CN111363453A - Ultraviolet-curable high-temperature container lining material and preparation method thereof - Google Patents
Ultraviolet-curable high-temperature container lining material and preparation method thereof Download PDFInfo
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- CN111363453A CN111363453A CN202010252008.2A CN202010252008A CN111363453A CN 111363453 A CN111363453 A CN 111363453A CN 202010252008 A CN202010252008 A CN 202010252008A CN 111363453 A CN111363453 A CN 111363453A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/752—Corrosion inhibitor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
- C08J2363/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses an ultraviolet-curable high-temperature container lining material and a preparation method thereof. According to the invention, the thermosetting prepreg sheet with super-strong wear resistance, scratch resistance and prominent corrosion resistance is combined with the ultraviolet curing resin primer, so that the chemical properties of the thermosetting prepreg sheet are stable, and the permeability is prevented, meanwhile, the adhesion capability of the thermosetting prepreg sheet and the inner wall of the container and the integrity of corrosion protection can be greatly improved, and the problems of low curing speed, large influence of external environment temperature and VOC (volatile organic compounds) emission of the traditional lining material are solved; and the prepreg sheet is a soft sheet before being cured, is suitable for irregular container linings and has strong general applicability.
Description
Technical Field
The invention belongs to the technical field of ultraviolet radiation curing and corrosion prevention, and particularly relates to an ultraviolet-curable lining material for a high-temperature container and a preparation method of the lining material.
Background
In the field of petrochemical engineering lining corrosion prevention, most of the petrochemical engineering lining corrosion prevention products adopt the forms of coating and hand-pasted glass fiber reinforced plastic. The use of the coating is limited under the increasingly strict requirements on environmental protection, because the coating has serious pollution to human bodies and environment and has poor use effect in a high-temperature acid gas environment; the hand-pasted glass fiber reinforced plastic adopts a construction process of two-cloth five-glue or three-cloth seven-glue, is low in speed, unstable in quality and seriously influenced by the environmental temperature, and wastes can cause secondary pollution to the surrounding environment.
Disclosure of Invention
The invention aims to solve the problems of the traditional lining material, and provides a container lining material which has the advantages of super wear resistance, scratch resistance, corrosion resistance, stable chemical performance, seepage prevention, high temperature resistance and ultraviolet light curing.
Aiming at the purposes, the lining material adopted by the invention consists of ultraviolet light curing resin primer and an ultraviolet light curing thermosetting prepreg sheet; wherein the violet curing resin primer comprises a phenolic vinyl resin and a photoinitiator; the ultraviolet-curable thermosetting prepreg sheet comprises an upper carrier film, a lower carrier film, resin paste and a fiber reinforcing material.
The ultraviolet curing resin primer comprises the following components in parts by weight: 100 parts of phenolic vinyl resin and 0.2-0.5 part of photoinitiator.
The ultraviolet light curable thermosetting prepreg sheet is manufactured according to the production process of a sheet molding compound, wherein the upper bearing film and the lower bearing film are both polyethylene/polyamide/polypropylene composite films; the fiber reinforced material is any one or more of glass fiber, metal fiber, ceramic fiber and organic fiber; the resin paste comprises the following components in parts by weight: 40-60 parts of phenolic vinyl resin, 0.105-0.22 part of photoinitiator, 0.07-0.16 part of wetting dispersant, 0.10-0.29 part of defoaming agent, 0.05-0.15 part of fiber wetting agent, 35-55 parts of 300-500 mesh silane coupling agent modified glass flake, 10-30 parts of 80-100 mesh silane coupling agent modified glass flake and 10-20 parts of silane coupling agent modified aluminum hydroxide with the particle size of 10-30 mu m.
In the resin paste, the wetting dispersant is one or two of BYK-W996 and CF-10 wetting dispersants, the defoaming agent is one or two of BYK-A555 and DF-2213, the fiber sizing agent is one or two of BYK-A560 and Solplus2000, and the silane coupling agent is one or more of silane coupling agents KH560, KH570 and KH 550.
In the above-mentioned violet light curing resin primer and resin paste, the photoinitiator is any one of photoinitiators 819, 907, 1173, TPO-L, IHT-PI 910, 659, and MBF.
The preparation method of the ultraviolet light curable high-temperature container lining comprises the following steps:
1. the ultraviolet light-cured thermosetting prepreg sheet is manufactured by utilizing the production process of the sheet molding compound.
2. Uniformly coating the ultraviolet curing resin primer on the inner surface of the container, then applying an ultraviolet curing thermosetting prepreg sheet on the surface of the primer, compacting by using a roller and removing air bubbles, and curing by using an ultraviolet lamp to form a layer of lining material on the inner surface of the container.
In the step 2, the coating thickness is preferably 150-200 μm, and an ultraviolet lamp with a wavelength of 300-400 nm is used for curing for 30-60 minutes.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the invention, the thermosetting prepreg sheet with super-strong wear resistance, scratch resistance and prominent corrosion resistance is combined with the ultraviolet curing resin primer, so that the chemical properties of the thermosetting prepreg sheet are stable, and the permeability is prevented, meanwhile, the adhesion capability of the thermosetting prepreg sheet and the inner wall of the container and the integrity of corrosion protection can be greatly improved, and a new solution is provided for the problem of internal corrosion of a high-temperature container.
2. The invention utilizes the theory of ultraviolet radiation curing to quickly cure the phenolic vinyl resin and the thermosetting prepreg, and the phenolic vinyl resin solves the problem of long-term high temperature resistance; the glass flakes form multiple barriers to solve the problem of permeation, and the defects that the traditional lining material is slow in curing speed and greatly influenced by the external environment temperature and the problem of VOC (volatile organic compounds) emission of the traditional lining paint are solved; and the prepreg sheet is a soft sheet before being cured, is suitable for irregular container linings and has strong general applicability.
Detailed Description
The present invention will be described in further detail with reference to examples, but the scope of the present invention is not limited to these examples.
Example 1
1. 400g of phenolic vinyl resin, 1.1g of photoinitiator 819, 1.0g of BYK-W996 wetting dispersant, 1.6g of BYK-A555 defoaming agent, 0.7g of BYK-A560 fiber impregnating compound, 380g of 300-mesh silane coupling agent KH560 modified glass flake, 180g of 80-mesh silane coupling agent KH560 modified glass flake and 120g of aluminum hydroxide with the particle size of 25 mu m are sequentially added into a stirring kettle and uniformly mixed to obtain the resin paste. The resin paste is prepared into the ultraviolet light curing thermosetting prepreg sheet by utilizing the production process of the sheet molding compound, the ultraviolet light curing thermosetting prepreg sheet comprises an upper bearing film, a lower bearing film, the resin paste and a fiber reinforced material, the upper bearing film and the lower bearing film are both polyethylene/polyamide/polypropylene composite films, the fiber reinforced material is glass fiber chopped yarns, and the ultraviolet light curing thermosetting prepreg sheet is 1.5mm in thickness, 1000mm in width and 10m in length.
2. Adding 1000g of phenolic vinyl resin and 2g of photoinitiator 819 into a stirring kettle in sequence, uniformly mixing to obtain a purple light cured resin primer, uniformly coating the inner surface of a container with the obtained purple light cured resin primer, wherein the coating thickness is 150-200 mu m, then applying the ultraviolet light curable thermosetting prepreg sheet prepared in the step 1 on the surface of the primer, compacting by using a roller, removing air bubbles, and curing for 30 minutes under an ultraviolet lamp with the wavelength of 300-400 nm to form a layer of lining material with the hardness of Shore 85 on the inner surface of the container.
The lining material obtained in this example had a high adhesive strength, and the average adhesive strength measured by the drawing method was 15.36 MPa.
Example 2
1. 500g of phenolic vinyl resin, 1.5g of photoinitiator 819, 1.2g of BYK-W996 wetting dispersant, 1.4g of BYK-A555 defoaming agent, 0.9g of BYK-A560 fiber impregnating compound, 420g of 300-mesh silane coupling agent KH560 modified glass flake, 220g of 100-mesh silane coupling agent KH560 modified glass flake and 100g of aluminum hydroxide with the particle size of 10 mu m are sequentially added into a stirring kettle and uniformly mixed to obtain resin paste. The resin paste is prepared into the ultraviolet light curing thermosetting prepreg sheet by utilizing the production process of the sheet molding compound, the ultraviolet light curing thermosetting prepreg sheet comprises an upper bearing film, a lower bearing film, the resin paste and a fiber reinforced material, the upper bearing film and the lower bearing film are both polyethylene/polyamide/polypropylene composite films, the fiber reinforced material is glass fiber chopped yarns, and the ultraviolet light curing thermosetting prepreg sheet is 1.5mm in thickness, 1000mm in width and 10m in length.
2. Adding 1000g of phenolic vinyl resin and 3g of photoinitiator 819 into a stirring kettle in sequence, uniformly mixing to obtain a purple light cured resin primer, uniformly coating the inner surface of a container with the obtained purple light cured resin primer, wherein the coating thickness is 150-200 mu m, then applying the ultraviolet light curable thermosetting prepreg sheet prepared in the step 1 on the surface of the primer, compacting by using a roller, removing air bubbles, and curing for 30 minutes under an ultraviolet lamp with the wavelength of 300-400 nm to form a layer of lining material with the hardness of Shore 85 on the inner surface of the container.
The lining material obtained in this example had a high adhesive strength, and the average adhesive strength measured by the drawing method was 15.92 MPa.
Example 3
1. 550g of phenolic vinyl resin, 1.6g of photoinitiator 819, 1.1g of BYK-W996 wetting dispersant, 2.0g of BYK-A555 defoaming agent, 0.6g of BYK-A560 fiber impregnating compound, 500g of 500-mesh silane coupling agent KH560 modified glass flake, 80g of 100-mesh silane coupling agent KH560 modified glass flake and 150g of aluminum hydroxide with the particle size of 25 mu m are sequentially added into a stirring kettle and uniformly mixed to obtain the resin paste. The resin paste is prepared into the ultraviolet light curing thermosetting prepreg sheet by utilizing the production process of the sheet molding compound, the ultraviolet light curing thermosetting prepreg sheet comprises an upper bearing film, a lower bearing film, the resin paste and a fiber reinforced material, the upper bearing film and the lower bearing film are both polyethylene/polyamide/polypropylene composite films, the fiber reinforced material is glass fiber chopped yarns, and the ultraviolet light curing thermosetting prepreg sheet is 1.5mm in thickness, 1000mm in width and 10m in length.
2. Adding 1000g of phenolic vinyl resin and 2.5g of photoinitiator 819 into a stirring kettle in sequence, uniformly mixing to obtain a purple light cured resin primer, uniformly coating the inner surface of a container with the obtained purple light cured resin primer, wherein the coating thickness is 150-200 mu m, then applying the ultraviolet light curable thermosetting prepreg sheet prepared in the step 1 on the surface of the primer, compacting by using a roller, removing air bubbles, and curing for 30 minutes under an ultraviolet lamp with the wavelength of 300-400 nm to form a layer of lining material with the hardness of Shore 85 on the inner surface of the container.
The lining material obtained in the above examples had a very high adhesive strength, and the average adhesive strength measured by the drawing method was 18.03 MPa.
In the above examples 1 to 3, the chopped glass fiber yarns may be replaced by metal fibers, ceramic fibers, or organic fibers, the BYK-W996 wetting dispersant may be replaced by CF-10 wetting dispersant, the BYK-A555 defoamer may be replaced by DF-2213 defoamer, the YK-A560 fiber wetting agent may be replaced by Solplus2000 fiber wetting agent, the silane coupling agent KH560 may be replaced by silane coupling agent KH570 or KH550, and the photoinitiator 819 may be replaced by any one of photoinitiators 907, 1173, TPO-L, IHT-PI 910, 659, or MBF, which are within the scope of the present invention.
Claims (10)
1. An ultraviolet light-curable high-temperature container lining material is characterized in that: the lining material consists of ultraviolet light curing resin primer and an ultraviolet light curing thermosetting prepreg sheet; wherein the violet curing resin primer comprises a phenolic vinyl resin and a photoinitiator; the ultraviolet-curable thermosetting prepreg sheet comprises an upper carrier film, a lower carrier film, resin paste and a fiber reinforcing material.
2. The uv-curable high-temperature vessel lining material according to claim 1, wherein: the ultraviolet curing resin primer comprises the following components in parts by weight: 100 parts of phenolic vinyl resin and 0.2-0.5 part of photoinitiator.
3. The uv-curable high-temperature vessel lining material according to claim 1, wherein: the upper bearing film and the lower bearing film are both polyethylene/polyamide/polypropylene composite films.
4. The uv-curable high-temperature vessel lining material according to claim 1, wherein: the fiber reinforced material is any one or more of glass fiber, metal fiber, ceramic fiber and organic fiber.
5. The uv-curable high-temperature vessel lining material according to claim 1, wherein: the resin paste comprises the following components in parts by weight: 40-60 parts of phenolic vinyl resin, 0.105-0.22 part of photoinitiator, 0.07-0.16 part of wetting dispersant, 0.10-0.29 part of defoaming agent, 0.05-0.15 part of fiber wetting agent, 35-55 parts of 300-500 mesh silane coupling agent modified glass flake, 10-30 parts of 80-100 mesh silane coupling agent modified glass flake and 10-20 parts of silane coupling agent modified aluminum hydroxide with the particle size of 10-30 mu m.
6. The uv-curable high-temperature vessel lining material according to claim 5, wherein: the wetting dispersant is one or two of BYK-W996 and CF-10 wetting dispersants, the defoaming agent is one or two of BYK-A555 and DF-2213 defoaming agents, the fiber sizing agent is one or two of BYK-A560 and Solplus2000 fiber sizing agents, and the silane coupling agent is one or more of silane coupling agents KH560, KH570 and KH 550.
7. The uv-curable high-temperature vessel lining material according to any one of claims 1, 2, 5 and 6, wherein: the photoinitiator is any one of photoinitiators 819, 907, 1173, TPO-L, IHT-PI 910, 659 and MBF.
8. The uv-curable high-temperature vessel lining material according to claim 1, wherein: the ultraviolet light curable thermosetting prepreg sheet is manufactured according to the production process of the sheet molding compound.
9. A method of preparing a uv-curable high temperature vessel liner according to claim 1, wherein:
(1) manufacturing an ultraviolet light curable thermosetting prepreg sheet by using a production process of sheet molding compound;
(2) uniformly coating the ultraviolet curing resin primer on the inner surface of the container, then applying an ultraviolet curing thermosetting prepreg sheet on the surface of the primer, compacting by using a roller and removing air bubbles, and curing by using an ultraviolet lamp to form a layer of lining material on the inner surface of the container.
10. The method of preparing a uv-curable high temperature vessel liner according to claim 9, wherein: in the step (2), the coating thickness is 150-200 μm, and an ultraviolet lamp with a wavelength of 300-400 nm is used for curing for 30-60 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010252008.2A CN111363453A (en) | 2020-04-01 | 2020-04-01 | Ultraviolet-curable high-temperature container lining material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010252008.2A CN111363453A (en) | 2020-04-01 | 2020-04-01 | Ultraviolet-curable high-temperature container lining material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116376425A (en) * | 2023-03-13 | 2023-07-04 | 浙江晨诺高分子材料有限公司 | Photo-curing vinyl scale daub |
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| US20130046036A1 (en) * | 2011-08-19 | 2013-02-21 | Frx Polymers, Inc. | Thermoplastic polyurethanes with exceptional fire resistance |
| CN104945857A (en) * | 2015-06-18 | 2015-09-30 | 石狮华宝新材料工程有限公司 | Formula and production process of photocuring fiber-reinforced plate |
| CN105602203A (en) * | 2016-02-01 | 2016-05-25 | 四川远鸣科技有限公司 | Visible-light-curing vinyl ester resin composite prepreg, and preparation method and application method thereof |
| CN108003756A (en) * | 2017-12-13 | 2018-05-08 | 厦门中凯新材石墨烯科技有限公司 | A kind of storage tank liner graphene photocureable coating and its application method and preparation method |
| CN208927892U (en) * | 2018-09-28 | 2019-06-04 | 石狮华宝新材料工程有限公司 | It is a kind of to carry out the liner that heavy antisepsis is reinforced at the pipe joint of absorption tower based on Photocurable sheet |
-
2020
- 2020-04-01 CN CN202010252008.2A patent/CN111363453A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130046036A1 (en) * | 2011-08-19 | 2013-02-21 | Frx Polymers, Inc. | Thermoplastic polyurethanes with exceptional fire resistance |
| CN104945857A (en) * | 2015-06-18 | 2015-09-30 | 石狮华宝新材料工程有限公司 | Formula and production process of photocuring fiber-reinforced plate |
| CN105602203A (en) * | 2016-02-01 | 2016-05-25 | 四川远鸣科技有限公司 | Visible-light-curing vinyl ester resin composite prepreg, and preparation method and application method thereof |
| CN108003756A (en) * | 2017-12-13 | 2018-05-08 | 厦门中凯新材石墨烯科技有限公司 | A kind of storage tank liner graphene photocureable coating and its application method and preparation method |
| CN208927892U (en) * | 2018-09-28 | 2019-06-04 | 石狮华宝新材料工程有限公司 | It is a kind of to carry out the liner that heavy antisepsis is reinforced at the pipe joint of absorption tower based on Photocurable sheet |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116376425A (en) * | 2023-03-13 | 2023-07-04 | 浙江晨诺高分子材料有限公司 | Photo-curing vinyl scale daub |
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