CN111533923B - Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof - Google Patents

Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof Download PDF

Info

Publication number
CN111533923B
CN111533923B CN202010256022.XA CN202010256022A CN111533923B CN 111533923 B CN111533923 B CN 111533923B CN 202010256022 A CN202010256022 A CN 202010256022A CN 111533923 B CN111533923 B CN 111533923B
Authority
CN
China
Prior art keywords
graphene
latex
hard material
resistance
composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202010256022.XA
Other languages
Chinese (zh)
Other versions
CN111533923A (en
Inventor
沙嫣
沙晓林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Johnson & Johnson New Material Technology Co ltd
Original Assignee
Nantong Johnson & Johnson New Material Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Johnson & Johnson New Material Technology Co ltd filed Critical Nantong Johnson & Johnson New Material Technology Co ltd
Priority to CN202010256022.XA priority Critical patent/CN111533923B/en
Publication of CN111533923A publication Critical patent/CN111533923A/en
Application granted granted Critical
Publication of CN111533923B publication Critical patent/CN111533923B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D06N3/106—Elastomers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00—Characterised by the use of natural rubber
    • C08J2307/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/02—Copolymers with acrylonitrile
    • C08J2309/04—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2244—Oxides; Hydroxides of metals of zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/06—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1642—Hardnes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing
    • D06N2211/103—Gloves

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Gloves (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to high-wear-resistance and high-cutting-resistance graphene-hard material base composite latex and application thereof, wherein the composite latex comprises the following components in parts by weight: 1-9 parts of graphene modified composite hard material, 0.1-0.5 part of dispersant, 0.05-0.1 part of stabilizer, 0.2-1 part of accelerator and 80-90 parts of latex. The composite latex prepared by the invention can use common cotton yarn, chemical fiber or blended yarn and the like as a bottom lining, and the composite material of textile and latex has high-grade wear resistance and cutting resistance through a dipping or coating process. The prepared gloves are especially tested by EN388 standard, the cutting resistance of the gloves is up to 5 grade, the wear resistance of the gloves is up to 4 grade, the tearing resistance of the gloves is up to 4 grade, and the puncture resistance of the gloves is up to 4 grade.

Description

Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof
Technical Field
The invention relates to the technical field of security glove preparation, in particular to graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof.
Background
At present, the method for improving the wear resistance and the cut resistance of textiles mainly uses high-strength fiber materials, such as aramid fibers, carbon fibers, high-modulus polyethylene, basalt fibers and the like, to prepare glove blanks or other textile base fabrics, for example, patent CN106555244A discloses a cut-resistant ultra-high molecular weight polyethylene fiber, including ultra-high molecular weight polyethylene fiber; hard fibers dispersed in the ultra high molecular weight polyethylene fibers; the mass ratio of the ultra-high molecular weight polyethylene fibers to the hard fibers is 100: (2-8). According to the preparation method, the tensile viscosity of the spinning solution in the preparation process is improved by controlling the content of the hard fibers, so that the mechanical property of the finished fiber is further improved, the obtained finished fiber has higher strength, the elongation at break is high, the number of broken ends is low, and the cutting resistance of the fiber reaches the European standard 5 (equivalent to American standard 3). Also, as disclosed in patent CN106555245A, a cut resistant ultra high molecular weight polyethylene fiber includes ultra high molecular weight polyethylene fiber; hard fibers and solvent oil dispersed in the ultra-high molecular weight polyethylene fibers; the mass ratio of the ultrahigh molecular weight polyethylene fibers to the hard fibers to the solvent oil is 100: (3-6): (0.3-2). According to the method, the hard fibers are better compatible with the ultra-high molecular weight polyethylene through the infiltration effect of the solvent oil on the hard fibers, and meanwhile, the addition of the solvent oil is beneficial to the uniform distribution of the hard fibers in the ultra-high molecular weight polyethylene, so that the finished fibers have higher elongation at break, and the cutting resistance of the finished fibers can reach the European standard 5 (equivalent to American standard 3).
However, the special functional fibers have the problems of high cost, relatively complex fiber processing technology and weaving technology, and hard hand feeling and poor comfort of finished gloves and other products prepared by the fibers.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the graphene-hard material base composite latex with high wear resistance and cutting resistance and the application thereof.
The purpose of the invention is realized by the following technical scheme:
the invention provides high-wear-resistance and cutting-resistance graphene-hard material base composite latex which comprises the following components in percentage by mass:
Figure BDA0002437353610000021
preferably, the hard material comprises one or more of silicon nitride, silicon carbide, glass powder, glass fiber powder, carbon fiber powder, basalt fiber powder and ceramic powder, and the particle size of the hard material is 1-20 μm.
Preferably, the hard material is a combination of silicon nitride, zirconia, carbon fiber powder.
More preferably, the mass ratio of the silicon nitride, the zirconia, and the carbon fiber powder is 0.1 to 5.
Preferably, in the graphene modified composite hard material, the adopted graphene is modified graphene; the modifying agent adopted by the modified graphene comprises one or more of a coupling agent, a surfactant and alkyl halide.
Preferably, the preparation method of the graphene modified composite hard material comprises the following steps:
s1, mixing graphene with a modifier, and preparing modified graphene through an ionic reaction;
s2, reacting the hard material with the modified graphene for 0.5-2.5 hours under stirring or ultrasonic treatment to obtain a graphene modified composite hard material;
in the step S1, the addition amount of the modifier is 12-38% of the mass of the graphene;
in the step S2, the mass ratio of the hard material to the modified graphene is 1-7.
According to the invention, the graphene modified composite hard material can improve the performance of the hard material, the modified hard material is added into the latex, the latex has more excellent cutting resistance, wear resistance and strength, and the modified hard material can be more uniformly dispersed in the latex.
Preferably, the dispersant is selected from one or more of sodium methylene bis naphthalene sulfonate, polyacrylamide and sodium dibutyl naphthalene sulfonate;
the stabilizer is selected from one or more of zinc-calcium stabilizer, mannitol and sodium dodecyl sulfate;
the accelerant is one or more selected from ethylene thiourea, zinc dibutyl dithiocarbamate and dibenzothiazyl disulfide.
Preferably, the latex is selected from one or more of butyronitrile, PE, PU, PVC, natural latex, styrene-butadiene latex and chloroprene latex.
The invention also provides a preparation method of the high-wear-resistance and cutting-resistance hard material-based composite latex, which comprises the following steps:
A. adding dispersant, stabilizer and accelerator into partial latex (natural latex needs to be heated to 45-65 deg.C, and other latexes are at normal temperature), and stirring for 1-5 hr;
B. adding the graphene modified composite hard material into the rest latex, and mechanically stirring for 1-5h to graft the graphene modified composite hard material onto latex particles;
C. and C, mixing the latexes treated in the step A and the step B, and stirring for 3-8 hours at the temperature of 10-60 ℃ to obtain the composite latex.
The invention also provides a high-strength, cutting-resistant and wear-resistant fabric product or yarn prepared from the graphene-hard material-based composite latex with high wear resistance and cutting resistance, wherein the fabric product comprises cloth, gloves and the like made of cotton yarn, nylon, terylene, polypropylene or blended yarn; the yarn is selected from cotton yarn, nylon, terylene, polypropylene or blended yarn.
The invention also provides a preparation method of the high-strength, cutting-resistant and wear-resistant fabric product or yarn, which comprises the following steps: and (3) dipping the fabric product or the yarn in the composite latex or coating the composite latex, and drying to obtain the fabric product or the yarn with high strength, cutting resistance and wear resistance.
The invention also provides a preparation method of the high-strength, cutting-resistant and wear-resistant functional glove, which comprises the following steps:
A. soaking the prepared glove blank with a coagulant, and drying at 30-50 deg.C for 2-5min;
B. dipping the glove blank treated by the A into the composite latex, and then drying for 15-30min at the temperature of 50-80 ℃;
C. cleaning the glove blank treated in the step B with redundant composite rubber materials, vulcanizing,
D. and D, repeating the processes of the step B and the step C, and then demoulding to obtain the high-strength, cutting-resistant and wear-resistant functional glove.
Preferably, the glove blank is made of cotton yarn, nylon, terylene, polypropylene or blended yarn.
Compared with the prior art, the invention has the following beneficial effects:
the composite latex prepared by the invention can use common cotton yarn, nylon, terylene, polypropylene fiber or blended yarn as a bottom lining, and the composite material of textile and latex has high-grade wear resistance and cutting resistance through a dipping or coating process. Compared with gloves prepared from special functional fibers, the gloves have the advantages of softer hand feeling, better comfort, better cutting resistance, better wear resistance and better tear resistance. Can be widely applied to the special fields of individual safety protection, sports protection, engineering safety, field survival and the like with higher wear resistance and cutting resistance requirements.
The gloves prepared by dipping the composite latex are tested by EN388 standard, the cutting resistance of the gloves is up to 5 grade, the wear resistance of the gloves is up to 4 grade, the tearing resistance of the gloves is up to 4 grade, and the puncture resistance of the gloves is up to 4 grade.
Detailed Description
The present invention will be described in detail with reference to specific examples. The following examples will assist those skilled in the art in further understanding the invention, but are not intended to limit the invention in any way. It should be noted that variations and modifications can be made by persons skilled in the art without departing from the concept of the invention. All falling within the scope of the present invention.
Examples 1 to 10
The embodiment 1 to 10 provides a preparation method of graphene-hard material-based composite latex with high wear resistance and high cutting resistance, which comprises the following steps:
1. mixing graphene with a silane coupling agent (the addition amount is 28% of the mass of the graphene) to prepare modified graphene;
2. reacting a hard material (the hard material adopted in each example is shown in table 1, the particle size of each hard material is 10-20 μm) with the modified graphene for 2 hours under stirring or ultrasonic waves to obtain a graphene modified composite hard material;
3. adding a dispersant of sodium methylene dinaphthalene sulfonate, a stabilizer of mannitol and an accelerator of ethylene thiourea into part of nitrile latex (at normal temperature) in sequence, and fully stirring for 1-5h;
4. adding the graphene modified composite hard material into the rest latex, and mechanically stirring for 1-5 hours to graft the graphene modified composite hard material onto latex particles;
it should be noted that, in the step 3 and the step 4, the latex is distributed only by being capable of being fully and uniformly stirred with other components;
5. and (4) mixing the latexes treated in the steps (3) and (4), and stirring for 5 hours at the temperature of 40 ℃ to obtain the composite latex.
In the preparation method, the weight parts of the components are shown in table 1.
TABLE 1
Figure BDA0002437353610000041
Figure BDA0002437353610000051
Example 11
The embodiment provides a preparation method of graphene-hard material-based composite latex with high wear resistance and high cutting resistance, which comprises the following steps:
1. mixing graphene with a surfactant (specifically, quaternary ammonium salt, the addition amount of which is 32% of that of graphene) to prepare modified graphene;
2. reacting a hard material (the hard material adopted in each example is shown in table 2, the particle size of each hard material is 10-20 μm) with the modified graphene under stirring or ultrasonic for 0.5 hour to obtain a graphene modified composite hard material;
3. adding a dispersant polyacrylamide, a sodium dodecyl sulfate as a fixing agent and an accelerator dibenzothiazyl disulfide into part of PE (normal temperature) in sequence according to a proportion, and fully stirring for 1-5h;
4. adding the graphene modified composite hard material into the rest PE, and mechanically stirring for 1-5h to graft the graphene modified composite hard material onto PE particles;
5. and (4) mixing the latexes treated in the steps (3) and (4), and stirring for 8 hours at the temperature of 10 ℃ to obtain the composite latex.
In the preparation method, the weight parts of the components are shown in table 2.
Example 12
The embodiment provides a preparation method of graphene-hard material-based composite latex with high wear resistance and high cutting resistance, which comprises the following steps:
1. mixing graphene with a silane coupling agent (the addition amount is 31% of the mass of the graphene) to prepare modified graphene;
2. reacting a hard material (the hard material adopted in each example is shown in table 2, the particle size of each hard material is 10-20 μm) with the modified graphene for 2.5 hours under stirring or ultrasound to obtain a graphene modified composite hard material;
3. adding a dispersant polyacrylamide, a stabilizer sodium dodecyl sulfate and an accelerator dibenzothiazyl disulfide into partial natural latex (the temperature of the natural latex needs to be raised to 45-65 ℃) in sequence according to a proportion, and fully stirring for 1-5 hours;
4. adding the graphene modified composite hard material into the rest PE, and mechanically stirring for 1-5h to graft the graphene modified composite hard material onto natural latex particles;
5. and (4) mixing the latexes treated in the steps (3) and (4), and stirring for 3 hours at the temperature of 60 ℃ to obtain the composite latex.
In the preparation method, the weight parts of the components are shown in table 2.
Example 13
The embodiment provides a preparation method of graphene-hard material-based composite latex with high wear resistance and high cutting resistance, which comprises the following steps:
1. mixing graphene with alkyl halide (specifically bromododecane, the addition amount is 23% of the mass of the graphene) to prepare modified graphene;
2. reacting a hard material (the hard material adopted in each example is shown in table 2, the particle size of each hard material is 10-20 μm) with the modified graphene for 2 hours under stirring or ultrasonic waves to obtain a graphene modified composite hard material;
3. adding a dispersant polyacrylamide, a stabilizer sodium dodecyl sulfate and an accelerator dibenzothiazyl disulfide into part of nitrile latex (at normal temperature) in turn according to a proportion, and fully stirring for 1-5h;
4. adding the graphene modified composite hard material into the rest latex, and mechanically stirring for 1-5 hours to graft the graphene modified composite hard material onto latex particles;
5. and (4) mixing the latexes treated in the steps (3) and (4), and stirring for 4 hours at the temperature of 40 ℃ to obtain the composite latex.
In the preparation method, the weight parts of the components are shown in table 2.
TABLE 2
Figure BDA0002437353610000061
Figure BDA0002437353610000071
Comparative example 1
This comparative example differs from example 8 only in that: in the comparative example, the basalt fiber powder is replaced by the montmorillonite.
Comparative example 2
This comparative example differs from example 8 only in that: in the comparative example, the basalt fiber powder and the silicon oxide are replaced by the montmorillonite.
Comparative example 3
This comparative example differs from example 5 only in that: in this comparative example, the modification treatment of step 1 was not performed, and the unmodified graphene was directly subjected to the treatment of step 2.
Comparative example 4
This comparative example differs from example 5 only in that: in this comparative example, the hard material was directly subjected to the treatment of step 3 without adding modified graphene.
Comparative example 5
This comparative example differs from example 9 only in that: in this comparative example, the carbon fiber powder was 4 parts by weight.
Comparative example 6
This comparative example differs from example 10 only in that: in this comparative example, no hard material was added, and the modified graphene prepared in step 1 was added to step 4 for processing.
And (3) performance testing:
a method of making a glove, comprising the steps of:
A. firstly, soaking a prepared glove blank (prepared from cotton yarns) with a coagulant (the coagulant is a mixture of calcium nitrate and ethanol with the weight ratio of 1;
B. respectively dipping the glove blanks treated in the step A into the composite latex prepared in each embodiment and comparative example, and then drying for 1-4h at the temperature of 60-120 ℃;
C. and (5) demolding to obtain the glove.
The gloves prepared by dipping the composite latexes prepared in the examples and comparative examples were subjected to a performance test using the method in the EN388 standard (the specific measurement method used in the examples and comparative examples is exactly the same), and the test results are shown in Table 2.
TABLE 3
Figure BDA0002437353610000081
The same treatment was carried out on a glove blank made of nylon using the glove making method described above, wherein the compounded latex used was prepared as in example 2, and the resulting glove was tested using the method in the EN388 standard, and the results were: the cutting resistance is up to 4 grade, the wear resistance is up to 4 grade, the tear resistance is up to 4 grade, and the puncture resistance is up to 4 grade.
The glove blanks made of polyester were subjected to the same treatment using the glove preparation method described above, wherein the composite latex used was prepared as in example 2, and the gloves obtained were tested using the method in the EN388 standard, with the following results: the cutting resistance is up to 4 grade, the wear resistance is up to 4 grade, the tear resistance is up to 4 grade, and the puncture resistance is up to 4 grade.
The invention can also be used for preparing other high-strength, cutting-resistant and wear-resistant fabric products or yarns (such as fabric products or yarns, wherein the fabric products comprise cloth materials made of cotton yarns, nylon, terylene, polypropylene fibers or blended yarns, and also comprise yarns made of cotton yarns, nylon, terylene, polypropylene fibers or blended yarns) by using the composite latex prepared by the embodiment in a specific method: the fabric product or the yarn is dipped in the composite latex prepared in the embodiment or coated with the composite latex prepared in the embodiment, and then dried at the temperature of 50-120 ℃. The resulting fabric product or yarn also achieves significantly improved cut resistance, abrasion resistance, tear resistance and puncture resistance over that prior to impregnation.
The embodiments described above are described to facilitate an understanding and use of the invention by those skilled in the art. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles described herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above embodiments, and those skilled in the art should make modifications and alterations without departing from the scope of the present invention.

Claims (4)

1. The high-wear-resistance and high-cutting-resistance graphene-hard material base composite latex is characterized by comprising the following components in parts by weight:
1-9 parts of graphene modified composite hard material,
0.1 to 0.5 portion of dispersant,
0.05 to 0.1 portion of stabilizer,
0.2 to 1 portion of an accelerant,
80-90 parts of latex;
the hard material is a combination of silicon nitride, zirconia and carbon fiber powder;
in the graphene modified composite hard material, the adopted graphene is modified graphene; the modifier adopted by the modified graphene comprises one or more of a coupling agent, a surfactant and alkyl halide;
the preparation method of the graphene modified composite hard material comprises the following steps:
s1, mixing graphene with a modifier, and preparing modified graphene through an ion reaction;
s2, reacting the hard material with the modified graphene for 0.5-2.5 hours under stirring or ultrasonic treatment to obtain a graphene modified composite hard material;
in the step S1, the addition amount of the modifier is 12-38% of the mass of the graphene;
in the step S2, the mass ratio of the hard material to the modified graphene is 1-7;
the dispersing agent is selected from one or more of methylene bis-naphthalene sodium sulfonate, polyacrylamide and dibutyl naphthalene sodium sulfonate;
the stabilizer is selected from one or more of zinc-calcium stabilizer, mannitol and sodium dodecyl sulfate;
the accelerant is one or more selected from ethylene thiourea, zinc dibutyl dithiocarbamate and dibenzothiazyl disulfide;
the latex is selected from one or more of butyronitrile, PE, PU, PVC, natural latex, styrene-butadiene latex and neoprene latex.
2. A method for preparing the highly wear-resistant and cut-resistant graphene-hard material-based composite latex according to claim 1, comprising the steps of:
A. adding the dispersant, the stabilizer and the accelerator into partial latex in proportion, and fully stirring for 1-5h;
B. adding the graphene modified composite hard material into the rest latex, and mechanically stirring for 1-5h to graft the graphene modified composite hard material onto latex particles;
C. and C, mixing the latexes treated in the step A and the step B, and stirring for 3-8 hours at the temperature of 10-60 ℃ to obtain the composite latex.
3. A high strength, cut resistant, abrasion resistant fabric product or yarn made from the high abrasion resistant, cut resistant graphene-hard material based composite latex of claim 1.
4. A method of making a high strength, cut and abrasion resistant functional fabric product or yarn according to claim 3, comprising the steps of:
dipping the fabric product or yarn in the composite latex of claim 1 or coating the composite latex of claim 1, and drying to obtain the fabric product or yarn with high strength, cutting resistance and wear resistance.
CN202010256022.XA 2020-04-02 2020-04-02 Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof Active CN111533923B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010256022.XA CN111533923B (en) 2020-04-02 2020-04-02 Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010256022.XA CN111533923B (en) 2020-04-02 2020-04-02 Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof

Publications (2)

Publication Number Publication Date
CN111533923A CN111533923A (en) 2020-08-14
CN111533923B true CN111533923B (en) 2022-10-28

Family

ID=71952224

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010256022.XA Active CN111533923B (en) 2020-04-02 2020-04-02 Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof

Country Status (1)

Country Link
CN (1) CN111533923B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113150408A (en) * 2021-05-13 2021-07-23 慕思健康睡眠股份有限公司 Temperature-reducing and heat-insulating graphene latex as well as preparation method and application thereof
CN113322691B (en) * 2021-07-08 2022-08-02 南安市哲兴皮革包袋有限公司 High-strength tear-resistant waterproof oxford fabric and preparation method thereof
CN113737511A (en) * 2021-08-24 2021-12-03 南通强生石墨烯科技有限公司 Graphene high-cutting-resistance special fiber and preparation method thereof
CN116791354A (en) * 2022-03-17 2023-09-22 南通强生新材料科技股份有限公司 Cutting-resistant yarn and production process thereof
CN115821585A (en) * 2022-12-10 2023-03-21 江苏金呢工程织物股份有限公司 Textile auxiliary for high-wear-resistance forming net and preparation method thereof
CN115960532B (en) * 2023-03-01 2024-03-12 东华大学 Preparation method of graphene anti-cutting coating

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6730393B1 (en) * 1997-10-08 2004-05-04 Honeywell International, Inc. Cut-resistant polymeric sheets and articles formed therefrom
CN106065095A (en) * 2016-06-08 2016-11-02 上海史墨希新材料科技有限公司 Functional high-strength protective gloves of Graphene latex and preparation method thereof
CN107043477A (en) * 2017-01-17 2017-08-15 南通强生安全防护科技股份有限公司 Graphene NBR latex composite mortar and preparation method thereof, purposes
CN109320807A (en) * 2018-09-23 2019-02-12 南通嘉得利安全用品有限公司 Graphene-latex proofing gloves and preparation method thereof
CN109629028A (en) * 2018-11-15 2019-04-16 南通强生安全防护科技股份有限公司 A kind of graphene ultra-high molecular weight polyethylene composite fibre and preparation method thereof
CN110128721A (en) * 2019-04-30 2019-08-16 鸿瀚防护科技南通有限公司 A kind of chemical defence gloves enhance the impregnation composite material of anti-cutting performance

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6730393B1 (en) * 1997-10-08 2004-05-04 Honeywell International, Inc. Cut-resistant polymeric sheets and articles formed therefrom
CN106065095A (en) * 2016-06-08 2016-11-02 上海史墨希新材料科技有限公司 Functional high-strength protective gloves of Graphene latex and preparation method thereof
CN107022124A (en) * 2016-06-08 2017-08-08 南通强生安全防护科技股份有限公司 High-strength protective gloves of graphene latex feature and preparation method thereof
CN107043477A (en) * 2017-01-17 2017-08-15 南通强生安全防护科技股份有限公司 Graphene NBR latex composite mortar and preparation method thereof, purposes
CN109320807A (en) * 2018-09-23 2019-02-12 南通嘉得利安全用品有限公司 Graphene-latex proofing gloves and preparation method thereof
CN109629028A (en) * 2018-11-15 2019-04-16 南通强生安全防护科技股份有限公司 A kind of graphene ultra-high molecular weight polyethylene composite fibre and preparation method thereof
CN110128721A (en) * 2019-04-30 2019-08-16 鸿瀚防护科技南通有限公司 A kind of chemical defence gloves enhance the impregnation composite material of anti-cutting performance

Also Published As

Publication number Publication date
CN111533923A (en) 2020-08-14

Similar Documents

Publication Publication Date Title
CN111533923B (en) Graphene-hard material base composite latex with high wear resistance and high cutting resistance and application thereof
CN110241472B (en) Ultrahigh-molecular-weight polyethylene fiber with ultrahigh cutting resistance and preparation method thereof
EP0575088B1 (en) Water-based liquid for treating glass fiber cord, glass fiber cord for reinforcing rubber and reinforced rubber product
CN109629028A (en) A kind of graphene ultra-high molecular weight polyethylene composite fibre and preparation method thereof
CN109796640A (en) A kind of wear-resisting antiskid emgloves and preparation method thereof
CN106149085A (en) A kind of cut resistant superhigh molecular weight polyethylene fibers and preparation technology thereof
CN108384078B (en) Preparation method of conductive protective colloid gloves
JP5502594B2 (en) Aromatic polyamide short fiber bundles for rubber reinforcement
CN115215561B (en) Glass fiber impregnating compound and preparation method and application thereof
CN117322695A (en) Oil-resistant anti-skid protective glove and preparation method thereof
KR960013472B1 (en) Composition for the surface treatment of polymer fibers
CN113481735A (en) Radiation-proof rubber gloves with linings and preparation method thereof
CN114672082B (en) Carboxylated nitrile emulsion and preparation method and application thereof
CN110028715B (en) Production formula of anti-shake and anti-tear spinning rubber ring
CN111057360A (en) Graphene conductive rubber fiber composite material and preparation method and application thereof
US4204984A (en) Lignin amine carboxylated conjugated diene tire cord adhesives
CN114149602A (en) Superstrong anti-puncture glove and preparation method thereof
KR102068120B1 (en) Synthetic rubber latex resin composition and manufacturing method of polymer textiles including micro cell using the same
WO2012085587A1 (en) Elastomeric films
CN113698710B (en) Wear-resistant antibacterial shoe material and preparation method thereof
JP4944742B2 (en) Rubber reinforcing fiber and method for producing the same
JP2011241503A (en) Method to manufacturing carbon fiber composite cord for reinforcement
Soltani et al. Mechanical and morphological properties of short nylon fibre reinforced NR/SBR composites: optimization of interfacial bonding agent
DE1544786A1 (en) Process for improving the adhesion of glass fibers to rubber
JPS63203405A (en) Heavy-duty pneumatic radial tire

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 226400 No.118, Jialingjiang Road, Rudong Economic Development Zone, Nantong City, Jiangsu Province

Applicant after: Nantong Johnson & Johnson New Material Technology Co.,Ltd.

Address before: 226400 No. 118 Jialingjiang Road, Rudong Economic Development Zone, Rudong County, Nantong City, Jiangsu Province

Applicant before: NANTONG QIANGSHENG SAFETY PROTECTION TECHNOLOGY Co.,Ltd.

CB02 Change of applicant information
GR01 Patent grant
GR01 Patent grant