Ultra-low temperature fresh-keeping transportation box based on multiple environment interaction
Technical Field
The invention belongs to the technical field of cold chain transportation equipment and control strategies, and particularly relates to an ultralow-temperature fresh-keeping transportation box body based on multiple environment interaction.
Background
China has seen the consumption of tuna in the ten thousand ton age. The domestic market demand is rapidly increased, and the annual consumption of tunas is increased by more than 30 percent in nearly 10 years. However, tuna contains abundant myoglobin and has high oxidation speed, and transportation and storage at-60 ℃ must be ensured in order to keep the nutrition, color and taste of the tuna fresh. However, vehicles suitable for the ultra-low temperature transportation of tunas are not available in the prior art, and the existing refrigerated truck cannot realize the refrigeration condition of 60 ℃ below zero.
Based on this problem, we have conducted intensive studies and found that temperature is the most important factor affecting the quality of perishable products, and that severe fluctuations in temperature cause a dramatic decrease in the quality of perishable products. In the transportation process, due to the heat exchange effect, the temperature fluctuation inside the carriage is severe, and the perishable products are easy to decay. The refrigerated transport box body is used as an important transport facility for guaranteeing the quality of perishable products, and in the transport process, the accurate control of the temperature in the refrigerated carriage is a key technology for guaranteeing that food is in the most suitable environment during the transport, thereby guaranteeing the food safety.
In the prior art, the refrigeration carriage is not ideal in cooling effect in long-distance transportation, and mainly shows the following aspects:
the temperature control mode is single: the constant temperature module sensor for controlling the temperature is positioned near the air supply outlet, and the data acquisition range is limited, so that the air supply system circularly executes a single instruction.
② the temperature control accuracy is low: the system management is lack of refinement and intellectualization, temperature extreme points cannot be identified, and the direction of the air supply outlet is simplified.
Temperature control effect is inconsistent: the work of the system is delayed and reduced, the quality of perishable products is seriously influenced, and huge economic waste is caused.
Fourthly, the temperature control effect is not uniform: the cold air diffuser is arranged at the front part of the carriage, and the cooling performance is poor due to the long air supply distance.
The system operation consumes long time, consumes high energy, has poor low-temperature effect and is far less than the ultralow temperature of minus 60 ℃.
Based on the defects in the aspect of the prior art, the ultra-low temperature fresh-keeping transportation box based on multiple environment interaction is urgently needed to be developed to solve the problems, the technical blank is filled, and the transportation and fresh-keeping effects of the tuna are improved.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides an ultra-low temperature fresh-keeping transportation box body based on multiple environment interaction, and aims to stably control the internal temperature environment of the ultra-low temperature fresh-keeping transportation box body within the range of-60 ℃ to-120 ℃ and realize accurate temperature control through the auxiliary adjustment of a refrigerated container and a movable ultra-low temperature fresh-keeping transportation refrigerated box.
The invention provides an ultra-low temperature fresh-keeping transportation box body based on multiple environment interaction, which comprises: a refrigerated container, a movable ultra-low temperature fresh-keeping transportation refrigerating box and an ultra-low temperature refrigerating box control system;
the refrigerated container comprises a container body, an air supply pipeline, a movable air port and a butterfly valve which are arranged above the container body, and a refrigerating area and a power supply area which are arranged in front of the container body; the container body consists of a first module, a second module and a third module, and turnover partition plates are arranged between the first module and the second module and between the second module and the third module;
the power supply area is connected with the refrigeration area through a circuit, and the power supply area supplies power to the refrigeration area; the movable air port is connected with the refrigerating area through the air supply pipeline and is used for blowing cold energy generated by the refrigerating area into the container body; the butterfly valve is arranged on the air supply pipeline and used for controlling the size of cold energy blown into the container body;
the movable ultra-low temperature fresh-keeping transportation refrigerating boxes are nested and installed in the first module, the second module and the third module, and the installation number of the movable ultra-low temperature fresh-keeping transportation refrigerating boxes can be adjusted according to requirements; the movable ultra-low temperature fresh-keeping transportation refrigerating box comprises a box body, a precooling shutter, an indicator light, a charging layer, a cold source and a temperature detector;
the box body is of a three-layer structure and is provided with a heat insulation plate, a polyurethane foaming layer and an aluminum alloy inner container from outside to inside respectively; the front surface of the box body is provided with the precooling shutter and the indicator light, the side surface is provided with a charging layer, the bottom surface is provided with a temperature detector, and the inside is provided with a cold source;
the ultra-low temperature refrigerating box control system detects the temperature in the box body through the temperature detector, then records real-time temperature data through connecting a computer, and displays whether the fluctuation range of a temperature curve exceeds a preset temperature threshold range through an indicator lamp; and adjusting the flux of the refrigerant in the cold source according to the relation between the temperature curve fluctuation range and the preset temperature threshold range, so as to realize the control of the temperature in the box body.
Further, be provided with the sensor on the removal wind gap, just the sensor has automatic identification locate function, but the accurate cooling is carried out to the screening temperature extreme point, improves cooling efficiency, shortens the cooling time to the quality and the safety of guarantee perishable class product.
Furthermore, four walls of the box body are of detachable structures. The detachable structure can realize the following three purposes, namely, the capacity of the box body can be adjusted to form a dynamic storage space according to the capacity of the transported articles, the types of the refrigerants can be exchanged according to the types of the transported articles, and the interaction degree between a large environment and a small environment can be changed; and when the box body is nested in the refrigerated container, the precooling shutter can be automatically set to open/close, so that the environment interaction between the refrigerated container and the movable ultra-low temperature fresh-keeping transportation refrigerating box is realized, and the ultra-low temperature control and energy-saving management of the box body are further realized.
Furthermore, the cold source realizes the refrigeration effect by filling liquid or gas refrigerant, and the preferable refrigerant is helium, so that the refrigerant can realize no harmful substance and no pollutant discharge during refrigeration while ensuring the refrigeration effect.
Furthermore, the boxes are connected in parallel and in series through the charging layer to form an integrated and dynamic module combination, so that the purpose of intelligent and orderly arrangement according to distribution demands is achieved.
Furthermore, the box body supplies power independently through the charging layer, and a common vehicle-mounted power supply can meet the power supply requirement.
Further, the indicator light comprises a red indicator light and a green indicator light, and when the fluctuation range of the temperature curve is larger than a preset temperature threshold range, the red indicator light is turned on to send out an early warning signal; when the temperature curve fluctuation range is within a preset temperature threshold value range, the green indicator light is turned on to indicate that the temperature is in a normal range.
Furthermore, a buckle fixing device is arranged outside the box bodies and used for splicing the box bodies, and a buckle groove capable of being fixed with the buckle fixing device is formed in the turnover partition plate. Such structure setting has increased stability, has solved because of the goods loads unscientific and rock the loss that causes in the transportation.
Further, an ultra-low temperature fresh-keeping transportation box based on multiple environment interaction adopts mobile base station data integration technology, realizes the self-arrangement of network deployment, guarantees the orderly transmission of information and the orderly arrangement of distribution, has realized the visual and traceability of transportation.
The invention has the advantages that:
the ultralow-temperature fresh-keeping transportation box based on multiple environment interactions can realize ultralow temperature control in the whole transportation process, and is good in environment temperature controllability and strong in stability.
Secondly, the ultra-low temperature fresh-keeping transportation box body based on multiple environment interaction can realize double refrigeration, the temperature control range can reach below 60 ℃ below zero, the refrigeration effect is good, and the energy consumption is low.
The ultralow-temperature fresh-keeping transportation box based on multiple environment interaction adopts autonomous helium for refrigeration, realizes no harmful substance and no pollutant emission of a refrigeration working medium, and meets the requirement on environmental friendliness.
The ultralow-temperature fresh-keeping transportation box based on multiple environment interaction can realize dynamic integration of small carriages, and is intelligently and orderly arranged according to distribution requirements.
The ultralow temperature fresh-keeping transportation box based on multiple environment interaction adopts modular power supply, each ultralow temperature fresh-keeping transportation box is a temperature zone, and multi-temperature zone co-distribution can be realized through splicing connection between the box bodies.
According to the ultra-low temperature fresh-keeping transportation box based on multiple environment interaction, independent power supply can be achieved, a vehicle-mounted power supply can meet power supply requirements, ultra-low temperature tail end distribution can be achieved, the box can be repeatedly used, and resource consumption is avoided.
Drawings
Fig. 1 is a schematic structural diagram of an ultra-low temperature fresh-keeping transportation box based on multiple environment interactions in embodiment 1 of the present invention;
FIG. 2 is a schematic view showing the internal structure of the mobile ultra-low temperature fresh-keeping transportation refrigerator according to embodiment 1 of the present invention;
FIG. 3 is a schematic view showing the external structure of the mobile ultra-low temperature fresh-keeping transportation refrigerator in embodiment 1 of the present invention;
FIG. 4 is a schematic diagram of the temperature distribution of an ultra-low temperature fresh-keeping transportation box based on multiple environmental interactions in the experimental group of Experimental example 1 of the present invention;
fig. 5 is a schematic view showing the temperature distribution of a control refrigerator car in experimental example 1 of the present invention;
FIG. 6 is a line graph showing sensory evaluation scores of tuna meat over time under different refrigeration conditions in Experimental example 2 of the present invention;
FIG. 7 is a graph showing the TVB-N values of tuna meat according to the refrigerating time under different refrigerating conditions in Experimental example 2 of the present invention;
FIG. 8 is a graph showing the change of pH of tuna meat with refrigeration time under different refrigeration conditions in Experimental example 2 of the present invention.
The reference numerals in the figures have the meaning: the method comprises the following steps of 1-an air supply pipeline, 2-a movable air port, 3-a butterfly valve, 4-a refrigeration area, 5-a power supply area, 6-a first module, 7-a second module, 8-a third module, 9-a turnover partition plate, 11-a box body, 12-an aluminum alloy inner container, 13-a heat insulation plate, 14-a precooling shutter, 15-an indicator light, 16-a polyurethane foaming layer, 17-a charging layer, 18-a cold source, 19-a temperature detector and 20-a buckle fixing device.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
As shown in fig. 1, an ultra-low temperature fresh-keeping transportation box based on multiple environment interaction comprises: a refrigerated container, a movable ultra-low temperature fresh-keeping transportation refrigerating box and an ultra-low temperature refrigerating box control system;
the refrigerated container comprises a container body, an air supply pipeline 1, a movable air port 2 and a butterfly valve 3 which are arranged above the container body, and a refrigerating area 4 and a power supply area 5 which are arranged in front of the container body; the container body consists of a first module 6, a second module 7 and a third module 8, and turnover partition plates 9 are arranged between the first module 6 and the second module 7 and between the second module 7 and the third module 8;
the power supply area 5 is connected with the refrigeration area 4 through a circuit, and the power supply area 5 supplies power to the refrigeration area 4; the movable air port 2 is connected with the refrigerating area 4 through an air supply pipeline 1 and is used for blowing cold energy generated by the refrigerating area 4 into the container body; the butterfly valve 3 is arranged on the air supply pipeline 1 and is used for controlling the amount of cold energy blown into the container body;
the movable ultra-low temperature fresh-keeping transportation cold storage boxes are nested in the first module 6, the second module 7 and the third module 8; the movable ultra-low temperature fresh-keeping transportation refrigerating box (see figure 2) comprises a box body 11, a precooling shutter 14, an indicator light 15, a charging layer 17, a cold source 18 and a temperature detector 19;
the box body 11 is of a three-layer structure and is respectively provided with a heat insulation plate 13, a polyurethane foam layer 16 and an aluminum alloy inner container 12 from outside to inside; the front surface of the box body 11 is provided with a precooling shutter 14 and an indicator light 15, the side surface is provided with a charging layer 17, the bottom surface is provided with a temperature detector 19, and the inside is provided with a cold source 18;
the ultra-low temperature refrigerating box control system detects the temperature in the box body 11 through the temperature detector 19, then records the real-time temperature data through connecting a computer, and displays whether the fluctuation range of the temperature curve exceeds the range of the preset temperature threshold value through the indicator light 15; and the flux of the refrigerant in the cold source 18 is adjusted according to the relationship between the fluctuation range of the temperature curve and the preset temperature threshold range, so as to realize the control of the temperature in the box body 11.
The utility model provides a specific working process of super low temperature fresh-keeping transportation box transportation tuna based on multiple environment is whole car and distributes with the temperature:
(1) after tunas are placed in the movable ultra-low temperature fresh-keeping transportation refrigerating box, the box body 11 is embedded into a refrigerated container, a power supply area 5 is arranged in front of the container body, the box body 11 can be supplied with power through a charging layer 17 on the box body 11 in the first module 6, current is introduced into the overturning partition plate 9, and when the box body 11 is embedded into the second module 7 and the third module 8, the movable ultra-low temperature fresh-keeping transportation refrigerating box embedded into the box body can be charged through the overturning partition plate 9; the turnover partition plate 9 plays a role in heat insulation, also plays a role in electric energy transmission, and realizes dual purposes of one plate.
(2) The outside of box 11 is provided with buckle fixing device 20 for concatenation between the box 11, and be provided with in the upset baffle 9 can with the buckle groove that buckle fixing device 20 is fixed, increased stability, solved because of the goods loads unscientific and rock the loss that causes in the transportation. The parallel series connection of circuit can be carried out through the layer 17 that charges between the box 11, forms the module combination that integrates, the dynamization, carries out intelligence, orderly arrangement according to the delivery demand.
(3) When box 11 nestification is put in the refrigerated container, the refrigerated container carries out the precooling, is provided with the sensor that has automatic identification locate function on the removal wind gap 2, can realize screening temperature extreme point and automatic positioning to by refrigeration district 4 through supply air duct 1 with remove wind gap 2 and carry out accurate cooling, improved cooling efficiency, shortened the cooling time. At this time, the precooling shutter 14 of the box body 11 can be automatically opened, so that the interaction of the environment between the refrigerated container and the movable ultra-low temperature fresh-keeping transportation refrigerating box is realized, and the ultra-low temperature control and energy-saving management of the box body 11 are further realized. When the temperature is reduced to-20 ℃, the pre-cooling shutter 14 is automatically closed, and the movable ultra-low temperature fresh-keeping transportation refrigerator starts to automatically refrigerate by the refrigerant in the cold source 18 until the temperature in the box body 11 reaches below-60 ℃.
(4) The control system of the ultra-low temperature refrigerating box in the whole refrigerating process detects the temperature in the box body 11 through the temperature detector 19, then carries out real-time temperature data recording through connecting a computer, and displays whether the fluctuation range of a temperature curve exceeds a preset temperature threshold range or not through the indicator lamp 15 (when the fluctuation range of the temperature curve is larger than the preset temperature threshold range, a red indicator lamp of the indicator lamp 15 sends out an early warning signal, and when the fluctuation range of the temperature curve is in the preset temperature threshold range, a green indicator lamp of the indicator lamp 15 is on to indicate that the temperature is in a normal range); and the flux of the refrigerant in the cold source 18 is adjusted according to the relationship between the fluctuation range of the temperature curve and the predetermined temperature threshold range, so as to realize the control of the temperature in the box body 11.
(5) When goods are loaded and unloaded, if the box body 11 serving as the base station is unloaded, the position of the base station is automatically arranged to the next box body 11, data acquisition of the mobile base station is realized, information acquisition and transportation process matching are ensured, and visualization and traceability of the transportation process are realized.
Experimental example 1
The ultra-low temperature fresh-keeping transport case based on the multiple environment interaction in the embodiment 1 is used as an experimental group, a refrigerated vehicle in the prior art is used as a control group, the temperature control is carried out according to respective control systems, after 5 hours, the temperature distribution inside the transport cases of the experimental group and the control group is analyzed by using CFD software, and the results are shown in fig. 4 and 5. The picture shows that the ultralow temperature fresh-keeping transportation box based on multiple environment interaction has good temperature control effect, uniform and consistent temperature distribution and remarkable advantages.
Experimental example 2
The tuna transported in example 1 was used as an experimental group, and the tuna transported in a refrigerator of the prior art was used as a control group, and sensory evaluation and measurement of TVB-N value and pH value were carried out, respectively.
1. Experimental methods
1.1 sensory evaluation
As the quality of tuna gradually decreases with the extension of the refrigerating time, various physical and chemical changes occur in the fish meat, resulting in significant changes in the external characteristics of the tuna, such as the meat texture, color and smell, and thus the quality of the tuna can be roughly judged through sensory organ evaluation.
The scoring standards are respectively made from three aspects of body surface color, muscle tissue and smell, the five ginsengs are scored, and the scores are averaged to obtain the experimental result. The scoring criteria are shown in table 1.
TABLE 1 tuna sensory evaluation criteria
1.2 volatile basic Nitrogen (TVB-N) determination
Tuna has a very high protein content and one of the main characteristics of its spoilage is protein breakdown, so the degree of spoilage can be measured by volatile basic nitrogen (TVB-N). Volatile basic nitrogen is a basic nitrogen-containing substance with specific odor generated after protein decomposition, and the higher the content of the substance, the stronger the odor is, which also indicates that the more serious the putrefaction degree is, the worse the quality is.
The experiment adopts a semi-micro Kjeldahl method for determination:
weighing 10.00g of minced and uniformly stirred tuna meat and placing the tuna meat in a conical flask; adding 100mL of water, shaking uniformly, soaking for 30min, filtering, and placing the filtrate in a refrigerator for later use; thirdly, placing a conical flask containing 10mL of absorption liquid and 5-6 drops of mixed indication liquid at the lower end of the condenser pipe, and inserting the lower end of the condenser pipe below the absorption liquid level; fourthly, accurately sucking 5.0mL of filtrate into a reaction chamber of the distiller, adding 5mL of magnesium oxide suspension (10g/L), quickly covering and plugging, and adding water to prevent air leakage; introducing steam, distilling for 5 min; sixthly, titrating the absorption liquid by using a hydrochloric acid standard titration solution (0.01mol/L), and finishing the end point to be bluish purple.
The calculation method comprises the following steps: volatile basic nitrogen content (mg/100g) =
;
Wherein: v1-titration of sample consumes standard acid solution volume (mL); v2Titration of the blank consumes a standard acid solution volume (mL); m-mass (g) of sample contained in the sample liquid for titration; c-specified concentration (mol/L) of standard acid solution; 14-molar mass of nitrogen (g/mol).
1.3 determination of pH
The tuna is acidic, the pH value of the oxidized myoglobin composition in the tuna is 6.0-6.5, and the quality of the tuna can be judged by measuring the pH value of the tuna at different temperatures in each refrigeration stage.
Weighing 10.00g of tuna meat as a sample for each measurement, shaking with 100mL of newly boiled and cooled water, soaking for 30min, filtering, putting 50mL of filtrate into a beaker, and measuring the pH value by using a precision acidimeter.
2 results of the experiment
2.1 sensory evaluation during refrigeration
Results referring to fig. 6, the quality of tuna refrigerated at-18 ℃ was most significantly reduced, the quality of tuna refrigerated at-30 ℃ was significantly reduced with the increase in the refrigeration time, while the sensory score of tuna refrigerated at-60 ℃ (example 1) was very little changed with the increase in the storage time, and showed no significant decrease.
2.2 variation of volatile basic Nitrogen TVB-N
Results see figure 7. refrigeration temperatures of-30 ℃ and-18 ℃ have some effect on freshness, -refrigeration conditions of-18 ℃ have the most significant effect on freshness, whereas the freshness of tuna (example 1) fish refrigerated at a refrigeration temperature of-60 ℃ does not change significantly.
2.3 change of pH
As a result, referring to FIG. 8, the pH curve of tuna (example 1) refrigerated at a refrigerating temperature of-60 ℃ was almost constant with little fluctuation, whereas the pH curve showed a tendency to decrease at refrigerating temperatures of-18 ℃ and-30 ℃ with the rate of decrease of pH at-18 ℃ being most significant.
Through the experimental data, the tuna transported by the transportation method (embodiment 1) can keep good quality, the transportation condition of the tuna is the most rigorous, and the transportation condition of the tuna is met, so that the transportation requirement of almost all objects with high temperature requirements in the transportation process is met, therefore, the ultralow-temperature fresh-keeping transportation box based on multiple environment interaction can be used for transporting other products with high fresh-keeping requirements, even living organs, and the transportation method is the same as that of embodiment 1.
Example 2
The specific working process of the ultralow-temperature fresh-keeping transportation box based on the multiple environment interaction in the embodiment 1 for transporting tunas and other perishable products is multi-temperature distribution: putting different box bodies 11 into tunas and other perishable products, putting the box bodies 11 filled with the same product into the same module of the refrigerated container, and putting the heat insulation boxes with the similar transportation temperature into the same module if the box bodies 11 are all different products; the subsequent transportation procedure was the same as the method of transporting tuna in example 1.
It should be understood that the above-described specific embodiments are merely illustrative of the present invention and are not intended to limit the present invention. Obvious variations or modifications which are within the spirit of the invention are possible within the scope of the invention.