CN111556741A - Composition for cleaning keratin materials - Google Patents
Composition for cleaning keratin materials Download PDFInfo
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- CN111556741A CN111556741A CN201780097970.XA CN201780097970A CN111556741A CN 111556741 A CN111556741 A CN 111556741A CN 201780097970 A CN201780097970 A CN 201780097970A CN 111556741 A CN111556741 A CN 111556741A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
Abstract
The present invention relates to a composition for cleansing and/or exfoliating keratin materials, comprising, in an aqueous phase: a) at least one C2‑C6A polyol; b) at least one glycinate surfactant; and c) at least 5% by weight, relative to the total amount of the composition, of at least one water-soluble inorganic salt. The composition provides a frosty feel to the keratin material while providing excellent lathering properties. Furthermore, the composition is mild and gentle to keratin materials, especially the skin.
Description
The present invention relates to cleansing and/or exfoliating compositions useful for personal skin care.
The skin is a protective barrier for the human body. It protects the interior of the body from physical damage (e.g., wounds) and biological damage (e.g., bacteria, viruses, or fungi). Human skin comprises dermis and epidermis. The epidermis is the uppermost layer of the skin, and its surface layer is called stratum corneum.
The stratum corneum or horny layer (horny layer) generally consists of 10 to 30 layers of dead cells. These cells are continuously replaced by new cells below. It is estimated that about 1 month is required for the stratum corneum to be completely replaced with new cells in adult human skin. The replacement time increased with age until approximately 120-150 days. The longer it takes to replace dead cells, the more layers of dead cells accumulate.
It is therefore desirable to remove an excessive layer of dead skin cells from the skin surface to provide a shiny skin with a youthful appearance. The process of removing dead skin cells from the surface of the skin is called exfoliation.
On the other hand, cleansing the skin is an essential step for caring for keratin materials, in particular facial skin. It must be as efficient as possible, since greasy residues, such as dust, excess sebum and residues of cosmetic and make-up products used daily, can lead to an unpleasant greasy appearance. Several types of skin cleansing products are known, such as flushable anhydrous cleansing oils and gels, foaming creams, lotions and gels, and non-foaming compositions.
Currently, human skin is cleaned and/or exfoliated in many different ways, such as cleaning products that are mechanically rubbed with or without the use of any kind of hard particles. These particles are also known as sanding beads. Classic cleansing or exfoliating compositions currently on the market can be classified as cleansing compositions with or without abrasive beads. The addition of abrasive beads is known to provide stronger and better cleaning of the skin, particularly pore cleaning. These beads may be hydrocarbon wax beads, particles such as silica, and Polyethylene (PE) beads.
However, each of these beads has some associated problems. In fact:
the hydrocarbon wax beads are relatively large in size, in particular 300 to 2000 μm, and tend to be soft in cleansing or exfoliating formulations, which is undesirable;
particles such as silica tend to be too small in size (i.e. nanoparticles) during production, which causes dusting problems; and
PE beads break during application, which is not suitable for cleaning purposes.
In addition, known scrub beads tend to be rough after application to the skin. This is even worse for consumers of sensitive skin types.
In other cases, sodium salts are used as abrasive beads in cleaning and exfoliating compositions. However, due to the high amount of salt present, it is inevitable to use surfactants such as SLES (sodium lauryl sulfate) to maintain the foaming properties of the composition. Surfactants of this type are known for their strong cleaning power and for their irritancy (harshness) to the skin, in particular to sensitive skin.
Therefore, there is a need to formulate compositions for the care of keratin materials that have excellent cleansing and/or exfoliating properties, while maintaining a mild and light feel after application.
There remains a need for new compositions having the above properties and having excellent foaming properties.
Furthermore, there is a need for cleansing and/or exfoliating compositions having the above properties while being stable over time.
Applicants have now found that by combining specific surfactants with high amounts of salt, compositions can be formulated having the desired properties as described above.
The present invention therefore relates to a composition for caring for keratin materials (also referred to as "composition of the invention") comprising, in an aqueous phase:
a) at least one C2-C6A polyol;
b) at least one glycinate surfactant; and
c) at least 5% by weight of at least one water-soluble inorganic salt, relative to the total amount of the composition.
The composition of the present invention can provide gentle massaging and cleansing of the skin without any harsh feeling.
The compositions of the present invention also provide good lathering during application.
It can be used daily as a facial or body cleanser and/or an exfoliating composition. In addition, the compositions of the present invention are stable over time. By stable is meant that the composition does not undergo any significant change in its structure or properties for at least one month, especially for at least two months, after its manufacture.
According to one embodiment, the present invention provides a composition for cleansing and/or exfoliating keratin materials comprising ingredients of natural origin. Preferably, all the ingredients of the composition of the invention are of natural origin.
The compositions of the present invention are rinse-off products. Thus, such compositions are applied to the skin (i.e., the face and/or body) and then rinsed.
Other objects and features, aspects and advantages of the present invention will become more apparent upon reading the following description and examples.
In the following and unless otherwise indicated, the limits of the numerical ranges are included within this range, in particular in the expressions "between …" and ". multidot..
Furthermore, the expression "at least one" as used in the present specification is equivalent to the expression "one or more".
Throughout this application, the term "comprising" is to be interpreted as covering all specifically mentioned elements as well as optional, additional, unspecified elements. As used herein, the use of the term "comprising" also discloses embodiments in which no element other than the specifically mentioned element is present (i.e., "consisting of …").
Thus, the composition of the invention comprises, in the aqueous phase:
a) at least one C2-C6A polyol;
b) at least one glycinate surfactant; and
c) at least 5% by weight of at least one water-soluble inorganic salt, relative to the total amount of the composition.
2 6One or more C-C polyols
The polyols according to the invention may preferably be selected from linear or branched, saturated or unsaturated C's having at least two hydroxyl groups2-C6A polyol, a dialkylene polyol having at least two hydroxyl groups, or a mixture thereof.
As polyols which may be used in the composition of the present invention, mention may be made of glycerol, propylene glycol, butylene glycol, sorbitol, hexylene glycol or mixtures thereof.
The polyols of the present invention are preferably selected from linear C's comprising at least two hydroxyl groups2-C4Polyol, C comprising at least two hydroxyl groups2-C4A dialkylene polyol or a mixture thereof.
The polyol of the present invention is preferably glycerol.
In particular, the composition of the invention comprises from 10% to 70% by weight, more preferably from 20% to 60% by weight of C, relative to the total weight of the composition2-C6A polyol.
One or more glycinate surfactants
The compositions of the present invention comprise at least one glycinate surfactant.
In one embodiment, the glycinate surfactant is derived from a carboxylic acid salt of glycine, wherein the amine group located on the α -carbon or β -carbon of the glycinate is replaced by a C8To C22Acylation of the fatty acid derivative.
These carboxylic acid salts of glycine may be formed by conventional means, such as by neutralizing glycine with a base.
The amine group located on the alpha-carbon or beta-carbon of the neutralized glycine is acylated with a fatty acid halide (acid halide) in the presence of a base by the well-known Schotten-Baumann reaction to produce an amide, thereby forming the desired surfactant reaction product, a glycinate salt surfactant.
Suitable acid halides for acylation of the amino acid carboxylate include acid chloride, bromide, fluoride, and iodide.
The acid halide may be obtained by reacting a saturated or unsaturated, linear or branched C8To C22Fatty acids are prepared by reaction with thionyl halides (bromine, chlorine, fluorine and iodine). Representative acid halides include, but are not limited to, acid chlorides selected from the group consisting of decanoyl chloride, dodecanoyl chloride (lauroyl chloride), cocoyl chloride (coconut oil derived fatty acid chloride), tetradecanoyl chloride (myristoyl chloride), hexadecanoyl chloride (palmitoyl chloride), octadecanoyl chloride (stearoyl chloride), 9-octadecenoyl chloride (oleanoyl chloride), eicosanoyl chloride (arachidoyl chloride), docosanoyl chloride (behenoyl chloride), and any mixtures thereof.
Other acid halides include bromides, fluorides, and iodides of the above fatty acids. Methods for preparing acid halides and alternative methods for acylating amino acids are set forth in U.S. patent application publication 2008/0200704, published on 21/8/2008, which is incorporated herein by reference.
In one embodiment, the glycinate surfactant is represented by formula (I):
Wherein:
z represents a saturated or unsaturated, linear or branched hydrocarbon radical having from 8 to 22 carbon atoms,
x and Y are hydrogen radicals,
n is a number of 0, and n is,
m is a salt-forming cation, such as sodium, potassium, ammonium, or triethanolamine, where COO is a counter anion.
Examples of glycinate surfactants are palmitoyl glycinate, sodium lauroyl glycinate, sodium cocoyl glycinate, sodium myristoyl glycinate, potassium lauroyl glycinate, potassium cocoyl glycinate and mixtures thereof.
In formula (I) preferably:
z represents a saturated straight chain C8To C22An alkyl group, a carboxyl group,
x and Y are hydrogen radicals,
n is a number of 0, and n is,
m is a salt-forming cation, such as sodium, potassium, ammonium, or triethanolamine, where COO is a counter anion.
Mention may be made of commercially available amino acid surfactants, for example Amilite from Ajinomoto®Sodium N-cocoyl glycinate sold under the name GCS-12K, potassium cocoyl glycinate sold under the name Eversoft YCK-100K by Sino Lion corporation or Amilite sold under the name Ajinomoto corporation®GCK-12K is a product sold under the name GCK-12K and mixtures thereof.
According to a preferred embodiment, the glycinate salt surfactant is sodium N-cocoyl glycinate.
According to the invention, the glycinate surfactant is present in an amount ranging from 1% to 30% by weight, preferably from 2% to 20% by weight and more preferably from 3% to 15% by weight relative to the total weight of the composition.
One or more water-soluble inorganic salts
According to one embodiment, the composition of the invention comprises at least 5% by weight of at least one water-soluble inorganic salt, relative to the total weight of the composition.
By "water soluble" is meant that the inorganic salt has a solubility in water of at least 100 g/L at room temperature, preferably at least 200 g/L at room temperature.
According to one embodiment, the inorganic salts suitable for use in the compositions of the present invention have a structure selected from Na+、K+、Li+、Ca2+、Mg2+、Cu2+Or Zn2+And a cation selected from the group consisting of halide, HCO3 -Or HPO4 -The anion of (4).
Preferably, a halogen ion is used.
The cation is preferably monovalent or divalent. Preferred cations are selected from Na, Ca, Li, K, Mg, Cu and Zn.
Preferred salts are selected from sodium chloride, potassium chloride, lithium chloride, ammonium chloride or mixtures thereof.
These salts are known for their good solubility in water and are therefore very often used in cosmetic formulations to adjust the pH of the formulation, to thicken micellar systems or to help stabilize emulsions.
Surprisingly, the present inventors have found that the combination of ingredients in the composition of the present invention enables the inorganic water soluble salt to be present in the composition in particulate form, rather than being dissolved, thus providing a frosting function to the skin during application. Thus, the compositions of the present invention provide excellent and mild exfoliating effects to the skin.
The inorganic salt may be present in the composition in a content of more than 5% by weight, preferably from 6% to 40% by weight, preferably from 7% to 35% by weight, more preferably from 10% to 30% by weight, relative to the total weight of the composition.
It is known to the person skilled in the art that salts, in particular water-soluble inorganic salts, have an influence on the foaming of compositions present on the market. Which in particular hampers foam generation or defoams in the cosmetic composition. To overcome this problem, conventional techniques use surfactants such as SLES in combination with low amounts of salts.
However, this type of composition does not provide an exfoliating effect because the salt is not present in the composition in particulate form. Furthermore, it does not provide a mild and gentle cleansing of the skin.
Surprisingly, the present invention makes it possible to formulate compositions for the cleansing and/or exfoliation of keratin materials comprising a high amount of salt in combination with glycinate surfactants and providing excellent lathering properties.
According to a preferred embodiment, said at least one C2-C6The weight ratio of the polyol to the at least one water-soluble inorganic salt is greater than or equal to 1, preferably from 1 to 10, more preferably from 1.5 to 5. According to this preferred embodiment, the at least one C is due to the fact that the salt is in particle form and provides the skin with the desired abrasive feel2-C6The ratio of the polyol and the at least one water-soluble inorganic salt may ensure excellent cleansing and exfoliating effects.
Aqueous phase
The compositions of the present invention comprise at least one aqueous phase.
According to a preferred embodiment, the composition of the invention is an aqueous solution.
According to one embodiment, the aqueous phase comprises water.
According to one embodiment, the amount of water in the composition according to the invention is from 1% to 30% by weight, preferably from 5% to 20% by weight, relative to the total weight of the composition.
According to a preferred embodiment, the present invention relates to a composition for cleansing and/or exfoliating keratin materials, in particular the skin, comprising, in an aqueous phase, by weight relative to the total weight of the composition:
a) 20 to 60% by weight of glycerol;
b) 3 to 15% by weight of sodium N-cocoyl glycinate; and
c) 10% to 30% of at least one halide salt.
One or more additional ingredients
Optionally, the present invention also relates to a composition ("cosmetic composition") for cleansing and/or exfoliating keratin materials, in particular the skin, comprising the composition of the invention as described above and at least one additional ingredient.
According to one embodiment, additional ingredients useful in the present invention include additional surfactants, such as anionic surfactants, nonionic surfactants, amphoteric surfactants, zwitterionic surfactants, thickeners, or mixtures thereof.
Preferably, the additional surfactant is selected from the group consisting of nonionic surfactants, amphoteric surfactants, zwitterionic surfactants, and mixtures thereof.
Nonionic surfactants that may be mentioned include the oxyalkylenated (more particularly polyoxyethylenated) esters of fatty acids and glycerol; alkylene oxide esters of fatty acids and sorbitan; oxyalkylenated (oxyethylenated and/or oxypropylenated) esters of fatty acids, such as, for example, the PEG-100 stearate/glyceryl stearate mixture sold under the name Arlacel 165 by ICI; oxyalkylenated (oxyethylenated and/or oxypropylenated) ethers of fatty alcohols; esters of sugars, such as sucrose stearate; ethanolamine and its derivatives, such as cocamide MEA; or ethers of fatty alcohols and sugars, in particular Alkylpolyglucosides (APG), such as decyl glucoside and lauryl glucoside, for example sold by the company Henkel under the names Plantaren 2000 and Plantaren 1200, respectively, cetearyl glucoside, optionally as a mixture with cetearyl alcohol, for example Montanov 68 by the company SEPPIC, Tegocare CG90 by the company Goldschmidt and Emulgade KE3302 by the company Henkel, and arachidol glucoside, for example in the form of a mixture of arachidol, behenyl alcohol and arachidol glucoside, montarov 202 by the company SEPPIC.
The amphoteric or zwitterionic surfactants which can be used according to the invention can be in particular derivatives of optionally quaternized aliphatic secondary or tertiary amines in which the aliphatic radical is a straight-chain or branched chain comprising from 8 to 22 carbon atoms, the amine derivatives containing at least one anionic group, for example a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. Mention may in particular be made of (C)8-C20) Alkyl betaines, sulfobetaines, (C)8-C20) Alkylamido (C)3-C8) Alkyl betaines and (C)8-C20) Alkylamido (C)6-C8) An alkyl sulfobetaine.
Among the useful optionally quaternized aliphatic secondary or tertiary amine derivatives as defined above, mention may also be made of the compounds having the following structures (a1) and (a2), respectively:
RaCONHCH2CH2N+(Rb)(Rc)(CH2COO-) (A1)
wherein:
·Rarepresents a derivative derived from an acid R preferably present in hydrolysed coconut oilaC of COOH10-C30Alkyl or alkenyl radicalsOr heptyl, nonyl or undecyl;
·Rbrepresents β -hydroxyethyl group, and
·Rcrepresents a carboxymethyl group;
and
Ra'CONHCH2CH2N(B)(B') (A2)
wherein:
b represents a group-CH2CH2OX'，
B' represents a radical- (CH)2)zY', wherein z = 1 or 2,
x' represents a group-CH2COOH、CH2COOZ'、-CH2CH2COOH、-CH2CH2COOZ' or a hydrogen atom,
y 'represents a group-COOH, -COOZ', a group-CH2CHOHSO3H or a group-CH2CHOHSO3Z'，
Z' represents an ion from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion from an organic amine,
·Ra'represents the acid R preferably present in coconut oil or hydrolysed linseed oila'C of COON10-C30Alkyl or alkenyl, alkyl, especially C17The radicals and their isomeric (iso) forms, or unsaturated C17A group.
These compounds are classified in the CTFA dictionary, 5 th edition, 1993 under the names disodium cocoyl amphodiacetate, disodium lauroamphodiacetate, disodium decanoamphodiacetate, disodium octanoamphodiacetate, disodium cocoyl amphodipropionate, disodium lauroamphodipropionate, disodium decanoamphodipropionate, disodium octanoamphodipropionate, disodium lauroamphodipropionate and cocoamphodipropionate. For example, mention may be made of the company Rhodia under the name Miranol®Cocoamphodiacetate sold by C2M Concentrate.
Among the amphoteric or zwitterionic surfactants mentioned above, it is preferred to use (C)8-C20) Alkyl betaines, e.g. cocoyl-sweetBetaine (or cocobetaine), and (C)8-C20) Alkylamido (C)3-C8) Alkyl betaines, such as cocamidopropyl betaine and mixtures thereof. More preferably, the additional surfactant is selected from the group consisting of oxyalkylenated (oxyethylenated and/or oxypropylenated) esters of fatty acids, (C)8-C20) Alkyl betaines or mixtures thereof.
According to a preferred embodiment, the additional surfactant, when present, is selected from PEG-100 stearate/glyceryl stearate, cocoyl betaine or mixtures thereof.
According to one embodiment, the amount of the one or more additional surfactants in the composition according to the invention, when present, is from 0.01% to 10% by weight, preferably from 0.5% to 5% by weight, relative to the total weight of the composition.
Optionally, the composition of the present invention may further comprise at least one thickener.
The thickener can advantageously be selected from xanthan gum, guar gum, hydroxypropyl guar gum, scleroglucan, methylcellulose, ethylcellulose (available as AQUACOTE)®Obtained), hydroxyethylcellulose (NATROSOL)®) Carboxymethyl cellulose, hydroxypropyl methyl cellulose, microcrystalline cellulose, hydroxybutyl methyl cellulose, and hydroxypropyl cellulose (which can be used as KLUCEL)®Obtained from natural sources of natural®Plus 330), N-vinylpyrrolidone (available as POVIDONE)®Obtained as a copolymer of acrylate/cetyl polyoxyethylene (20) ether itaconate (available as a STRUCTURE)®3001 obtained from starch, hydroxypropyl starch phosphate (available as starch)®XL), polyethoxylated urethanes or polycarboxypolyesters (e.g., PEG-150/Decyl/SMDI copolymers (e.g., ACULYN)®44) PEG-150/Stearyl/SMDI copolymer (as ACULYN)®46), trihydroxystearin (which can be used as THIXCIN)®Obtained as ACULYN), acrylate copolymers (e.g. as ACULYN)®33) or hydrophobically modified acrylate copolymers (b)For example, acrylate/stearyl polyoxyethylene (20) ether-20 methacrylate copolymer (available as ACULYN)®22), acrylate/stearyl polyoxyethylene (20) ether-20 methacrylate crosspolymer (available as ACULYN)®88), acrylate/vinyl neodecanoate crosspolymer (available as ACULYN)®38), acrylate/polyoxyethylene (25) behenyl alcohol ether methacrylate copolymer (available as ACULYN)®28 obtained) and acrylate/acrylic acid C10-30Alkyl ester crosslinked polymers (available as Carbopol)®ETD 2020).
When present, the thickener is present in an amount of 0.01 to 10 wt%, preferably 0.1 to 8 wt%, more preferably 1 to 5 wt%, relative to the total weight of the composition.
The cosmetic composition of the present invention may further comprise at least one additive. The type and amount of additives present in the compositions according to the invention can be adjusted by the skilled person by means of routine procedures so that the desired cosmetic and stabilizing properties of these compositions are not affected by the additives.
The composition according to the invention can be applied by any means capable of uniform distribution, in particular using a finger or cotton ball, stick, brush, gauze or spatula, and can be removed by rinsing with water.
The compositions of the present invention are useful for improving the general condition of the epidermis, in particular the skin.
The invention also relates to a method for cleansing and/or exfoliating keratin materials, in particular the skin, comprising applying the composition according to the invention to the keratin materials, in particular the skin.
The invention also relates to the use of the composition according to the invention for cleansing and/or exfoliating keratin materials, in particular the skin.
The following examples serve to illustrate the invention, but are not limiting in nature.
Examples
Example 1Preparation of examples
The following formulations were prepared.
Comparative formulations a1 and a2 contained sodium lauroyl sarcosinate and sodium laureth sulfate, respectively, in place of the glycinate surfactants as set forth in the present invention.
The above-listed formulations were prepared according to known preparation methods in the cosmetic field.
Example 2Evaluation of the Properties of the above-listed formulations
The properties of the above-listed formulations of the present invention and comparative formulations were evaluated by 30 consumers (15 men and 15 women) aged 20-40 years by using the above-mentioned formulations as cleansing and exfoliating products.
The procedure was as follows:
0.5 g of the above-mentioned formulation was placed in the palm of a hand, respectively;
mix the formulation with 1 gram of water with a pipette;
rub between palms for 15 seconds (4 cycles per second);
gathering foam in the palm to prevent dripping;
evaluating the volume and density of the resulting foam;
evaluating the exfoliating effect of the formulation on the palm;
the foam was rinsed off with water and the skin feel after application was evaluated (mildness).
Finally, 30 consumers scored lather, exfoliate, and mildness.
A score of 5: at least 80% of consumers deem to be good and expected;
consumers scoring 4: 60% to 80% (not included) believe to be working well and are expected;
a score of 3: at least 50% of the consumers believe the effect is good and in line with expectations;
score 2 > 60% of consumers considered poor and unacceptable;
a score of 1: more than 80% of consumers deems the effect poor and unacceptable.
Stability was measured after 1 month storage at 4 ℃, 25 ℃ (room temperature or RT), 40 ℃ or 45 ℃.
Stability tests were also performed under the sun test and over the course of several cycles.
The stability under the sun test was carried out by placing the cosmetic composition of the invention in Suntest CPS + from Atlas for 24 hours.
The cycling stability test was performed for 10 days at cycles of-20 ℃ to 20 ℃ every 24 hours.
The evaluation results were as follows:
| formulations | Stability of | Foaming | Exfoliating agents | Skin feel |
| A | 5 | 4 | 4 | 3 |
| B | 5 | 5 | 5 | 5 |
| A1 | 1, immediate phase separation | N/A | N/A | N/A |
| A2 | 3, becoming thinner with time | 2 | 4 | 2 |
The results show that both inventive formulations a and B are stable over time, have improved lathering and skin feel (mildness) effects compared to comparative formulation a2, and in addition, they provide excellent exfoliation effects to the skin.
In particular, the formulation B of the invention has excellent properties in each of the above tests and is therefore a preferred embodiment of the invention.
On the other hand, comparative formulation a1 was unstable: phase separation was seen immediately after formulation.
Claims (14)
1. A composition for cleansing and/or exfoliating keratin materials comprising, in an aqueous phase:
a) at least one C2-C6A polyol;
b) at least one glycinate surfactant; and
c) at least 5% by weight of at least one water-soluble inorganic salt, relative to the total amount of the composition.
2. The composition according to claim 1, wherein said C is2-C6The polyol is selected from linear or branched, saturated or unsaturated C having at least two hydroxyl groups2-C6A polyol, a dialkylene polyol having at least two hydroxyl groups, or a mixture thereof; preferably selected from linear C comprising at least two hydroxyl groups2-C4Polyol, C comprising at least two hydroxyl groups2-C4A dialkylene polyol or mixtures thereof; more preferably, the polyol is glycerol.
3. The composition according to claim 1 or 2, wherein said C is2-C6The polyol is present in an amount of from 10 to 70 wt%, more preferably from 20 to 60 wt% polyol, relative to the total weight of the composition.
4. A composition according to any one of the preceding claims 1 to 3, wherein the glycinate surfactant is a compound of formula (I),
Wherein:
z represents a saturated or unsaturated, linear or branched hydrocarbon radical having from 8 to 22 carbon atoms,
x and Y are hydrogen radicals,
n is a number of 0, and n is,
m is a salt-forming cation, such as sodium, potassium, ammonium, or triethanolamine, wherein COO is a counter anion;
in formula (I) preferably:
z represents a saturated straight chain C8To C22An alkyl group, a carboxyl group,
n is a number of 0, and n is,
m, X and Y are as defined above.
5. A composition according to any one of the preceding claims 1 to 4, wherein the glycinate surfactant is present in an amount ranging from 1% to 30% by weight, preferably from 2% to 20% by weight, more preferably from 3% to 15% by weight, relative to the total weight of the composition.
6. The composition according to any one of the preceding claims 1 to 5, wherein the water-soluble inorganic salt has a structure selected from Na+、K+、Li+、Ca2+、Mg2+、Cu2+Or Zn2+And a cation selected from the group consisting of halogen ions、HCO3 -Or HPO4 -An anion of (a); the salt is preferably selected from halides; more preferably, the salt is selected from sodium chloride, potassium chloride, lithium chloride, ammonium chloride or mixtures thereof.
7. The composition according to any one of the preceding claims 1 to 6, wherein the water-soluble inorganic salt is present in an amount ranging from 6% to 40% by weight, preferably from 7% to 35% by weight, more preferably from 10% to 30% by weight, relative to the total weight of the composition.
8. The composition according to any one of the preceding claims 1 to 7, wherein the at least one C2-C6The weight ratio of polyol to the at least one water-soluble inorganic salt is greater than or equal to 1, preferably from 1 to 10, more preferably from 1.5 to 5.
9. The composition according to any one of the preceding claims 1 to 8, wherein the aqueous phase comprises water in an amount of from 1% to 30% by weight, preferably from 5% to 20% by weight, relative to the total weight of the composition.
10. Composition for cleansing and/or exfoliating keratin materials, in particular the skin, comprising, in an aqueous phase, by weight relative to the total weight of the composition:
a) 20 to 60% by weight of glycerol;
b) 3 to 15% by weight of sodium N-cocoyl glycinate; and
c) 10% to 30% of at least one halide salt.
11. The composition of any of the preceding claims 1 to 10, further comprising at least one additional surfactant selected from the group consisting of nonionic surfactants, amphoteric surfactants, zwitterionic surfactants, and mixtures thereof; preferably selected from the group consisting of the oxyalkylenated (oxyethylenated and/or oxypropylenated) esters of fatty acids, (C)8-C20) Alkyl betaines or mixtures thereof.
12. The composition of any of the preceding claims 1 to 11, further comprising at least one thickener.
13. A method for cleansing and/or exfoliating keratin materials, in particular the skin, comprising applying a composition according to any of claims 1 to 12 to keratin materials, in particular the skin.
14. Use of a composition according to any one of claims 1 to 12 for cleansing and/or exfoliating keratin materials, in particular the skin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2017/118952 WO2019127089A1 (en) | 2017-12-27 | 2017-12-27 | Composition for cleansing keratin materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111556741A true CN111556741A (en) | 2020-08-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780097970.XA Pending CN111556741A (en) | 2017-12-27 | 2017-12-27 | Composition for cleaning keratin materials |
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| Country | Link |
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| CN (1) | CN111556741A (en) |
| WO (1) | WO2019127089A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2024504235A (en) * | 2020-12-02 | 2024-01-31 | ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ | A personal care composition comprising a glycinate surfactant, a polyol, and a nonionic surfactant comprising an alkyl glucoside. |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104586703A (en) * | 2015-02-05 | 2015-05-06 | 梁丁 | Bath salt |
| US20160296442A1 (en) * | 2013-11-13 | 2016-10-13 | L'oreal | Foaming composition comprising at least one glycinate type surfactant |
| CN106535869A (en) * | 2014-05-30 | 2017-03-22 | 欧莱雅 | Foaming cleanser |
| CN107106431A (en) * | 2014-12-22 | 2017-08-29 | 欧莱雅 | Rapidly dissolving film for cleaning keratin material |
| US20170340540A1 (en) * | 2014-12-12 | 2017-11-30 | L'oreal | Cosmetic composition containing linear olefin sulfonates, non-oxyalkylated anionic surfactants, and non-ionic and/or amphoteric surfactants, and cosmetic treatment method |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060183662A1 (en) * | 2005-02-16 | 2006-08-17 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Liquid cleansing composition with unique sensory properties |
| FR2939658A1 (en) * | 2008-12-15 | 2010-06-18 | Oreal | Foaming composition, useful for cleaning or removing makeup of keratin material e.g. skin, comprises foaming surfactant system including e.g. anionic surfactant, and guar gum modified with hydroxyalkyl groups, in aqueous medium |
| CN106619214A (en) * | 2016-09-29 | 2017-05-10 | 益盐堂（应城）健康盐制盐有限公司 | Scrub cream and application thereof |
| CN107280990A (en) * | 2017-05-03 | 2017-10-24 | 上海宏度精细化工有限公司 | A kind of frosted exfoliating cosmetics and preparation method |
-
2017
- 2017-12-27 CN CN201780097970.XA patent/CN111556741A/en active Pending
- 2017-12-27 WO PCT/CN2017/118952 patent/WO2019127089A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160296442A1 (en) * | 2013-11-13 | 2016-10-13 | L'oreal | Foaming composition comprising at least one glycinate type surfactant |
| CN106535869A (en) * | 2014-05-30 | 2017-03-22 | 欧莱雅 | Foaming cleanser |
| US20170340540A1 (en) * | 2014-12-12 | 2017-11-30 | L'oreal | Cosmetic composition containing linear olefin sulfonates, non-oxyalkylated anionic surfactants, and non-ionic and/or amphoteric surfactants, and cosmetic treatment method |
| CN107106431A (en) * | 2014-12-22 | 2017-08-29 | 欧莱雅 | Rapidly dissolving film for cleaning keratin material |
| CN104586703A (en) * | 2015-02-05 | 2015-05-06 | 梁丁 | Bath salt |
Non-Patent Citations (1)
| Title |
|---|
| 科颜氏: "科颜氏金盏花洁面啫喱", 《进口化妆品备案查询网》 * |
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| Publication number | Publication date |
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| WO2019127089A1 (en) | 2019-07-04 |
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