CN111446082A - Reactive compensation dry-type capacitor - Google Patents
Reactive compensation dry-type capacitor Download PDFInfo
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- CN111446082A CN111446082A CN202010289756.8A CN202010289756A CN111446082A CN 111446082 A CN111446082 A CN 111446082A CN 202010289756 A CN202010289756 A CN 202010289756A CN 111446082 A CN111446082 A CN 111446082A
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- 239000003990 capacitor Substances 0.000 title claims abstract description 50
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 49
- 239000004917 carbon fiber Substances 0.000 claims abstract description 49
- 238000004070 electrodeposition Methods 0.000 claims abstract description 7
- 239000004744 fabric Substances 0.000 claims description 44
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 44
- 239000000243 solution Substances 0.000 claims description 32
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 16
- 239000011259 mixed solution Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000004140 cleaning Methods 0.000 claims description 15
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000005518 polymer electrolyte Substances 0.000 claims description 8
- 229920000428 triblock copolymer Polymers 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 6
- 238000000137 annealing Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000004246 zinc acetate Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 2
- -1 nitrate amine Chemical class 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000011573 trace mineral Substances 0.000 claims 1
- 235000013619 trace mineral Nutrition 0.000 claims 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 13
- FXOOEXPVBUPUIL-UHFFFAOYSA-J manganese(2+);nickel(2+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Mn+2].[Ni+2] FXOOEXPVBUPUIL-UHFFFAOYSA-J 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 238000012423 maintenance Methods 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000002052 molecular layer Substances 0.000 description 3
- 229920000867 polyelectrolyte Polymers 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- BLYYANNQIHKJMU-UHFFFAOYSA-N manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O--].[O--].[Mn++].[Ni++] BLYYANNQIHKJMU-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The invention provides a reactive compensation dry capacitor, which improves the integral capacitor characteristics by improving a polar plate in a reactive compensation dry capacitor body and enabling an electrode layer of the polar plate to have nickel-manganese hydroxide, zinc oxide nanowires and carbon fibers. For example, the zinc oxide nanowires can greatly increase the overall surface area of the electrode layer, thereby greatly improving the overall specific capacitance. In addition, after the service life of the capacitor is measured by a pulse electrodeposition method, the maintenance rate of the capacitor still reaches about 86% after more than 3000 circles of tests, so that the capacitor has the advantage of long service life.
Description
Technical Field
The invention relates to the technical field of capacitors, in particular to a reactive compensation dry-type capacitor.
Background
With the development of technology, an electric double layer capacitor (ED L C, also called super capacitor) has been used as a passive component of a circuit, and is gradually used as a storage battery.
Because most of the existing energy storage units are developed towards the directions of high energy density, long service life, high reversibility and the like, the capacitor can be applied to various purposes, such as electric locomotives. Therefore, the inventor of the present invention has considered that the practical applicability of the capacitor can be greatly improved if the specific capacitance and the service life of the entire capacitor can be improved.
Disclosure of Invention
The problem to be solved by the present invention is the above-mentioned problems regarding the specific capacitance value of the capacitor as a whole, the service life, etc.
In order to solve the above problems, the present invention provides a reactive compensation dry capacitor, which has the following technical scheme:
the reactive compensation dry type capacitor comprises a shell and a reactive compensation dry type capacitor body, wherein the reactive compensation dry type capacitor body is arranged in the shell and comprises a polar plate, and the polar plate comprises a substrate and an electrode layer arranged on the surface of the substrate.
The manufacturing method of the polar plate comprises the following steps:
(1) sequentially carrying out ultrasonic vibration cleaning on the carbon fiber cloth by using an acetone solution, an alcohol solution and a deionized water solution, and then putting the carbon fiber cloth into a baking oven for drying; putting the carbon fiber cloth into a zinc acetate absolute ethyl alcohol solution for ultrasonic vibration cleaning, and then putting the carbon fiber cloth into the baking oven for drying; and putting the carbon fiber cloth into a nitrogen environment for annealing treatment.
(2) And mixing a zinc acetate solution and a hexamethyltetramine solution to obtain a second mixed solution, putting the carbon fiber cloth into the first mixed solution, maintaining the fixed temperature for a period of time, and then putting the carbon fiber cloth into the baking oven to be dried after being cleaned by deionized water.
(3) Mixing a nickel nitrate solution and a potassium permanganate solution to obtain a second mixed solution, putting the carbon fiber cloth into the second mixed solution for electrochemical deposition, cleaning the carbon fiber cloth with deionized water, and putting the carbon fiber cloth into the baking oven for drying.
(4) And putting the carbon fiber cloth into a high-temperature furnace for thermal annealing treatment, cleaning the carbon fiber cloth with deionized water, putting the carbon fiber cloth into the baking oven for drying, and arranging the carbon fiber cloth on the surface of the substrate.
Compared with the prior art, the invention has the advantages that: the electrode layer is provided with nickel-manganese hydroxide, zinc oxide nanowires and carbon fibers, and the zinc oxide nanowires and the carbon fibers are penetrated, so that the whole capacitor has a very large surface area, and the specific capacitance value of the whole capacitor is greatly improved. In addition, the service life of the whole capacitor is greatly prolonged through the matching of the nickel-manganese hydroxide, the zinc oxide nanowires and the carbon fibers, and after 3000 circles of tests of a pulse electrodeposition method, the capacitor still has a maintenance rate of about 86 percent, so that the advantage of long service life of the capacitor is highlighted.
Drawings
FIG. 1 is a schematic diagram illustrating an appearance of the present invention;
FIG. 2 is a schematic view of an embodiment of a conductive terminal;
FIG. 3 is a flow chart of a method of fabricating a plate;
FIG. 4 is a flow chart of a method of making the electrolyte;
fig. 5 is a schematic connection diagram of the components.
Description of reference numerals:
a housing; 11-a top wall; 2-reactive compensation dry capacitor body; 3-conductive terminal; 4-strip plate body; 5-discharge resistance; 6-temperature controller; 7-circuit breaker.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention comprehensible, embodiments accompanied with figures are described in detail below.
Example 1
Referring to fig. 1, the present invention relates to a reactive compensation dry capacitor, which is characterized in that the reactive compensation dry capacitor comprises:
the reactive compensation dry type capacitor comprises a shell 1 and a reactive compensation dry type capacitor body 2, wherein the reactive compensation dry type capacitor body 2 is arranged in the shell 1, the reactive compensation dry type capacitor body 2 comprises a polar plate, and the polar plate comprises a substrate and an electrode layer arranged on the surface of the substrate.
The manufacturing method of the polar plate comprises the following steps:
(1) sequentially carrying out ultrasonic vibration cleaning on the carbon fiber cloth by using an acetone solution, an alcohol solution and a deionized water solution, and then putting the carbon fiber cloth into a baking oven for drying; putting the carbon fiber cloth into a zinc acetate absolute ethyl alcohol solution for ultrasonic vibration cleaning, and then putting the carbon fiber cloth into the baking oven for drying; and putting the carbon fiber cloth into a nitrogen environment for annealing treatment.
In this way, the carbon fiber cloth forms a zinc oxide layer on the surface.
(2) Mixing a zinc acetate solution and a hexamethyltetramine solution to obtain a first mixed solution, putting the carbon fiber cloth into the first mixed solution, maintaining the fixed temperature for a period of time (preferably repeating the above process at least once), and then putting the carbon fiber cloth into the baking oven to be dried after being cleaned by deionized water.
Thus, the zinc oxide layer starts to grow zinc oxide nanowires.
(3) Mixing a nickel nitrate solution and a potassium permanganate solution to obtain a second mixed solution, putting the carbon fiber cloth into the second mixed solution for electrochemical deposition, cleaning the carbon fiber cloth with deionized water, and putting the carbon fiber cloth into the baking oven for drying.
Therefore, the nickel-manganese hydroxide nano-layer can grow on the surface of the zinc oxide nano-wire. In addition, during the electrochemical deposition process, the counter electrode and the reference electrode are preferably selected from platinum and silver chloride, respectively.
(4) And putting the carbon fiber cloth into a high-temperature furnace for thermal annealing treatment, cleaning the carbon fiber cloth with deionized water, putting the carbon fiber cloth into the baking oven for drying, so that the nickel-manganese hydroxide nano-layer becomes a nickel-manganese oxide nano-layer, and finally arranging the carbon fiber cloth on the surface of the substrate to complete the polar plate.
Through the above description, the electrode layer of the present invention has nickel-manganese hydroxide, zinc oxide nanowires, and carbon fibers, and the zinc oxide nanowires greatly increase the overall surface area and thus increase the overall specific capacitance. In the aspect of service life, the maintenance rate of the invention is about 86% after more than 3000 circles of tests by using a pulse electrodeposition method, and the invention has the advantage of long service life.
Example 2:
referring to fig. 4, the electrolyte of the reactive compensation dry capacitor body 2 is preferably a colloidal polyelectrolyte film. The following describes a method of manufacturing the colloidal polyelectrolyte thin film:
(1) adding polyethylene glycol (PEG), deionized water and nitrogen into a double-neck reactor, heating and stirring for a period of time, preferably at about 40 ℃, adding acrylonitrile (PAN) into the double-neck reactor, and heating and stirring for a period of time, preferably at about 40 ℃; dissolving ceric nitrate amine into a nitric acid solution to obtain a third mixed solution; and slowly adding the third mixed solution into the double-neck reactor until complete reaction to obtain a heterogeneous solution, performing air-suction filtration on the heterogeneous solution, then repeatedly cleaning the heterogeneous solution by deionized water and acetone for multiple times, and then performing drying treatment, preferably drying the heterogeneous solution in a vacuum oven at about 80 ℃ to obtain PAN-b-PEG-b-PAN triblock copolymer polymer, wherein the chain segment ratio between AN and EG in the PAN-b-PEG-b-PAN triblock copolymer polymer can be adjusted by changing the weight of acrylonitrile. The molecular formula of the PAN-b-PEG-b-PAN triblock copolymer is as follows:
(2) putting PAN-b-PEG-b-PAN triblock copolymer polymer, lithium perchlorate and dimethylformamide into a container, heating the container by a high-temperature oven at about 80 ℃ to obtain a homogeneous polymer electrolyte solution, putting a trace (such as 0.1g) of the homogeneous polymer electrolyte solution into an aluminum disc, and heating the aluminum disc to evaporate the dimethylformamide to obtain the colloidal polymer electrolyte film.
The colloidal polyelectrolyte film has a special linear structure through the triblock copolymer, and can effectively reduce the ion mobility resistance (equivalent series resistance) and the mass transfer diffusion resistance (Warburgregation) in impedance. In summary, the synergistic effect of acrylonitrile and ethylene glycol can greatly improve the surface of the reactive compensation dry capacitor in terms of energy storage performance, specific energy, specific power, etc., for example, at a specific power of 10 kWkg-1Under the condition of (1), the specific energy can reach up to 21Wh kg-1At a low discharge rate of 0.12Ag-1Under the condition of (2), the maximum specific energy can also be up to 30kWkg-1。
Example 3:
please refer to fig. 2, the embodiment is: the surface of the shell 1 is provided with a plurality of conductive terminals 3 which are arranged in sequence at intervals, each conductive terminal 3 is electrically connected with the reactive compensation dry-type capacitor body 2, the bottom end of each conductive terminal 3 penetrates through the top wall 11 of the shell 1 and the strip-shaped plate 4 in sequence, and a space is formed between the strip-shaped plate 4 and the top wall 11 of the shell 1.
Therefore, through the top wall 11 and the strip-shaped plate 4 which are spaced apart from each other, the conductive terminals 3 can be more stably disposed on the top surface of the housing 1, and are not easily damaged by external force.
Example 4:
referring to fig. 5, in order to ensure the safety of the present invention during the use of electricity, the present invention further makes each conductive terminal 3 electrically connected to a discharge resistor 5, and each discharge resistor 5 is disposed outside the top wall 11 of the housing 1.
Example 5:
referring to fig. 5, in order to ensure the safety of the power utilization of the present invention, the operation is stopped when the temperature rises to the default value to avoid accidents, and for this reason, the present invention may further be implemented as follows: a temperature controller 6 is arranged in the shell 1, a circuit breaker 7 is arranged on a section of a path of each conductive terminal 3 electrically connected with the reactive compensation dry type capacitor body 2, and when the temperature controller 6 detects that the temperature of the reactive compensation dry type capacitor body 2 exceeds the default temperature, the circuit breaker 7 is controlled to form a circuit break.
Example 6:
in order to avoid the over-high temperature of the present creation during use, the housing 1 is preferably made of metal material, and a plurality of heat dissipation fins are disposed on the outer side of the housing, so that the creation can keep a low temperature during use and is not easy to cause accidents.
Although the present disclosure has been described above, the scope of the present disclosure is not limited thereto. Various changes and modifications may be effected therein by one of ordinary skill in the pertinent art without departing from the spirit and scope of the present disclosure, and these changes and modifications are intended to be within the scope of the present disclosure.
Claims (6)
1. A reactive compensation dry capacitor comprising:
the reactive compensation dry type capacitor comprises a shell and a reactive compensation dry type capacitor body, wherein the reactive compensation dry type capacitor body is arranged in the shell and comprises a polar plate, and the polar plate comprises a substrate and an electrode layer arranged on the surface of the substrate;
the manufacturing method of the polar plate comprises the following steps:
(1) sequentially carrying out ultrasonic vibration cleaning on the carbon fiber cloth by using an acetone solution, an alcohol solution and a deionized water solution, and then putting the carbon fiber cloth into a baking oven for drying; putting the carbon fiber cloth into a zinc acetate absolute ethyl alcohol solution for ultrasonic vibration cleaning, and then putting the carbon fiber cloth into the baking oven for drying; putting the carbon fiber cloth into a nitrogen environment for annealing treatment;
(2) mixing a zinc acetate solution and a hexamethyltetramine solution to obtain a first mixed solution, putting the carbon fiber cloth into the first mixed solution, maintaining the fixed temperature for a period of time, cleaning the carbon fiber cloth with deionized water, and then putting the carbon fiber cloth into the baking oven for drying;
(3) mixing a nickel nitrate solution and a potassium permanganate solution to obtain a second mixed solution, putting the carbon fiber cloth into the second mixed solution for electrochemical deposition, cleaning the carbon fiber cloth with deionized water, and putting the carbon fiber cloth into the baking oven for drying;
(4) and putting the carbon fiber cloth into a high-temperature furnace for thermal annealing treatment, cleaning the carbon fiber cloth with deionized water, putting the carbon fiber cloth into the baking oven for drying, and arranging the carbon fiber cloth on the surface of the substrate.
2. A reactive power compensation dry capacitor as claimed in claim 1, wherein the electrolyte of the reactive power compensation dry capacitor body is a colloidal polymer electrolyte film, and the colloidal polymer electrolyte film is fabricated by: (1) adding polyethylene glycol (PEG), deionized water and nitrogen into a double-neck reactor, heating and stirring for a period of time, adding acrylonitrile (PAN) into the double-neck reactor, and heating and stirring for a period of time; dissolving ceric nitrate amine into a nitric acid solution to obtain a third mixed solution; slowly adding the third mixed solution into the double-neck reactor, obtaining a heterogeneous solution after complete reaction, performing air-extraction filtration on the heterogeneous solution, then respectively cleaning with deionized water and acetone, and then drying to obtain a PAN-b-PEG-b-PAN triblock copolymer polymer; the molecular formula of the PAN-b-PEG-b-PAN triblock copolymer is as follows:
(2) putting PAN-b-PEG-b-PAN triblock copolymer polymer, lithium perchlorate and dimethylformamide into a container, heating by a high-temperature oven to obtain homogeneous polymer electrolyte solution, and taking trace elements
And placing the homogeneous polymer electrolyte solution in an aluminum disc, and then heating to evaporate the dimethylformamide to obtain the colloidal polymer electrolyte film.
3. A reactive compensation dry capacitor as claimed in claim 2, wherein the housing has a plurality of conductive terminals arranged in sequence at intervals, each conductive terminal is electrically connected to the reactive compensation dry capacitor body, the bottom end of each conductive terminal is sequentially inserted through the top wall of the housing, and the strip-shaped plate is spaced from the top wall of the housing.
4. A reactive compensation dry capacitor as claimed in claim 3, wherein each conductive terminal is electrically connected to a discharge resistor, and each discharge resistor is disposed outside the top wall of the housing.
5. A reactive compensation dry capacitor as claimed in claim 4 wherein a temperature controller is provided in the housing, a circuit breaker is provided on a section of the path where each conductive terminal is electrically connected to the reactive compensation dry capacitor body, and the circuit breaker is controlled to open when the temperature controller detects that the temperature of the reactive compensation dry capacitor body exceeds a predetermined temperature.
6. A reactive compensation dry capacitor as claimed in claim 5 wherein the housing is made of metal and has a plurality of heat dissipating fins on the outside.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201518278U (en) * | 2009-09-16 | 2010-06-30 | 厦门法拉电子股份有限公司 | Dry capacitor structure with temperature fuse |
JP2010267669A (en) * | 2009-05-12 | 2010-11-25 | Nissin Electric Co Ltd | Dry capacitor |
CN205159103U (en) * | 2015-09-29 | 2016-04-13 | 李叶 | Multipurpose dry condenser |
CN207397955U (en) * | 2017-10-23 | 2018-05-22 | 苏州士林电机有限公司 | The external band temperature control dry-type capacitor device of resistance |
-
2020
- 2020-04-14 CN CN202010289756.8A patent/CN111446082A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010267669A (en) * | 2009-05-12 | 2010-11-25 | Nissin Electric Co Ltd | Dry capacitor |
CN201518278U (en) * | 2009-09-16 | 2010-06-30 | 厦门法拉电子股份有限公司 | Dry capacitor structure with temperature fuse |
CN205159103U (en) * | 2015-09-29 | 2016-04-13 | 李叶 | Multipurpose dry condenser |
CN207397955U (en) * | 2017-10-23 | 2018-05-22 | 苏州士林电机有限公司 | The external band temperature control dry-type capacitor device of resistance |
Non-Patent Citations (2)
Title |
---|
洪鉅晁: "鎳-錳氫氧化物/氧化鋅奈米線/碳纤维複合電極在超級電容器之應用", 《台湾博硕士论文知识加值系统》 * |
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