CN111470785B - Self-cleaning glass - Google Patents

Self-cleaning glass Download PDF

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Publication number
CN111470785B
CN111470785B CN202010265839.3A CN202010265839A CN111470785B CN 111470785 B CN111470785 B CN 111470785B CN 202010265839 A CN202010265839 A CN 202010265839A CN 111470785 B CN111470785 B CN 111470785B
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CN
China
Prior art keywords
self
layer
glass
cleaning
base layer
Prior art date
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Active
Application number
CN202010265839.3A
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Chinese (zh)
Other versions
CN111470785A (en
Inventor
董清世
付明军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Benson Automobile Glass Co ltd
Original Assignee
Dongguan Benson Automobile Glass Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN202010265839.3A priority Critical patent/CN111470785B/en
Publication of CN111470785A publication Critical patent/CN111470785A/en
Application granted granted Critical
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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B7/00Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
    • B24B7/20Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground
    • B24B7/22Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain
    • B24B7/24Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain for grinding or polishing glass
    • B24B7/242Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain for grinding or polishing glass for plate glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00Surface treatment of glass, not in the form of fibres or filaments, by etching
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/29Mixtures
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/71Photocatalytic coatings

Abstract

The invention belongs to the technical field of glass, and particularly relates to self-cleaning glass which comprises a glass base layer, an adhesive layer and a self-cleaning film layer, wherein the glass base layer is provided with two end faces which are oppositely arranged and an outer peripheral surface which is arranged between the two end faces in a surrounding mode, one end face of the glass base layer is frosted to form a frosted structure, the adhesive layer is adhered to the frosted structure, and the self-cleaning film layer is coated on the adhesive layer. Because the frosted structure can diffuse reflection to the light, the light is uniformly dispersed on the glass base layer after diffuse reflection of the frosted structure even when the light is intensively irradiated on the glass base layer, and the occurrence of local dazzling spots on the glass base layer is effectively reduced. And the frosted structure is arranged on the glass base layer, so that the roughness of the glass base layer on the end face is greatly improved, and the adhesive force of the adhesive layer on the end face of the glass base layer can be effectively improved, so that the self-cleaning film layer is adhered on the glass base layer more firmly.

Description

Self-cleaning glass
Technical Field
The invention belongs to the technical field of glass, and particularly relates to self-cleaning glass.
Background
"Easy-to-clean glass" is also commonly referred to visually as "self-cleaning glass". It means that super-hydrophilic or super-hydrophobic coating (wherein the water drop contact angle is less than 10 DEG is super-hydrophilic coating and the water drop contact angle is more than 110 DEG is super-hydrophobic coating) is formed on the surface of glass, so that dust or dirty liquid is difficult to adhere to the surface of glass, and can be easily washed away by water, and thus the surface of glass is very easy to keep clean. Self-cleaning glass has wide application, such as front windshields of automobiles, and outer walls of buildings, etc. However, when the existing self-cleaning glass is used, after the light irradiates on the self-cleaning glass, the light directly penetrates, so that the existing self-cleaning glass is easy to dazzle; for example, when an automobile runs, a driver cannot observe the automobile normally easily when the opposite automobile is irradiated by a high beam, and running safety is seriously affected; or people stand in the building, sunlight irradiates in, and the people are easy to dazzle.
Disclosure of Invention
The invention aims to provide self-cleaning glass, and aims to solve the technical problem that the self-cleaning glass in the prior art is relatively easy to dazzle.
In order to achieve the above purpose, the invention adopts the following technical scheme: the utility model provides a self-cleaning glass, includes glass basic unit, adhesive linkage and self-cleaning rete, the glass basic unit has two terminal surfaces that set up relatively and encloses to locate two peripheral face between the terminal surface, one of them of glass basic unit the frosting forms the frosting structure on the terminal surface, the adhesive linkage bond in on the frosting structure, the self-cleaning rete is scribbled and is located on the adhesive linkage.
Optionally, the frosted structure is formed by chemical etching or by mechanical polishing.
Optionally, a reflective layer for reflecting light is coated between the adhesive layer and the self-cleaning film layer.
Optionally, the light reflecting layer is provided with a plurality of through holes for transmitting light.
Optionally, the light reflecting layer is a blue light reflecting layer.
Optionally, a scratch-proof film net for protecting the self-cleaning film layer is coated on the self-cleaning film layer, and the edge of the scratch-proof film net is surrounded on the peripheral surface.
Optionally, the glass substrate is provided with a plurality of annular cavities, the normal line of the plane where the annular cavities are located passes through the two end faces, at least two annular cavities are sleeved in sequence, and annular ductile bands are filled in the annular cavities.
Optionally, a plurality of strip-shaped cavities are arranged on the glass substrate, the extending directions of the strip-shaped cavities are mutually perpendicular to the plane where the end faces are located, and strip-shaped ductile bands are filled in the strip-shaped cavities.
Optionally, the strip-shaped ductile band is disposed crosswise to the annular ductile band.
Optionally, the annular cavity is located on the same plane as the glass substrate.
The self-cleaning glass provided by the embodiment of the invention has the beneficial effects that: compared with the prior art, the self-cleaning glass has the advantages that the frosted structure is arranged on the end face of the glass base layer, so that when light irradiates on the glass base layer, the frosted structure can diffuse-reflect the light, so that the light is uniformly dispersed at all positions of the glass base layer after diffuse reflection of the frosted structure even when the light intensively irradiates on the glass base layer, and then irradiates one side of a user, the phenomenon that local dazzling spots appear on the glass base layer is effectively reduced, or the brightness of the spots is effectively reduced, and the stimulation to eyes of the user is reduced. And moreover, by arranging the frosted structure on the glass base layer, the roughness of the glass base layer on the end face is greatly improved, and the bonding force of the bonding layer on the end face of the glass base layer can be effectively improved, so that the self-cleaning film layer is bonded on the glass base layer more firmly, and the self-cleaning effect of glass is ensured.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are needed in the embodiments or the description of the prior art will be briefly described below, it being obvious that the drawings in the following description are only some embodiments of the present invention, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a schematic structural view of a self-cleaning glass according to an embodiment of the present invention;
FIG. 2 is a schematic cross-sectional view of the glass substrate of FIG. 1.
Wherein, each reference sign in the figure:
10-a glass substrate;
11—a first glass layer; 12-a second glass layer; 13-end face; 14-an outer peripheral surface; 15-a frosted structure; 16-an annular ductile band; 17-a strip-shaped ductile tape; 18-an annular chamber; 19-a bar-shaped cavity;
20-an adhesive layer;
30-self-cleaning film layer;
40-a light reflecting layer;
41-a through hole;
50-scratch-resistant film net.
Detailed Description
Embodiments of the present invention are described in detail below, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to like or similar elements or elements having like or similar functions throughout. The embodiments described below by referring to fig. 1-2 are exemplary and intended to illustrate the present invention and should not be construed as limiting the invention.
In the description of the present invention, it should be understood that the terms "length," "width," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like indicate orientations or positional relationships based on the orientation or positional relationships shown in the drawings, merely to facilitate describing the present invention and simplify the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and therefore should not be construed as limiting the present invention.
Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more such feature. In the description of the present invention, the meaning of "a plurality" is two or more, unless explicitly defined otherwise.
In the present invention, unless explicitly specified and limited otherwise, the terms "mounted," "connected," "secured," and the like are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communicated with the inside of two elements or the interaction relationship of the two elements. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art according to the specific circumstances.
As shown in fig. 1 to 2, the self-cleaning glass provided by the embodiment of the present invention will now be described. The self-cleaning glass comprises a glass base layer 10, an adhesive layer 20 and a self-cleaning film layer 30, wherein the glass base layer 10 is provided with two opposite end surfaces 13 and an outer peripheral surface 14 which is arranged between the two end surfaces 13 in a surrounding mode, one end surface 13 of the glass base layer 10 is frosted to form a frosted structure 15, the adhesive layer 20 is adhered to the frosted structure 15, and the self-cleaning film layer 30 is coated on the adhesive layer 20.
Compared with the prior art, the self-cleaning glass provided by the embodiment of the invention has the advantages that the frosted structure 15 is arranged on the end face 13 of the glass base layer 10, so that when light irradiates on the glass base layer 10, the frosted structure 15 can diffuse reflection of the light, so that the light is uniformly dispersed at each position of the glass base layer 10 after diffuse reflection of the frosted structure 15 even when the light intensively irradiates on the glass base layer 10, and then irradiates into one side of a user, thereby effectively reducing the occurrence of local dazzling spots on the glass base layer 10, or effectively reducing the brightness of the spots and reducing the stimulation to eyes of the user. Moreover, by arranging the frosted structure 15 on the glass base layer 10, the roughness of the glass base layer 10 on the end face 13 is greatly improved, and the adhesion force of the adhesive layer 20 on the end face 13 of the glass base layer 10 can be effectively improved, so that the adhesive of the self-cleaning film layer 30 on the glass base layer 10 is more stable, and the self-cleaning effect of glass is ensured.
Wherein, the self-cleaning film layer 30 is a nano material with photocatalytic activity, and comprises photocatalyst TiO2 and air catalyst titanium phosphate, wherein the TiO2 can absorb light with a certain wavelength and generate free electrons and holes, so that the pollutants absorbed on the surface of the film are subjected to redox decomposition to remove and kill surface microorganisms, thereby achieving the purpose of self cleaning; and because TiO2 can produce good photocatalytic property under the action of light energy (ultraviolet rays) and has super-hydrophilicity, very small water drops can be converged into large water drops by utilizing the super-hydrophilicity, and the large water drops fall off under the action of gravity, so that stains stained on the large water drops can be easily washed away by water, and the glass has the characteristic of easy cleaning, thereby being particularly suitable for outdoor building glass. The bonding layer 20 is an epoxy acrylic resin layer, has excellent chemical bonding force, has the thickness of 20-25 um, and can bond the self-cleaning film layer 30 and the glass base layer 10 together well.
In another embodiment of the present invention, the frosted structure 15 is formed by chemical etching or by mechanical polishing. Specifically, when the frosted structure 15 is formed, the end face 13 of the glass base layer 10 can be corroded by hydrofluoric acid, and also can be treated in a polishing mode, so that the glass base layer is convenient to manufacture.
In another embodiment of the present invention, as shown in fig. 1, a reflective layer 40 for reflecting light is coated between the adhesive layer 20 and the self-cleaning film layer 30. Specifically, by providing the reflective layer 40 to reflect part of the light, the light penetrating the glass substrate 10 from the outside is reduced, so that the temperature in the building can be effectively reduced in summer and the like when the illumination is strong, and a comfortable environment is provided for the user; and, light can be effectively reduced to emit to the bonding layer 20, so that the intensity of light irradiation and heat receiving of the bonding layer 20 is reduced, the bonding layer 20 is further protected, the bonding layer 20 maintains good bonding efficacy, and the service life of the bonding layer 20 is effectively prolonged. Wherein, the light-reflecting layer 40 can achieve the effect of partial light reflection by adjusting the light transmittance of the light-reflecting layer 40;
In another embodiment of the present invention, as shown in fig. 1, a plurality of through holes 41 for transmitting light are formed in the reflective layer 40. Specifically, by providing the through holes 41 on the light reflecting layer 40, a part of light can pass through each through hole 41, another part can not pass through the reflection of the light reflecting layer 40, and the light passing through each through hole 41 can be uniformly distributed on the glass base layer 10 under the diffuse reflection of the frosted structure 15, so that no light spot or local dazzling can occur, and the use effect is good.
In another embodiment of the present invention, the light reflecting layer 40 is a blue light reflecting layer 40. Specifically, the blue reflective layer 40 can effectively absorb ultraviolet rays in sunlight to reduce the intensity of ultraviolet rays emitted into a room, thereby achieving good sun protection.
In another embodiment of the present invention, as shown in fig. 1, the self-cleaning film layer 30 is coated with a scratch-proof film net 50 for protecting the self-cleaning film layer 30, and the edge of the scratch-proof film net 50 is wrapped around the outer circumferential surface 14. Specifically, the scratch-resistant film net 50 located at the outer side of the self-cleaning film layer 30 plays a certain role in isolation, and the scratch-resistant film net 50 can reduce the probability of contact between sharp objects and the self-cleaning film layer 30, and plays a role in protecting the self-cleaning film layer 30 to a certain extent. And by wrapping the edge of the scratch-resistant film net 50 on the outer peripheral surface 14 of the glass base layer 10, the scratch-resistant film net 50 can be effectively prevented from falling off, and the use effect is good.
In another embodiment of the present invention, as shown in fig. 1-2, the glass substrate 10 is provided with a plurality of annular cavities 18, the normal line of the plane of the annular cavities 18 passes through two end surfaces 13, at least two annular cavities 18 are sleeved in sequence, and the annular cavities 18 are filled with annular ductile tapes 16. Specifically, each annular cavity 18 is tiled in the direction of the end faces 13 (i.e. the normal line of the plane where the annular cavity 18 is located passes through the two end faces 13), each annular cavity 18 is gradually and outwards expanded from the middle of the glass substrate 10 to form a sleeved arrangement, namely, each annular ductile band 16 is sleeved on the glass substrate 10, the toughness of the ductile bands is greatly increased by arranging the sealed annular ductile bands 16 connected end to end in each annular cavity 18, and each annular ductile band 16 enables the toughness of the glass substrate 10 in the direction of the end faces 13 to be greatly improved, so that the glass is not easy to break, is impact-resistant, has long service life, can avoid splashing of fragments even when broken, and reduces potential safety hazards. Wherein the annular flexible band 16 is comprised of polyoxypropylene glycol, polyepoxysuccinic acid, and glutaraldehyde.
In another embodiment of the present invention, as shown in fig. 1, a plurality of strip-shaped cavities 19 are provided on the glass substrate 10, the extending direction of the strip-shaped cavities 19 is perpendicular to the plane of the end face 13, and the strip-shaped cavities 19 are filled with strip-shaped ductile tapes 17. Specifically, by arranging the strip-shaped ductile tape 17 between the two end surfaces 13, the toughness of the glass substrate 10 between the two end surfaces 13 can be greatly improved, so that the glass is not easy to break, is impact-resistant, has long service life, can avoid fragments from splashing even when broken, and reduces potential safety hazards. The strip-shaped flexible strip 17 is composed of polyoxypropylene glycol, polyepoxysuccinic acid and glutaraldehyde.
In another embodiment of the present invention, as shown in fig. 1-2, a strip-shaped ductile band 17 is disposed across an annular ductile band 16. Specifically, through making bar toughness area 17 and the crisscross setting of annular toughness area 16, just so form the toughness structure that is similar to "cross" between bar toughness area 17 and the annular toughness area 16, can greatly improve the toughness of glass basic unit 10 for glass is difficult for broken, and is shock-resistant, long service life, even when broken, also can avoid the piece to splash, reduce the potential safety hazard, safe in utilization.
In another embodiment of the present invention, as shown in FIGS. 1-2, the annular chamber 18 is located in the same plane as the glass substrate 10. Specifically, by locating the annular chambers 18 on the same level and at intermediate positions between the strip-shaped chambers 19, that is, locating the annular ductile bands 16 at intermediate height positions of the strip-shaped ductile bands 17, it is possible to uniformly stress the respective positions of the glass substrate 10 with good pressure resistance.
In another embodiment of the present invention, as shown in fig. 1, the glass substrate 10 includes a first glass layer 11 and a second glass layer 12, when the annular cavity 18 is disposed in the glass substrate 10, the glass substrate 10 is first divided into the first glass layer 11 and the second glass layer 12, and the annular cavity 18 may be disposed on the first glass layer 11 or on the second glass layer 12 according to the process requirement, and then the first glass layer 11 and the second glass layer 12 are bonded; the annular cavity 18 may be divided into two halves, that is, the first glass layer 11 and the second glass layer 12 are respectively provided with a semi-annular cavity, and then when the first glass layer 11 and the second glass layer 12 are bonded, the two semi-annular cavities are opposite to each other to splice the annular cavity 18. Then when the strip-shaped cavities 19 intersecting with the annular cavities 18 are provided, when the annular cavities 18 are independently provided on the first glass layer 11 or the second glass layer 12, the strip-shaped cavities 19 are also independently provided on the corresponding first glass layer 11 or the second glass layer 12, respectively, and the strip-shaped cavities 19 are communicated with the annular cavities 18; when the semi-annular concave cavities are correspondingly arranged on the first glass layer 11 and the second glass layer 12, the semi-strip-shaped cavities are correspondingly arranged on the first glass layer 11 and the second glass layer 12, and the semi-strip-shaped cavities are communicated with the semi-annular concave cavities.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the invention.

Claims (7)

1. A self-cleaning glass, characterized in that: the self-cleaning glass comprises a glass base layer, an adhesive layer and a self-cleaning film layer, wherein the glass base layer is provided with two end faces which are oppositely arranged and an outer peripheral surface which is arranged between the two end faces in a surrounding mode, one end face of the glass base layer is frosted to form a frosted structure, the adhesive layer is adhered to the frosted structure, and the self-cleaning film layer is coated on the adhesive layer;
a reflective layer for reflecting light is coated between the bonding layer and the self-cleaning film layer;
The reflecting layer is provided with a plurality of through holes for transmitting light;
The light reflecting layer is a blue light reflecting layer.
2. A self-cleaning glass according to claim 1, wherein: the frosted structure is formed by chemical etching or by mechanical polishing.
3. A self-cleaning glass according to claim 1 or claim 2, wherein: the self-cleaning film layer is coated with a scratch-resistant film net for protecting the self-cleaning film layer, and the edge of the scratch-resistant film net is surrounded on the peripheral surface.
4. A self-cleaning glass according to claim 1 or claim 2, wherein: the glass substrate is provided with a plurality of annular cavities, the normal line of the plane where the annular cavities are located penetrates through the two end faces, at least two annular cavities are sequentially sleeved and arranged, and annular ductile bands are filled in the annular cavities.
5. A self-cleaning glass according to claim 4, wherein: the glass substrate is provided with a plurality of strip-shaped cavities, the extending directions of the strip-shaped cavities are mutually perpendicular to the plane where the end faces are located, and strip-shaped flexible strips are filled in the strip-shaped cavities.
6. A self-cleaning glass according to claim 5, wherein: the strip-shaped ductile band is crossed with the annular ductile band.
7. A self-cleaning glass according to claim 6, wherein: the annular cavities are located on the same plane of the glass substrate.
CN202010265839.3A 2020-04-07 2020-04-07 Self-cleaning glass Active CN111470785B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010265839.3A CN111470785B (en) 2020-04-07 2020-04-07 Self-cleaning glass

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Application Number Priority Date Filing Date Title
CN202010265839.3A CN111470785B (en) 2020-04-07 2020-04-07 Self-cleaning glass

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CN111470785A CN111470785A (en) 2020-07-31
CN111470785B true CN111470785B (en) 2024-04-23

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012018424A (en) * 2011-10-18 2012-01-26 Sony Corp Optical body, wall material, fittings and solar shading device
CN105670565A (en) * 2014-11-18 2016-06-15 中国科学院兰州化学物理研究所 Self-clean material having self-repair function and preparation method thereof
CN107641345A (en) * 2017-11-03 2018-01-30 张家港外星人新材料科技有限公司 A kind of self-cleaning nona coating, inorganic transparent coating and automatically cleaning product
WO2019008596A1 (en) * 2017-07-04 2019-01-10 Saint-Gobain Glass France A frosted glass article
CN209128321U (en) * 2018-10-31 2019-07-19 大冶市古冶玻璃有限公司 A kind of high-strength armoured-glass
CN212425876U (en) * 2020-04-07 2021-01-29 东莞奔迅汽车玻璃有限公司 Self-cleaning glass

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012018424A (en) * 2011-10-18 2012-01-26 Sony Corp Optical body, wall material, fittings and solar shading device
CN105670565A (en) * 2014-11-18 2016-06-15 中国科学院兰州化学物理研究所 Self-clean material having self-repair function and preparation method thereof
WO2019008596A1 (en) * 2017-07-04 2019-01-10 Saint-Gobain Glass France A frosted glass article
CN107641345A (en) * 2017-11-03 2018-01-30 张家港外星人新材料科技有限公司 A kind of self-cleaning nona coating, inorganic transparent coating and automatically cleaning product
CN209128321U (en) * 2018-10-31 2019-07-19 大冶市古冶玻璃有限公司 A kind of high-strength armoured-glass
CN212425876U (en) * 2020-04-07 2021-01-29 东莞奔迅汽车玻璃有限公司 Self-cleaning glass

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