CN111407365A - Gasbag pressure indication type cricothyroid membrane cuts suit - Google Patents

Gasbag pressure indication type cricothyroid membrane cuts suit Download PDF

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Publication number
CN111407365A
CN111407365A CN202010244535.9A CN202010244535A CN111407365A CN 111407365 A CN111407365 A CN 111407365A CN 202010244535 A CN202010244535 A CN 202010244535A CN 111407365 A CN111407365 A CN 111407365A
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cricothyroid membrane
surface layer
kit
knife
blade
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CN111407365B (en
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潘菲
黎檀实
宋海楠
杨健
陈威
刘钰
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Chinese PLA General Hospital
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B17/00Surgical instruments, devices or methods, e.g. tourniquets
    • A61B17/32Surgical cutting instruments
    • A61B17/3209Incision instruments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B17/00Surgical instruments, devices or methods, e.g. tourniquets
    • A61B17/28Surgical forceps
    • A61B17/285Surgical forceps combined with cutting implements
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L31/00Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
    • A61L31/08Materials for coatings
    • A61L31/082Inorganic materials
    • A61L31/088Other specific inorganic materials not covered by A61L31/084 or A61L31/086
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L31/00Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
    • A61L31/14Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
    • A61L31/16Biologically active materials, e.g. therapeutic substances
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61MDEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M16/00Devices for influencing the respiratory system of patients by gas treatment, e.g. mouth-to-mouth respiration; Tracheal tubes
    • A61M16/04Tracheal tubes
    • A61M16/0465Tracheostomy tubes; Devices for performing a tracheostomy; Accessories therefor, e.g. masks, filters
    • A61M16/0472Devices for performing a tracheostomy
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/06Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases
    • C23C10/14Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases more than one element being diffused in one step
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2300/00Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
    • A61L2300/10Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices containing or releasing inorganic materials
    • A61L2300/102Metals or metal compounds, e.g. salts such as bicarbonates, carbonates, oxides, zeolites, silicates
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2300/00Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
    • A61L2300/40Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a specific therapeutic activity or mode of action
    • A61L2300/404Biocides, antimicrobial agents, antiseptic agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2300/00Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
    • A61L2300/60Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a special physical form
    • A61L2300/606Coatings

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Surgery (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Engineering & Computer Science (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Molecular Biology (AREA)
  • Pulmonology (AREA)
  • Medical Informatics (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Inorganic Chemistry (AREA)
  • Epidemiology (AREA)
  • Vascular Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ophthalmology & Optometry (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Anesthesiology (AREA)
  • Hematology (AREA)
  • Medicinal Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Surgical Instruments (AREA)

Abstract

Discloses a cricothyroid membrane cutting kit, which comprises a surgical blade, a knife handle and a forceps body; the front end of the surgical knife blade is provided with a knife tip, and the two sides of the surgical knife blade are provided with arc-shaped knife edges; and is made of a metal material and further has a structural inner layer and an antibacterial surface layer. According to the invention, the antibacterial surface layer with a specific composition is formed on the cutting blade of the cutting set of the cricothyroid membrane, so that the cutting set of the cricothyroid membrane has a better antibacterial effect; especially has strong antibacterial effect on Escherichia coli and Staphylococcus aureus.

Description

Gasbag pressure indication type cricothyroid membrane cuts suit
Technical Field
The invention belongs to the technical field of medical instruments, and particularly relates to a cricothyroid membrane cutting device; and more particularly to a balloon pressure indicating cricothyroid dissection kit (or device) for use in a cricothyroid dissection.
Background
The cricothyroid membrane is located between the cricoid cartilage and the thyroid cartilage, is a conical elastic fibrous connective tissue membrane, and is a part of the elastic cone in front of the elastic diaphragm of the larynx. The laryngeal elastic membrane is located on the deep surface of the mucous membrane of the laryngeal cavity, belongs to a connective tissue membrane containing elastic fibers, is divided into an upper part and a lower part by a laryngeal chamber, the upper part is called a square membrane, the lower part is called an elastic cone, and the elastic cone starts from the lower part of the inner surface of the horn of the thyroid cartilage and is attached to the inner side of the upper edge of the cricoid cartilage in a fan shape downwards. The anterior middle part of the elastic cone is attached between the lower edge of the thyroid cartilage and the upper edge of the cricoid cartilage arch and is called the cricothyroid membrane, the thickened part at the center is called the middle ligament of the cricothyroid membrane, and when the cricothyroid membrane incision or puncture is performed, the cricothyroid membrane and the middle ligament of the cricothyroid membrane are mainly incised.
Thyrocricocentesis or incision is a commonly used first-aid technique in otolaryngology and is widely applied clinically; when acute laryngeal obstruction occurs, it can establish an artificial respiration channel in time and supply oxygen, suck phlegm or intratracheal therapeutic drugs and the like through the channel.
In contrast to thyrocricocentesis, a thyrocricocentesis requires a transverse cervical incision at the level of the thyrocricoid, with a single incision of skin, subcutaneous tissue and platysma, usually 4-5 cm in length. After the ring nail film is cut by the knife tip, the finger is used for pressing the ring nail film stoma to prevent the hemostatic liquid from entering the trachea, the tracheal catheter is inserted through the ring nail film stoma, and the cuff of the tracheal catheter is inflated to prevent blood from entering the lower respiratory tract, so that artificial respiration or mechanical assisted respiration can be performed.
However, since there is no special clinical incision instrument, it has been reported that incision is performed with a scalpel in many cases. However, it is difficult to control the incision width using a scalpel, the laryngeal tube is not fixed well, and the anterior cervical skin slides to both sides, thereby damaging the cricoid cartilage and its adjacent soft tissues, and also easily causing vascular or nerve damage. In addition, the operation is required to be carried out by a doctor specialized in otolaryngology, and the first-line clinical rescue of a patient is easy to delay the rescue opportunity, so that the clinical application is relatively limited. More importantly, the scalpel is an all-metal product and belongs to an invasive treatment means, and if the disinfection measure is not in place, the treatment environment is not clean, or the autoimmune system of a patient is incomplete, the possibility of bacterial infection caused by pathogen transmission exists. It has been shown that approximately 15-25% of patients undergoing a cricothyroid procedure develop various complications from infection.
Chinese utility model patent CN2635034Y discloses a quick cutter of cricothyroid membrane, and it includes that cross hinge connects two fixed blade heads and the double knives frame of handle is taken to the other end to constitute, and the cutting edge of blade head is outside, is convenient for insert and open the incision, cuts the width according to width limiting device and masters easily, guarantees that the inside and outside unanimity of notched width. However, in this patent, the cricothyroid membrane is incised with a knife edge, which causes defects such as varied incision sizes, excessive bleeding in incisions, and complicated operation. Moreover, the above described quick-cutter is still prone to residual bacteria at the blade edge and blade.
Therefore, in addition to the conventional clinical instrument disinfection process and the wrapping antibacterial composite membrane which are generally adopted in hospitals, the improvement of the incision device itself is needed to endow the incision device with antibacterial performance, and the incision device is simple, convenient and quick in disinfection and can still meet clinical requirements after being repeatedly used for many times.
Disclosure of Invention
In view of the above problems, it is an object of the present invention to provide a cricothyroid dissection kit (or device) for use in a cricothyroid dissection.
In order to achieve the purpose, on one hand, the invention adopts the following technical scheme: a cricothyroid membrane cutting kit comprises a surgical blade, a knife handle and a forceps body; the surgical blade is mounted on the knife handle; the clamp body is formed by hinging two clamp walls, and a clamping part is formed at the front end of each of the two clamp arms; the tool shank is arranged in the concave space of the clamping part; the front end of the surgical knife blade is provided with a knife tip, and arc-shaped knife edges are arranged on two sides of the surgical knife blade; characterized in that the surgical blade is made of a metal material and further has a structural inner layer and an antibacterial surface layer.
The cricothyroid membrane cutting kit according to the present invention, wherein said metallic material is selected from stainless steel materials.
Preferably, the metallic material is selected from 440C stainless steel.
The cricothyroid membrane cutting kit in accordance with the present invention is characterized in that the antimicrobial surface layer contains more than or equal to 2.9 wt% copper.
Preferably, the antimicrobial surface layer contains 2.9-3.5 wt% copper.
The cricothyroid membrane cutting kit according to the present invention, wherein said antimicrobial surface layer further comprises 0.23-0.30 wt% praseodymium.
Preferably, the antibacterial surface layer contains 0.25-0.28 wt% of praseodymium.
The cricothyroid membrane cutting kit in accordance with the present invention is characterized in that the thickness of said antimicrobial surface layer is 15-24 μm.
Preferably, the thickness of the antibacterial surface layer is 17-21 μm.
The cricothyroid membrane cutting kit is characterized in that the antibacterial surface layer is obtained by a dual-glow diffusion plating method; wherein, the source electrode material is selected from a copper praseodymium alloy.
The cricothyroid membrane cutting kit is characterized in that the source electrode material is selected from the group consisting of copper and praseodymium in a mass ratio of 8: 2, copper praseodymium alloy.
The cricothyroid membrane cutting kit is characterized in that the process parameters of the dual-glow diffusion plating method are as follows: ar pressure is 30 Pa; the source voltage is 950V; the cathode voltage is 450V; the distance between the cathode plates is 15 mm; the heat preservation temperature is 1050 ℃; the heat preservation time is 3-7 h.
Preferably, the process parameters of the dual-glow diffusion plating method are as follows: ar pressure is 30 Pa; the source voltage is 950V; the cathode voltage is 450V; the distance between the cathode plates is 15 mm; the heat preservation temperature is 1050 ℃; the heat preservation time is 4-6 h.
The cricothyroid membrane incision kit according to the present invention is characterized in that an endotracheal tube is further provided on the forceps body.
The cricothyroid membrane incision kit of the present invention, wherein the endotracheal tube is connected to a pressure indicating balloon.
Compared with the prior art, the cricothyroid membrane cutting sleeve is endowed with antibacterial performance by the improvement of the cricothyroid membrane cutting sleeve device, the cricothyroid membrane cutting sleeve is simple, convenient and quick in disinfection, and can still meet clinical requirements after repeated use.
Without wishing to be bound by any theory, the present invention imparts a better antimicrobial effect to the circumcision kit by forming an antimicrobial surface layer of a specific composition on the circumcision kit surgical blades; especially has strong antibacterial effect (the antibacterial rate is more than or equal to 99%) against escherichia coli and staphylococcus aureus.
Detailed Description
The following examples are merely illustrative of embodiments of the present invention and do not limit the scope of the invention.
Example 1
A cricothyroid membrane cutting kit comprises a surgical blade, a knife handle and a forceps body; the surgical blade is mounted on the knife handle; the clamp body is formed by hinging two clamp walls, and a clamping part is formed at the front end of each of the two clamp arms; the tool shank is arranged in the concave space of the clamping part; the front end of the surgical knife blade is provided with a knife tip, and arc-shaped knife edges are arranged on two sides of the surgical knife blade; the surgical blade is made of a metal material and further has a structural inner layer and an antibacterial surface layer; the metal material is selected from 440C stainless steel. An endotracheal tube is further arranged on the forceps body; an endotracheal tube is further arranged on the forceps body. The antimicrobial surface layer contains 2.9 wt% copper and 0.25 wt% praseodymium. The thickness of the antibacterial surface layer is 17 μm. The antibacterial surface layer is obtained by a dual-glow diffusion plating method; wherein the source electrode material is selected from the group consisting of copper and praseodymium in a mass ratio of 8: 2, copper praseodymium alloy. The technological parameters of the dual-glow diffusion plating method are as follows: ar pressure is 30 Pa; the source voltage is 950V; the cathode voltage is 450V; the distance between the cathode plates is 15 mm; the heat preservation temperature is 1050 ℃; the heat preservation time is 4 h.
Example 2
A cricothyroid membrane cutting kit comprises a surgical blade, a knife handle and a forceps body; the surgical blade is mounted on the knife handle; the clamp body is formed by hinging two clamp walls, and a clamping part is formed at the front end of each of the two clamp arms; the tool shank is arranged in the concave space of the clamping part; the front end of the surgical knife blade is provided with a knife tip, and arc-shaped knife edges are arranged on two sides of the surgical knife blade; the surgical blade is made of a metal material and further has a structural inner layer and an antibacterial surface layer; the metal material is selected from 440C stainless steel. An endotracheal tube is further arranged on the forceps body; an endotracheal tube is further arranged on the forceps body. The antimicrobial surface layer contains 3.5 wt% copper and 0.28 wt% praseodymium. The thickness of the antibacterial surface layer is 21 μm. The antibacterial surface layer is obtained by a dual-glow diffusion plating method; wherein the source electrode material is selected from the group consisting of copper and praseodymium in a mass ratio of 8: 2, copper praseodymium alloy. The technological parameters of the dual-glow diffusion plating method are as follows: ar pressure is 30 Pa; the source voltage is 950V; the cathode voltage is 450V; the distance between the cathode plates is 15 mm; the heat preservation temperature is 1050 ℃; the heat preservation time is 6 h.
Comparative example 1
The other conditions were the same as in example 1, except that the incubation time was 2 hours. The resulting antimicrobial surface layer contained 2.4 wt% copper and 0.16 wt% praseodymium; the thickness was 13 μm.
Comparative example 2
The other conditions were the same as in example 1, except that the incubation time was 10 hours. The resulting antimicrobial surface layer contained 4.3 wt% copper and 0.33 wt% praseodymium; the thickness was 25 μm.
Test of antibacterial Property
The antibacterial performance test is carried out according to a standard antibacterial test method, and the used test bacterial liquid has the concentration of (5.0-10.0) × 105coli and staphylococcus aureus solutions of cfu/ml were prepared by contacting the scalpel blades of the cyclotomy kit of examples 1-2 and comparative examples 1-2 (made of 440C stainless steel, but not containing an antibacterial surface layer) with the above solutions for 24 hours, diluting the diluted solutions appropriately, plating the diluted solutions on a plate, incubating the diluted solutions at 37 ℃ for 24 hours, calculating the viable cell counts a and B of the cyclotomy kits of examples 1-2 and comparative examples 1-2 according to GB 4789.2-2016, and calculating the antibacterial ratio (%) as (a-B)/a × 100%.
The results are shown in Table 1.
TABLE 1
Figure BDA0002433632320000061
Figure BDA0002433632320000071
The results show that compared with the comparative examples 1-2, the cricothyroid membrane incision kit of the examples 1-2 of the present invention has strong antibacterial effect (more than or equal to 99%) against both Escherichia coli and Staphylococcus aureus. As the copper and praseodymium contents decreased, it was observed that comparative example 1 had no antibacterial effect (< 90%) against E.coli, but had a general antibacterial effect (< 99% and > 90%) against Staphylococcus aureus. On the other hand, although comparative example 2 was observed to have a strong antibacterial effect against escherichia coli as the copper and praseodymium contents increased, it had only a general antibacterial effect against staphylococcus aureus, but rather decreased.
Without wishing to be bound by any theory, the present invention imparts a better antimicrobial effect to the circumcision kit by forming an antimicrobial surface layer of a specific composition on the blades of the circumcision kit.
It should be understood that the detailed description of the invention is merely illustrative of the spirit and principles of the invention and is not intended to limit the scope of the invention. Furthermore, it should be understood that various changes, substitutions, deletions, modifications or adjustments may be made by those skilled in the art after reading the disclosure of the present invention, and such equivalents are also within the scope of the invention as defined in the appended claims.

Claims (10)

1. A cricothyroid membrane cutting kit comprises a surgical blade, a knife handle and a forceps body; the surgical blade is mounted on the knife handle; the clamp body is formed by hinging two clamp walls, and a clamping part is formed at the front end of each of the two clamp arms; the tool shank is arranged in the concave space of the clamping part; the front end of the surgical knife blade is provided with a knife tip, and arc-shaped knife edges are arranged on two sides of the surgical knife blade; characterized in that the surgical blade is made of a metal material and further has a structural inner layer and an antibacterial surface layer.
2. The cricothyroid membrane cutting kit of claim 1, wherein said metallic material is selected from the group consisting of stainless steel materials.
3. The cricothyroid membrane cutting kit of claim 1, wherein said antimicrobial surface layer comprises greater than or equal to 2.9 wt% copper.
4. The cyclothyrocrine cutting kit according to claim 1, wherein said antimicrobial surface layer further comprises 0.23-0.30 wt% praseodymium.
5. The cricothyroid membrane cutting kit of claim 1, wherein said antimicrobial surface layer has a thickness of 15-24 μ ι η.
6. The cricothyroid membrane cutting kit of claim 1, wherein said antimicrobial surface layer is obtained by a bi-glow diffusion process; wherein, the source electrode material is selected from a copper praseodymium alloy.
7. The cyclothyrocrine cutting kit according to claim 6, wherein the source material is selected from the group consisting of copper and praseodymium in a mass ratio of 8: 2, copper praseodymium alloy.
8. The cycloonychin cut kit according to claim 6, characterised in that the process parameters of the dual glow diffusion process are: ar pressure is 30 Pa; the source voltage is 950V; the cathode voltage is 450V; the distance between the cathode plates is 15 mm; the heat preservation temperature is 1050 ℃; the heat preservation time is 3-7 h.
9. The cricothyroid membrane incision kit of claim 1, wherein said forceps body further comprises an endotracheal tube.
10. The cricothyroid membrane incision kit of claim 1, wherein said endotracheal tube is connected to a pressure indicating balloon.
CN202010244535.9A 2020-03-31 2020-03-31 Gasbag pressure indication type cricothyroid membrane cuts suit Active CN111407365B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1948535A (en) * 2006-11-09 2007-04-18 安徽工业大学 Rare earth improving antibacterial performance silver containing stainless steel
CN201519352U (en) * 2009-10-20 2010-07-07 王剑平 Improved type trachea cannula
CN202054883U (en) * 2011-03-24 2011-11-30 桂林电子科技大学 Antibacterial stainless steel containing copper and cerium on surface
CN203424998U (en) * 2013-09-04 2014-02-12 中国人民解放军第三军医大学第三附属医院 Fast cricothyroid membrane cutter
CN208339573U (en) * 2017-12-31 2019-01-08 杨冬 Intercricothyrotomy Special surgical blade

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1948535A (en) * 2006-11-09 2007-04-18 安徽工业大学 Rare earth improving antibacterial performance silver containing stainless steel
CN201519352U (en) * 2009-10-20 2010-07-07 王剑平 Improved type trachea cannula
CN202054883U (en) * 2011-03-24 2011-11-30 桂林电子科技大学 Antibacterial stainless steel containing copper and cerium on surface
CN203424998U (en) * 2013-09-04 2014-02-12 中国人民解放军第三军医大学第三附属医院 Fast cricothyroid membrane cutter
CN208339573U (en) * 2017-12-31 2019-01-08 杨冬 Intercricothyrotomy Special surgical blade

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