CN111592168A - Phenol ammonia recovery unit of long period operation - Google Patents
Phenol ammonia recovery unit of long period operation Download PDFInfo
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- CN111592168A CN111592168A CN202010621295.XA CN202010621295A CN111592168A CN 111592168 A CN111592168 A CN 111592168A CN 202010621295 A CN202010621295 A CN 202010621295A CN 111592168 A CN111592168 A CN 111592168A
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- preheater
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- ammonia
- phenol
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- 238000011084 recovery Methods 0.000 title claims abstract description 31
- XABJJJZIQNZSIM-UHFFFAOYSA-N azane;phenol Chemical compound [NH4+].[O-]C1=CC=CC=C1 XABJJJZIQNZSIM-UHFFFAOYSA-N 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 28
- 239000002253 acid Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 18
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 29
- 238000000605 extraction Methods 0.000 claims description 17
- 239000000428 dust Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 238000005189 flocculation Methods 0.000 claims description 2
- 230000016615 flocculation Effects 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 5
- 239000000571 coke Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000011552 falling film Substances 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/10—Separation of ammonia from ammonia liquors, e.g. gas liquors
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/72—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/74—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/048—Purification of waste water by evaporation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/26—Treatment of water, waste water, or sewage by extraction
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/40—Devices for separating or removing fatty or oily substances or similar floating material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
- C02F2101/345—Phenols
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/14—Maintenance of water treatment installations
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Water Treatments (AREA)
Abstract
The invention belongs to the technical field of phenol ammonia recovery, and discloses a phenol ammonia recovery device with long period operation, which comprises an acid water stripping tower and a raw material water tank, wherein one end of the raw material water tank is connected with a first cooler, one end of the first cooler is connected with a third preheater, one end of the third preheater is connected with a second preheater, one end of the second preheater is connected with a first preheater, one end of the first preheater is fixedly connected with the middle upper part of the acid water stripping tower, the middle part of the acid water stripping tower is fixedly connected with one side of the second preheater, the ammonia outlet end of the second preheater is connected with an ammonia recovery system, and the bottom of the ammonia recovery system is connected with a collection tank. The effects of reducing the running cost of the device and improving the economic benefit are achieved.
Description
Technical Field
The invention belongs to the technical field of phenol ammonia recovery, and particularly relates to a phenol ammonia recovery device capable of operating for a long period.
Background
The production of the semi-coke takes low-rank coal as a raw material, the low-rank coal has more volatile components, more organic matters such as tar and phenol oil can be produced in the production process, and finally the organic matters enter semi-coke wastewater, the phenol ammonia recovery process is relatively mature, and although the semi-coke wastewater can be used for treating the semi-coke wastewater, the semi-coke wastewater cannot run for a long period due to serious blockage of heat exchangers on an acid ammonia tower and a bottom extraction pipeline and serious corrosion of a gas phase part of a reboiler at the bottom of a solvent recovery tower, so that the running economy is greatly reduced.
In Chinese patent No. 200910192442.X, a method for treating coal gasification sewage containing high-concentration phenol and ammonia is disclosed, the patent introduces a method for removing acid gas and ammonia by single-tower alkali injection and pressure steam stripping, the sewage after ammonia removal is subjected to MIBK extraction and separation to obtain crude phenol, condensate containing partial water and a small amount of ammonia returns to a raw material tank after three-stage segregation in the process, the raw material tank is continuously fed to cause continuous oil enrichment of an acid ammonia tower until new balance is achieved, the oil content of produced materials in the tower is increased, heat exchangers on tower plates and produced pipelines and a crude phenol extraction tower are seriously blocked, the operation of a phenol and ammonia recovery device is seriously restricted, and secondary oil removal is not facilitated.
Disclosure of Invention
The invention aims to provide a phenol ammonia recovery device which operates for a long period so as to solve the problems of serious limitation on the operation of the phenol ammonia recovery device and inconvenience for secondary oil removal in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides a phenol ammonia recovery unit of long period operation, includes acid water stripping tower and raw materials water pitcher, the one end of raw materials water pitcher is connected with cooler I, the one end of cooler I is connected with preheater III, the one end of preheater III is connected with preheater II, the one end of preheater II is connected with preheater I, the one end of preheater I and the well upper portion fixed connection of acid water stripping tower, the middle part and two one side fixed connection of preheater of acid water stripping tower, the ammonia end of going out of preheater II is connected with ammonia recovery system, ammonia recovery system bottom is connected with the collection tank, the one end and the raw materials water pitcher fixed connection of collection tank, one side fixed connection of preheater II has the coarse phenol extraction tower, the preheater is installed to the coarse phenol extraction tower bottom, the coarse phenol product tower is installed to one side of preheater, coarse phenol product tower top is provided with top of the tower condenser and the backward flow jar, be provided with recovery water deoiling device on the pipeline that collection tank and raw water tank link to each other, acid water stripping tower lower part is provided with bypass deoiling device, be provided with the deoiling dirt device on the pipeline that acid water stripping tower bottom and preheater link to each other, coarse phenol product tower bottom is provided with the falling liquid film reboiler.
Preferably, the oil dust removing device adopts a settling type, a flocculation settling type or an absorption filtration type device.
Preferably, the bypass oil removal device and the recovered water oil removal device adopt a layered oil discharge or tank-in-tank mode.
Compared with the prior art, the invention has the beneficial effects that:
(1) the invention has compact structure, solves the problem of higher oil content of the feeding material of the acidic water stripper by the oil removing device of the reclaimed water, reduces the oil-dust content of the material extracted from the bottom of the acidic water stripper by the oil-dust removing device, can effectively reduce the oil enrichment degree in the system, can effectively reduce the corrosion of high-temperature corrosive steam by arranging the falling film reboiler at the bottom of the crude phenol product tower, realizes the long-period operation of equipment, can achieve the purpose of energy saving and efficiency improvement, greatly improves the resource utilization rate, can realize the reconstruction on similar devices, and achieves the effects of reducing the operation cost of the device and improving the economic benefit.
(2) The invention carries out oil removal by a rectification heating mode, has certain demulsification capacity, causes separation and aggregation of oil and dust, thereby causing blockage, and the state is more beneficial to secondary oil removal and improves the secondary oil removal effect.
Drawings
FIG. 1 is a schematic view of the present invention;
in the figure: 1. a first cooler; 2. an acid water stripper; 3. a first preheater; 4. a second preheater; 5. a third preheater; 6. an ammonia recovery system; 7. a collection tank; 8. a second cooler; 9. a crude phenol extraction column; 10. a preheater; 11. a crude phenol product column; 12. a tower top condenser; 13. a reflux tank; 14. a device for removing oil dust; 15. a bypass oil removal device; 16. a reclaimed water oil removing device; 17. a falling film reboiler.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The general phenol ammonia recovery flow path is as follows: one path of raw material water of a raw material water tank enters the top of the tower after being cooled by a cooler I1, one path of raw material water sequentially enters the middle upper part of the tower after passing through a preheater III 5, a preheater II 4 and a preheater I3, acid gas is produced at the top of the tower, crude ammonia extracted from the side line of the middle part of the tower enters an ammonia recovery system 6 through a preheater II 4 heat exchanger, ammonia extracted from the top of the ammonia recovery system 6, recovered water extracted from the bottom enters a collection tank 7, the recovered water in the collection tank 7 returns to the raw material water tank through the recovered water, materials at the bottom of an acid water stripper 2 enter the middle upper part of a crude phenol extraction tower 9 after being sequentially cooled by the preheater I3, the preheater III 5 and the cooler II 8, the materials at the top of the crude phenol extraction tower 9 are extracted into a water tower for recovering solvent, the extracted water at the bottom enters the middle upper part of a crude phenol product tower 11 after being preheated, the bottom material is extracted after being cooled by the preheater 10.
In the process, an oil dust removing device 14, a bypass oil removing device 15 and a recovered water oil removing device 16 are not arranged, in the normal production process, recovered water generated by side-sampling ammonia segregation is not subjected to oil removal and enters a raw material water tank, the raw material water tank is fed again, so that oil accumulation is caused, the content of oil dust extracted from the tower bottom is high, each heat exchanger and a tower tray of a crude phenol extraction tower 9 extracted from the tower bottom are blocked by the oil dust, an ammonia recovery system 6 has to be stopped and cleaned, and long-period operation of equipment cannot be realized; the reboiler of the crude phenol product tower is usually set as a thermosyphon reboiler, and the gas phase part of the reboiler is seriously corroded in the production process, so that the reboiler cannot be operated for a long period, and the maintenance cost is increased.
In order to solve the problems of blockage and corrosion, please refer to fig. 1, the present invention provides the following technical solutions:
this long period operation's phenol ammonia recovery unit, including cooler 1, acid water stripping tower 2, preheater 3, preheater two 4, preheater three 5, ammonia recovery system 6, holding vessel 7, cooler two 8, crude phenol extraction tower 9, preheater 10, crude phenol product tower 11, overhead condenser 12, reflux drum 13, remove oil dust device 14, bypass deoiling device 15, recovered water deoiling device 16, falling liquid film reboiler 17, wherein remove oil dust device 14, bypass deoiling device 15, recovered water deoiling device 16 is newly-increased equipment, falling liquid film reboiler 17 is equipment optimization.
6 top extraction ammonia of ammonia recovery system, bottom extraction recovery water gets into collecting tank 7, the recovery water in collecting tank 7 returns the raw materials water pitcher after the deoiling of recovery water deoiling device 16, the problem of reducing the acidic water stripper 2 feeding oil content on the high side has been realized, the ejection of compact of acidic water stripper 2 bottom is provided with deoiling dirt device 14, an oil dirt content for reducing bottom extraction material, thereby it is provided with bypass deoiling device 15 and adopts each heat exchanger and crude phenol extraction tower tray jam to delay the lower part, 2 lower parts of acidic water stripper are provided with bypass deoiling device 15, a preliminary oil extraction to the bottom material, with load and the scale that effectively reduces deoiling dirt device 14.
The falling film reboiler 17 arranged at the bottom of the crude phenol product tower 11 can effectively reduce the corrosion of high-temperature corrosive steam and realize the purpose of long-period operation of equipment.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (3)
1. The utility model provides a phenol ammonia recovery unit of long period operation which characterized in that: comprises an acid water stripping tower (2) and a raw material water tank, wherein one end of the raw material water tank is connected with a cooler I (1), one end of the cooler I (1) is connected with a preheater III (5), one end of the preheater III (5) is connected with a preheater II (4), one end of the preheater II (4) is connected with a preheater I (3), one end of the preheater I (3) is fixedly connected with the middle upper part of the acid water stripping tower (2), the middle part of the acid water stripping tower (2) is fixedly connected with one side of the preheater II (4), the ammonia outlet end of the preheater II (4) is connected with an ammonia recovery system (6), the bottom of the ammonia recovery system (6) is connected with a collecting tank (7), one end of the collecting tank (7) is fixedly connected with the raw material water tank, one side of the preheater II (4) is fixedly connected with a crude phenol extraction tower (9), preheater (10) is installed to crude phenol extraction tower (9) bottom, crude phenol product tower (11) is installed to one side of preheater (10), crude phenol product tower (11) top is provided with overhead condenser (12) and reflux drum (13), be provided with on the pipeline that collection tank (7) and raw water tank link to each other and retrieve water deoiling device (16), acid water stripper (2) lower part is provided with bypass deoiling device (15), be provided with on the pipeline that acid water stripper (2) bottom and preheater (3) link to each other and remove oil dust device (14), crude phenol product tower (11) bottom is provided with falling liquid film reboiler (17).
2. The apparatus for recovering phenol and ammonia according to claim 1, wherein: the oil dust removing device (14) adopts a settling type, a flocculation settling type or an absorption filtration type device.
3. The apparatus for recovering phenol and ammonia according to claim 1, wherein: the bypass oil removing device (15) and the recovered water oil removing device (16) adopt a layered oil discharging or tank-in-tank mode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010621295.XA CN111592168A (en) | 2020-06-30 | 2020-06-30 | Phenol ammonia recovery unit of long period operation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010621295.XA CN111592168A (en) | 2020-06-30 | 2020-06-30 | Phenol ammonia recovery unit of long period operation |
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| CN111592168A true CN111592168A (en) | 2020-08-28 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102010292A (en) * | 2010-10-18 | 2011-04-13 | 青岛科技大学 | Method for producing high-purity optical isoamylol through decompression and rectification and technical process thereof |
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| CN207632635U (en) * | 2017-11-28 | 2018-07-20 | 北京中科康仑环境科技研究院有限公司 | A kind of pretreatment system for low temperature distillation waste water in coal |
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-
2020
- 2020-06-30 CN CN202010621295.XA patent/CN111592168A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102010292A (en) * | 2010-10-18 | 2011-04-13 | 青岛科技大学 | Method for producing high-purity optical isoamylol through decompression and rectification and technical process thereof |
| CN102259943A (en) * | 2011-07-21 | 2011-11-30 | 天津市昊永化工科技有限公司 | Energy-saving method for recycling wastewater containing phenol and ammonia |
| CN102674609A (en) * | 2012-05-11 | 2012-09-19 | 华南理工大学 | Separation treatment method for waste water in coal tar machining process |
| CN102863112A (en) * | 2012-10-19 | 2013-01-09 | 天津市昊永化工科技有限公司 | Phenol and ammonia wastewater recycling treatment method by using single tower for performing de-acidification and de-amination simultaneously |
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| CN212387913U (en) * | 2020-06-30 | 2021-01-22 | 查都（上海）科技有限公司 | Phenol ammonia recovery unit of long period operation |
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