CN111519436B - Production process of garment fabric added with graphene - Google Patents

Production process of garment fabric added with graphene Download PDF

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CN111519436B
CN111519436B CN202010213596.9A CN202010213596A CN111519436B CN 111519436 B CN111519436 B CN 111519436B CN 202010213596 A CN202010213596 A CN 202010213596A CN 111519436 B CN111519436 B CN 111519436B
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graphene
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CN111519436A (en
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任礼新
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Hefei Clarence Technology Co ltd
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Hefei Clarence Technology Co ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G13/00—Mixing, e.g. blending, fibres; Mixing non-fibrous materials with fibres
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic System
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
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    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a production process of a garment fabric added with graphene, which uses a synthetic fiber raw material and an adhesive fiber raw material as raw materials, obtains raw strips through wool mixing, opening, mixing and carding, then uses copper chloride and a graphene solution for dip-dyeing the raw strips to obtain dip-dyed raw strips, then carries out drawing and weaving, and finally obtains the fabric after washing.

Description

Production process of garment fabric added with graphene
Technical Field
The invention relates to the technical field of garment fabric production, and in particular belongs to a garment fabric production process added with graphene.
Background
Graphene is a two-dimensional carbon nanomaterial and has excellent optical, electrical and mechanical properties, wherein the thermal conductivity of the graphene can reach 5300W/(m.K) at most. Therefore, the graphene is used for producing the clothing fabric, so that the heat conduction performance of the clothing fabric can be remarkably improved, meanwhile, the graphene also has lubricating capability, the smoothness and wear resistance of the fabric can be improved when the graphene is applied to the clothing fabric, in addition, the graphene also has certain antibacterial capability, and the produced fabric has antibacterial performance. However, the graphene and the synthetic fiber fabric have poor fiber bonding capability, are difficult to compound on the synthetic fiber, and the graphene is easy to fall off after washing, so that the durability of the graphene synthetic fiber fabric is low.
Disclosure of Invention
The invention aims to provide a production process of a garment fabric added with graphene, which improves the bonding strength of graphene and synthetic fibers and improves the durability of the graphene synthetic fiber fabric.
In order to solve the problems, the technical scheme adopted by the invention is as follows:
the production process of the garment fabric added with the graphene comprises the following steps of:
(1) The method comprises the steps of blending wool, namely blending wool of a synthetic fiber raw material and a viscose fiber raw material respectively, wherein the synthetic fiber raw material is added with blending wool process oil A in the process of blending wool, and the viscose fiber raw material is added with blending wool process oil B in the process of blending wool;
(2) Opening, namely respectively opening the synthetic fiber raw material and the viscose fiber raw material after the roughening;
(3) Mixing, namely mixing the opened synthetic fiber raw material with the viscose fiber raw material according to the mass ratio of 90-80:10-20 to form a mixed raw material;
(4) Carding, namely carding the mixed raw materials by using a carding machine;
(5) Dip dyeing, namely immersing the raw strips in a copper chloride solution containing 8wt% for 15 minutes, immersing the raw strips in a graphene solution for 2-3 hours, and taking out the raw strips and drying the raw strips at 80 ℃ for 8 hours to obtain dip dyed raw strips;
(6) Drawing, namely drawing the dip-dyed raw strips in a two-way combination mode, feeding 6 strips in each way, and warping after drawing;
(7) Weaving, namely weaving the cooked strips, and washing with water to obtain the fabric.
Preferably, the sum crude process oil A comprises 1.2wt% of sum crude oil AL106, 0.4wt% of polyvinylpyrrolidone, 3.6wt% of carboxyl-terminated polyethylene glycol, 16 wt% of spindle oil and the balance of water; the sum hair process oil B is 4.3wt% of carboxyl-terminated polyethylene glycol, 3.0wt% of span-80 and the balance of silica gel.
Preferably, the graphene solution contains 13% of graphene, 7% of cellulase and the balance of water, wherein the ph=6.5 of the graphene solution and the temperature is 40 ℃.
Preferably, in the step (4), the cylinder speed is 300r/min, the licker-in speed is 700r/min, the doffer speed is 23r/min, and the raw strip ration is 32g/5m.
Preferably, the strip-out speed in the step (6) is 80-85m/min, and the cooked strip evenness CV value is 4.0-4.5%.
Preferably, the synthetic fiber raw material is terylene raw material or chinlon raw material.
Compared with the prior art, the invention has the following implementation effects: in the production process, polyvinylpyrrolidone and carboxyl-terminated polyethylene glycol are added as antistatic agents in the hair mixing process, so that the polyvinylpyrrolidone, the carboxyl-terminated polyethylene glycol and the synthetic fiber raw materials are uniformly mixed, and the surface of the synthetic fiber can uniformly anchor polyvinylpyrrolidone molecules; in the dip dyeing process, copper chloride is complexed with polyvinylpyrrolidone and carboxyl-terminated polyethylene glycol, and part of copper chloride is immersed into the viscose raw material, so that the copper chloride is adsorbed and stably complexed on the raw strips; then after the raw strips are immersed in a graphene solution, carboxyl and hydroxyl on the surface of the graphene are subjected to coordination complexing with copper chloride on polyvinylpyrrolidone and carboxyl-terminated polyethylene glycol, so that the graphene is uniformly adsorbed on the raw strips, and the polyvinylpyrrolidone and the carboxyl-terminated polyethylene glycol play an anchoring role on the graphene on the synthetic fiber raw materials; and as the raw strips are soaked in the graphene solution for a long time, cellulose is soaked in the viscose fiber, and part of the viscose fiber is catalytically decomposed by the cellulose, so that the structural bulkiness between the synthetic fiber raw materials is increased, graphene sheets can enter between the synthetic fiber raw materials, and then after washing, drying and drawing, the bonding strength of graphene on the synthetic fiber raw materials is further enhanced, and the durability of the graphene synthetic fiber fabric is enhanced.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The graphene in the raw materials of the invention adopts LG-1410 nano graphene of Henan Liujia graphite limited company, and the crude oil AL106 adopts products of Fuyang Fuchunjiang chemical limited company, hangzhou.
Example 1
The production process of the garment fabric added with the graphene comprises the following steps of: adding polyester raw material into crude oil A, wherein the crude oil A comprises crude oil AL 106.2 wt%, polyvinylpyrrolidone 0.4wt%, carboxyl-terminated polyethylene glycol 3.6wt%, spindle oil 16 wt% and water for the rest; adding a sum crude process oil B into a viscose raw material, wherein the sum crude process oil B is 4.3wt% of carboxyl-terminated polyethylene glycol, 803.0wt% of span and the balance of silica gel; then, the sum was performed separately. After finishing the wool mixing, respectively opening the polyester raw material and the viscose raw material after the wool mixing; and then mixing the opened terylene raw material and the viscose raw material according to the mass ratio of 90:10 to form a mixed raw material.
Carding the mixed raw materials by using a carding machine, wherein the cylinder speed is 300r/min, the licker-in speed is 700r/min, the doffer speed is 23r/min, and the raw sliver ration is 32g/5m; immersing the obtained raw bar in a copper chloride solution containing 8wt% for 15 minutes, immersing the raw bar in a graphene solution for 2 hours, wherein the graphene solution contains 13% of graphene, 7% of cellulase and the balance of water, wherein the pH=6.5 of the graphene solution is at 40 ℃, and then taking out the raw bar and drying the raw bar at 80 ℃ for 8 hours to obtain the dip-dyed raw bar.
Drawing the dip dyed raw strips in a two-way combination mode, feeding 6 strips in each way, discharging at a strip speed of 80-85m/min, and warping after drawing, wherein the dry CV value of the cooked strips is 4.0-4.5%; and finally, weaving the cooked strips, and washing with water to obtain the fabric.
Example 2
The production process of the garment fabric added with the graphene comprises the following steps of: adding a sum crude process oil A into a chinlon raw material, wherein the sum crude process oil A comprises 1.2wt% of sum crude oil AL 106.2 wt%, 0.4wt% of polyvinylpyrrolidone, 3.6wt% of carboxyl-terminated polyethylene glycol, 16 wt% of spindle oil and the balance of water; adding a sum crude process oil B into a viscose raw material, wherein the sum crude process oil B is 4.3wt% of carboxyl-terminated polyethylene glycol, 803.0wt% of span and the balance of silica gel; then, the sum was performed separately. After finishing the wool mixing, respectively opening the nylon raw material and the viscose raw material after the wool mixing; and then, mixing the loosened nylon raw material and the viscose raw material according to a mass ratio of 85:15 to form a mixed raw material.
Carding the mixed raw materials by using a carding machine, wherein the cylinder speed is 300r/min, the licker-in speed is 700r/min, the doffer speed is 23r/min, and the raw sliver ration is 32g/5m; immersing the obtained raw bar in a copper chloride solution containing 8wt% for 15 minutes, immersing the raw bar in a graphene solution for 3 hours, wherein the graphene solution contains 13% of graphene, 7% of cellulase and the balance of water, wherein the pH=6.5 of the graphene solution is at 40 ℃, and then taking out the raw bar and drying the raw bar at 80 ℃ for 8 hours to obtain the dip-dyed raw bar.
Drawing the dip dyed raw strips in a two-way combination mode, feeding 6 strips in each way, discharging at a strip speed of 80-85m/min, and warping after drawing, wherein the dry CV value of the cooked strips is 4.0-4.5%; and finally, weaving the cooked strips, and washing with water to obtain the fabric.
Comparative example 1
The difference from example 1 is that no polyvinylpyrrolidone is present in the crude process oil a.
Comparative example 2
The difference from example 1 is that the green strip was immersed in a 0wt% copper chloride solution for 15 minutes and then immersed in the graphene solution for 2 to 3 hours.
Comparative example 3
The difference from example 1 is that there is no cellulase in the graphene solution.
The fabrics of examples 1-2 and comparative examples 1-3 were tested for thermal conductivity using a TC3000 hot wire thermal conductivity meter, and the results are shown in the following table:
the magnitude of the heat conductivity coefficient represents the loading amount of the graphene on the fabric, and the larger the loading amount is, the larger the heat conductivity coefficient of the fabric is. From the table, the anchoring effect of polyvinylpyrrolidone on the synthetic fiber raw material effectively improves the adsorption capacity of raw strips to graphene and the stability of the graphene on the fabric, the coordination effect of copper chloride and polyvinylpyrrolidone further improves the loading capacity of the graphene on the raw strips, and the combination of cellulase and viscose fiber raw material in the raw strips obviously improves the firmness of the graphene loaded on the raw strips.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (1)

1. The production process of the garment fabric added with the graphene is characterized by comprising the following steps of:
(1) The method comprises the steps of blending wool, namely blending wool of a synthetic fiber raw material and a viscose fiber raw material respectively, wherein the synthetic fiber raw material is added with blending wool process oil A in the process of blending wool, and the viscose fiber raw material is added with blending wool process oil B in the process of blending wool;
(2) Opening, namely respectively opening the synthetic fiber raw material and the viscose fiber raw material after the roughening;
(3) Mixing, namely mixing the opened synthetic fiber raw material with the viscose fiber raw material according to the mass ratio of 90-80:10-20 to form a mixed raw material;
(4) Carding, namely carding the mixed raw materials by using a carding machine;
(5) Dip dyeing, namely immersing the raw strips in a copper chloride solution containing 8wt% for 15 minutes, immersing the raw strips in a graphene solution for 2-3 hours, and taking out the raw strips and drying the raw strips at 80 ℃ for 8 hours to obtain dip dyed raw strips;
(6) Drawing, namely drawing the dip-dyed raw strips in a two-way combination mode, feeding 6 strips in each way, and warping after drawing;
(7) Weaving, namely weaving the cooked strips, and washing with water to obtain a fabric;
the sum crude process oil A comprises sum crude oil AL 106.2 wt%, polyvinylpyrrolidone 0.4wt%, carboxyl-terminated polyethylene glycol 3.6wt%, spindle oil 16 wt% and water for the rest; the sum wool process oil B is 4.3wt% of carboxyl-terminated polyethylene glycol, 3.0wt% of span-80 and the balance of silica gel;
the graphene solution contains 13% of graphene, 7% of cellulase and the balance of water, wherein the pH=6.5 of the graphene solution and the temperature is 40 ℃;
in the step (4), the cylinder speed is 300r/min, the licker-in speed is 700r/min, the doffer speed is 23r/min, and the raw strip ration is 32g/5m;
the strip-out speed in the step (6) is 80-85m/min, and the cooked strip evenness CV value is 4.0-4.5%;
the synthetic fiber raw material is terylene raw material or chinlon raw material;
the graphene adopts LG-1410 nano graphene of Henan Liujia graphite Co.
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CN114032653A (en) * 2021-11-26 2022-02-11 绍兴耀沃针纺股份有限公司 Graphene color-changing crease-resistant fabric production process and drafting and fixing device thereof
CN115491801B (en) * 2022-11-22 2023-01-13 天津红晨岛服饰有限公司 Graphene, carbon fiber and silica gel composite heat-preservation spinning thread and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276532A (en) * 2013-06-19 2013-09-04 南京际华三五二一环保科技有限公司 Method for preparing antistatic filter material
CN106120333A (en) * 2016-06-27 2016-11-16 苏州宇希新材料科技有限公司 A kind of preparation method of Graphene/Caulis et Folium Lini composite fibre
CN106948068A (en) * 2017-05-09 2017-07-14 南通薇星纺织科技有限公司 A kind of fabric of antistatic and preparation method thereof
CN107503114A (en) * 2017-08-23 2017-12-22 江苏英瑞世家实业有限公司 A kind of preparation method of biomass graphite olefinic functionality denim fabric
CN108081712A (en) * 2017-11-30 2018-05-29 湖州科博信息科技有限公司 A kind of sofa cushion fabric of low static behaviour
WO2018166477A1 (en) * 2017-03-15 2018-09-20 山东圣泉新材料股份有限公司 Modified fibre product, preparation method therefor and use thereof
CN109972385A (en) * 2019-04-25 2019-07-05 湖南恒信新型建材有限公司 A kind of surface treatment method of bamboo and woods fiber
CN110085349A (en) * 2019-02-03 2019-08-02 深圳前海皓隆科技有限公司 A kind of transparent graphene loading nano silvery line electrostatic prevention film and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI596245B (en) * 2015-10-20 2017-08-21 聚隆纖維股份有限公司 Method of preparing graphene-natural cellulose blended fiber

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276532A (en) * 2013-06-19 2013-09-04 南京际华三五二一环保科技有限公司 Method for preparing antistatic filter material
CN106120333A (en) * 2016-06-27 2016-11-16 苏州宇希新材料科技有限公司 A kind of preparation method of Graphene/Caulis et Folium Lini composite fibre
WO2018166477A1 (en) * 2017-03-15 2018-09-20 山东圣泉新材料股份有限公司 Modified fibre product, preparation method therefor and use thereof
CN106948068A (en) * 2017-05-09 2017-07-14 南通薇星纺织科技有限公司 A kind of fabric of antistatic and preparation method thereof
CN107503114A (en) * 2017-08-23 2017-12-22 江苏英瑞世家实业有限公司 A kind of preparation method of biomass graphite olefinic functionality denim fabric
CN108081712A (en) * 2017-11-30 2018-05-29 湖州科博信息科技有限公司 A kind of sofa cushion fabric of low static behaviour
CN110085349A (en) * 2019-02-03 2019-08-02 深圳前海皓隆科技有限公司 A kind of transparent graphene loading nano silvery line electrostatic prevention film and preparation method thereof
CN109972385A (en) * 2019-04-25 2019-07-05 湖南恒信新型建材有限公司 A kind of surface treatment method of bamboo and woods fiber

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