthetic restoration; in addition, the existing processing method for using PEEK as the dental prosthesis mainly comprises the traditional injection molding pressing and digital milling methods, wherein the processing procedure of the traditional injection molding pressing and digital milling methods is complicated, time and labor are wasted, and the traditional digital milling methods have large material waste and are not suitable for forming a finished product with a complex thin-wall shape. The 3D printing is an ideal method for realizing the low-cost quick manufacture of a single finished product with a complex shape, and how to apply the advanced 3D printing technology to print the PEEK dental restoration is a hot problem in the field.
Disclosure of Invention
The invention aims to solve the technical problem of overcoming the defect that the traditional 3D printing technology can only print one color of oral cavity prosthesis and provides a method for manufacturing the polyether-ether-ketone oral cavity prosthesis by integrated 3D printing.
In order to solve the technical problems, the technical scheme of the invention is as follows:
an integrated 3D printing method of a polyether-ether-ketone dental prosthesis comprises the following steps:
s1: scanning the upper jaw and the lower jaw of a patient by using a digital oral scanner, obtaining digital three-dimensional model data of the upper jaw and the lower jaw, obtaining the occlusion relation between the upper dentition and the lower dentition, and simultaneously respectively recording the personalized tooth color and the gum color of the patient;
s2: importing the obtained three-dimensional data into digital denture design software, and designing different parts of the digital dental prosthesis and adjusting the overall occlusion relation on the basis of the three-dimensional data to obtain a three-dimensional data model of the dental prosthesis;
s3: separating the three-dimensional data model of the teeth and the gum part of the oral cavity prosthesis, designing a connecting interface of the three-dimensional data model, thereby obtaining printing data of the teeth and the gum part, and then importing the printing data into 3D printing equipment (Jugao-AM vector 200, Shanxi focused high-material-added development Co., Ltd.);
s4: according to the color requirement of teeth and gum parts of the dental prosthesis determined clinically, color matching is carried out on the 3D printing polyether-ether-ketone materials of the teeth and the gum parts of the dental prosthesis respectively, the materials are respectively conveyed to two printing heads of integrated 3D printing equipment (Jugao-AM vector 200, Shaanxi high-polymer additive manufacturing technology development Co., Ltd.), and then integrated printing is carried out according to printing data led into the integrated 3D printing equipment, so that the polyether-ether-ketone dental prosthesis is prepared.
As a preferred technical scheme of the invention:
further, in the method for integrally 3D printing the polyether-ether-ketone dental restoration, when the 3D printing is performed in S4, the two printing heads may respectively and independently perform printing of polyether-ether-ketone materials with different colors on the teeth and the gum component of the dental restoration, when the printing is performed to the boundary area of each component, the two printing heads perform printing simultaneously, and when the printing is completed in the boundary area, the 3D printing process of the entire dental restoration is completed.
In the method for integrally printing the polyether-ether-ketone dental prosthesis, the contact surfaces between different parts of the polyether-ether-ketone dental prosthesis in the step S3 are provided with the micro-textures for improving the surface roughness.
According to the method for integrally printing the polyether-ether-ketone dental restoration with different colors in the 3D mode, the micro-texture comprises the serrated groove bodies and the serrated fixture blocks which are respectively arranged on the surfaces of all the components of the dental restoration.
The invention has the beneficial effects that:
(1) the invention utilizes the integrated 3D printing technology to lead the two printing heads to respectively adopt the polyether-ether-ketone materials with different colors for printing, leads the colors of different parts in the printed prosthesis to be respectively matched with the clinical common tooth color and gum color phase, and ensures the connection stability between different parts in the prosthesis;
(2) according to the invention, when different parts of the polyether-ether-ketone dental prosthesis are designed, the micro-textures are arranged on the contact surfaces among the parts, and the roughness of the contact surfaces is improved through the micro-textures, so that the connection stability among the parts of the polyether-ether-ketone dental prosthesis is further improved.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise.
Fig. 1 is a schematic view of a color palette of a peek dental color restoration component provided in the present invention;
fig. 2 is a schematic diagram of a color palette of a peek gingival color dental restoration component provided in the present invention.
Detailed Description
In order that the present invention may be more readily and clearly understood, a more particular description of the invention briefly described above will be rendered by reference to specific embodiments that are illustrated in the appended drawings.
Polyetheretherketone (PEEK) is a special engineering plastic with excellent properties such as high temperature resistance, self-lubrication, processed performance and high mechanical strength, and can be manufactured and processed into various mechanical parts; the PEEK material has the following performance advantages: compared with resin materials, the high-strength wear-resistant and wear-resistant composite material has good strength, and is durable and wear-resistant and ageing-resistant; compared with metal materials, the material has the advantages of large space for improving aesthetic properties, excellent biocompatibility and semi-radiation resistance; compared with ceramic materials, the material toughness is far better than that of ceramics, the weight is lighter and the cost is lower; the prior application of the PEEK material in the field of oral restoration is limited to be made into a single-color restoration, and the clinical requirement of dental aesthetic restoration materials cannot be met.
Example 1
The embodiment discloses a method for integrally printing polyether-ether-ketone oral prostheses with different colors in a 3D mode, which comprises the following steps:
s1: scanning the surface morphology of the upper jaw and the lower jaw of a patient by using a digital oral scanner, acquiring digital three-dimensional model data of the upper jaw and the lower jaw of the patient, and acquiring the occlusion relation of the upper dentition and the lower dentition of the patient;
s2: importing the obtained three-dimensional data into digital denture design software, and designing different parts of the digital dental prosthesis and adjusting the overall occlusion relation on the basis of the three-dimensional data to obtain a three-dimensional data model of the dental prosthesis;
s3: separating the three-dimensional data model of the teeth and the gum part of the oral cavity prosthesis, designing a connecting interface of the three-dimensional data model, thereby obtaining printing data of the teeth and the gum part, and then importing the printing data into 3D printing equipment (Jugao-AM vector 200, Shanxi focused high-material-added development Co., Ltd.);
s4: according to the color requirement of teeth and gum parts of the dental prosthesis determined clinically, color matching is carried out on the 3D printing polyether-ether-ketone materials of the teeth and the gum parts of the dental prosthesis respectively, the materials are respectively conveyed to two printing heads of integrated 3D printing equipment (Jugao-AM vector 200, Shaanxi high-polymer additive manufacturing technology development Co., Ltd.), and then integrated printing is carried out according to printing data led into the integrated 3D printing equipment, so that the polyether-ether-ketone dental prosthesis is prepared.
Wherein, the 3D printing materials of the polyether-ether-ketone dental restoration teeth and the gum component are mixed according to the components and the proportion provided by the embodiment.
The dental prosthesis and the gingival part of the dental prosthesis related in the embodiment are both made of polyether-ether-ketone prosthesis materials; wherein, the material of the tooth color component of the polyether-ether-ketone dental restoration comprises polyether-ether-ketone and toning powder, the toning powder is one of titanium oxide, zirconium oxide and aluminum oxide, and the mass percentage of the toning powder is 2-20%; the material of the gum color component of the polyether-ether-ketone dental restoration comprises the following components: polyether-ether-ketone and ferric oxide, wherein the weight percentage of the ferric oxide is 0.2-1.2%.
The embodiment also relates to a color shade guide for the teeth and the gum of the polyether-ether-ketone dental restoration, wherein:
the tooth color colorimetric plate for the polyether-ether-ketone dental prosthesis comprises nine color mark plates from Dentin-A to Dentin-I, wherein a DA color mark plate is formed by mixing polyether-ether-ketone and titanium oxide with the mass percent of 2-5%, a DB color mark plate is formed by mixing polyether-ether-ketone and titanium oxide with the mass percent of 6-15%, a DC color mark plate is formed by mixing polyether-ether-ketone and titanium oxide with the mass percent of 16-20%, a DD color mark plate is formed by mixing polyether-ether-ketone and zirconium oxide with the mass percent of 2-5%, a DE color mark plate is formed by mixing polyether-ether-ketone and zirconium oxide with the mass percent of 6-15%, a DF color mark plate is formed by mixing polyether-ether-ketone and zirconium oxide with the mass percent of 16-20%, a DG color mark plate is formed by mixing polyether-ether-ketone and aluminum oxide with the mass percent of 2-5%, the DH color mark plate is formed by mixing polyether-ether-ketone and alumina with the mass percent of 6-15%, and the DI color mark plate is formed by mixing polyether-ether-ketone and alumina with the mass percent of 16-20%.
According to the types of the color-mixing powder, DA-DI is divided into three groups, DA, DB and DC are one group, and the white color degree of the material is gradually increased along with the increase of the content of the titanium oxide, namely the denture prosthesis is gradually changed from light yellow to white; DD. DE, DF is a series, with the increase of zirconia content, the material white color degree increases gradually, namely the false tooth prosthesis gradually changes from light yellow to white; DG. DH, DI is a series, with the increase of alumina content, the white color degree of the false tooth material increases gradually, namely the false tooth prosthesis is changed from light yellow to white gradually; wherein, when the content of the toning powder is the same, the color of the oral cavity restoration added with the titanium oxide is white than that of the oral cavity restoration added with the zirconium oxide, and the color of the oral cavity restoration added with the zirconium oxide is white than that of the oral cavity restoration added with the aluminum oxide.
The polyether-ether-ketone gingival color colorimetric plate comprises six color colorimetric plates from Gingiva-A to Gingiva-F, the GA color target is formed by mixing polyether-ether-ketone and 0.2-0.5% of iron oxide, the GB color target is formed by mixing polyether-ether-ketone and 0.6-0.8% of iron oxide, the GC color target is formed by mixing polyether-ether-ketone and 0.9-1.2% of titanium oxide, the GD color target is formed by mixing polyether-ether-ketone, 10-15% of zirconium oxide and 2-5% of titanium oxide, the GE color target is formed by mixing polyether-ether-ketone, 0.6-0.8% of zirconium oxide and 10-15% of titanium oxide, and the GF color target is formed by mixing polyether-ether-ketone, 0.9-1.2% of zirconium oxide and 16-20% of titanium oxide.
According to the types of the added materials, GA-GF is divided into two groups, wherein the GA, the GB and the GC are one group and are formed by mixing polyether-ether-ketone and ferric oxide; with the increase of the content of the ferric oxide, the color of the material gradually turns red; GD. GE and GF are a group and are respectively formed by mixing polyether-ether-ketone, ferric oxide and titanium oxide; with the increase of the content of the ferric oxide, the color of the material gradually turns red; meanwhile, as the content of the titanium oxide increases, the color of the material gradually changes from light yellow to white.
In the embodiment, the polyether-ether-ketone material is used as a base material of the oral cavity restoration, the white toning powder is added and uniformly mixed with the polyether-ether-ketone, so that colors with different gradients are formed and are matched with the clinically common tooth colors, a patient can check and freely select the required color of the oral cavity restoration, and the red medicinal iron oxide powder is uniformly mixed with the polyether-ether-ketone material to form colors with different gradients and adapt to the clinically common gingival color, so that the requirements of different groups on the appearance of the oral cavity restoration are met;
in the embodiment, white titanium dioxide powder can be added into the polyetheretherketone gingival color material, and the color of the base support restoration body is closer to the color of the gingiva of a human body and more attractive after the white titanium dioxide powder is uniformly mixed with the ferric oxide powder and the polyetheretherketone material; the color comparison board for the dental polyether-ether-ketone restoration material is designed in the embodiment, so that the color comparison board can be selected by patients more visually, and the requirements of different groups on the appearance of the restoration are met;
in addition, the contact surfaces between different parts of the polyether-ether-ketone dental prosthesis are provided with micro-ornamentations for improving the surface roughness, and the micro-ornamentations comprise saw-toothed groove bodies and saw-toothed fixture blocks which are respectively arranged on the surfaces of the different parts; the roughness of the contact surface is improved through the micro-texture decoration, so that the plastic-baking resin can be bonded conveniently, and the connection stability among different parts in the polyether-ether-ketone is further improved; the micro-texture can be in other shapes, and only the roughness of the contact surface needs to be improved.
Therefore, the invention utilizes the integrated 3D printing technology to ensure that the two printing heads respectively adopt the PEEK gum color material and the PEEK denture color material for printing, so that the colors of different parts in the printed restoration are respectively matched with the clinical common tooth color and the gum color phase, and the requirements of different groups on the appearance of the dental restoration are met.
Example 2
The teeth and the gum part of the oral cavity prosthesis related in the embodiment are both made of polyether-ether-ketone prosthesis materials; the tooth color material of polyether-ether-ketone comprises polyether-ether-ketone and toning powder, wherein the toning powder is one of titanium oxide, zirconium oxide and aluminum oxide, and the mass percentage of the toning powder is 2-20%; the polyetheretherketone gingival color material comprises the following components: polyether-ether-ketone and ferric oxide, wherein the weight percentage of the ferric oxide is 0.2-1.2%.
The embodiment relates to a color shade guide for the teeth and the gum of the polyether-ether-ketone dental restoration;
wherein, the tooth color colorimetric plate of the polyether-ether-ketone dental restoration comprises nine color mark plates from Dentin-A to Dentin-I, wherein, the DA color mark plate is formed by mixing polyether-ether-ketone with 3 percent by mass of titanium oxide, the DB color mark plate is formed by mixing polyether-ether-ketone with 10 percent by mass of titanium oxide, the DC color mark plate is formed by mixing polyether-ether-ketone with 17 percent by mass of titanium oxide, the DD color mark plate is formed by mixing polyether-ether-ketone with 3 percent by mass of zirconium oxide, the DE color mark plate is formed by mixing polyether-ether-ketone with 11 percent by mass of zirconium oxide, the DF color mark plate is formed by mixing polyether-ether-ketone with 18 percent by mass of zirconium oxide, the DG color mark plate is formed by mixing polyether-ether-ketone with 3 percent by mass of aluminum oxide, the DH color mark plate is formed by mixing polyether-ether-ketone with 13 percent by mass of aluminum oxide, the DI color mark plate is formed by mixing polyether-ether-ketone and 18% of alumina by mass percent.
According to the types of the color-mixing powder, DA-DI is divided into three groups, DA, DB and DC are one group, and the white color degree of the material is gradually increased along with the increase of the content of the titanium oxide, namely the denture prosthesis is gradually changed from light yellow to white; DD. DE, DF is a series, with the increase of zirconia content, the material white color degree increases gradually, namely the false tooth prosthesis gradually changes from light yellow to white; DG. DH, DI is a series, with the increase of alumina content, the white color degree of the false tooth material increases gradually, namely the false tooth prosthesis is changed from light yellow to white gradually; wherein, when the content of the toning powder is the same, the color of the oral cavity restoration added with the titanium oxide is white than that of the oral cavity restoration added with the zirconium oxide, and the color of the oral cavity restoration added with the zirconium oxide is white than that of the oral cavity restoration added with the aluminum oxide.
The polyetheretherketone gingival color colorimetric plate comprises six color calibration plates from Gingiva-A to Gingiva-F, wherein the GA color calibration plate is formed by mixing polyetheretherketone and 0.3% of ferric oxide, the GB color calibration plate is formed by mixing polyetheretherketone and 0.7% of ferric oxide, the GC color calibration plate is formed by mixing polyetheretherketone and 1% of titanium oxide, the GD color calibration plate is formed by mixing polyetheretherketone, 13% of zirconium oxide and 3% of titanium oxide, the GE color calibration plate is formed by mixing polyetheretherketone, 0.7% of zirconium oxide and 13% of titanium oxide, and the GF color calibration plate is formed by mixing polyetheretherketone, 1% of zirconium oxide and 19% of titanium oxide.
According to the types of the added materials, GA-GF is divided into two groups, wherein the GA, the GB and the GC are one group and are formed by mixing polyether-ether-ketone and ferric oxide; with the increase of the content of the ferric oxide, the color of the material gradually turns red; GD. GE and GF are a group and are respectively formed by mixing polyether-ether-ketone, ferric oxide and titanium oxide; with the increase of the content of the ferric oxide, the color of the material gradually turns red; meanwhile, as the content of the titanium oxide increases, the color of the material gradually changes from light yellow to white.
In addition to the above embodiments, the present invention may have other embodiments; all technical solutions formed by adopting equivalent substitutions or equivalent transformations fall within the protection scope of the claims of the present invention.

Claims (4)

1. An integrated 3D printing method of a polyether-ether-ketone oral prosthesis with different colors is characterized by comprising the following steps: the method comprises the following steps:
s1: scanning the upper jaw and the lower jaw of a patient by using a digital oral scanner, obtaining digital three-dimensional model data of the upper jaw and the lower jaw, obtaining the occlusion relation between the upper dentition and the lower dentition, and simultaneously respectively recording the personalized tooth color and the gum color of the patient;
s2: importing the acquired three-dimensional data into digital denture design software, and carrying out personalized design on the dental prosthesis and adjusting the occlusion contact relation between the dental prosthesis and the jaw teeth on the basis of the three-dimensional data to obtain a three-dimensional data model of the dental prosthesis;
s3: separating the three-dimensional data model of the tooth and the gum part of the prosthesis according to the difference between the color of the tooth and the color of the gum, designing a connecting interface of the three-dimensional data model, obtaining the printing data of the tooth and the gum part, and then importing the printing data into 3D printing equipment;
s4: according to the color requirements of teeth and gum components of the dental prosthesis recorded clinically, the colors of the teeth and gum components of the dental prosthesis are determined respectively, 3D printing materials of different components are subjected to corresponding color matching respectively, the materials are conveyed to two printing heads of the integrated 3D printing equipment respectively, then the printing data led into the integrated 3D printing equipment are subjected to integrated printing, and a final dental prosthesis real object is prepared.
2. The method for integrated 3D printing of a polyetheretherketone dental restoration according to claim 1, wherein: when the 3D printing is carried out in the S4, the two printing heads can respectively and independently carry out the printing of the polyetheretherketone materials with different colors on different parts of the oral prosthesis, when the printing is carried out to the boundary area of each part, the two printing heads simultaneously carry out the printing, and when the printing in the boundary area is finished, the 3D printing processing of the whole oral prosthesis is finished.
3. The method of integrated 3D printing of a polyetheretherketone dental restoration according to claim 2, wherein: and the contact surfaces of all the parts of the polyether-ether-ketone dental prosthesis in the S3 are provided with micro-textures for improving the surface roughness.
4. The method of integrated 3D printing of a polyetheretherketone dental restoration according to claim 4, wherein: the micro-texture ornament comprises a sawtooth-shaped groove body and a sawtooth-shaped fixture block which are respectively arranged on the surfaces of all the parts of the dental prosthesis.
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