CN111472067A - Antistatic polymer composite fiber - Google Patents
Antistatic polymer composite fiber Download PDFInfo
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- CN111472067A CN111472067A CN202010550869.9A CN202010550869A CN111472067A CN 111472067 A CN111472067 A CN 111472067A CN 202010550869 A CN202010550869 A CN 202010550869A CN 111472067 A CN111472067 A CN 111472067A
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
Abstract
The invention relates to the field of antistatic polymers, in particular to an antistatic polymer composite fiber which comprises the following components in parts by weight: 60-80 parts of polyvinyl chloride, 20-40 parts of polyamide, 1-10 parts of carbon nanofiber, 1-5 parts of antistatic agent, 1-3 parts of antioxidant and 0.5-1 part of stabilizer. The invention solves the problem of poor antistatic property of the existing polymer composite fiber, and finally prepares the antistatic polymer composite fiber.
Description
Technical Field
The invention relates to the field of antistatic polymers, in particular to an antistatic polymer composite fiber.
Background
The polymer has the advantages of low price, light weight, high specific strength, small heat conductivity coefficient, good chemical stability and the like, and is widely applied to various fields of production and life. However, most polymers are good electrical insulators, have high electrical resistivity, and are prone to static electricity, thereby limiting their applications. The accumulation of static electricity in human body may affect the normal work of each visceral organ, especially the heart, thereby causing abnormal heart rate and premature heart beat; static electricity on the body can also induce various diseases in the elderly, young, sick, pregnant population. For example, static electricity can cause a decline in maternal hormone levels, which in turn can lead to miscarriage or premature delivery; the static electricity accumulated in children may affect the physiological balance of central nerves and body. Of course, the electrostatic hazard is far more than this. In recent years, along with the development of the electronic industry, the harm of static electricity to human beings is increasing. For example, interfering with the proper functioning of the aircraft radio, thereby affecting aircraft flight; the polymer shell of pharmaceutical factory equipment is easy to adsorb dust due to electrostatic effect, thereby reducing the purity of the medicine; the surface of the television screen adsorbs dust due to static electricity, so that the definition and brightness of images watched by people are reduced. The antistatic property of the existing polymer composite fiber is poor, so that the preparation of the antistatic polymer composite fiber becomes the direction of the current industrial development.
Disclosure of Invention
Aiming at the problems, the invention provides an antistatic polymer composite fiber which comprises the following components in parts by weight:
60-80 parts of polyvinyl chloride, 20-40 parts of polyamide, 1-10 parts of carbon nanofiber, 1-5 parts of antistatic agent, 1-3 parts of antioxidant and 0.5-1 part of stabilizer.
Preferably, the antistatic polymer composite fiber consists of the following components in parts by weight:
70-80 parts of polyvinyl chloride, 20-30 parts of polyamide, 4-6 parts of carbon nanofiber, 2-3 parts of antistatic agent, 1-3 parts of antioxidant and 0.5-1 part of stabilizer.
Preferably, the preparation method of the antistatic agent is as follows:
s1, weighing 1-p-toluenesulfonyl pyrrole-2-acetaldehyde, adding into tetrahydrofuran, and stirring uniformly to obtain a 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution; weighing 50% by mass of hydrazine hydrate aqueous solution, adding the hydrazine hydrate aqueous solution into tetrahydrofuran, and stirring and dispersing the hydrazine hydrate aqueous solution uniformly to obtain hydrazine hydrate mixed solution; under the protection of nitrogen, placing the hydrazine hydrate mixed solution in a water bath at 60-70 ℃ for reflux, dropwise adding the 1-p-toluenesulfonylpyrrole-2-acetaldehyde solution, continuing reflux reaction for 0.5-1 h after the dropwise addition is finished, and cooling to room temperature to obtain a mixed solution A;
wherein in the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution, the mass ratio of 1-p-toluenesulfonyl pyrrole-2-acetaldehyde to tetrahydrofuran is 1: 15-20; in the hydrazine hydrate mixed solution, the mass ratio of a hydrazine hydrate aqueous solution to tetrahydrofuran is 1: 2-5; the volume ratio of the hydrazine hydrate mixed solution to the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution is 1: 2-3;
s2, weighing stannous chloride, adding the stannous chloride into the mixed solution A, stirring and dispersing the stannous chloride uniformly, placing the mixed solution A in a water bath under the protection of nitrogen for refluxing at the temperature of 60-70 ℃, reacting for 10-15 hours, cooling to room temperature, washing with deionized water and extracting with ethyl acetate, repeating washing and extracting for three times, and performing rotary evaporation on a substance obtained by the last extraction to remove a solvent to obtain a product B;
wherein the solid-to-liquid ratio of the stannous chloride to the mixed liquid A is 1: 100-150;
s3, weighing the product B, adding the product B into tetrahydrofuran, stirring uniformly, then dropwise adding concentrated hydrochloric acid with the mass concentration of 36-38%, and stirring until no precipitate is generated, so as to obtain a mixed solution C; weighing zirconium tetrachloride, adding the zirconium tetrachloride into tetrahydrofuran, and stirring the mixture uniformly to obtain a mixed solution D; mixing and stirring the mixed solution C and the mixed solution D at room temperature for 1-2 hours, sealing, standing for 5-10 days to obtain a mixed solution containing crystals, filtering to obtain the crystals, and freeze-drying to obtain the antistatic agent;
in the mixed solution C, the mass ratio of the product B to tetrahydrofuran is 1: 10-15; in the mixed solution D, the mass ratio of zirconium tetrachloride to tetrahydrofuran is 1: 5-8; the mass ratio of the product B to the concentrated hydrochloric acid is 1: 0.5-2; the volume ratio of the mixed liquid C to the mixed liquid D is 1: 1-1.2.
Preferably, the antioxidant is a phenolic antioxidant and/or a phosphite antioxidant.
Preferably, the stabilizer is fumed silica and/or fumed alumina.
The invention has the beneficial effects that:
1. the polymer composite fiber material is prepared by compounding polyvinyl chloride and polyamide, wherein the polyvinyl chloride has excellent transparency, flame retardance and electrical insulation, but poor stability and is easy to degrade under the action of light and heat; the polyamide has stronger solvent resistance, better wear resistance and better stabilizer, but has poorer heat resistance and larger water absorption, so the polyvinyl chloride and the polyamide are compounded, and the obtained composite material has the advantages and the disadvantages of the two materials which are complementary.
2. The carbon nanofiber is added, the mechanical property of the composite material is further improved, the antistatic effect of the material is enhanced by adding the antistatic agent, the oxidation resistance of the material is enhanced by adding the antioxidant, and the use stability of the material is enhanced by adding the stabilizer.
3. The antistatic agent of the invention is prepared by reacting 1-p-toluenesulfonylpyrrole-2-acetaldehyde with hydrazine hydrate under the action of tetrahydrofuran and water as solvents, then grafting with zirconium tetrachloride, forming organic metal salt complex by using solution volatilization method, which is different from general crystal structure, the organic metal salt complex prepared by the invention is a non-porous flexible ligand crystal structure and has a one-dimensional chain, two-dimensional surface and three-dimensional stacked crystal structure, in the structure, organic and inorganic metals are grafted alternately and can be extended infinitely, therefore, after the three-dimensional framework formed by the organic metal salt complex is added into the composite material, the organic system can be tightly combined with the composite material, the inorganic system can improve the microstructure of the surface of the composite material, so that the antistatic property of the composite material is greatly enhanced.
Detailed Description
The invention is further described with reference to the following examples.
Example 1
An antistatic polymer composite fiber comprises the following components in parts by weight:
70 parts of polyvinyl chloride, 30 parts of polyamide, 5 parts of carbon nano fiber, 3 parts of antistatic agent, 2 parts of antioxidant and 0.75 part of stabilizer.
The preparation method of the antistatic agent comprises the following steps:
s1, weighing 1-p-toluenesulfonyl pyrrole-2-acetaldehyde, adding into tetrahydrofuran, and stirring uniformly to obtain a 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution; weighing 50% by mass of hydrazine hydrate aqueous solution, adding the hydrazine hydrate aqueous solution into tetrahydrofuran, and stirring and dispersing the hydrazine hydrate aqueous solution uniformly to obtain hydrazine hydrate mixed solution; under the protection of nitrogen, placing the hydrazine hydrate mixed solution in a water bath at 60-70 ℃ for reflux, dropwise adding the 1-p-toluenesulfonylpyrrole-2-acetaldehyde solution, continuing reflux reaction for 0.5-1 h after the dropwise addition is finished, and cooling to room temperature to obtain a mixed solution A;
wherein in the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution, the mass ratio of 1-p-toluenesulfonyl pyrrole-2-acetaldehyde to tetrahydrofuran is 1: 15-20; in the hydrazine hydrate mixed solution, the mass ratio of a hydrazine hydrate aqueous solution to tetrahydrofuran is 1: 2-5; the volume ratio of the hydrazine hydrate mixed solution to the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution is 1: 2-3;
s2, weighing stannous chloride, adding the stannous chloride into the mixed solution A, stirring and dispersing the stannous chloride uniformly, placing the mixed solution A in a water bath under the protection of nitrogen for refluxing at the temperature of 60-70 ℃, reacting for 10-15 hours, cooling to room temperature, washing with deionized water and extracting with ethyl acetate, repeating washing and extracting for three times, and performing rotary evaporation on a substance obtained by the last extraction to remove a solvent to obtain a product B;
wherein the solid-to-liquid ratio of the stannous chloride to the mixed liquid A is 1: 100-150;
s3, weighing the product B, adding the product B into tetrahydrofuran, stirring uniformly, then dropwise adding concentrated hydrochloric acid with the mass concentration of 36-38%, and stirring until no precipitate is generated, so as to obtain a mixed solution C; weighing zirconium tetrachloride, adding the zirconium tetrachloride into tetrahydrofuran, and stirring the mixture uniformly to obtain a mixed solution D; mixing and stirring the mixed solution C and the mixed solution D at room temperature for 1-2 hours, sealing, standing for 5-10 days to obtain a mixed solution containing crystals, filtering to obtain the crystals, and freeze-drying to obtain the antistatic agent;
in the mixed solution C, the mass ratio of the product B to tetrahydrofuran is 1: 10-15; in the mixed solution D, the mass ratio of zirconium tetrachloride to tetrahydrofuran is 1: 5-8; the mass ratio of the product B to the concentrated hydrochloric acid is 1: 0.5-2; the volume ratio of the mixed liquid C to the mixed liquid D is 1: 1-1.2.
The antioxidant is a phenolic antioxidant and/or a phosphite antioxidant.
The stabilizer is fumed silica and/or fumed alumina.
Example 2
An antistatic polymer composite fiber comprises the following components in parts by weight:
60 parts of polyvinyl chloride, 20 parts of polyamide, 1 part of carbon nanofiber, 1 part of antistatic agent, 1 part of antioxidant and 0.5 part of stabilizer.
The preparation method of the antistatic agent comprises the following steps:
s1, weighing 1-p-toluenesulfonyl pyrrole-2-acetaldehyde, adding into tetrahydrofuran, and stirring uniformly to obtain a 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution; weighing 50% by mass of hydrazine hydrate aqueous solution, adding the hydrazine hydrate aqueous solution into tetrahydrofuran, and stirring and dispersing the hydrazine hydrate aqueous solution uniformly to obtain hydrazine hydrate mixed solution; under the protection of nitrogen, placing the hydrazine hydrate mixed solution in a water bath at 60-70 ℃ for reflux, dropwise adding the 1-p-toluenesulfonylpyrrole-2-acetaldehyde solution, continuing reflux reaction for 0.5-1 h after the dropwise addition is finished, and cooling to room temperature to obtain a mixed solution A;
wherein in the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution, the mass ratio of 1-p-toluenesulfonyl pyrrole-2-acetaldehyde to tetrahydrofuran is 1: 15-20; in the hydrazine hydrate mixed solution, the mass ratio of a hydrazine hydrate aqueous solution to tetrahydrofuran is 1: 2-5; the volume ratio of the hydrazine hydrate mixed solution to the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution is 1: 2-3;
s2, weighing stannous chloride, adding the stannous chloride into the mixed solution A, stirring and dispersing the stannous chloride uniformly, placing the mixed solution A in a water bath under the protection of nitrogen for refluxing at the temperature of 60-70 ℃, reacting for 10-15 hours, cooling to room temperature, washing with deionized water and extracting with ethyl acetate, repeating washing and extracting for three times, and performing rotary evaporation on a substance obtained by the last extraction to remove a solvent to obtain a product B;
wherein the solid-to-liquid ratio of the stannous chloride to the mixed liquid A is 1: 100-150;
s3, weighing the product B, adding the product B into tetrahydrofuran, stirring uniformly, then dropwise adding concentrated hydrochloric acid with the mass concentration of 36-38%, and stirring until no precipitate is generated, so as to obtain a mixed solution C; weighing zirconium tetrachloride, adding the zirconium tetrachloride into tetrahydrofuran, and stirring the mixture uniformly to obtain a mixed solution D; mixing and stirring the mixed solution C and the mixed solution D at room temperature for 1-2 hours, sealing, standing for 5-10 days to obtain a mixed solution containing crystals, filtering to obtain the crystals, and freeze-drying to obtain the antistatic agent;
in the mixed solution C, the mass ratio of the product B to tetrahydrofuran is 1: 10-15; in the mixed solution D, the mass ratio of zirconium tetrachloride to tetrahydrofuran is 1: 5-8; the mass ratio of the product B to the concentrated hydrochloric acid is 1: 0.5-2; the volume ratio of the mixed liquid C to the mixed liquid D is 1: 1-1.2.
The antioxidant is a phenolic antioxidant and/or a phosphite antioxidant.
The stabilizer is fumed silica and/or fumed alumina.
Example 3
An antistatic polymer composite fiber comprises the following components in parts by weight:
80 parts of polyvinyl chloride, 40 parts of polyamide, 10 parts of carbon nano fiber, 5 parts of antistatic agent, 3 parts of antioxidant and 1 part of stabilizer.
The preparation method of the antistatic agent comprises the following steps:
s1, weighing 1-p-toluenesulfonyl pyrrole-2-acetaldehyde, adding into tetrahydrofuran, and stirring uniformly to obtain a 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution; weighing 50% by mass of hydrazine hydrate aqueous solution, adding the hydrazine hydrate aqueous solution into tetrahydrofuran, and stirring and dispersing the hydrazine hydrate aqueous solution uniformly to obtain hydrazine hydrate mixed solution; under the protection of nitrogen, placing the hydrazine hydrate mixed solution in a water bath at 60-70 ℃ for reflux, dropwise adding the 1-p-toluenesulfonylpyrrole-2-acetaldehyde solution, continuing reflux reaction for 0.5-1 h after the dropwise addition is finished, and cooling to room temperature to obtain a mixed solution A;
wherein in the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution, the mass ratio of 1-p-toluenesulfonyl pyrrole-2-acetaldehyde to tetrahydrofuran is 1: 15-20; in the hydrazine hydrate mixed solution, the mass ratio of a hydrazine hydrate aqueous solution to tetrahydrofuran is 1: 2-5; the volume ratio of the hydrazine hydrate mixed solution to the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution is 1: 2-3;
s2, weighing stannous chloride, adding the stannous chloride into the mixed solution A, stirring and dispersing the stannous chloride uniformly, placing the mixed solution A in a water bath under the protection of nitrogen for refluxing at the temperature of 60-70 ℃, reacting for 10-15 hours, cooling to room temperature, washing with deionized water and extracting with ethyl acetate, repeating washing and extracting for three times, and performing rotary evaporation on a substance obtained by the last extraction to remove a solvent to obtain a product B;
wherein the solid-to-liquid ratio of the stannous chloride to the mixed liquid A is 1: 100-150;
s3, weighing the product B, adding the product B into tetrahydrofuran, stirring uniformly, then dropwise adding concentrated hydrochloric acid with the mass concentration of 36-38%, and stirring until no precipitate is generated, so as to obtain a mixed solution C; weighing zirconium tetrachloride, adding the zirconium tetrachloride into tetrahydrofuran, and stirring the mixture uniformly to obtain a mixed solution D; mixing and stirring the mixed solution C and the mixed solution D at room temperature for 1-2 hours, sealing, standing for 5-10 days to obtain a mixed solution containing crystals, filtering to obtain the crystals, and freeze-drying to obtain the antistatic agent;
in the mixed solution C, the mass ratio of the product B to tetrahydrofuran is 1: 10-15; in the mixed solution D, the mass ratio of zirconium tetrachloride to tetrahydrofuran is 1: 5-8; the mass ratio of the product B to the concentrated hydrochloric acid is 1: 0.5-2; the volume ratio of the mixed liquid C to the mixed liquid D is 1: 1-1.2.
The antioxidant is a phenolic antioxidant and/or a phosphite antioxidant.
The stabilizer is fumed silica and/or fumed alumina.
Comparative example
An antistatic polymer composite fiber comprises the following components in parts by weight:
70 parts of polyvinyl chloride, 30 parts of polyamide, 5 parts of carbon nano fiber, 2 parts of antioxidant and 0.75 part of stabilizer.
The antioxidant is a phenolic antioxidant and/or a phosphite antioxidant.
The stabilizer is fumed silica and/or fumed alumina.
The results of the tests of the antistatic polymer composite fibers prepared in examples 1 to 3 and the comparative example are shown in table 1: (wherein, the antistatic ratio is measured as the ratio of the difference between the volume resistivity and the surface resistivity of the material)
TABLE 1 composite fiber test results
Detection standard | Example 1 | Example 2 | Example 3 | Comparative example | |
Water absorption (%) | ASTM D570-98 | 0.008 | 0.010 | 0.007 | 0.010 |
Heat distortion temperature (. degree. C.) | ASTM D648-06 | 92 | 86 | 89 | 87 |
Antistatic ratio (%) | GB 1944-78 | 95 | 93 | 95 | 46 |
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention, and not for limiting the protection scope of the present invention, although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (5)
1. The antistatic polymer composite fiber is characterized by comprising the following components in parts by weight:
60-80 parts of polyvinyl chloride, 20-40 parts of polyamide, 1-10 parts of carbon nanofiber, 1-5 parts of antistatic agent, 1-3 parts of antioxidant and 0.5-1 part of stabilizer.
2. The antistatic polymer composite fiber according to claim 1, wherein the antistatic polymer composite fiber comprises the following components in parts by weight:
70-80 parts of polyvinyl chloride, 20-30 parts of polyamide, 4-6 parts of carbon nanofiber, 2-3 parts of antistatic agent, 1-3 parts of antioxidant and 0.5-1 part of stabilizer.
3. An antistatic polymer composite fiber according to claim 1 or 2, said antistatic agent being prepared by:
s1, weighing 1-p-toluenesulfonyl pyrrole-2-acetaldehyde, adding into tetrahydrofuran, and stirring uniformly to obtain a 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution; weighing 50% by mass of hydrazine hydrate aqueous solution, adding the hydrazine hydrate aqueous solution into tetrahydrofuran, and stirring and dispersing the hydrazine hydrate aqueous solution uniformly to obtain hydrazine hydrate mixed solution; under the protection of nitrogen, placing the hydrazine hydrate mixed solution in a water bath at 60-70 ℃ for reflux, dropwise adding the 1-p-toluenesulfonylpyrrole-2-acetaldehyde solution, continuing reflux reaction for 0.5-1 h after the dropwise addition is finished, and cooling to room temperature to obtain a mixed solution A;
wherein in the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution, the mass ratio of 1-p-toluenesulfonyl pyrrole-2-acetaldehyde to tetrahydrofuran is 1: 15-20; in the hydrazine hydrate mixed solution, the mass ratio of a hydrazine hydrate aqueous solution to tetrahydrofuran is 1: 2-5; the volume ratio of the hydrazine hydrate mixed solution to the 1-p-toluenesulfonyl pyrrole-2-acetaldehyde solution is 1: 2-3;
s2, weighing stannous chloride, adding the stannous chloride into the mixed solution A, stirring and dispersing the stannous chloride uniformly, placing the mixed solution A in a water bath under the protection of nitrogen for refluxing at the temperature of 60-70 ℃, reacting for 10-15 hours, cooling to room temperature, washing with deionized water and extracting with ethyl acetate, repeating washing and extracting for three times, and performing rotary evaporation on a substance obtained by the last extraction to remove a solvent to obtain a product B;
wherein the solid-to-liquid ratio of the stannous chloride to the mixed liquid A is 1: 100-150;
s3, weighing the product B, adding the product B into tetrahydrofuran, stirring uniformly, then dropwise adding concentrated hydrochloric acid with the mass concentration of 36-38%, and stirring until no precipitate is generated, so as to obtain a mixed solution C; weighing zirconium tetrachloride, adding the zirconium tetrachloride into tetrahydrofuran, and stirring the mixture uniformly to obtain a mixed solution D; mixing and stirring the mixed solution C and the mixed solution D at room temperature for 1-2 hours, sealing, standing for 5-10 days to obtain a mixed solution containing crystals, filtering to obtain the crystals, and freeze-drying to obtain the antistatic agent;
in the mixed solution C, the mass ratio of the product B to tetrahydrofuran is 1: 10-15; in the mixed solution D, the mass ratio of zirconium tetrachloride to tetrahydrofuran is 1: 5-8; the mass ratio of the product B to the concentrated hydrochloric acid is 1: 0.5-2; the volume ratio of the mixed liquid C to the mixed liquid D is 1: 1-1.2.
4. An antistatic polymer composite fiber according to claim 1 or 2, said antioxidant being a phenolic antioxidant and/or a phosphite antioxidant.
5. An antistatic polymer composite fiber according to claim 1 or 2, said stabilizer being fumed silica and/or fumed alumina.
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