CN111533175B - Multi-stage type manganese sulfate solution oil and impurity removing device and control method thereof - Google Patents
Multi-stage type manganese sulfate solution oil and impurity removing device and control method thereof Download PDFInfo
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- CN111533175B CN111533175B CN202010537157.3A CN202010537157A CN111533175B CN 111533175 B CN111533175 B CN 111533175B CN 202010537157 A CN202010537157 A CN 202010537157A CN 111533175 B CN111533175 B CN 111533175B
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Abstract
The invention relates to the technical field of battery production, in particular to a multistage manganese sulfate solution oil-removing and impurity-removing device and a control method thereof, wherein the multistage manganese sulfate solution oil-removing and impurity-removing device comprises a plurality of groups of manganese sulfate solution oil-removing and impurity-removing devices, valves are arranged at the feed end and the discharge end of each group of manganese sulfate solution oil-removing and impurity-removing devices, the groups of manganese sulfate solution oil-removing and impurity-removing devices are sequentially connected through a pipeline, the discharge end of the tail end manganese sulfate solution oil-removing and impurity-removing device is connected with a collecting tank through a second pipeline, and the feed end of the head end manganese sulfate solution oil-removing and impurity-removing device is connected with the output end of a conveying pump; the multi-stage manganese sulfate solution oil removal and impurity removal device provided by the invention can achieve the effects of adjusting the pH value of the solution and removing impurities and oil, and can be used for carrying out operations such as maintenance, material loading and unloading, activated carbon cleaning and the like on any one stage of device on the premise of not losing the capacity.
Description
Technical Field
The invention relates to the technical field of battery production, in particular to a multistage manganese sulfate solution oil removal and impurity removal device and a control method thereof.
Background
After the manganese sulfate solution is extracted, an oily extractant is often carried in the solution, and trace impurities in the extracted solution are as follows: cu, Cr, Cd, Pb, Ag, Hg, As, Ni, Co and the like affect the quality of finished products and cannot reach the quality standard of customers. In addition, the pH value of the manganese sulfate solution after extraction is usually about 1-3, and a large amount of alkali is consumed in subsequent production to adjust the pH value to 5-7, so that the production cost is influenced.
When the primary oil removal and impurity removal device is used in the using process, after manganese powder is completely consumed or the active carbon adsorbs oil to reach a saturated state, the produced product oil or metal impurities can rise, the machine needs to be stopped to fill the manganese powder or replace the active carbon or regenerate the oil removal and impurity removal device, and the capacity loss can be caused in the stopping process.
Disclosure of Invention
In order to solve the problems, the invention provides a multistage manganese sulfate solution oil and impurity removing device and a control method thereof.
The invention is realized by the following technical scheme:
a multi-stage manganese sulfate solution oil-removing and impurity-removing device comprises a plurality of groups of manganese sulfate solution oil-removing and impurity-removing devices, wherein valves are arranged at the feed end and the discharge end of each group of manganese sulfate solution oil-removing and impurity-removing devices, the groups of manganese sulfate solution oil-removing and impurity-removing devices are sequentially connected through pipelines, the discharge end of the tail end manganese sulfate solution oil-removing and impurity-removing device is connected with a collecting tank through a second pipeline, the feed end of the head end manganese sulfate solution oil-removing and impurity-removing device is connected with the output end of a conveying pump, the second pipeline, the adjacent pipelines and the adjacent pipelines are communicated through connecting pipelines, the connecting pipelines are all provided with second valves, except the manganese sulfate solution oil removing and impurity removing device at the tail end, the feeding pipes of the other groups of adjacent manganese sulfate solution oil and impurity removal devices are connected through connecting pipes, and a third valve is arranged on each group of connecting pipes.
Furthermore, the oil and impurity removing device for the manganese sulfate solution is provided with three or more groups.
Preferably, the valve, the second valve and the third valve are all manual valves or electromagnetic valves.
Further, the manganese sulfate solution oil and impurity removing device comprises a reaction tank body, wherein the lower part of the reaction tank body is conical, and the upper part of the reaction tank body is cylindrical;
the inner conical part of the reaction tank body is provided with a liquid distribution pore plate, a felt and manganese powder removing layer from bottom to top, and the inner cylindrical part of the reaction tank body is provided with a liquid distribution pore plate, a felt and an activated carbon layer from bottom to top.
Further, a manganese powder filling opening is formed in the side wall of the reaction tank body corresponding to the manganese powder layer; the top of the reaction tank body is provided with an activated carbon layer filling opening, and the side wall of the reaction tank body corresponding to the bottom of the activated carbon layer is provided with an activated carbon layer discharging opening.
Further, the initial volume V of the manganese powder layer is 69.4 cubic decimeters, and the initial flow Q of the manganese sulfate solution per minute is controlled to be 0.24-0.48V.
The invention further provides a control method based on the multistage manganese sulfate solution oil and impurity removal device, which comprises the following steps:
selecting a group of manganese sulfate solution oil-removing and impurity-removing devices as a first group of oil-removing and impurity-removing devices of a multistage manganese sulfate solution oil-removing and impurity-removing device, and opening corresponding third valves according to the positions of the selected first group of manganese sulfate solution oil-removing and impurity-removing devices;
opening valves at the inlet end and the outlet end of a device which needs to use a manganese sulfate solution for removing oil and impurities, and keeping a second valve on an adjacent connecting pipeline in a closed state; the valves at the inlet end and the outlet end of the oil and impurity removing device of the manganese sulfate solution which is not needed to be used are in a closed state, and the second valve on the connecting pipeline adjacent to the valve is in an open state.
Further, when the manganese sulfate solution oil and impurity removing device at the head end is selected as the first group of oil and impurity removing devices, all the third valves are in a closed state;
and when the non-head end manganese sulfate solution oil and impurity removing device is selected as the first group of oil and impurity removing devices, the third valves on the connecting pipes on the right side of the selected manganese sulfate solution oil and impurity removing device are opened, and the other third valves are in a closed state.
The invention has the beneficial effects that:
the multistage manganese sulfate solution oil removal and impurity removal device provided by the invention at least uses a 3-stage oil removal and impurity removal device, and the use of the oil removal and impurity removal device is controlled by a control valve according to a principle of two-purpose one-standby. And the quality of the product discharged from the next stage can be ensured by using two-stage combination. The utility of each device is managed and controlled through each detection result of using the device to output solution, and abnormal devices can be replaced at any time when the quality fluctuates, so that continuous production is guaranteed.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are required to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained according to the drawings without inventive efforts.
FIG. 1 is a schematic structural diagram of a multistage manganese sulfate solution oil and impurity removal device in example 1;
FIG. 2 is a schematic diagram of a device for removing oil and impurities from a manganese sulfate solution in the invention;
FIG. 3 is a schematic view of a multi-stage apparatus for removing oil and impurities from manganese sulfate solution in example 2.
Description of the main elements
A manganese sulfate solution oil and impurity removing device-1; a valve-2; a conduit-3; a connecting pipeline-4; a second valve-5; a connecting pipe-6; a third valve-7; a delivery pump-8; a collecting tank-9; a second conduit-10; a manganese powder filling port-11; an activated carbon layer discharge opening-12; activated carbon layer filling port-13; a reaction tank body-101; a liquid distribution pore plate-102; removing the asphalt felt-103; a manganese powder layer-104; activated carbon layer-105.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the embodiments of the present invention will be described in detail and completely with reference to the accompanying drawings, and it is to be understood that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments of the present invention. All other embodiments obtained by a person of ordinary skill in the art based on the embodiments of the present invention without any creative effort belong to the protection scope of the present invention. Thus, the following detailed description of the embodiments of the present invention, presented in the figures, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implying any number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.
Example 1
Referring to the attached drawing 1, a multi-stage manganese sulfate solution oil and impurity removing device comprises three groups of manganese sulfate solution oil and impurity removing devices 1, wherein a valve 2 is arranged at the feed end and the discharge end of each group of manganese sulfate solution oil and impurity removing devices 1, the feed end and the discharge end of each group of manganese sulfate solution oil and impurity removing devices 1 are sequentially connected through a pipeline 3, the discharge end of the tail end manganese sulfate solution oil and impurity removing device 1 (the tail end manganese sulfate solution oil and impurity removing device 1 is the end farthest from a conveying pump 8) is connected with a collecting tank 9 through a second pipeline 10, the feed end of the head end manganese sulfate solution oil and impurity removing device 1 (the head end manganese sulfate solution oil and impurity removing device 1 is the end closest to the conveying pump 8) is connected with the output end of the conveying pump 8, the second pipeline 10 is communicated with the adjacent pipelines 3 and the adjacent pipelines 3 through connecting pipelines 4, all be provided with second valve 5 on connecting tube 4, except terminal manganese sulfate solution deoiling edulcoration device 1, link to each other through connecting pipe 6 between the inlet pipe of each adjacent manganese sulfate solution deoiling edulcoration device 1 of other group, all be equipped with third valve 7 on each connecting pipe 6 of group.
The valves 2, 5 and 7 are all manual valves or electromagnetic valves.
Further, the manganese sulfate solution oil and impurity removing device comprises a reaction tank body 101, wherein the lower part of the tank body 101 is conical, and the upper part of the tank body is cylindrical;
a liquid distribution pore plate 102, a degreasing felt 103 and a manganese powder layer 104 are arranged from the lower part to the upper part of the inner conical part of the tank body 101, and the liquid distribution pore plate 102, the degreasing felt 103 and an activated carbon layer 105 are arranged from the lower part to the upper part of the inner cylindrical part of the reaction tank body 101; the solution is subjected to liquid separation by a liquid distribution pore plate 102 and then is subjected to primary oil removal by an oil removal felt 103, and then the solution treated by the oil removal felt 103 enters manganese powder, and the manganese powder and H are mixed+Reacting to consume H in solution+Thereby increasing the pH of the solution, the reaction equation being: mn +2H+=Mn2++H2In addition, most of impurity metal ions, such As impurities of Cu, Cr, Cd, Pb, Ag, Hg, As, Ni, Co and the like, can also be subjected to a displacement reaction with Mn with higher activity, so that the impurity metal ions are removed; manganese powder is used for pH adjustment and impurity ion removal, and manganese ions are generated after the manganese powder reacts, so that other impurities cannot be introduced;
the solution reacted with manganese powder is subjected to liquid separation by a liquid distribution pore plate 102 and treatment by an oil removal felt 103, and then enters an activated carbon layer 105 for oil removal and particle impurity filtration.
Further, a manganese powder filling opening 11 is formed in the side wall of the reaction tank body 101 corresponding to the manganese powder layer 104, so that the manganese powder can be conveniently replaced; the top of the reaction tank body 101 is provided with an activated carbon layer filling opening 13, and the side wall of the reaction tank body 101 corresponding to the bottom of the activated carbon layer 105 is provided with an activated carbon layer discharging opening 12 so as to facilitate the replacement of the activated carbon.
Sampling ports are arranged at the discharge pipeline positions of the manganese sulfate solution oil and impurity removing devices 1; during production, the sampling port of the oil removing and impurity removing device used in the production is used for sampling and detecting the pH, oil content, Cu, Cr, Cd, Pb, Ag, Hg, As, Ni, Co and other ion concentrations every day.
The initial mass of the manganese dust layer 4 is defined as 500, units: kg (manganese powder density of 7.2 kg/dm)3) (ii) a Volume is 69.4, unit: cubic decimeter; the grain diameter is 100 meshes. Because most of the metal ions in the manganese sulfate solution are inert metal ions such As Cu, Cr, Cd, Pb, Ag, Hg, As, Ni, Co and the like, the replacement reaction rate of the metal ions with Mn is slow. Therefore, the time during which the manganese sulfate solution flows through the manganese powder layer 4 can be controlled substantially by controlling the flow rate of the manganese sulfate solution. Preferably, the initial flow rate Q of the manganese sulphate solution per minute0Can be controlled to be 0.24-0.48V/min (wherein V is the volume of the manganese powder layer), so that the flowing time of the manganese sulfate solution in the manganese powder layer 4 is controlled to be about 2.1-4.2 minutes, and the battery grade standard is achieved. In this example, the initial flow rate Q of the manganese sulfate solution per minute0The flow time of the manganese sulfate solution in the manganese powder layer 4 is controlled to be about 2.8 minutes by controlling 0.36V, namely 0.36V/min. It is understood that too fast a flow rate is not conducive to adequate reaction; the flow rate is too slow, which affects the production efficiency.
The embodiment further provides a control method based on the multistage manganese sulfate solution oil removal and impurity removal device, which comprises the following specific steps:
selecting a group of manganese sulfate solution oil and impurity removing devices 1 as a first group of oil and impurity removing devices of a multistage manganese sulfate solution oil and impurity removing device, and opening corresponding third valves 7 according to the positions of the selected first group of manganese sulfate solution oil and impurity removing devices 1;
opening a valve 2 at the inlet end and the outlet end of a manganese sulfate solution oil and impurity removing device 1 to be used, and closing a second valve 5 on a connecting pipeline 4 adjacent to the valve (namely, closing a second valve 5 adjacent to the upper right of the manganese sulfate solution oil and impurity removing device 1 in the attached drawing 1); the valves 2 at the inlet and outlet ends of the manganese sulfate solution oil-removing and impurity-removing device 1 which is not required to be used are in a closed state, and the second valve 5 on the connecting pipeline 4 adjacent to the valves is in an open state (i.e. the second valve 5 adjacent to the upper right of the manganese sulfate solution oil-removing and impurity-removing device 1 is in an open state as shown in the attached drawing 1); the first manganese sulfate solution oil and impurity removing device 1 is not provided with a connecting pipeline 4 adjacent to the first manganese sulfate solution oil and impurity removing device.
Further, when the manganese sulfate solution oil and impurity removing device 1 at the head end is selected as the first group of oil and impurity removing device, each third valve 7 is in a closed state;
when the non-head end manganese sulfate solution oil and impurity removing device 1 is selected as the first group of oil and impurity removing devices, the third valves 7 on the connecting pipes 6 on the right side of the selected manganese sulfate solution oil and impurity removing device 1 are opened, and the rest of the third valves 7 are in a closed state.
The working principle is as follows:
for convenience of explaining the principle, each manganese sulfate solution oil and impurity removing device 1 is sequentially marked as a first-stage oil and impurity removing device, a second-stage oil and impurity removing device and a third-stage oil and impurity removing device from right to left; and each second valve 5 is sequentially marked as a second valve-1 and a second valve-2 from right to left.
When the first-stage oil and impurity removing device and the second-stage oil and impurity removing device need to be combined, a valve 2 on the inlet end and the outlet end of the first-stage oil and impurity removing device and the second-stage oil and impurity removing device is opened, and a second valve-1 on a connecting pipeline 4 adjacent to the second-stage oil and impurity removing device is in a closed state; the valves 2 at the inlet end and the outlet end of the third-stage oil and impurity removing device are in a closed state, and the second valve-2 on the connecting pipeline 4 adjacent to the third-stage oil and impurity removing device is in an open state; the third valve 7 is in a closed state;
when the first-stage oil and impurity removing device and the third-stage oil and impurity removing device need to be combined, a valve 2 on the inlet end and the outlet end of the first-stage oil and impurity removing device and the third-stage oil and impurity removing device is opened, and a second valve-2 on a connecting pipeline 4 adjacent to the third-stage oil and impurity removing device is in a closed state; the valves 2 at the inlet end and the outlet end of the second-stage oil and impurity removing device are in a closed state, and the second valve-1 on the connecting pipeline 4 adjacent to the second-stage oil and impurity removing device is in an open state; the third valve 7 is in a closed state;
when a second-stage oil and impurity removing device and a third-stage oil and impurity removing device are combined (at the moment, the second-stage oil and impurity removing device is used as a first group of feeding oil and impurity removing device), the valves 2 on the feeding and discharging ends of the second-stage oil and impurity removing device and the third-stage oil and impurity removing device are opened, the second valve-1 on the connecting pipeline 4 adjacent to the second-stage oil and impurity removing device is in a closed state, and the second valve-2 on the connecting pipeline 4 adjacent to the third-stage oil and impurity removing device is also in a closed state; a valve 2 on the material inlet end and the material outlet end of the first-stage oil and impurity removing device is in a closed state; and a third valve 7 on a connecting pipe 6 at the right side of the second-stage oil and impurity removing device is opened.
During production, the metal impurity content, the pH value and the oil content of the manganese sulfate solution are detected by sampling from a storage tank regularly. Further, a threshold value can be set, and when the content of metal impurities or the pH reaches the set threshold value, the flow rate Q of the manganese sulfate solution per minute can be properly reduced1Wherein, 0.5Q0≤Q1<Q0(wherein Q)00.24V/min). Proved by experiments, when Q is1Less than 0.5Q0In the case of the method, the content of metal impurities is difficult to reduce to the standard of the battery, which is probably caused by that oil or replaced metal partially coats the surface of manganese powder metal in the reaction process. The threshold value is that the pH value is less than 5, and the oil content is higher than 5 mg/L. If the flow Q of the manganese sulfate solution per minute is reduced1When the content of metal impurities in the manganese sulfate solution cannot be reduced, skipping over the previous oil and impurity removing device, using the other two devices to continue production, and adding manganese powder in the previous device; if the flow Q of the manganese sulfate solution per minute is reduced1And skipping the previous oil removal and impurity removal device when the oil content of the solution cannot be reduced, using the rest two devices to continue production, and cleaning or replacing the active carbon by the previous device.
Before and after the manganese sulfate solution is deoiled and decontaminated, the oil content can be reduced from 10mg/L to below 0.01mg/L, and impurities such As Cu, Cr, Cd, Pb, Ag, Hg, As, Ni, Co and the like can also reach the battery grade standard. The pH value is increased from 1-3 to 5-7 after the reaction, which is beneficial to the subsequent production of the precursor material of the battery.
Example 2
Referring to the attached drawing 2, the multistage manganese sulfate solution oil and impurity removing device provided in this embodiment is basically the same as that in embodiment 1, and the difference is that four sets of manganese sulfate solution oil and impurity removing devices 1 are provided in the multistage manganese sulfate solution oil and impurity removing device, and each set of manganese sulfate solution oil and impurity removing devices 1 are sequentially connected through a pipeline 3.
The working principle is as follows:
for convenience of explaining the principle, each manganese sulfate solution oil and impurity removing device 1 is sequentially marked as a first-stage oil and impurity removing device, a second-stage oil and impurity removing device, a third-stage oil and impurity removing device and a fourth-stage oil and impurity removing device from right to left; each second valve 5 is sequentially marked as a second valve-1, a second valve-2 and a second valve-3 from right to left; and the third valves 7 are sequentially marked as a third valve-1 and a third valve-2 from right to left.
When a first-stage oil and impurity removing device and a second-stage oil and impurity removing device are required to be combined, a valve 2 on the inlet and outlet ends of the first-stage oil and impurity removing device and the second-stage oil and impurity removing device is opened, and a second valve-1 on a connecting pipeline 4 adjacent to the second-stage oil and impurity removing device is in a closed state; the third-stage oil and impurity removing device and the fourth-stage oil and impurity removing device are in a closed state at the inlet and outlet ends of the valve 2, and the second valve-2 and the second valve-3 on the connecting pipeline 4 adjacent to the third-stage oil and impurity removing device are in an open state; the third valve-1 and the third valve-2 are in a closed state.
When the first-stage oil and impurity removing device and the third-stage oil and impurity removing device are required to be combined, the valves 2 at the inlet and outlet ends of the first-stage oil and impurity removing device and the third-stage oil and impurity removing device are opened, and the second valve-2 on the connecting pipeline 4 adjacent to the third-stage oil and impurity removing device is in a closed state; the valve 2 on the inlet end and the outlet end of the second and fourth-stage oil and impurity removing devices is in a closed state, and the second valve-1 and the second valve-3 on the connecting pipeline 4 adjacent to the second and fourth-stage oil and impurity removing devices are in an open state; the third valve-1 and the third valve-2 are in a closed state.
When a first-stage oil and impurity removing device and a fourth-stage oil and impurity removing device are required to be combined, the valves 2 on the inlet and outlet ends of the first-stage oil and impurity removing device and the fourth-stage oil and impurity removing device are opened, and the second valve-3 on the connecting pipeline 4 adjacent to the fourth-stage oil and impurity removing device is in a closed state; the valves 2 at the inlet end and the outlet end of the second and third oil and impurity removing devices are in a closed state, and the second valve-1 and the second valve-2 on the connecting pipeline 4 adjacent to the second and third oil and impurity removing devices are in an open state; the third valve-1 and the third valve-2 are in a closed state.
When a secondary oil and impurity removing device and a third oil and impurity removing device are combined (at the moment, the secondary oil and impurity removing device serves as a first group of feeding oil and impurity removing devices), valves 2 on the feeding end and the discharging end of the second oil and impurity removing device and the third oil and impurity removing device are opened, and a second valve-1 and a second valve-2 on a connecting pipeline 4 adjacent to the second oil and impurity removing device and the third oil and impurity removing device are in a closed state; the valves 2 at the inlet and outlet ends of the first and fourth-stage oil and impurity removing devices are in a closed state, and the second valve-3 on the connecting pipeline 4 adjacent to the fourth-stage oil and impurity removing device is in an open state; and a third valve-1 on a connecting pipe 6 at the right side of the second-stage oil and impurity removing device is opened, and a third valve-2 is in a closed state.
When a secondary oil and impurity removing device and a fourth oil and impurity removing device are required to be combined (at the moment, the secondary oil and impurity removing device is used as a first group of feeding oil and impurity removing device), valves 2 on the feeding end and the discharging end of the second and fourth oil and impurity removing devices are opened, and a second valve-1 and a second valve-3 on a connecting pipeline 4 adjacent to the second and fourth oil and impurity removing devices are in a closed state; the valves 2 at the inlet and outlet ends of the first and third oil and impurity removing devices are in a closed state, and the second valve-2 on the connecting pipeline 4 adjacent to the third oil and impurity removing device is in an open state; and a third valve-1 on a connecting pipe 6 at the right side of the second-stage oil and impurity removing device is opened, and a third valve-2 is in a closed state.
When the three-stage oil and impurity removing device and the fourth-stage oil and impurity removing device are required to be used in a combined manner (at the moment, the third-stage oil and impurity removing device is used as a first group of feeding oil and impurity removing device), the valves 2 on the feeding end and the discharging end of the third-stage oil and impurity removing device and the fourth-stage oil and impurity removing device are opened, and the second valve-2 and the second valve-3 on the connecting pipeline 4 adjacent to the third-stage oil and impurity removing device are in a closed state; the valves 2 at the inlet end and the outlet end of the first and second oil and impurity removing devices are in a closed state, and the second valve-1 on the connecting pipeline 4 adjacent to the second oil and impurity removing device is in an open state; and a third valve-1 and a third valve-2 on a connecting pipe 6 at the right side of the third-stage oil and impurity removing device are opened.
During production, sampling from a sampling port of an oil removal and impurity removal device used in the production every day to detect the concentration of ions such As pH, oil content, Cu, Cr, Cd, Pb, Ag, Hg, As, Ni and Co of the solution, and jumping over a previous-stage oil removal and impurity removal device if the pH of the solution is lower than 5 or the concentration of ions such As Cu, Cr, Cd, Pb, Ag, Hg, As, Ni and Co is higher than a standard value, and using the other two devices to continue production, wherein the previous-stage device is used for adding manganese powder; if the oil content of the sampling solution is higher than 5mg/L, skipping a previous oil and impurity removing device, using the rest two devices to continue production, and cleaning or replacing the active carbon by the previous device.
Before and after the manganese sulfate solution is deoiled and decontaminated, the oil content can be reduced from 10mg/L to below 0.01mg/L, and impurities such As Cu, Cr, Cd, Pb, Ag, Hg, As, Ni, Co and the like can also reach the battery grade standard. The pH value is increased from 1-3 to 5-7 after the reaction, which is beneficial to the subsequent production of the precursor material of the battery.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made without departing from the spirit and principle of the present invention shall fall within the protection scope of the present invention.
Claims (6)
1. A multi-stage manganese sulfate solution oil-removing and impurity-removing device is characterized by comprising a plurality of groups of manganese sulfate solution oil-removing and impurity-removing devices (1), wherein valves (2) are arranged at the feed end and the discharge end of each group of manganese sulfate solution oil-removing and impurity-removing devices (1), each group of manganese sulfate solution oil-removing and impurity-removing devices (1) are sequentially connected through pipelines (3), the discharge end of each tail end manganese sulfate solution oil-removing and impurity-removing device (1) is connected with a collecting tank (9) through a second pipeline (10), the feed end of each head end manganese sulfate solution oil-removing and impurity-removing device (1) is connected with the output end of a conveying pump (8), the second pipelines (10) and adjacent pipelines (3) as well as adjacent pipelines (3) are communicated through connecting pipelines (4), the connecting pipelines (4) are respectively provided with a second valve (5), except the tail end manganese sulfate solution oil-removing and impurity-removing devices (1), the feeding pipes of the other groups of adjacent manganese sulfate solution oil and impurity removal devices (1) are connected through connecting pipes (6), and each group of connecting pipes (6) is provided with a third valve (7);
the manganese sulfate solution oil and impurity removing device comprises a reaction tank body (101), wherein the lower part of the reaction tank body (101) is conical, and the upper part of the reaction tank body is cylindrical;
a liquid distribution pore plate (102), an oil removing felt (103) and a manganese powder layer (104) are arranged on the inner conical part of the reaction tank body (101) from bottom to top, the liquid distribution pore plate (102), the oil removing felt (103) and an activated carbon layer (105) are arranged on the inner cylindrical part of the reaction tank body (101) from bottom to top;
the manganese sulfate solution oil removing and impurity removing device is provided with more than three groups.
2. The multi-stage manganese sulfate solution oil and impurity removing device according to claim 1, wherein the valve (2), the second valve (5) and the third valve (7) are manual valves or electromagnetic valves.
3. The multi-stage manganese sulfate solution oil and impurity removal device according to claim 1, wherein a manganese powder filling port (11) is formed in the side wall of the reaction tank body (101) corresponding to the manganese powder layer (104); the top of the reaction tank body (101) is provided with an activated carbon layer filling opening (13), and the side wall of the reaction tank body (101) corresponding to the bottom of the activated carbon layer (105) is provided with an activated carbon layer discharge opening (12).
4. The multistage manganese sulfate solution oil and impurity removal device as claimed in claim 1, wherein the initial volume of the manganese powder layer is V =69.4 cubic decimeters, and the initial flow rate Q of the manganese sulfate solution per minute is controlled to be 0.24-0.48V.
5. A control method of a multistage manganese sulfate solution oil and impurity removal device as defined in any one of claims 1 to 3, which is characterized by comprising the following steps:
selecting a group of manganese sulfate solution oil-removing and impurity-removing devices (1) as a first group of oil-removing and impurity-removing devices of a multi-stage manganese sulfate solution oil-removing and impurity-removing device, and opening corresponding third valves (7) according to the positions of the selected first group of manganese sulfate solution oil-removing and impurity-removing devices (1);
opening a valve (2) on the inlet end and the outlet end of a manganese sulfate solution oil and impurity removing device (1) to be used, and closing a second valve (5) on a connecting pipeline (4) adjacent to the valve; the valves (2) on the inlet end and the outlet end of the manganese sulfate solution oil-removing and impurity-removing device (1) which is not needed to be used are in a closed state, and the second valve (5) on the adjacent connecting pipeline (4) is in an open state.
6. The control method of the multistage manganese sulfate solution oil and impurity removal device according to claim 5, characterized in that:
when the manganese sulfate solution oil and impurity removing device (1) at the head end is selected as the first group of oil and impurity removing devices, all the third valves (7) are in a closed state;
when the non-head end manganese sulfate solution oil and impurity removing device (1) is selected as the first group of oil and impurity removing devices, the third valves (7) on the connecting pipes (6) on the right side of the selected manganese sulfate solution oil and impurity removing device (1) are opened, and the rest of the third valves (7) are in a closed state.
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CN203529957U (en) * | 2013-10-23 | 2014-04-09 | 陕西天沐新材料有限公司 | Oil removing system suitable for nickel sulfate solution |
CN209507613U (en) * | 2019-01-22 | 2019-10-18 | 荆州市联达精细化工有限公司 | A kind of zinc sulfate dissolution of raw material impurity removed system |
CN212769908U (en) * | 2020-06-12 | 2021-03-23 | 福建常青新能源科技有限公司 | Multi-stage type manganese sulfate solution deoiling edulcoration device |
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CN103193274A (en) * | 2013-05-02 | 2013-07-10 | 宜春市同舟新材料科技有限公司 | Manganese sulfate purification method and manganese sulfate |
KR101602111B1 (en) * | 2015-09-18 | 2016-03-09 | 강원대학교산학협력단 | Manufacturing Method of High Purity Manganese Sulphate from the Waste Liquid of Battery recycling process |
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CN203529957U (en) * | 2013-10-23 | 2014-04-09 | 陕西天沐新材料有限公司 | Oil removing system suitable for nickel sulfate solution |
CN209507613U (en) * | 2019-01-22 | 2019-10-18 | 荆州市联达精细化工有限公司 | A kind of zinc sulfate dissolution of raw material impurity removed system |
CN212769908U (en) * | 2020-06-12 | 2021-03-23 | 福建常青新能源科技有限公司 | Multi-stage type manganese sulfate solution deoiling edulcoration device |
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