CN111381016A - Method for detecting cracking of lead-acid storage battery cell - Google Patents
Method for detecting cracking of lead-acid storage battery cell Download PDFInfo
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- CN111381016A CN111381016A CN202010161529.7A CN202010161529A CN111381016A CN 111381016 A CN111381016 A CN 111381016A CN 202010161529 A CN202010161529 A CN 202010161529A CN 111381016 A CN111381016 A CN 111381016A
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- Prior art keywords
- battery
- cracking
- storage battery
- detecting
- oil
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- 238000003860 storage Methods 0.000 title claims abstract description 26
- 238000005336 cracking Methods 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 18
- 239000002253 acid Substances 0.000 title abstract description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 20
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 20
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 20
- 239000003921 oil Substances 0.000 claims description 12
- 239000003502 gasoline Substances 0.000 claims description 8
- 239000010705 motor oil Substances 0.000 claims description 8
- 239000010687 lubricating oil Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/44—Resins; Plastics; Rubber; Leather
- G01N33/442—Resins; Plastics
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
The invention relates to the field of lead-acid storage batteries, in particular to a method for detecting cracking of a storage battery tank, which comprises the following steps of 1, coating sulfuric acid on the battery tank, and coating a first material after the sulfuric acid liquid is dried; step 2, standing the battery jar under certain pressure; and 3, judging whether the battery jar cracks. By adopting the method, the invention can effectively detect the cracking reason of the battery jar.
Description
Technical Field
The invention relates to a lead-acid storage battery.
Background
Lead-acid storage batteries for low-speed electric vehicles have been widely used, and the storage battery groove of the lead-acid storage battery is formed by modifying ABS materials and performing extrusion molding and injection molding. ABS is a terpolymer of acrylonitrile, butadiene and styrene, A represents acrylonitrile, B represents butadiene and S represents styrene. The plastic ABS is not influenced by water, inorganic salt, alkali and various acids, has better liquid resistance, such as lubricant, gasoline, engine oil, acid, alkali, organic solvent, brake oil and the like, and has excellent performance due to three compositions; acrylonitrile endows ABS resin with chemical stability, oil resistance, certain rigidity and hardness; the toughness, impact resistance and cold resistance of the butadiene are improved; styrene gives it good dielectric properties and good processability. In addition, the thermal deformation temperature of the ABS plastic is 93-118 ℃, and the temperature of the product can be increased by about 10 ℃ after annealing treatment. ABS still can show certain toughness at-40 ℃ and can be used within the temperature range of-40-100 ℃. Therefore, the lead-acid storage battery can is widely applied to raw materials of lead-acid storage battery cells for electric road vehicles. The cracking phenomenon of the storage battery groove in the use process troubles customers and storage battery manufacturers, and the method for detecting the cracking of the storage battery groove is very important in order to find out the reason of the cracking of the storage battery groove and avoid the occurrence of the same faults.
Disclosure of Invention
In order to solve the technical problem, the invention provides a method for detecting the cracking of a storage battery jar, which comprises the following steps of 1, coating sulfuric acid on the storage battery jar, and coating a first material after the sulfuric acid solution is dried; step 2, standing the battery jar under certain pressure; and 3, judging whether the battery jar cracks.
Further, the pressure of the battery jar in the step 2 is between 10 and 20 kpa.
Further, the standing time of the battery jar in the step 2 is 12 hours.
Further, the first material is a material contacted in the production process of the storage battery or a material contacted in the use process.
Further, the first material is one or a combination of more of rosin water, boiled oil water, brake oil, engine oil, gasoline and lubricating oil.
The method for detecting the cracking of the storage battery can effectively detect the cracking reason of the storage battery.
Detailed Description
The invention is further illustrated by the following specific examples.
The method for detecting the cracking of the storage battery jar comprises the following steps of 1, coating sulfuric acid on the battery jar, and coating a first material after the sulfuric acid solution is dried; step 2, standing the battery jar under certain pressure; and 3, judging whether the battery jar cracks.
Rosin water, boiled oil water and the like are commonly used in the production process of the storage battery, and lubricating oil, brake oil, gasoline, engine oil and the like may be encountered in the use process. In the test, rosin water, brake oil, engine oil, lubricating oil and gasoline are respectively coated on the end faces of 5 battery tanks, and the tank body does not crack after standing for 12 hours. In the production process, the assembly pressure of the battery is 10-20kpa, so that in the test, the pressure of the monomer tank of the battery tank is adjusted to 15kpa, rosin water, brake oil, engine oil, gasoline, lubricating oil and the like are respectively coated on the end face of the storage battery, and the storage battery tank does not crack after standing for 12 hours.
Because the lead-acid battery has sulfuric acid in the production process, the method for detecting the cracking of the storage battery tank comprises the following steps of 1, smearing the sulfuric acid with the density of 1.35g/cm3 on the end face of the first battery tank, and smearing rosin water after the sulfuric acid liquid is dried; step 2, standing the battery jar for 12 hours under the pressure of 15 kpa; and 3, judging that the tank body coated with the rosin water cracks.
And (3) replacing the rosin water in the step (1) with brake oil, repeating the steps, and cracking.
And (3) replacing the rosin water in the step (1) with engine oil, and repeating the steps without cracking.
And (3) replacing the rosin water in the step (1) with gasoline, and repeating the steps without cracking.
And (3) replacing the rosin water in the step (1) with lubricating oil, and repeating the steps without cracking.
And (3) replacing the rosin water in the step (1) with the rosin water and the brake oil, repeating the steps, and cracking.
And (3) replacing the rosin water in the step (1) with the rosin water and the engine oil, repeating the steps, and cracking.
And (3) changing the rosin water in the step (1) into the rosin water and the gasoline, repeating the steps, and cracking. And (3) replacing the rosin water in the step (1) with the rosin water and the lubricating oil, repeating the steps, and cracking.
The first material of the invention can be one or any combination of materials contacted in the production process of the storage battery or materials contacted in the use process.
The brake fluid is non-mineral oil system, and is prepared by blending alcohol ether type synthetic brake fluid which is based on polyglycol and mainly contains glycol and glycol derivatives, and then adding a lubricant, a diluent, an antirust agent, a rubber inhibitor and the like; the main components of the rosin water are amyl acetate and strong oxidant substances. The electrolyte belongs to organic solvents and battery tanks, residual sulfuric acid is on the surface of the battery tank on the premise of external stress, and when the battery tank meets the organic solvents, chemical reaction can be generated to generate acetic acid substances, so that the battery tank is cracked.
Claims (5)
1. A method for detecting the cracking of a storage battery jar comprises the following steps of 1, coating sulfuric acid on the battery jar, and coating a first material after the sulfuric acid liquid is dried; step 2, standing the battery jar under certain pressure; and 3, judging whether the battery jar cracks.
2. The method of detecting battery cell cracking according to claim 1, wherein the pressure of the battery cell in step 2 is between 10-20 kpa.
3. The method for detecting the cracking of a battery container according to claim 2, wherein the battery container is left for 12 hours in the step 2.
4. A method of detecting cracking of a battery cell according to any of claims 1-3, characterized in that the first material is the material which is in contact during the battery production process or the material which is in contact during use.
5. The method according to claim 4, wherein the first material is one or more of rosin water, boiled oil water, brake oil, engine oil, gasoline, and lubricating oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010161529.7A CN111381016A (en) | 2020-03-10 | 2020-03-10 | Method for detecting cracking of lead-acid storage battery cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010161529.7A CN111381016A (en) | 2020-03-10 | 2020-03-10 | Method for detecting cracking of lead-acid storage battery cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111381016A true CN111381016A (en) | 2020-07-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010161529.7A Pending CN111381016A (en) | 2020-03-10 | 2020-03-10 | Method for detecting cracking of lead-acid storage battery cell |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111381016A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104241610A (en) * | 2014-07-31 | 2014-12-24 | 超威电源有限公司 | Surface acidification method and device for lead-acid storage battery pole plates |
| CN105199303A (en) * | 2015-09-16 | 2015-12-30 | 广东天保新材料有限责任公司 | High-impact greasy-dirt-resistant modified regenerated ABS material and preparation method thereof |
| CN205067302U (en) * | 2015-10-26 | 2016-03-02 | 超威电源有限公司 | Lead acid battery ABS kerve device of nai corrosion detection |
| CN106198521A (en) * | 2016-07-01 | 2016-12-07 | 天能电池集团有限公司 | A kind of method detecting lead battery acid adding effect |
| CN208458901U (en) * | 2018-07-18 | 2019-02-01 | 超威电源有限公司 | A kind of battery case internal stress test device |
| CN110261777A (en) * | 2019-07-09 | 2019-09-20 | 安徽新动新能源科技有限公司 | A kind of test device in battery pack production process |
-
2020
- 2020-03-10 CN CN202010161529.7A patent/CN111381016A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104241610A (en) * | 2014-07-31 | 2014-12-24 | 超威电源有限公司 | Surface acidification method and device for lead-acid storage battery pole plates |
| CN105199303A (en) * | 2015-09-16 | 2015-12-30 | 广东天保新材料有限责任公司 | High-impact greasy-dirt-resistant modified regenerated ABS material and preparation method thereof |
| CN205067302U (en) * | 2015-10-26 | 2016-03-02 | 超威电源有限公司 | Lead acid battery ABS kerve device of nai corrosion detection |
| CN106198521A (en) * | 2016-07-01 | 2016-12-07 | 天能电池集团有限公司 | A kind of method detecting lead battery acid adding effect |
| CN208458901U (en) * | 2018-07-18 | 2019-02-01 | 超威电源有限公司 | A kind of battery case internal stress test device |
| CN110261777A (en) * | 2019-07-09 | 2019-09-20 | 安徽新动新能源科技有限公司 | A kind of test device in battery pack production process |
Non-Patent Citations (5)
| Title |
|---|
| 侯晓东等: "《汽车拖拉机用铅蓄电池》", 30 September 1976 * |
| 杨清德: "铅酸蓄电池故障诊、修", 《家电检修技术》 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200707 |
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| RJ01 | Rejection of invention patent application after publication |