CN111446082A - Reactive compensation dry-type capacitor - Google Patents

Reactive compensation dry-type capacitor Download PDF

Info

Publication number
CN111446082A
CN111446082A CN202010289756.8A CN202010289756A CN111446082A CN 111446082 A CN111446082 A CN 111446082A CN 202010289756 A CN202010289756 A CN 202010289756A CN 111446082 A CN111446082 A CN 111446082A
Authority
CN
China
Prior art keywords
carbon fiber
fiber cloth
solution
putting
reactive compensation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010289756.8A
Other languages
Chinese (zh)
Inventor
童克锋
赵凤龙
洪磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NINGBO JIANGBEI GOFRONT HERONG ELECTRIC CO Ltd
Original Assignee
NINGBO JIANGBEI GOFRONT HERONG ELECTRIC CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NINGBO JIANGBEI GOFRONT HERONG ELECTRIC CO Ltd filed Critical NINGBO JIANGBEI GOFRONT HERONG ELECTRIC CO Ltd
Priority to CN202010289756.8A priority Critical patent/CN111446082A/en
Publication of CN111446082A publication Critical patent/CN111446082A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/24Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/46Metal oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/84Processes for the manufacture of hybrid or EDL capacitors, or components thereof
    • H01G11/86Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

The invention provides a reactive compensation dry capacitor, which improves the integral capacitor characteristics by improving a polar plate in a reactive compensation dry capacitor body and enabling an electrode layer of the polar plate to have nickel-manganese hydroxide, zinc oxide nanowires and carbon fibers. For example, the zinc oxide nanowires can greatly increase the overall surface area of the electrode layer, thereby greatly improving the overall specific capacitance. In addition, after the service life of the capacitor is measured by a pulse electrodeposition method, the maintenance rate of the capacitor still reaches about 86% after more than 3000 circles of tests, so that the capacitor has the advantage of long service life.

Description

Reactive compensation dry-type capacitor
Technical Field
The invention relates to the technical field of capacitors, in particular to a reactive compensation dry-type capacitor.
Background
With the development of technology, an electric double layer capacitor (ED L C, also called super capacitor) has been used as a passive component of a circuit, and is gradually used as a storage battery.
Because most of the existing energy storage units are developed towards the directions of high energy density, long service life, high reversibility and the like, the capacitor can be applied to various purposes, such as electric locomotives. Therefore, the inventor of the present invention has considered that the practical applicability of the capacitor can be greatly improved if the specific capacitance and the service life of the entire capacitor can be improved.
Disclosure of Invention
The problem to be solved by the present invention is the above-mentioned problems regarding the specific capacitance value of the capacitor as a whole, the service life, etc.
In order to solve the above problems, the present invention provides a reactive compensation dry capacitor, which has the following technical scheme:
the reactive compensation dry type capacitor comprises a shell and a reactive compensation dry type capacitor body, wherein the reactive compensation dry type capacitor body is arranged in the shell and comprises a polar plate, and the polar plate comprises a substrate and an electrode layer arranged on the surface of the substrate.
The manufacturing method of the polar plate comprises the following steps:
(1) sequentially carrying out ultrasonic vibration cleaning on the carbon fiber cloth by using an acetone solution, an alcohol solution and a deionized water solution, and then putting the carbon fiber cloth into a baking oven for drying; putting the carbon fiber cloth into a zinc acetate absolute ethyl alcohol solution for ultrasonic vibration cleaning, and then putting the carbon fiber cloth into the baking oven for drying; and putting the carbon fiber cloth into a nitrogen environment for annealing treatment.
(2) And mixing a zinc acetate solution and a hexamethyltetramine solution to obtain a second mixed solution, putting the carbon fiber cloth into the first mixed solution, maintaining the fixed temperature for a period of time, and then putting the carbon fiber cloth into the baking oven to be dried after being cleaned by deionized water.
(3) Mixing a nickel nitrate solution and a potassium permanganate solution to obtain a second mixed solution, putting the carbon fiber cloth into the second mixed solution for electrochemical deposition, cleaning the carbon fiber cloth with deionized water, and putting the carbon fiber cloth into the baking oven for drying.
(4) And putting the carbon fiber cloth into a high-temperature furnace for thermal annealing treatment, cleaning the carbon fiber cloth with deionized water, putting the carbon fiber cloth into the baking oven for drying, and arranging the carbon fiber cloth on the surface of the substrate.
Compared with the prior art, the invention has the advantages that: the electrode layer is provided with nickel-manganese hydroxide, zinc oxide nanowires and carbon fibers, and the zinc oxide nanowires and the carbon fibers are penetrated, so that the whole capacitor has a very large surface area, and the specific capacitance value of the whole capacitor is greatly improved. In addition, the service life of the whole capacitor is greatly prolonged through the matching of the nickel-manganese hydroxide, the zinc oxide nanowires and the carbon fibers, and after 3000 circles of tests of a pulse electrodeposition method, the capacitor still has a maintenance rate of about 86 percent, so that the advantage of long service life of the capacitor is highlighted.
Drawings
FIG. 1 is a schematic diagram illustrating an appearance of the present invention;
FIG. 2 is a schematic view of an embodiment of a conductive terminal;
FIG. 3 is a flow chart of a method of fabricating a plate;
FIG. 4 is a flow chart of a method of making the electrolyte;
fig. 5 is a schematic connection diagram of the components.
Description of reference numerals:
a housing; 11-a top wall; 2-reactive compensation dry capacitor body; 3-conductive terminal; 4-strip plate body; 5-discharge resistance; 6-temperature controller; 7-circuit breaker.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention comprehensible, embodiments accompanied with figures are described in detail below.
Example 1
Referring to fig. 1, the present invention relates to a reactive compensation dry capacitor, which is characterized in that the reactive compensation dry capacitor comprises:
the reactive compensation dry type capacitor comprises a shell 1 and a reactive compensation dry type capacitor body 2, wherein the reactive compensation dry type capacitor body 2 is arranged in the shell 1, the reactive compensation dry type capacitor body 2 comprises a polar plate, and the polar plate comprises a substrate and an electrode layer arranged on the surface of the substrate.
The manufacturing method of the polar plate comprises the following steps:
(1) sequentially carrying out ultrasonic vibration cleaning on the carbon fiber cloth by using an acetone solution, an alcohol solution and a deionized water solution, and then putting the carbon fiber cloth into a baking oven for drying; putting the carbon fiber cloth into a zinc acetate absolute ethyl alcohol solution for ultrasonic vibration cleaning, and then putting the carbon fiber cloth into the baking oven for drying; and putting the carbon fiber cloth into a nitrogen environment for annealing treatment.
In this way, the carbon fiber cloth forms a zinc oxide layer on the surface.
(2) Mixing a zinc acetate solution and a hexamethyltetramine solution to obtain a first mixed solution, putting the carbon fiber cloth into the first mixed solution, maintaining the fixed temperature for a period of time (preferably repeating the above process at least once), and then putting the carbon fiber cloth into the baking oven to be dried after being cleaned by deionized water.
Thus, the zinc oxide layer starts to grow zinc oxide nanowires.
(3) Mixing a nickel nitrate solution and a potassium permanganate solution to obtain a second mixed solution, putting the carbon fiber cloth into the second mixed solution for electrochemical deposition, cleaning the carbon fiber cloth with deionized water, and putting the carbon fiber cloth into the baking oven for drying.
Therefore, the nickel-manganese hydroxide nano-layer can grow on the surface of the zinc oxide nano-wire. In addition, during the electrochemical deposition process, the counter electrode and the reference electrode are preferably selected from platinum and silver chloride, respectively.
(4) And putting the carbon fiber cloth into a high-temperature furnace for thermal annealing treatment, cleaning the carbon fiber cloth with deionized water, putting the carbon fiber cloth into the baking oven for drying, so that the nickel-manganese hydroxide nano-layer becomes a nickel-manganese oxide nano-layer, and finally arranging the carbon fiber cloth on the surface of the substrate to complete the polar plate.
Through the above description, the electrode layer of the present invention has nickel-manganese hydroxide, zinc oxide nanowires, and carbon fibers, and the zinc oxide nanowires greatly increase the overall surface area and thus increase the overall specific capacitance. In the aspect of service life, the maintenance rate of the invention is about 86% after more than 3000 circles of tests by using a pulse electrodeposition method, and the invention has the advantage of long service life.
Example 2:
referring to fig. 4, the electrolyte of the reactive compensation dry capacitor body 2 is preferably a colloidal polyelectrolyte film. The following describes a method of manufacturing the colloidal polyelectrolyte thin film:
(1) adding polyethylene glycol (PEG), deionized water and nitrogen into a double-neck reactor, heating and stirring for a period of time, preferably at about 40 ℃, adding acrylonitrile (PAN) into the double-neck reactor, and heating and stirring for a period of time, preferably at about 40 ℃; dissolving ceric nitrate amine into a nitric acid solution to obtain a third mixed solution; and slowly adding the third mixed solution into the double-neck reactor until complete reaction to obtain a heterogeneous solution, performing air-suction filtration on the heterogeneous solution, then repeatedly cleaning the heterogeneous solution by deionized water and acetone for multiple times, and then performing drying treatment, preferably drying the heterogeneous solution in a vacuum oven at about 80 ℃ to obtain PAN-b-PEG-b-PAN triblock copolymer polymer, wherein the chain segment ratio between AN and EG in the PAN-b-PEG-b-PAN triblock copolymer polymer can be adjusted by changing the weight of acrylonitrile. The molecular formula of the PAN-b-PEG-b-PAN triblock copolymer is as follows:
Figure BDA0002449947140000051
(2) putting PAN-b-PEG-b-PAN triblock copolymer polymer, lithium perchlorate and dimethylformamide into a container, heating the container by a high-temperature oven at about 80 ℃ to obtain a homogeneous polymer electrolyte solution, putting a trace (such as 0.1g) of the homogeneous polymer electrolyte solution into an aluminum disc, and heating the aluminum disc to evaporate the dimethylformamide to obtain the colloidal polymer electrolyte film.
The colloidal polyelectrolyte film has a special linear structure through the triblock copolymer, and can effectively reduce the ion mobility resistance (equivalent series resistance) and the mass transfer diffusion resistance (Warburgregation) in impedance. In summary, the synergistic effect of acrylonitrile and ethylene glycol can greatly improve the surface of the reactive compensation dry capacitor in terms of energy storage performance, specific energy, specific power, etc., for example, at a specific power of 10 kWkg-1Under the condition of (1), the specific energy can reach up to 21Wh kg-1At a low discharge rate of 0.12Ag-1Under the condition of (2), the maximum specific energy can also be up to 30kWkg-1
Example 3:
please refer to fig. 2, the embodiment is: the surface of the shell 1 is provided with a plurality of conductive terminals 3 which are arranged in sequence at intervals, each conductive terminal 3 is electrically connected with the reactive compensation dry-type capacitor body 2, the bottom end of each conductive terminal 3 penetrates through the top wall 11 of the shell 1 and the strip-shaped plate 4 in sequence, and a space is formed between the strip-shaped plate 4 and the top wall 11 of the shell 1.
Therefore, through the top wall 11 and the strip-shaped plate 4 which are spaced apart from each other, the conductive terminals 3 can be more stably disposed on the top surface of the housing 1, and are not easily damaged by external force.
Example 4:
referring to fig. 5, in order to ensure the safety of the present invention during the use of electricity, the present invention further makes each conductive terminal 3 electrically connected to a discharge resistor 5, and each discharge resistor 5 is disposed outside the top wall 11 of the housing 1.
Example 5:
referring to fig. 5, in order to ensure the safety of the power utilization of the present invention, the operation is stopped when the temperature rises to the default value to avoid accidents, and for this reason, the present invention may further be implemented as follows: a temperature controller 6 is arranged in the shell 1, a circuit breaker 7 is arranged on a section of a path of each conductive terminal 3 electrically connected with the reactive compensation dry type capacitor body 2, and when the temperature controller 6 detects that the temperature of the reactive compensation dry type capacitor body 2 exceeds the default temperature, the circuit breaker 7 is controlled to form a circuit break.
Example 6:
in order to avoid the over-high temperature of the present creation during use, the housing 1 is preferably made of metal material, and a plurality of heat dissipation fins are disposed on the outer side of the housing, so that the creation can keep a low temperature during use and is not easy to cause accidents.
Although the present disclosure has been described above, the scope of the present disclosure is not limited thereto. Various changes and modifications may be effected therein by one of ordinary skill in the pertinent art without departing from the spirit and scope of the present disclosure, and these changes and modifications are intended to be within the scope of the present disclosure.

Claims (6)

1. A reactive compensation dry capacitor comprising:
the reactive compensation dry type capacitor comprises a shell and a reactive compensation dry type capacitor body, wherein the reactive compensation dry type capacitor body is arranged in the shell and comprises a polar plate, and the polar plate comprises a substrate and an electrode layer arranged on the surface of the substrate;
the manufacturing method of the polar plate comprises the following steps:
(1) sequentially carrying out ultrasonic vibration cleaning on the carbon fiber cloth by using an acetone solution, an alcohol solution and a deionized water solution, and then putting the carbon fiber cloth into a baking oven for drying; putting the carbon fiber cloth into a zinc acetate absolute ethyl alcohol solution for ultrasonic vibration cleaning, and then putting the carbon fiber cloth into the baking oven for drying; putting the carbon fiber cloth into a nitrogen environment for annealing treatment;
(2) mixing a zinc acetate solution and a hexamethyltetramine solution to obtain a first mixed solution, putting the carbon fiber cloth into the first mixed solution, maintaining the fixed temperature for a period of time, cleaning the carbon fiber cloth with deionized water, and then putting the carbon fiber cloth into the baking oven for drying;
(3) mixing a nickel nitrate solution and a potassium permanganate solution to obtain a second mixed solution, putting the carbon fiber cloth into the second mixed solution for electrochemical deposition, cleaning the carbon fiber cloth with deionized water, and putting the carbon fiber cloth into the baking oven for drying;
(4) and putting the carbon fiber cloth into a high-temperature furnace for thermal annealing treatment, cleaning the carbon fiber cloth with deionized water, putting the carbon fiber cloth into the baking oven for drying, and arranging the carbon fiber cloth on the surface of the substrate.
2. A reactive power compensation dry capacitor as claimed in claim 1, wherein the electrolyte of the reactive power compensation dry capacitor body is a colloidal polymer electrolyte film, and the colloidal polymer electrolyte film is fabricated by: (1) adding polyethylene glycol (PEG), deionized water and nitrogen into a double-neck reactor, heating and stirring for a period of time, adding acrylonitrile (PAN) into the double-neck reactor, and heating and stirring for a period of time; dissolving ceric nitrate amine into a nitric acid solution to obtain a third mixed solution; slowly adding the third mixed solution into the double-neck reactor, obtaining a heterogeneous solution after complete reaction, performing air-extraction filtration on the heterogeneous solution, then respectively cleaning with deionized water and acetone, and then drying to obtain a PAN-b-PEG-b-PAN triblock copolymer polymer; the molecular formula of the PAN-b-PEG-b-PAN triblock copolymer is as follows:
(2) putting PAN-b-PEG-b-PAN triblock copolymer polymer, lithium perchlorate and dimethylformamide into a container, heating by a high-temperature oven to obtain homogeneous polymer electrolyte solution, and taking trace elements
Figure FDA0002449947130000021
And placing the homogeneous polymer electrolyte solution in an aluminum disc, and then heating to evaporate the dimethylformamide to obtain the colloidal polymer electrolyte film.
3. A reactive compensation dry capacitor as claimed in claim 2, wherein the housing has a plurality of conductive terminals arranged in sequence at intervals, each conductive terminal is electrically connected to the reactive compensation dry capacitor body, the bottom end of each conductive terminal is sequentially inserted through the top wall of the housing, and the strip-shaped plate is spaced from the top wall of the housing.
4. A reactive compensation dry capacitor as claimed in claim 3, wherein each conductive terminal is electrically connected to a discharge resistor, and each discharge resistor is disposed outside the top wall of the housing.
5. A reactive compensation dry capacitor as claimed in claim 4 wherein a temperature controller is provided in the housing, a circuit breaker is provided on a section of the path where each conductive terminal is electrically connected to the reactive compensation dry capacitor body, and the circuit breaker is controlled to open when the temperature controller detects that the temperature of the reactive compensation dry capacitor body exceeds a predetermined temperature.
6. A reactive compensation dry capacitor as claimed in claim 5 wherein the housing is made of metal and has a plurality of heat dissipating fins on the outside.
CN202010289756.8A 2020-04-14 2020-04-14 Reactive compensation dry-type capacitor Pending CN111446082A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010289756.8A CN111446082A (en) 2020-04-14 2020-04-14 Reactive compensation dry-type capacitor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010289756.8A CN111446082A (en) 2020-04-14 2020-04-14 Reactive compensation dry-type capacitor

Publications (1)

Publication Number Publication Date
CN111446082A true CN111446082A (en) 2020-07-24

Family

ID=71651852

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010289756.8A Pending CN111446082A (en) 2020-04-14 2020-04-14 Reactive compensation dry-type capacitor

Country Status (1)

Country Link
CN (1) CN111446082A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201518278U (en) * 2009-09-16 2010-06-30 厦门法拉电子股份有限公司 Dry capacitor structure with temperature fuse
JP2010267669A (en) * 2009-05-12 2010-11-25 Nissin Electric Co Ltd Dry capacitor
CN205159103U (en) * 2015-09-29 2016-04-13 李叶 Multipurpose dry condenser
CN207397955U (en) * 2017-10-23 2018-05-22 苏州士林电机有限公司 The external band temperature control dry-type capacitor device of resistance

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010267669A (en) * 2009-05-12 2010-11-25 Nissin Electric Co Ltd Dry capacitor
CN201518278U (en) * 2009-09-16 2010-06-30 厦门法拉电子股份有限公司 Dry capacitor structure with temperature fuse
CN205159103U (en) * 2015-09-29 2016-04-13 李叶 Multipurpose dry condenser
CN207397955U (en) * 2017-10-23 2018-05-22 苏州士林电机有限公司 The external band temperature control dry-type capacitor device of resistance

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
洪鉅晁: "鎳-錳氫氧化物/氧化鋅奈米線/碳纤维複合電極在超級電容器之應用", 《台湾博硕士论文知识加值系统》 *
薛玫芳: "乙二醇及丙烯腈官能基的協同效應對高分子膠態電解質在電容器應用的影響", 《台湾博硕士论文知识加值系统》 *

Similar Documents

Publication Publication Date Title
Wang et al. An aqueous rechargeable Zn//Co3O4 battery with high energy density and good cycling behavior
CN108511761B (en) Current collector with PTC coating and lithium ion battery with current collector
KR101882975B1 (en) Method for menufacturing a cathode of lithium primary battery
CN105932207B (en) Lithium ion battery is reversible to overcharge protection gelatin polymer composite diaphragm and preparation method thereof
CN113270585A (en) Electrode material and preparation method and application thereof
CN110828754B (en) Inorganic fast ion conductor nano fiber and preparation method and application thereof
CN109167099A (en) A kind of battery of high safety and preparation method thereof
JPS60216461A (en) Cell
KR101490024B1 (en) Oxide capped anode materials for high performance lithium ion batteries
CN114256516B (en) Water-based zinc ion battery based on temperature response type self-protection electrolyte, and preparation method and application thereof
CN111446082A (en) Reactive compensation dry-type capacitor
CN107195965A (en) A kind of polymer dielectric and lithium ion battery
CN111370229A (en) Improved structure of metallized safety film explosion-proof capacitor
KR102495330B1 (en) Manufacturing method of electrode active material for supercapacitor co-doped with nitrogen and fluorine and high power supercapacitor using the same and method of manufacturing thereof
CN110760025B (en) Solid electrolyte based on 2-acrylamide-2-methylpropanesulfonic acid/styrene copolymer and preparation method thereof
KR20140043788A (en) An energy storage device, an inorganic gelled electrolyte and methods thereof
CN108777234B (en) Graphite fiber electrode coated with activated carbon and supercapacitor prepared from graphite fiber electrode
CN111370230A (en) High-power dry-type capacitor
KR101936044B1 (en) Supercapacitor electrode for high temperature, manufactureing method of the electrode, and Supercapacitor for high temperature using the electrode
KR100606487B1 (en) A lithium secondary battery
CN105070914A (en) Preparation method and application of deoxyribonucleic acid (DNA) double-helix carbon nano-fibre and preparation method of lithium ion battery anode material
CN109920972A (en) PTC electrode based on pyrroles and preparation method thereof
Bullock et al. Use of Conductive Materials to Enhance Lead‐Acid Battery Formation
CN112670099B (en) PANI-Co3O4Preparation method and application of nano material
CN111341976B (en) Electrolyte diaphragm, manufacturing method thereof and solid battery

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20200724

RJ01 Rejection of invention patent application after publication