CN111455672A - Sports wear with sterilization function and preparation method thereof - Google Patents
Sports wear with sterilization function and preparation method thereof Download PDFInfo
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- CN111455672A CN111455672A CN202010327642.8A CN202010327642A CN111455672A CN 111455672 A CN111455672 A CN 111455672A CN 202010327642 A CN202010327642 A CN 202010327642A CN 111455672 A CN111455672 A CN 111455672A
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- parts
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- silver powder
- sportswear
- fabric
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/0015—Sports garments other than provided for in groups A41D13/0007 - A41D13/088
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/14—Air permeable, i.e. capable of being penetrated by gases
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Abstract
The invention discloses sportswear with a sterilization function and a preparation method thereof, wherein the sportswear comprises a fabric, and the fabric comprises the following raw materials, by weight, 18-22 parts of a base fabric, 14-18 parts of epoxy resin, 8-12 parts of an aromatic, 11-15 parts of ethyl orthosilicate, 8-12 parts of calcium carbonate, 8-12 parts of porous silver powder, 6-8 parts of an adhesive, 9-11 parts of sodium sulfate, 1-3 parts of a flame-retardant additive, 10-12 parts of a deodorant, 6-8 parts of a dispersing agent, 6-10 parts of modified β -cyclodextrin and 15-20 parts of deionized water.
Description
Technical Field
The invention relates to the technical field of sports clothes, in particular to a sports clothes with a sterilization function and a preparation method thereof.
Background
With the improvement of living standard of substances, the requirements of people on textiles are not limited to the original basic characteristics of warmth retention, comfort and the like. And turns the eyesight to the functional fabrics for health care, sterilization and the like. The bactericidal fabric has good safety, can efficiently and completely remove bacteria, fungi and mould on the fabric, keeps the fabric clean, and can prevent bacteria from regenerating and propagating. The mainstream treatment methods in the market at present have two types: one is a built-in silver ion antibacterial fabric, and an antibacterial agent is directly made into chemical fibers by adopting a spinning-grade antibacterial technology; the other is a post-processing technology, namely adding the fabric through a subsequent shaping process of the fabric. However, the built-in silver ion antibacterial fabric has many defects, such as poor air permeability and weak antibacterial ability. Therefore, the technical problem to be solved by the invention is how to design the sportswear with good air permeability and strong sterilization capability and the sterilization function and the preparation method thereof.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides the sports wear with good air permeability and strong sterilization capability and the sterilization function and the preparation method thereof.
The invention solves the technical problems through the following technical means:
the sportswear with the sterilization function comprises, by weight, 18-22 parts of basic fabric, 14-18 parts of epoxy resin, 8-12 parts of an aromatic, 11-15 parts of tetraethoxysilane, 8-12 parts of calcium carbonate, 8-12 parts of porous silver powder, 6-8 parts of an adhesive, 9-11 parts of sodium sulfate, 1-3 parts of a flame retardant additive, 10-12 parts of a deodorant, 6-8 parts of a dispersing agent, 6-10 parts of modified β -cyclodextrin and 15-20 parts of deionized water.
Preferably, the porous silver powder for sportswear with a sterilization function is prepared by the following steps: mixing silver powder, nano montmorillonite powder and paraffin, and stirring uniformly; then the mixture is made into a block shape and is molded by a die casting machine; and heating the formed block to gasify the paraffin, cooling and grinding to obtain the porous silver powder.
Preferably, the sportswear with the sterilization function comprises the following silver powder, nano montmorillonite powder and paraffin in parts by weight: 65% of silver powder, 30% of nano montmorillonite powder and 5% of paraffin.
Preferably, the pressure of the sports wear with the sterilization function is 750-850MPa when a die casting machine is adopted for die forming.
Preferably, the conditions for the heat treatment of the formed block are as follows: heating to 850 ℃ and 950 ℃, and preserving heat for 3-4 h.
The preparation method of the fabric comprises the following steps:
(1) soaking the base fabric in deionized water, heating to 55-65 ℃, soaking, softening for 1-2h, adding an aromatic, a flame retardant additive, a deodorant and modified β -cyclodextrin, heating to 75-80 ℃, and slowly stirring and mixing for 1-2h to obtain a mixture a;
(2) mixing epoxy resin, ethyl orthosilicate and a dispersing agent, feeding the mixture into a reaction kettle, stirring and reacting for 35-45min under the water bath heating of 100-105 ℃, cooling to 80-88 ℃, adding calcium carbonate and porous silver powder, and stirring and mixing for 30-35min at the rotating speed of 220-260r/min under a magnetic stirrer to obtain a mixture b;
(3) mixing the mixture a and the mixture b, carrying out ultrasonic oscillation treatment for 12-16min, then heating at 50-60 ℃, and stirring and mixing for 1-2h to obtain a mixture c;
(4) and (3) adding sodium sulfate and an adhesive into the mixture c, pressurizing and heating the mixture for mixing for 30-40min at the temperature of 68-72 ℃ under the pressure of 4-6MPa, filtering and drying to obtain the fabric.
The preparation method of the sports wear with the sterilization function is characterized in that the sports wear is made of the fabric through sewing.
The invention has the advantages that: the silver powder is used as a bactericide and plays a role in killing bacteria, the nano montmorillonite is used as a carrier of the silver powder on one hand and has an adsorption effect on bacteria on the other hand, and the nano montmorillonite can adsorb the bacteria onto the silver powder after being compounded with the silver powder, so that the sterilization capability is improved; the paraffin is used for fusing the silver powder and the nano-montmorillonite to enable the silver powder and the nano-montmorillonite to be easy to form blocks, and on the other hand, tiny holes can be formed after gasification, so that a processed mixture has a porous structure, and the air permeability of the fabric is improved.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The sportswear with the sterilization function comprises fabric, wherein the fabric comprises the following raw materials in parts by weight (kg) of base fabric 20, epoxy resin 16, aromatic 10, tetraethoxysilane 13, calcium carbonate 10, porous silver powder 10, adhesive 7, sodium sulfate 10, flame-retardant additive 2, deodorant 11, dispersing agent 7, modified β -cyclodextrin 8 and deionized water 17.
Preferably, the preparation method of the porous silver powder comprises the following steps: mixing silver powder, nano montmorillonite powder and paraffin, and stirring uniformly; then the mixture is made into a block shape and is molded by a die casting machine; and heating the formed block to gasify the paraffin, cooling and grinding to obtain the porous silver powder.
Preferably, the silver powder, the nano montmorillonite powder and the paraffin are in the following weight ratio: 65% of silver powder, 30% of nano montmorillonite powder and 5% of paraffin.
Preferably, the pressure intensity of the sports wear with the sterilization function is 800MPa when the sports wear is molded by a die-casting machine.
Preferably, the conditions for the heat treatment of the formed block are as follows: heating to 900 deg.C, and maintaining for 3.5 h.
The preparation method of the fabric comprises the following steps:
(1) soaking the base fabric in deionized water, heating to 60 ℃, soaking, softening for 1.5h, adding an aromatic, a flame retardant additive, a deodorant and modified β -cyclodextrin, heating to 78 ℃, and slowly stirring and mixing for 1.2h to obtain a mixture a;
(2) mixing epoxy resin, tetraethoxysilane and a dispersing agent, feeding the mixture into a reaction kettle, stirring and reacting for 40min under the heating of water bath at 103 ℃, cooling to 84 ℃, adding calcium carbonate and porous silver powder, and stirring and mixing for 33min at the rotating speed of 240r/min under a magnetic stirrer to obtain a mixture b;
(3) mixing the mixture a and the mixture b, carrying out ultrasonic oscillation treatment for 14min, and then heating and stirring at 55 ℃ for 1.2h to obtain a mixture c;
(4) and (3) adding sodium sulfate and an adhesive into the mixture c, pressurizing, heating and mixing for 35min at the temperature of 70 ℃ under the pressure of 5MPa, filtering and drying to obtain the fabric.
The preparation method of the sports wear with the sterilization function is characterized in that the sports wear is made of the fabric through sewing.
In the above embodiment, the silver powder is used as a bactericide to kill bacteria, and the nano montmorillonite is used as a carrier of the silver powder on one hand and has an adsorption effect on bacteria on the other hand, and can adsorb the bacteria on the silver powder after being compounded with the silver powder, so that the bactericidal ability is improved; the paraffin is used for fusing the silver powder and the nano-montmorillonite to enable the silver powder and the nano-montmorillonite to be easy to form blocks, and on the other hand, tiny holes can be formed after gasification, so that a processed mixture has a porous structure, and the air permeability of the fabric is improved.
It is noted that, in this document, relational terms such as first and second, and the like, if any, are used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (7)
1. The sportswear with the sterilization function comprises fabric and is characterized in that the fabric comprises, by weight, 18-22 parts of basic fabric, 14-18 parts of epoxy resin, 8-12 parts of an aromatic, 11-15 parts of tetraethoxysilane, 8-12 parts of calcium carbonate, 8-12 parts of porous silver powder, 6-8 parts of an adhesive, 9-11 parts of sodium sulfate, 1-3 parts of a flame-retardant additive, 10-12 parts of a deodorant, 6-8 parts of a dispersant, 6-10 parts of modified β -cyclodextrin and 15-20 parts of deionized water.
2. The sportswear with bactericidal function according to claim 1, characterized in that: the preparation method of the porous silver powder comprises the following steps: mixing silver powder, nano montmorillonite powder and paraffin, and stirring uniformly; then the mixture is made into a block shape and is molded by a die casting machine; and heating the formed block to gasify the paraffin, cooling and grinding to obtain the porous silver powder.
3. The sportswear with the sterilization function according to claim 2, wherein the weight ratio of the silver powder, the nano montmorillonite powder and the paraffin is as follows: 65% of silver powder, 30% of nano montmorillonite powder and 5% of paraffin.
4. The sportswear with bactericidal function according to claim 2, characterized in that: when a die casting machine is adopted for die forming, the pressure is 750-850 MPa.
5. The sportswear with bactericidal function according to claim 2, characterized in that: the conditions for the heat treatment of the formed block are as follows: heating to 850 ℃ and 950 ℃, and preserving heat for 3-4 h.
6. The sportswear with the sterilization function according to claim 1, wherein the preparation method of the fabric comprises the following steps:
(1) soaking the base fabric in deionized water, heating to 55-65 ℃, soaking, softening for 1-2h, adding an aromatic, a flame retardant additive, a deodorant and modified β -cyclodextrin, heating to 75-80 ℃, and slowly stirring and mixing for 1-2h to obtain a mixture a;
(2) mixing epoxy resin, ethyl orthosilicate and a dispersing agent, feeding the mixture into a reaction kettle, stirring and reacting for 35-45min under the water bath heating of 100-105 ℃, cooling to 80-88 ℃, adding calcium carbonate and porous silver powder, and stirring and mixing for 30-35min at the rotating speed of 220-260r/min under a magnetic stirrer to obtain a mixture b;
(3) mixing the mixture a and the mixture b, carrying out ultrasonic oscillation treatment for 12-16min, then heating at 50-60 ℃, and stirring and mixing for 1-2h to obtain a mixture c;
(4) and (3) adding sodium sulfate and an adhesive into the mixture c, pressurizing and heating the mixture for mixing for 30-40min at the temperature of 68-72 ℃ under the pressure of 4-6MPa, filtering and drying to obtain the fabric.
7. A method for preparing the sportswear with the bactericidal function according to claim 1, which is characterized in that: is made by sewing the fabrics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010327642.8A CN111455672A (en) | 2020-04-23 | 2020-04-23 | Sports wear with sterilization function and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010327642.8A CN111455672A (en) | 2020-04-23 | 2020-04-23 | Sports wear with sterilization function and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111455672A true CN111455672A (en) | 2020-07-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010327642.8A Pending CN111455672A (en) | 2020-04-23 | 2020-04-23 | Sports wear with sterilization function and preparation method thereof |
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| Country | Link |
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| CN (1) | CN111455672A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1120819A (en) * | 1993-12-10 | 1996-04-17 | 东陶机器株式会社 | Multi-functional material having photo-catalytic function and production method therefor |
| CN108716113A (en) * | 2018-06-13 | 2018-10-30 | 合肥云都棉花有限公司 | A kind of deodorization garment material and preparation method thereof |
| CN108951162A (en) * | 2018-07-26 | 2018-12-07 | 合肥远科服装设计有限公司 | A kind of new waterproof garment material and preparation method thereof |
| CN108976871A (en) * | 2018-05-02 | 2018-12-11 | 安徽沛隆智能机械科技有限公司 | A kind of additive improving wooden toy coating biocidal property |
| CN109468030A (en) * | 2018-11-13 | 2019-03-15 | 安徽桑瑞斯环保新材料有限公司 | A kind of environment-friendly powder coating of fragrance sterilization |
-
2020
- 2020-04-23 CN CN202010327642.8A patent/CN111455672A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1120819A (en) * | 1993-12-10 | 1996-04-17 | 东陶机器株式会社 | Multi-functional material having photo-catalytic function and production method therefor |
| CN108976871A (en) * | 2018-05-02 | 2018-12-11 | 安徽沛隆智能机械科技有限公司 | A kind of additive improving wooden toy coating biocidal property |
| CN108716113A (en) * | 2018-06-13 | 2018-10-30 | 合肥云都棉花有限公司 | A kind of deodorization garment material and preparation method thereof |
| CN108951162A (en) * | 2018-07-26 | 2018-12-07 | 合肥远科服装设计有限公司 | A kind of new waterproof garment material and preparation method thereof |
| CN109468030A (en) * | 2018-11-13 | 2019-03-15 | 安徽桑瑞斯环保新材料有限公司 | A kind of environment-friendly powder coating of fragrance sterilization |
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Application publication date: 20200728 |
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