CN111437727B - Method and device for manufacturing hollow fiber membrane component with uniformly distributed membrane filaments - Google Patents

Method and device for manufacturing hollow fiber membrane component with uniformly distributed membrane filaments Download PDF

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CN111437727B
CN111437727B CN202010325474.9A CN202010325474A CN111437727B CN 111437727 B CN111437727 B CN 111437727B CN 202010325474 A CN202010325474 A CN 202010325474A CN 111437727 B CN111437727 B CN 111437727B
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rod
membrane
adhesive tape
hollow fiber
filaments
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CN111437727A (en
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彭跃莲
侯春光
庞志广
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Beijing University of Technology
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Beijing University of Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof

Abstract

A method and a device for manufacturing a hollow fiber membrane component with uniformly distributed membrane filaments belong to the technical field of hollow fiber membrane component preparation. The membrane component is prepared by uniformly distributing membrane filaments on an adhesive tape and coiling the adhesive tape; the device comprises an operating table with scale strips, a roller and a rod which can fix the adhesive tape, the scale strips, a pressure rod, a winding rod and a power source, wherein the power source is connected with the winding rod through a driving shaft and a belt. The rollers can be used for placing the adhesive tape and are fixed on the rod, and the distance between the two rollers on the rod can be regulated and controlled. The hollow fiber membrane module manufactured by the method has the advantages of uniform membrane filament distribution and uniform membrane flux distribution, and improves the efficiency of the membrane module.

Description

Method and device for manufacturing hollow fiber membrane component with uniformly distributed membrane filaments
Technical Field
The invention relates to a method and a device for uniformly distributing and arranging membrane filaments of a hollow fiber membrane component, in particular to a method and a device for uniformly distributing and arranging membrane filaments by using adhesive tapes, and belongs to the technical field of preparation of hollow fiber membrane components.
Background
Membrane modules are the core of membrane technology applications. In particular to a hollow fiber membrane component, the preparation technology is relatively simple, no support body is needed, the filling density is high, the efficiency is high, and the like, and the hollow fiber membrane component is widely applied to various fields of membrane separation. Most of ideal hollow fiber membrane components are membrane filaments which are arranged in parallel along the axial direction of the component, but the problem of uneven arrangement and distribution of the hollow fiber membrane filaments always exists in the process of actually manufacturing the membrane components, so that the distribution of the permeability coefficient of the membrane filaments is uneven, the three-dimensional unevenness of flux distribution is caused, the energy consumption of equipment is increased, and the efficiency of the component is reduced.
Particularly, in the hollow fiber membrane module for membrane distillation, the uneven arrangement and distribution of membrane filaments in the membrane module can cause uneven distribution of shell-side fluid, and the channeling effect, which is an undesirable behavior such as channeling, dead zones and the like, exists. The effect greatly reduces the mass transfer and heat transfer efficiency of the membrane component.
At present, most of adopted hollow fiber membrane component manufacturing methods have the game effect (sacrificing the uniform distribution of membrane filaments in the component, improving the production efficiency, or reducing the production efficiency and optimizing the distribution of the membrane filaments in the component). The existing methods for manufacturing hollow fiber membrane modules are method 1 and method 2.
Method 1
The comparative example is a self-made PVDF hollow fiber membrane filament with self-support, the membrane filament is subjected to end capping treatment (preventing epoxy resin glue from entering from a membrane filament port) before casting, all the end capped membrane filaments are randomly placed in a membrane shell of a membrane component at one time, the epoxy resin glue is used as a binder, the hollow fiber membrane filament and an outer structural member are subjected to centrifugal or standing casting bonding together, the hollow fiber membrane filament and the outer structural member are cut after complete curing is required, the adhesion among the membrane filaments in the membrane component is serious, the distance distribution among the membrane filaments is extremely uneven, the membrane filaments in the component are in a loose state, the membrane filaments can swing in the fluid flowing process to cause damage to the root of the membrane filaments, and the filtering performance and the service life of the membrane component are influenced.
Method 2
The comparative example is a self-made self-supporting PVDF hollow fiber membrane filament, the membrane filament is subjected to end sealing treatment before casting, all the end-sealed membrane filaments are divided into a plurality of bundles, then each bundle is sequentially inserted into a mould (petal) of the membrane component, epoxy resin is used as a binder, the hollow fiber membrane filament and an outer structural member are centrifuged or statically cast and bonded together, and cutting is carried out after complete curing is carried out to obtain the membrane component, wherein the distribution among the fiber filaments of each bundle is better, but serious adhesion exists among the membrane filaments of each bundle, and the filtering performance of the membrane component is seriously influenced. The number of petals in the mould is not too large, otherwise, the manufacturing process of the membrane component is more complicated, and the efficiency is reduced; petals in the die are not too few, otherwise, the number of membrane filaments in each bundle is more, and the phenomenon of adhesion among the membrane filaments is more serious.
Disclosure of Invention
The main purpose of the present invention is to provide a method for uniformly distributing membrane filaments in a hollow fiber membrane module and an implementation apparatus thereof, which are directed to the current state of the prior art. The method is innovative in that the adhesive tapes are used for uniformly distributing and fixing the membrane filaments, so that the membrane filaments can be uniformly distributed in the membrane component.
The invention is realized by the following technical scheme.
A method for manufacturing a hollow fiber membrane module with uniformly distributed membrane filaments is characterized by comprising a membrane filament distribution process, a membrane filament coiling process and a membrane module preparation process in a hollow fiber membrane distribution device by using an adhesive tape;
the device comprises an operating table (1) with scale strips, a roller (2) and a rod (3) which can fix an adhesive tape (10), the scale strips (6), a first pressure lever (4), a second pressure lever (5), a winding rod (8) and a power source (9); the operating platform (1) is a horizontal operating platform, and the front end part in the length direction is provided with a downward inclined plane; a first pressure lever (4) is arranged at the upper rear end part of the operating platform (1) along the width direction, two ends of the first pressure lever (4) are fixed on the operating platform (1), and the first pressure lever (4) can fixedly rotate or can not rotate around the shaft of the first pressure lever; a rod (3) is fixedly arranged at the upper part in front of the first pressure rod (4), the rod (3) is parallel to the first pressure rod (4), two ends of the rod (3) are coaxially sleeved with a roller (2), the roller (2) can rotate around the rod (3) on the rod (3), a second pressure rod (5) is fixed at the front end part of the horizontal surface of the operating platform (1) in front of the rod (3), the second pressure rod (5) is parallel to the first pressure rod (4) and is basically positioned on the same horizontal surface, a winding rod (8) is arranged at the lower end of the downward inclined plane of the operating platform (1), and the winding rod (8) is parallel to the second pressure rod (5); the power source (9) and the two ends of the winding rod (8) and the driving shaft (11) are connected by belts (12), the power source (9) is fixedly connected with the driving shaft (11) to drive the driving shaft (11) to rotate, and the driving shaft (11) drives the winding rod (8) to rotate around the self shaft through the belts (12); the rollers (2) can be used for placing adhesive tapes and are fixed on the rod (3), and the distance between the two rollers on the rod (3) can be regulated and controlled; scale strips (6) are arranged on two side edges of the operating platform (1);
the winding rod (8) collects the adhesive tape (10) with the film filaments uniformly distributed;
the method specifically comprises the following steps: and (3) carrying out a distribution process on the membrane filaments: (A) respectively winding adhesive tapes (10) with certain thickness on two rollers (2), wherein the distance between the rollers is greater than the length of the membrane component, and the distance between the rollers on the rod (3) can be controlled; (B) the adhesive tape is led out from the roller, guided by a first pressure lever (4) and a second pressure lever (5) to be positioned on a horizontal plane parallel to the operation table (1), scale strips (6) which are placed in parallel are arranged on two sides of the operation table, and the adhesive tape is led to one end of a thin rolling rod (8) through the second pressure lever (5) to be fixed; (C) according to the determined membrane filament spacing, the hollow fiber membrane filaments (7) are uniformly distributed and fixed on the adhesive tape in parallel through the scale strips, and the length direction of the hollow fiber membrane filaments (7) is vertical to the length direction of the adhesive tape; then the hollow fiber membrane yarn coiling process is carried out, which comprises the following steps: (D) the thin rolling rod (8) can continuously rotate and is easy to disassemble, and if a water distribution pipe exists in the fruit membrane component, the thin rolling rod can be replaced; (E) the power for rotating the winding rod is provided by a power source (9); (F) and starting power, wherein the driving shaft (11) drives the winding rod (8) to wind the adhesive tape with uniformly distributed film yarns through the transmission of the belt (12).
In the method for uniformly distributing the membrane filaments in the hollow fiber membrane module, the processes of distributing the membrane filaments and winding the membrane filaments are continuously performed.
In the method for uniformly distributing the membrane filaments in the hollow fiber membrane module, the uniform distribution of the membrane filaments is realized by using the adhesive tape (single-sided or double-sided adhesive tape), the membrane filaments can be fixed by using the adhesive tape on the adhesive tape, and the space between the membrane filaments is obtained by using the thickness of the adhesive tape or the overlapping thickness of the adhesive tape.
The device for uniformly distributing the membrane filaments in the hollow fiber membrane component is used for uniformly distributing the membrane filaments in the membrane component.
In the device for uniformly distributing the membrane filaments in the hollow fiber membrane module, the uniform filament distributing process and the filament winding process can be performed synchronously or continuously and alternately.
Compared with the prior art, the invention has the advantages that: the method of distributing membrane filaments by using the adhesive tape and then collecting the membrane filaments by using the winding rod can ensure that the hollow fiber membrane filaments are uniformly arranged in the membrane component, thereby increasing the filtering performance of fluid. The device is designed for uniformly distributing and arranging the membrane filaments, and the hollow fiber membrane component can be prepared more simply and efficiently.
Description of the drawings:
in order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required in the description of the embodiments or the prior art will be briefly described below. The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
FIG. 1 is a schematic view of a method and an apparatus for uniformly distributing membrane filaments in a hollow fiber membrane module
1 operating platform, 2 rollers, 3 rods, 4 first pressure rods, 5 second pressure rods, 6 scale bars, 7 fiber membrane wires, 8 winding rods, 9 power sources, 10 adhesive tapes, 11 power driving shafts, 12 driving belts and 13 cross section positions shown in figure 2.
FIG. 2 is a cross-sectional view of the membrane filament distribution after collection on a spool.
10 adhesive tapes, 8 winding rods and 7 fiber membrane yarns.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings.
The following examples and comparative examples employ the same hollow fiber membrane filaments, and membrane modules of the same size. The optimal filling density value is obtained through dynamic and thermodynamic calculation of the membrane module fluid, then the optimal spacing between membrane filaments in the membrane module can be obtained through calculation of the filling density and the size of the module, the calculation process is complex, and the universal membrane filament spacing is selected to be 1 mm.
Presetting the inner diameter of a membrane component as D; the outer diameter of the water collecting pipe/wire winder is L; the diameter of the hollow fiber membrane filament is d; the thickness of the selected adhesive tape is 1 mm. Namely, the required ideal length of the adhesive tape is as follows:
the tape desirably has a total length of π x [ D + (D- (D +1)) + (D-2(D +1) + … + L) ]
The total number of membrane filaments uniformly distributed and arranged in the membrane component is as follows:
Figure BDA0002462611090000051
the method of uniformly distributing membrane filaments in the hollow fiber membrane module and the method of manufacturing the membrane module using the device according to the present invention are described in example 1.
Example 1
In the embodiment, the self-made PVDF hollow fiber membrane with self-support is prepared by performing end-capping treatment on membrane filaments before casting, as shown in FIG. 1, placing an adhesive tape on two rollers 2 with a certain distance, leading out the adhesive tape 10, fixing the adhesive tape on a winding rod 8 through a pressure rod 4 and a pressure rod 5, determining the distance of the adhesive tape on the winding rod, connecting the winding rod with a driving shaft 11 through a belt, and providing power for the driving shaft by a power source 9; fixing the hollow fiber membrane filaments 7 on the adhesive tape in parallel by the membrane filaments subjected to the end sealing treatment through the scale strips according to the determined membrane filament spacing; and starting a power source, distributing the membrane wires and winding the membrane wires by using a winding rod at the same time until the diameter size of the winding rod is equivalent to the size of the assembly. Then, winding rods (shown in figure 2) with uniformly distributed membrane filaments are placed in a membrane shell of the membrane component to be subjected to centrifugation or standing casting bonding, and cutting is carried out after complete solidification is required, so that the hollow fiber membrane component with uniformly distributed membrane filaments and vertical membrane filaments is obtained.
The above description is only a part of the embodiments of the present invention, and is not intended to limit the present invention in any way, and all simple modifications, equivalent variations and modifications made to the above embodiments according to the technical spirit of the present invention are still within the scope of the technical solution of the method and apparatus for uniformly distributing membrane filaments in a hollow fiber membrane module of the present invention.

Claims (2)

1. A method for manufacturing a hollow fiber membrane component with uniformly distributed membrane filaments is characterized in that the membrane filaments are uniformly distributed by using an adhesive tape, the adhesive glue on the adhesive tape fixes the membrane filaments and ensures the space between the membrane filaments, and the thickness control layer of the adhesive tape and the space between the membrane filaments are changed by rolling;
the device comprises an operating table (1) with scale strips, a roller (2) and a rod (3) which can fix an adhesive tape (10), the scale strips (6), a first pressure lever (4), a second pressure lever (5), a winding rod (8) and a power source (9); the operating platform (1) is a horizontal operating platform, and the front end part in the length direction is provided with a downward inclined plane; a first pressure lever (4) is arranged at the upper rear end part of the operating platform (1) along the width direction, two ends of the first pressure lever (4) are fixed on the operating platform (1), and the first pressure lever (4) can fixedly rotate or can not rotate around the shaft of the first pressure lever; a rod (3) is fixedly arranged at the upper part in front of the first pressure rod (4), the rod (3) is parallel to the first pressure rod (4), two ends of the rod (3) are coaxially sleeved with a roller (2), the roller (2) can rotate around the rod (3) on the rod (3), a second pressure rod (5) is fixed at the front end part of the horizontal surface of the operating platform (1) in front of the rod (3), the second pressure rod (5) is parallel to the first pressure rod (4) and is basically positioned on the same horizontal surface, a winding rod (8) is arranged at the lower end of the downward inclined plane of the operating platform (1), and the winding rod (8) is parallel to the second pressure rod (5); the power source (9) and the two ends of the winding rod (8) and the driving shaft (11) are connected by belts (12), the power source (9) is fixedly connected with the driving shaft (11) to drive the driving shaft (11) to rotate, and the driving shaft (11) drives the winding rod (8) to rotate around the self shaft through the belts (12); the rollers (2) can be used for placing adhesive tapes and are fixed on the rod (3), and the distance between the two rollers on the rod (3) can be regulated and controlled; scale strips (6) are arranged on two side edges of the operating platform (1);
the winding rod (8) collects the adhesive tape (10) with the film filaments uniformly distributed;
comprises a membrane silk distribution process, a membrane silk coiling process and a membrane component preparation process by using adhesive tapes in a hollow fiber filter membrane distribution device; the method specifically comprises the following steps: and (3) carrying out a distribution process on the membrane filaments: (A) respectively winding adhesive tapes (10) with certain thickness on two rollers (2), wherein the distance between the rollers is greater than the length of the membrane component, and the distance between the rollers on the rod (3) can be controlled; (B) the adhesive tape is led out from the roller, guided by a first pressure lever (4) and a second pressure lever (5) to be positioned on a horizontal plane parallel to the operation table (1), scale strips (6) which are placed in parallel are arranged on two sides of the operation table, and the adhesive tape is led to one end of a winding rod (8) through the second pressure lever (5) to be fixed; (C) according to the determined membrane filament spacing, the hollow fiber membrane filaments (7) are uniformly distributed and fixed on the adhesive tape in parallel through the scale strips, and the length direction of the hollow fiber membrane filaments (7) is vertical to the length direction of the adhesive tape; then the hollow fiber membrane yarn coiling process is carried out, which comprises the following steps: (D) the winding rod (8) can rotate continuously and is easy to disassemble, and if a water distribution pipe exists in the membrane module, the winding rod can be replaced; (E) the power for rotating the winding rod is provided by a power source (9); (F) starting power, wherein a driving shaft (11) drives a winding rod (8) to wind the adhesive tape with uniformly distributed film yarns through the transmission of a belt (12);
the hollow fiber membrane filament distribution and membrane filament coiling processes are continuously carried out;
the uniform distribution of the membrane filaments is realized by using an adhesive tape, and the membrane filaments are fixed by using adhesive glue on the adhesive tape.
2. The method for manufacturing a hollow fiber membrane module with uniformly distributed membrane filaments according to claim 1, wherein the uniform filament distribution process and the filament winding process are performed simultaneously or continuously and alternately.
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CN112242543B (en) * 2020-09-16 2021-10-15 东风汽车集团有限公司 Hollow fiber membrane tube collecting device, collecting method and membrane tube humidifier
CN112174299A (en) * 2020-11-02 2021-01-05 碧水源膜技术研究中心(北京)有限公司 Hollow fiber membrane filament arranging device

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TWI292335B (en) * 1999-01-29 2008-01-11 Entegris Inc Method of forming a perfluroinated, thermoplastic hollow fiber module
CN102574063A (en) * 2009-10-27 2012-07-11 陶氏环球技术有限责任公司 Method for applying tape layer to outer periphery of spiral wound module
CN204699589U (en) * 2015-06-04 2015-10-14 贵阳时代沃顿科技有限公司 A kind of rolling device of wound membrane element
KR20170112599A (en) * 2016-03-31 2017-10-12 도레이케미칼 주식회사 perforated flux pipe manufacturing apparatus

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Publication number Priority date Publication date Assignee Title
EP1946823A1 (en) * 2005-09-30 2008-07-23 Kureha Corporation Hollow fiber bundle, process for producing hollow fiber bundle, tubular hollow fiber membrane module and immersion type hollow fiber membrane module
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Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI292335B (en) * 1999-01-29 2008-01-11 Entegris Inc Method of forming a perfluroinated, thermoplastic hollow fiber module
CN102574063A (en) * 2009-10-27 2012-07-11 陶氏环球技术有限责任公司 Method for applying tape layer to outer periphery of spiral wound module
CN204699589U (en) * 2015-06-04 2015-10-14 贵阳时代沃顿科技有限公司 A kind of rolling device of wound membrane element
KR20170112599A (en) * 2016-03-31 2017-10-12 도레이케미칼 주식회사 perforated flux pipe manufacturing apparatus

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