CN111524558B - Ozone generation sensitivity indicator, and method and device for determining same - Google Patents
Ozone generation sensitivity indicator, and method and device for determining same Download PDFInfo
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Abstract
The invention provides an ozone generation sensitivity indicator, a determination method and a device thereof, wherein the method comprises the following steps: acquiring a reference space distribution map corresponding to a to-be-detected ozone pollution place; generating an indication space distribution map corresponding to each indicator according to the benchmark test; determining a target indicator corresponding to the ozone pollution area to be detected according to the indication space distribution map and the reference space distribution map; determining a judgment threshold value of the target indicator and a transition region corresponding to the judgment threshold value according to the target indicator, wherein the judgment threshold value is determined according to the target indicatorThe ratio of the rate of change to the indicator yield was generated for the determination. The method and the device have the advantages that the target indicator suitable for the ozone pollution place to be detected is accurately determined according to different actual pollution conditions of different ozone pollution places to be detected, so that the judgment threshold value of the target indicator is obtained, and the effectiveness and the accuracy of the ozone pollution treatment of the pollution places are further improved.
Description
Technical Field
The invention relates to the technical field of environmental pollution treatment, in particular to an ozone generation sensitivity indicator, and a determination method and a determination device thereof.
Background
Ozone pollution is receiving increasing attention as one of environmental pollution. Ozone is formed by irradiating nitrogen oxides and hydrocarbons in the atmosphere with the sun to cause optical reactions. Normal ozone in the atmosphere can absorb most of the short-wavelength radiation, raise the temperature of the atmosphere, and protect the living things on earth from excessive ultraviolet rays, so it is called "umbrella for protecting living things on earth".
However, atmospheric ozone pollution is in an aggravating situation, ozone near the ground is an air pollutant generated secondarily after photochemical reaction, the ozone serves as a strong oxidant, the distribution and change of the ozone in a troposphere directly influence the concentration and service life of other chemical substances, free radicals and the like, and the temperature structure of the troposphere is changed by absorbing ultraviolet light of solar radiation, so that the circulation and balance of atmospheric chemistry are influenced.
For the problem of ozone pollution, the problem of sensitivity of ozone photochemical reaction is needed, namely, volatile organic compounds (according to the main components participating in the process of ozone photochemical reaction: () Nitrogen oxide(s) (iii)) And the ozone precursor is more sensitive and is easier to form the problem of ozone chemical pollution. However, prior art observation-based research methods use a large number of observation-based research methodsEvaluation of dataDischarging andthe effect of emission reduction is realized by emission, and the effect that the concentration of ozone can reach the standard cannot be predictedDischarging andthe specific reduction of emissions. Or using nested grid air quality prediction mode NAQPMS or other numerical modes, based on the study of source emission, using modification of emission list, e.g. reduction of ozone precursor in a specific proportion、Etc. to simulate the generation response of the ozone concentration to judge which substance is more easily controlled. However, the method consumes a great deal of computing resources and computing time for the calculation of the ozone generation sensitivity and the precursor control ratio, and has no wide usability and good timeliness.
Disclosure of Invention
The invention provides an ozone generation sensitivity indicator, and a determination method and a determination device thereof, which are used for improving the accuracy of determining a target indicator suitable for an ozone pollution area to be detected according to different actual pollution conditions of different ozone pollution areas to be detected, further obtaining a judgment threshold value of the target indicator, and further improving the effectiveness and accuracy of the ozone pollution control of the pollution areas.
In a first aspect, embodiments of the present invention provide a method for determining an ozone generation sensitivity indicator, including:
acquiring a reference space distribution map corresponding to an ozone pollution place to be detected, wherein the reference space distribution map simulates a space distribution map of the ozone concentration change of the ozone pollution place to be detected according to a preset emission pollution source test and a reference test;
generating an indication space distribution diagram corresponding to each indicator according to the reference test, wherein the indication space distribution diagram is used for respectively generating space distribution diagrams corresponding to the indicator concentration change based on the reference test;
and determining the target indicator corresponding to the ozone pollution area to be detected according to the indication space distribution map and the reference space distribution map.
In an alternative embodiment, after determining the corresponding target indicator to be detected for ozone contamination, the method further comprises: determining a judgment threshold value of the target indicator and a transition region corresponding to the judgment threshold value according to the target indicator, wherein the judgment threshold value is determined according to the target indicatorThe ratio of the rate of change to the indicator yield was generated for the determination.
In an alternative embodiment, obtaining a corresponding reference spatial profile of the site to be tested for ozone contamination comprises:
according to the benchmark test, obtaining a first space distribution map of the to-be-detected ozone polluted area;
generating a second spatial distribution map of the to-be-detected ozone-polluted site according to the preset emission pollution source test;
and generating the reference spatial distribution map according to the first spatial distribution map and the second spatial distribution map.
In an alternative embodiment, determining the target indicator corresponding to the ozone contamination to be detected according to the indication spatial distribution map and the reference spatial distribution map includes:
matching each indicated spatial distribution map with the reference spatial distribution map respectively;
and if the indication space distribution diagram is matched with the reference space distribution diagram, obtaining the target indicator corresponding to the indication space distribution diagram.
In an alternative embodiment, determining the decision threshold for the target indicator comprises:
obtaining the emission according to the preset emission pollution source testGenerating a scatter diagram of the corresponding relation between the change rate and each indicator;
comparing the scatter diagram to obtain theGenerating a change scatter value of the rate of change with the indicator;
and determining a judgment threshold value of the target indicator corresponding to the area to be detected with ozone pollution according to the change scatter value.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further includes:
obtaining a scatter value corresponding to the target indicator in the same group of preset emission pollution source tests,
and if the difference between the scatter value corresponding to the target indicator in the first preset emission pollution source test in the same group of preset emission pollution source tests and the scatter value corresponding to the target indicator in the second preset emission pollution source test in the same group of preset emission pollution source tests meets a preset threshold range, determining a transition area corresponding to the judgment threshold.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further comprises:
and obtaining pollution source treatment guidance conditions corresponding to the to-be-detected ozone pollution area according to the judgment threshold value.
in a second aspect, embodiments of the present invention provide an ozone generation sensitivity indicator based on the determination in the first aspect, the ozone generation sensitivity indicator beingThe judgment threshold value of the ozone generation sensitivity indicator comprises0.19 and 0.42, the transition region corresponding to the judgment threshold value comprisesIs 0.19-0.42.
In a third aspect, an embodiment of the present invention provides an apparatus for determining an ozone generation sensitivity indicator, including:
the acquisition module is used for acquiring a reference spatial distribution map corresponding to an ozone pollution place to be detected, and the reference spatial distribution map simulates a spatial distribution map of the ozone concentration change of the ozone pollution place to be detected according to a preset emission pollution source test and a reference test;
the generating module is used for generating an indication space distribution map corresponding to each indicator according to the benchmark test;
and the determining module is used for determining the target indicator corresponding to the ozone pollution area to be detected according to the indication space distribution map and the reference space distribution map.
In an alternative embodiment, after determining the corresponding target indicator to be detected for ozone contamination, the method further comprises: determining a judgment threshold value of the target indicator and a transition region corresponding to the judgment threshold value according to the target indicator, wherein the judgment threshold value is determined according to the target indicatorThe ratio of the rate of change to the indicator yield was generated for the determination.
In an optional embodiment, the obtaining module is specifically configured to:
according to the benchmark test, obtaining a first space distribution map of the to-be-detected ozone polluted area;
generating a second spatial distribution map of the to-be-detected ozone-polluted site according to the preset emission pollution source test;
and generating the reference spatial distribution map according to the first spatial distribution map and the second spatial distribution map.
In an optional embodiment, the determining module is specifically configured to:
matching each indicated spatial distribution map with the reference spatial distribution map respectively;
and if the indication space distribution diagram is matched with the reference space distribution diagram, obtaining the target indicator corresponding to the indication space distribution diagram.
In an alternative embodiment, determining the decision threshold for the target indicator comprises:
obtaining the emission according to the preset emission pollution source testGenerating a scatter diagram of the corresponding relation between the change rate and each indicator;
comparing the scatter diagram to obtain theGenerating a change scatter value of the rate of change with the indicator;
and determining a judgment threshold value of the target indicator corresponding to the area to be detected with ozone pollution according to the change scatter value.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further includes:
obtaining a scatter value corresponding to the target indicator in the same group of preset emission pollution source tests,
and if the difference between the scatter value corresponding to the target indicator in the first preset emission pollution source test in the same group of preset emission pollution source tests and the scatter value corresponding to the target indicator in the second preset emission pollution source test in the same group of preset emission pollution source tests meets a preset threshold range, determining a transition area corresponding to the judgment threshold.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further comprises:
and obtaining pollution source treatment guidance conditions corresponding to the to-be-detected ozone pollution area according to the judgment threshold value.
in a fourth aspect, embodiments of the present invention provide a system for determining an ozone generation sensitivity indicator, comprising: a storage and processor having stored therein executable instructions of the process; wherein the processor is configured to perform the method of determining an ozone generation sensitivity indicator of any one of the first aspect via execution of the executable instructions.
In a fifth aspect, embodiments of the present invention provide a computer-readable storage medium, on which a computer program is stored, which when executed by a processor, implements the method for determining an ozone generation sensitivity indicator according to any one of the first aspect.
The invention provides an ozone generation sensitivity indicator, a determination method and a device thereof, wherein the method comprises the following steps: acquiring a reference space distribution map corresponding to an ozone pollution place to be detected, wherein the reference space distribution map simulates a space distribution map of the ozone concentration change of the ozone pollution place to be detected according to a preset emission pollution source test and a reference test; generating an indication space distribution map corresponding to each indicator according to the benchmark test; determining a target indicator corresponding to the ozone pollution area to be detected according to the indication space distribution map and the reference space distribution map; determining a judgment threshold value of the target indicator and a transition region corresponding to the judgment threshold value according to the target indicator, wherein the judgment threshold value is used for judging whether the target indicator is in a transition region or notCutoff threshold value according toThe ratio of the rate of change to the indicator yield was generated for the determination. The method and the device have the advantages that the target indicator suitable for the ozone pollution place to be detected is accurately determined according to different actual pollution conditions of different ozone pollution places to be detected, so that the judgment threshold value of the target indicator is obtained, and the effectiveness and the accuracy of the ozone pollution treatment of the pollution places are further improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a diagram of an exemplary application scenario of the present invention;
FIG. 2 is a flow chart of a method for determining an ozone generation sensitivity indicator provided by an embodiment of the present invention;
fig. 3a) is a first schematic view of a reference spatial distribution corresponding to a predetermined emission pollutant test according to an embodiment of the present invention;
fig. 3b) is a schematic view of a reference spatial distribution corresponding to a preset emission pollution source test according to an embodiment of the present invention;
FIG. 4a) is a schematic illustration showing a corresponding indicating space distribution of an indicator according to an embodiment of the present invention;
FIG. 4b) is a schematic illustration of a corresponding indicating spatial distribution of an indicator according to an embodiment of the present invention;
FIG. 4c) is a schematic illustration showing a corresponding indicating spatial distribution of an indicator according to an embodiment of the present invention;
FIG. 4d) is a schematic illustration of a corresponding indicating spatial distribution of an indicator according to an embodiment of the present invention;
FIG. 5a) is a schematic diagram of an embodiment of the present inventionGenerating a first schematic diagram of the change rate and the change scatter of the indicator;
FIG. 5b) is a schematic diagram of an embodiment of the present inventionGenerating a second schematic diagram of the change rate and the change scatter of the indicator;
FIG. 5c) is a schematic diagram of an embodiment of the present inventionGenerating a scatter plot schematic diagram III of the change rate along with the change of the indicator;
FIG. 5d) is a drawing provided by an embodiment of the present inventionGenerating a change scatter diagram of the change rate and the indicator;
FIG. 6 is a schematic diagram of an apparatus for determining an ozone generation sensitivity indicator according to an embodiment of the present invention;
FIG. 7 is a schematic diagram of a system for determining an ozone generation sensitivity indicator according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The terms "first," "second," "third," "fourth," and the like in the description and in the claims, as well as in the drawings, if any, are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It is to be understood that the data so used is interchangeable under appropriate circumstances such that the embodiments of the invention described herein are, for example, capable of operation in sequences other than those illustrated or otherwise described herein. Furthermore, the terms "comprises," "comprising," and "having," and any variations thereof, are intended to cover a non-exclusive inclusion, such that a process, system, article, or apparatus that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed, but may include other steps or elements not expressly listed or inherent to such process, article, or apparatus.
The following describes the technical solutions of the present invention and how to solve the above technical problems with specific embodiments. The following several specific embodiments may be combined with each other, and details of the same or similar concepts or processes may not be repeated in some embodiments. Embodiments of the present invention will be described below with reference to the accompanying drawings.
Ozone generation sensitivity is a nonlinear chemical and kinetic mechanism of action between a precursor and a product in a photochemical reaction system mainly composed of ozone and the precursor thereof, and the response rule of the product to the change of the concentration of the precursor or source emission. The control of photochemical smog pollution is mainly carried out by a way of controlling ozone precursor, so that the research on the sensitivity of ozone to the emission of the precursor is of great significance to the establishment of relevant control policies. However, prior art observation-based research methods use a large number of observation-based data sources for evaluationDischarging andthe effect of emission reduction is realized by emission, and the effect that the concentration of ozone can reach the standard cannot be predictedDischarging andthe specific reduction of emissions. Or using nested grid air quality prediction mode NAQPMS or other numerical modes, based on the study of source emission, using modification of emission list, e.g. reduction of ozone precursor in a specific proportion、Etc. to simulate the generation response of the ozone concentration to judge which substance is more easily controlled. However, the method consumes a great deal of computing resources and computing time for the calculation of the ozone generation sensitivity and the precursor control ratio, and has no wide usability and good timeliness.
Fig. 1 is a typical application scenario diagram of the present invention, as shown in fig. 1, detection is performed by an ozone generation sensitivity indicator determination system 11, so as to accurately determine a target indicator suitable for a to-be-detected ozone pollution site according to different actual pollution conditions of different to-be-detected ozone pollution sites, and further obtain a determination threshold of the target indicator, thereby further improving effectiveness and accuracy of the pollution site in ozone pollution treatment.
Fig. 2 is a flowchart of a method for determining an ozone generation sensitivity indicator according to an embodiment of the present invention, and as shown in fig. 2, the method for determining an ozone generation sensitivity indicator according to the embodiment may include:
s201, obtaining a reference space distribution map corresponding to the ozone pollution area to be detected, and simulating the space distribution map of the ozone concentration change of the ozone pollution area to be detected according to a preset emission pollution source test and a reference test by using the reference space distribution map.
Specifically, on the basis of the air quality numerical mode NAQPMS, a first spatial distribution map corresponding to the average ozone concentration change of the ozone pollution site to be detected is obtained through a benchmark test for detecting 100% emission of each pollution source, and the first spatial distribution map is respectively detected50% reduction of pollution source and passing detectionIn an optional implementation, a reference spatial distribution map is generated according to a variation difference value of the average ozone concentration in the first spatial distribution map and the average ozone concentration in the second spatial distribution map, and the reference spatial distribution map is used for displaying the variation of the average ozone concentration in the corresponding second spatial distribution map and the average ozone concentration in the first spatial distribution map. So as to obtain the corresponding target indicator of the ozone pollution to be detected by comparing with the reference space distribution diagram.
And S202, generating an indication space distribution map corresponding to each indicator according to the reference test, wherein the indication space distribution map is used for generating a space distribution map corresponding to the indicator concentration change based on the reference test.
In the embodiment, the average concentration of each indicator in the benchmark test in the high-value period of the ozone pollution area to be detected is detected, so that the indication space distribution map corresponding to each group of indicators is generated. And then determining the corresponding target indicator of the ozone pollution to be detected through the indicating space distribution diagram and the reference space distribution diagram.
S203, determining a target indicator corresponding to the ozone pollution area to be detected according to the indication space distribution map and the reference space distribution map.
With reference to the above example, the present embodiment performs detection on the indication spatial distribution map and the reference spatial distribution map corresponding to each indicator, and if it is detected that there is a match between one indication spatial distribution map and the reference spatial distribution map (in an alternative embodiment, the match between the indication spatial distribution map and the reference spatial distribution map may be obtained by analyzing similarity or consistency of correspondence between image content, features, structures, relationships, textures, that is, gray levels, and the like), then the target indicator corresponding to the indication spatial distribution map is obtained. So that the treatment guidance of the ozone pollution to be detected can be carried out according to the target indicator.
According to the embodiment, the target indicator suitable for the ozone pollution place to be detected can be accurately determined according to different actual pollution conditions of different ozone pollution places to be detected, so that the judgment threshold value of the target indicator is obtained, and the effectiveness and the accuracy of the ozone pollution treatment of the pollution places are further improved.
In an alternative embodiment, after determining the corresponding target indicator to be tested for ozone contamination, further comprising: s204, determining a judgment threshold value of the target indicator and a transition region corresponding to the judgment threshold value according to the target indicator. With particular reference to FIG. 2, wherein the decision threshold is based onIs determined by generating a ratio of the rate of change to the indicator yield, whereinMay compriseAnd. In an alternative embodiment of the method according to the invention,in relation to each indicator, e.g.Sensitivity andis concentration dependent or isSensitivity and (A) to-)、/And/are related to, or areSensitivity andandthe present invention is mainly described in detail by taking the above-mentioned examples and other related examples as examples, and in an alternative embodiment, the target indicator and the target indicator are usedCorrelation relationships, e.g. according toThe ratio of the change rate to the indicator yield is generated for determinationDetermining a judgment threshold, and further obtaining a judgment threshold of the target indicator and a transition region corresponding to the judgment threshold, specifically referring to the description of the subsequent embodiment. The embodiment also comprises a judgment threshold value for determining the target indicator after determining the target indicator corresponding to the ozone pollution area to be detected, and the judgment threshold value is based on(can represent+) The correlation with each indicator was obtained. Wherein the indicator may include:/、/、/、. WhereinRepresents NO and,to representNitric acid, nitrate.
The target indicator suitable for the ozone pollution site to be detected is accurately determined according to the actual pollution conditions of different ozone pollution sites to be detected (such as xxx), for example,. To obtain a threshold value for the target indicator, e.g., whenWhen less than A, ozone is generatedControl, greater than B isControl in which the transition zone between A and B isAndand jointly controlling, so that a transition area corresponding to the judgment threshold is A-B, and B is larger than A. Further improving the effectiveness and accuracy of the pollution land for ozone pollution treatment. In an alternative embodiment, a is 0.19 and B is 0.42.
With reference to the embodiment shown in fig. 2, obtaining a reference spatial distribution map corresponding to the area to be detected with ozone pollution can be further achieved by specifically obtaining a first spatial distribution map of the area to be detected with ozone pollution according to a benchmark test; generating a second spatial distribution map of the to-be-detected ozone-polluted site according to a preset emission pollution source test; and generating a reference spatial distribution map according to the first spatial distribution map and the second spatial distribution map.
In this embodiment, based on the air quality numerical mode NAQPMS, a first spatial distribution map corresponding to the ozone pollution area to be detected is obtained by a benchmark test for detecting 100% emission of each pollution source, a second spatial distribution map of the ozone pollution area to be detected is generated by respectively setting a pollution source test for reducing 50% emission and a pollution source test for reducing 50% emission, and then a spatial distribution map of average ozone concentration change in a high-value period of the ozone pollution area to be detected is respectively generated by the first spatial distribution map and the second spatial distribution map corresponding to each preset emission pollution source test, that is, a reference spatial distribution map is obtained. This embodiment reduces the discharge amount by only 50%Pollution source test and 50% reduction of emissionsFor example, the pollution source test generates a corresponding second spatial distribution diagram, and further generates a first reference spatial distribution diagram and a second reference spatial distribution diagram according to the corresponding second spatial distribution diagram, for example, see fig. 3a) and fig. 3b), and the depth in fig. 3a) and fig. 3b) represents the difference of the average ozone concentration difference. FIG. 3a) is a first schematic view of a reference spatial distribution corresponding to a predetermined emission pollution source test according to an embodiment of the present invention, wherein the predetermined emission pollution source test is reduced by 50%The emission source test of (1); FIG. 3b) is a schematic diagram of a reference spatial distribution corresponding to a preset emission pollution source test according to an embodiment of the present invention, wherein the preset emission pollution source test is reduced by 50%The emission source test of (1). However, this embodiment is not limited thereto.
In an alternative implementation, the reference spatial profile is generated based on a difference in the variation of the average ozone concentration in the first spatial profile and the average ozone concentration in the second spatial profile. With reference to the embodiment shown in fig. 2, determining the target indicator corresponding to the ozone pollution area to be detected according to the indication space distribution map and the reference space distribution map can be implemented by respectively matching each indication space distribution map with the reference space distribution map; and if the detection indication space distribution diagram is matched with the reference space distribution diagram, obtaining the target indicator corresponding to the indication space distribution diagram.
In this embodiment, the indication spatial distribution map is matched with the reference spatial distribution map, and if one indication spatial distribution map is matched with the reference spatial distribution map, the target indicator corresponding to the indication spatial distribution map is obtained. For example, refer to fig. 4a), 4b), 4c), 4d) to show the indication spatial distribution maps corresponding to different indicators, and fig. 4a) is a schematic view of the indication spatial distribution map corresponding to an indicator according to an embodiment of the present invention, wherein the indicator is/,For representingAndthe yield ratio of (a); FIG. 4b) is a schematic view of a corresponding indicating space distribution of an indicator according to an embodiment of the present invention, wherein the indicator is/,P()/P() For representingAndthe yield ratio of (a); FIG. 4c) is a schematic view showing a corresponding indicating space distribution of an indicator according to an embodiment of the present invention, wherein the indicator is/,P()/P() For representingAndthe yield ratio of (a); FIG. 4d) is a schematic view of a corresponding indicating space distribution of an indicator according to an embodiment of the present invention, wherein the indicator is, P() For representingThe yield value of (a). From the above-described fig. 4a) to 4d), it can be derived that fig. 4a) matches fig. 3a)Thus, the target indicator corresponding to FIG. 4a) can be obtained as/. Similarly, the indicated spatial profiles were obtained from baseline tests (i.e., 100% emissions source tests) using the above-described indicator yield ratios. In an alternative embodiment, the matching of the indication spatial distribution map and the reference spatial distribution map may be obtained by analyzing similarity or consistency of correspondence between image content, features, structures, relationships, textures, i.e. gray scales, and the like.
In an alternative embodiment, determining the decision threshold corresponding to the target indicator includes: obtaining according to a preset emission pollution source testGenerating a scatter diagram of the corresponding relation between the change rate and each indicator; comparing scatter diagrams to obtainGenerating a change scatter value of the rate of change with the indicator; and determining a judgment threshold value of the target indicator corresponding to the area to be detected with ozone pollution according to the change scatter value.
In the experiment of analyzing each preset emission pollution source in the embodimentAnd generating a corresponding relation between the change rate and each indicator, and determining a judgment threshold value of the target indicator corresponding to the area to be detected with ozone pollution. Specially tested according to predetermined sources of emissions, e.g. reduced by 50%Pollution source test and 50% reduction of emissionsPollution source test in which preset discharge amount of pollution source is obtainedThe generation change rate of (2) is specifically realized by the following formula I.
Andrespectively representing the preset emission pollution source test and the benchmark testThe concentration of (c). And can further obtainA scatter plot of the change rate versus the indicator is generated (in an alternative embodiment, the yield ratio in each indicator is plotted on the abscissa,generating a scatter plot with the rate of change as the ordinate); by analytically comparing these scatter plots, a scatter plot is obtainedAnd generating a change scatter value of which the change rate is changed along with the indicator, and determining a judgment threshold value of the ozone pollution source to be detected corresponding to the target indicator according to the change scatter value. For example, refer to fig. 5a), fig. 5b), fig. 5c), fig. 5d), fig. 5a) is provided for an embodiment of the present inventionGenerating a rate of change and indicationFIG. 5b) is a schematic view of the variation of the first agentGenerating a second schematic diagram of the change scatter of the rate of change and indicator, FIG. 5c) providing a second schematic diagram of the change scatter of the indicatorGenerating a scatter plot of the change rate with indicator III, FIG. 5d) is provided for an embodiment of the present inventionAnd generating a change scatter diagram of the change rate and the indicator.
As can be seen from FIG. 5a), the reduction is 50%In the tests, it was determined that,rate of change of formation withThe ratio is increased by increasing, i.e. gradually increasing from the initial negative percentage in reference to fig. 5a), andthe degree of control becomes gradually weaker and becomes subjectControlling; but is reduced by 50 percentIn the tests, it was determined that,rate of change of formation withThe ratio increases and decreases, in particular with reference to fig. 5a), from an initial positive percentage to a negative percentage. This illustratesHas good correlation with the generation of ozone. In addition, referring to fig. 5b), fig. 5c),/and/also have the following effectsSimilar trend, but the correlation is not significant, and it cannot be directly judgedAndthe threshold of the control zone. See, for example, FIG. 5d)Andthe correlation of the rate of change of the generation is very weak. Thus from P: () Rate of change andcan calculate the correlationThe judgment threshold value of (1). In an alternative embodiment, referring to FIG. 5a), the reduction is 50%The test sum is reduced by 50 percentIn the tests, it was determined that,followed byThe ratio is in a linear change trend, and then a change scatter point value of the change trend turning of the scatter diagram can be obtained to obtain a judgment threshold corresponding to the target indicator, so as to determine the judgment threshold corresponding to the target indicator of the ozone pollution to be detected, and in an alternative embodiment, the judgment threshold may include 0.19 and 0.42.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further comprises: and obtaining a scatter value corresponding to the target indicator in the same group of preset emission pollution source tests, and if the difference between the scatter value corresponding to the target indicator in the first preset emission pollution source test in the same group of preset emission pollution source tests and the scatter value corresponding to the target indicator in the second preset emission pollution source test in the same group of preset emission pollution source tests meets a preset threshold range, determining a transition region corresponding to the judgment threshold.
E.g. by 50%Tested and reduced by 50%The test is the same group of preset emission pollution source tests, and P (in) of the two preset emission pollution source tests relative to a reference test is set) The transition zone is the change rate less than 10% (namely the preset threshold range). For example, whenEqual to 0.2, reduced by 50%Test average P: () The change rate is-35 percent and is reduced by 50 percentTest average P: () The rate of change is-36%, and the difference is 1%, thenEqual to 0.2 belongs to the transition zone and so on. Thus, the decision thresholds for the two transition regions of 0.19 and 0.42 (see FIG. 5a) can be obtained whenWhen the ozone concentration is less than 0.19, ozone is generatedControl, greater than 0.42 isControl, the transition zone between 0.19 and 0.42 is influencedAndjointly controlling to obtain a transition region corresponding to the judgment threshold value。
In this embodiment, the target indicator suitable for the place to be detected with ozone pollution is accurately determined according to the actual pollution conditions of different places to be detected with ozone pollution, such asAnd then obtaining a judgment threshold value of the target indicator, for example, whenWhen the ozone concentration is less than 0.19, ozone is generatedControlled to be greater than 0.42, and the transition region between 0.19 and 0.42 is controlledAndand (4) controlling together. Further improving the effectiveness and accuracy of the pollution land for ozone pollution treatment.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further comprises: and obtaining pollution source treatment guidance conditions corresponding to the ozone pollution area to be detected according to the judgment threshold value.
For example, in connection with the above examples, whenWhen the ozone concentration is less than 0.19, ozone is generatedControl, greater than 0.42 isControl, intermediate transition zone being subject toAndand (4) controlling together. Namely, accurate and effective pollution treatment guidance can be realized through the judgment threshold value of the target indicator, and then controllable treatment of ozone pollution and the like can be realized.
In an alternative embodiment, the indicator comprises at least one of the following groups/、/、/、Wherein the indicator refers to an ozone generation sensitive indicator. Based on the large number of studies of formation sensitive indicators available in the recent past, table 1 summarizes several of the indicators described above, see table 1 in particular.
TABLE 1
aSielman suggests 0.35 as a decision threshold, while Tonnesen and Dennis suggestRatio of<0.06、0.06-0.2、>0.2 respectively asControl zone, transition zone andthe threshold of the control zone.
bSillman suggests 0.28 as a decision threshold, while Lu and Chang (1998) considers 0.5-0.9 as a decision threshold.
According to the analysis of the mechanism of photochemical reaction, whenIn excess, free radicals () The termination reaction of (a) is:
at this timeThe rate of generation is governed by the rate of generation of free radicals,generating a recipientControl, therefore, ofCan be used asA controlled indicator. When in useWhen the degree of vacancy is low, the reaction between free radicals controlsRemoving:
at this timeThe generation rate is subject toAndthe concentration level of the NO reacted is limited byAnd (5) controlling. Thus the yield of ROOH and HOOH can be usedAn indication of control. Sillman (1995) suggested useAndas a ratio of the yield ofGenerating a recipientControl orControl judgment threshold:
in the formula:andare respectivelyAndthe yield of (a). I.e. the ratioIn excess of 0.35 of the total weight of the composition,generating a recipientControlling; the ratio is less than 0.35, and the ratio is less than 0.35,to be receivedAnd (5) controlling.
(Tonnesen and Dennis, 2000a) showed that HCHO @As an indicator of the sensitivity of ozone generation, it is considered that when the ratio is more than 1, ozone generation is affectedControlling the ozone generation when the ratio is less than 1And (5) controlling. (Witte et al, 2011) study of the Beijing Olympic Games period HCHO/Is considered to be HCHOCan be used as indicator for judging ozone generation sensitivity.
(Milford et al, 1994) et al use regional air quality models to demonstrateSensitivity and afternoonThe concentration of the water is correlated with the concentration of the water,can be used asProducing a sensitive indicator. (Sillman, 1995) further developed the sense of the indicator species, suggesting a ratio of 3/()、HCHO/And/can also be used asProducing a sensitive indicator. The result of the model shows thatA control area, the ratio being relatively large; in addition, theA control region, the ratio being small; in the region of the transition zone,/()=8~10、HCHO/=0.2 ~ 0.39 and/=0.25~0.6。
however, the existing indicator and the corresponding judgment threshold thereof cannot flexibly adapt to the treatment of ozone pollution conditions in different regions, different seasons and other time periods in the same region.
According to the embodiment, the target indicator suitable for the ozone pollution place to be detected is accurately determined according to different actual pollution conditions of the ozone pollution place to be detected, so that the judgment threshold value of the target indicator is obtained, and the effectiveness and the accuracy of the ozone pollution treatment of the pollution place are further improved.
Fig. 6 is a schematic structural diagram of an apparatus for determining an ozone generation sensitivity indicator according to an embodiment of the present invention, and as shown in fig. 6, the apparatus for determining an ozone generation sensitivity indicator according to the embodiment may include:
the acquisition module 31 is configured to acquire a reference spatial distribution map corresponding to the ozone pollution site to be detected, where the reference spatial distribution map simulates a spatial distribution map of ozone concentration change of the ozone pollution site to be detected according to a preset emission pollution source test and a reference test;
a generating module 32, configured to generate an indication spatial distribution map corresponding to each indicator according to the benchmark test;
and the determining module 33 is configured to determine the target indicator corresponding to the ozone pollution area to be detected according to the indication spatial distribution map and the reference spatial distribution map.
In an alternative embodiment, referring to fig. 6, further comprising: a obtaining module 34, configured to determine a judgment threshold of the target indicator and a transition region corresponding to the judgment threshold according to the target indicator, where the judgment threshold is determined according toThe ratio of the rate of change to the indicator yield was generated for the determination.
In an alternative embodiment, the obtaining module 31 is specifically configured to:
according to a reference test, obtaining a first spatial distribution map of a to-be-detected ozone polluted area;
generating a second spatial distribution map of the to-be-detected ozone-polluted site according to a preset emission pollution source test;
and generating a reference spatial distribution map according to the first spatial distribution map and the second spatial distribution map.
In an alternative embodiment, the determining module 33 is specifically configured to:
matching each indication space distribution map with a reference space distribution map respectively;
and if the detection indication space distribution diagram is matched with the reference space distribution diagram, obtaining the target indicator corresponding to the indication space distribution diagram.
In an alternative embodiment, determining the decision threshold for the target indicator comprises:
obtaining according to a preset emission pollution source testGenerating a scatter diagram of the corresponding relation between the change rate and each indicator;
comparing scatter diagrams to obtainGenerating a change scatter value of the rate of change with the indicator;
and determining a judgment threshold value of the target indicator corresponding to the area to be detected with ozone pollution according to the change scatter value.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further comprises:
obtaining a scatter value corresponding to a target indicator in the same group of preset emission pollution source tests,
and if the difference between the scatter value corresponding to the target indicator in the first preset emission pollution source test in the same group of preset emission pollution source tests and the scatter value corresponding to the target indicator in the second preset emission pollution source test in the same group of preset emission pollution source tests meets a preset threshold range, determining a transition area corresponding to the judgment threshold.
In an alternative embodiment, after determining the judgment threshold of the target indicator, the method further comprises:
and obtaining pollution source treatment guidance conditions corresponding to the ozone pollution area to be detected according to the judgment threshold value.
the device for determining the ozone generation sensitivity indicator in this embodiment can implement the technical scheme in the method shown in fig. 2, and the specific implementation process and technical principle thereof are described in relation to the method shown in fig. 2, and are not described herein again.
Fig. 7 is a schematic structural diagram of a system for determining an ozone generation sensitivity indicator according to an embodiment of the present invention, and as shown in fig. 7, a system 40 for determining an ozone generation sensitivity indicator according to this embodiment may include: a processor 41 and a memory 42.
A memory 42 for storing computer programs (such as application programs, functional modules, etc. that implement the above-described method of determining an ozone generation sensitivity indicator), computer instructions, etc.;
the computer programs, computer instructions, etc. described above may be stored in one or more memories 42 in partitions. And the above-mentioned computer program, computer instructions, data, etc. can be called by the processor 41.
A processor 41 for executing the computer program stored in the memory 42 to implement the steps of the method according to the above embodiments.
Reference may be made in particular to the description relating to the preceding method embodiment.
The processor 41 and the memory 42 may be separate structures or may be integrated structures integrated together. When the processor 41 and the memory 42 are separate structures, the memory 42 and the processor 41 may be coupled by a bus 43.
The server in this embodiment may execute the technical solution in the method shown in fig. 2, and for the specific implementation process and the technical principle, reference is made to the relevant description in the method shown in fig. 2, which is not described herein again.
In addition, an embodiment of the present application further provides a computer-readable storage medium, in which computer-executable instructions are stored, and when at least one processor of the user equipment executes the computer-executable instructions, the user equipment performs the above possibilities.
Computer-readable media includes both computer storage media and communication media including any medium that facilitates transfer of a computer program from one place to another. A storage media may be any available media that can be accessed by a general purpose or special purpose computer. An exemplary storage medium is coupled to the processor such the processor can read information from, and write information to, the storage medium. Of course, the storage medium may also be integral to the processor. The processor and the storage medium may reside in an ASIC. Additionally, the ASIC may reside in user equipment. Of course, the processor and the storage medium may reside as discrete components in a communication device.
Those of ordinary skill in the art will understand that: all or a portion of the steps of implementing the embodiments described above may be performed by hardware associated with program instructions. The program may be stored in a computer-readable storage medium. When executed, the program performs the steps comprising the above embodiments; and the aforementioned storage medium includes: various media that can store program codes, such as ROM, RAM, magnetic or optical disks.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Claims (9)
1. A method of determining an ozone-generating susceptibility indicator, comprising:
acquiring a reference space distribution map corresponding to an ozone pollution place to be detected, wherein the reference space distribution map simulates the space distribution map of the ozone concentration change of the ozone pollution place to be detected according to a preset emission pollution source test and a benchmark test, and the benchmark test comprises the step of detecting each pollutionTesting the source 100% emissions, said predetermined emissions test comprising separately passing the test50% reduction of pollution source and passing detectionTesting for reducing 50% of emission of pollution sources;
generating an indication space distribution map corresponding to each group of indicators by detecting the average concentration of each indicator in the benchmark test in a high-value time period of the ozone pollution source to be detected;
determining a target indicator corresponding to the ozone pollution area to be detected according to the indication space distribution map and the reference space distribution map;
wherein, according to the indication space distribution diagram and the reference space distribution diagram, determining the target indicator corresponding to the ozone pollution area to be detected comprises:
matching each indicated spatial distribution map with the reference spatial distribution map respectively;
and if the indication space distribution diagram is matched with the reference space distribution diagram, obtaining the target indicator corresponding to the indication space distribution diagram.
2. The method of claim 1, further comprising, after determining the corresponding target indicator to be tested for ozone contamination:
determining a judgment threshold value of the target indicator and a transition region corresponding to the judgment threshold value according to the target indicator, wherein the judgment threshold value is determined according to the target indicatorThe ratio of the rate of change to the indicator yield was generated for the determination.
3. The method of claim 1, wherein obtaining a corresponding reference spatial profile of the site to be tested for ozone contamination comprises:
according to the benchmark test, obtaining a first space distribution map of the to-be-detected ozone polluted area;
generating a second spatial distribution map of the to-be-detected ozone-polluted site according to the preset emission pollution source test;
and generating the reference spatial distribution map according to the first spatial distribution map and the second spatial distribution map.
4. The method of any one of claims 1-3, wherein determining the decision threshold for the target indicator comprises:
obtaining the emission according to the preset emission pollution source testGenerating a scatter diagram of the corresponding relation between the change rate and each indicator;
comparing the scatter diagram to obtain theGenerating a change scatter value of the rate of change with the indicator;
and determining a judgment threshold value of the target indicator corresponding to the area to be detected with ozone pollution according to the change scatter value.
5. The method of claim 4, further comprising, after determining the decision threshold for the target indicator:
obtaining a scatter value corresponding to the target indicator in the same group of preset emission pollution source tests,
and if the difference between the scatter value corresponding to the target indicator in the first preset emission pollution source test in the same group of preset emission pollution source tests and the scatter value corresponding to the target indicator in the second preset emission pollution source test in the same group of preset emission pollution source tests meets a preset threshold range, determining a transition area corresponding to the judgment threshold.
6. The method of claim 4, further comprising, after determining the decision threshold for the target indicator:
and obtaining pollution source treatment guidance conditions corresponding to the to-be-detected ozone pollution area according to the judgment threshold value.
8. the method of claim 1, wherein the ozone generation sensitivity indicator is/A judgment threshold value of the ozone generation sensitivity indicator0.19 and 0.42, the transition region corresponding to the judgment threshold value0.19 to 0.42, whenWhen the ozone concentration is less than 0.19, ozone is generatedControl whenGreater than 0.42, ozone generation is affectedControl when0.19-0.42, ozone generation is receivedAndand (4) controlling together.
9. An apparatus for determining an ozone-generating susceptibility indicator, comprising:
the acquisition module is used for acquiring a reference space distribution map corresponding to the ozone pollution area to be detected, the reference space distribution map simulates the space distribution map of the ozone concentration change of the ozone pollution area to be detected according to a preset emission pollution source test and a benchmark test, wherein the benchmark test comprises the step of detecting each pollution areaTesting the 100% emission of the dye source, wherein the preset emission test comprises respectively passing detection50% reduction of pollution source and passing detectionTesting for reducing 50% of emission of pollution sources;
the generation module is used for generating an indication space distribution map corresponding to each group of indicators by detecting the average concentration of each indicator in the benchmark test in the high-value time period of the ozone pollution source to be detected;
the determining module is used for determining the target indicator corresponding to the ozone pollution area to be detected according to the indicating space distribution map and the reference space distribution map;
wherein, according to the indication space distribution diagram and the reference space distribution diagram, determining the target indicator corresponding to the ozone pollution area to be detected comprises:
matching each indicated spatial distribution map with the reference spatial distribution map respectively;
and if the indication space distribution diagram is matched with the reference space distribution diagram, obtaining the target indicator corresponding to the indication space distribution diagram.
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