CN111363411A - Rubber ink composition, preparation method and application method - Google Patents
Rubber ink composition, preparation method and application method Download PDFInfo
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- CN111363411A CN111363411A CN202010392470.2A CN202010392470A CN111363411A CN 111363411 A CN111363411 A CN 111363411A CN 202010392470 A CN202010392470 A CN 202010392470A CN 111363411 A CN111363411 A CN 111363411A
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- ink composition
- castor oil
- rubber
- rubber ink
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2461/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2461/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2461/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08J2461/14—Modified phenol-aldehyde condensates
Abstract
The invention belongs to the technical field of printing ink, and particularly relates to a rubber printing ink composition, a preparation method and an application method, wherein the rubber printing ink composition comprises, by weight, 5-15 parts of rosin modified castor oil phenolic resin, 1-3 parts of castor oil mercaptopropionate, 3-20 parts of a pigment, 0.5-2 parts of a dispersing agent, 0.5-1.5 parts of an anti-settling agent, 1-5 parts of an adhesion promoter and 60-80 parts of an organic solvent. The rubber ink composition can be directly sprayed on tire rubber at a temperature of 80-130 ℃, vulcanized for 20-50 minutes at a temperature of 150-180 ℃, and has the advantages of high adhesive force, good temperature resistance and difficult discoloration.
Description
Technical Field
The invention belongs to the technical field of printing ink, and relates to a rubber printing ink composition, a preparation method and an application method.
Background
The rubber ink is an ink printed on rubber, and is required to resist high temperature in a rubber processing process, and has less yellowing or no yellowing and good adhesive force, but the existing rubber ink has defects.
Disclosure of Invention
It is an object of the present invention to overcome the disadvantages of the prior art and to provide a rubber ink composition.
Another object of the present invention is to provide a method for preparing a rubber ink composition.
It is still another object of the present invention to provide a method for using a rubber ink composition.
The technical scheme of the invention is as follows:
the rubber ink composition comprises, by weight, 5-15 parts of rosin modified castor oil phenolic resin, 1-3 parts of castor oil mercaptopropionate, 3-20 parts of pigment, 0.5-2 parts of dispersing agent, 0.5-1.5 parts of anti-settling agent, 1-5 parts of adhesion promoter and 60-80 parts of organic solvent.
In the invention, the viscosity (35 ℃) of the rosin modified castor oil phenolic resin is 2000-4000 cP.
In the invention, the castor oil mercaptopropionate is obtained by esterification reaction of castor oil and mercaptopropionic acid.
In the invention, the pigment is selected from one or more of inorganic pigments or organic pigments. The inorganic pigment may be at least one selected from titanium dioxide, cadmium yellow, iron blue, chrome red, lithopone, iron red, iron yellow, chromium oxide green, lead chrome green, iron blue, cobalt blue and ultramarine. The organic pigment may be selected from at least one of permanent orange RN, gold brilliant red C, benzidine yellow G, macromolecular orange 4R, macromolecular red R, permanent red F5R, c.i. pigment violet 1, c.i. pigment orange 17, c.i. pigment blue 17, c.i. pigment violet 3, c.i. phthalocyanine blue 15, phthalocyanine red, phthalocyanine violet, permanent violet RL, pigment yellow 2GLT and permanent orange HSL.
In the present invention, the dispersant is selected from polymeric dispersants. The polymeric dispersant may be selected from polycarboxylate dispersants.
In the invention, the anti-settling agent is selected from one or more of organic bentonite, fumed silica, castor oil derivatives, polyamide wax and modified hydrogenated castor oil.
In the invention, the adhesion promoter is selected from silane coupling agents. The silane coupling agent may be selected from the group consisting of silane coupling agents containing a carbon-carbon unsaturated double bond, including but not limited to vinyltrimethoxysilane, vinyltriethoxysilane, vinylmethyldimethoxysilane, vinylmethyldiethoxysilane, methacryloxypropyltrimethoxysilane, methacryloxypropyltriethoxysilane, methacryloxypropylmethyldimethoxysilane, and methacryloxypropylmethyldiethoxysilane.
In the invention, the organic solvent is one or more selected from butanone, cyclohexanone, butyl acetate, N-butanol, propylene glycol monomethyl ether, ethylene glycol monomethyl ether, dipropylene glycol monomethyl ether, diethylene glycol monomethyl ether, N-Dimethylformamide (DMF), N-dimethylacetamide (DMAc), 1,2, 4-trimethylbenzene and 1,3, 5-trimethylbenzene.
According to the preparation method of the rubber ink composition, the raw material components are accurately weighed according to the formula, the organic solvent is added into a stirring kettle, the rosin modified castor oil phenolic resin and the castor oil mercaptopropionate are added, stirring and dissolving are carried out, the pigment, the dispersing agent, the anti-settling agent and the adhesion promoter are added, and the rubber ink composition is obtained after full mixing and uniform dispersion.
The application method of the rubber ink composition disclosed by the invention is directly sprayed on rubber at the temperature of 80-130 ℃, and the rubber ink composition is cured for 20-50 minutes at the temperature of 150-180 ℃. Or spraying the coating on rubber at room temperature, and curing at 150-180 ℃ for 20-50 minutes. The rubber may be selected from natural rubber, tyre rubber, ethylene propylene rubber, styrene butadiene rubber, neoprene rubber, isoprene rubber or butyl rubber.
The rubber ink composition of the present invention has a viscosity (25 ℃) of 1 to 18 mPas.
The invention has the beneficial effects that:
(1) after the rubber ink composition is sprayed on rubber and heated and cured, the rubber ink composition has good adhesive force and good temperature resistance and is not easy to yellow.
(2) The rubber ink composition is convenient to apply, can be directly sprayed on rubber at normal temperature and then heated and cured, and can also be directly sprayed on rubber at 80-130 ℃ and then heated and cured.
Detailed Description
The technical solution of the present invention is further illustrated and described by the following detailed description.
Unless otherwise specified, the parts in the following embodiments are parts by weight.
Example 1
According to the formula: 5 parts of rosin modified castor oil phenolic resin, 1 part of castor oil mercaptopropionate, 3 parts of iron yellow pigment, 0.5 part of polymeric dispersant, 0.5 part of organic bentonite, 1 part of vinyl trimethoxy silane and 60 parts of diethylene glycol monomethyl ether.
Adding diethylene glycol monomethyl ether into a stirring kettle, adding rosin modified castor oil phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding iron yellow pigment, a polymer type dispersant, organic bentonite and vinyl trimethoxy silane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, which is marked as C-1.
Example 2
According to the formula: 15 parts of rosin modified castor oil phenolic resin, 3 parts of castor oil mercaptopropionate, 18.5 parts of titanium dioxide, 1.5 parts of permanent violet RL pigment, 2 parts of polymeric dispersant, 1.5 parts of fumed silica, 5 parts of methacryloxypropyltriethoxysilane, 20 parts of 1,3, 5-trimethylbenzene and 60 parts of propylene glycol monomethyl ether.
Adding 1,3, 5-trimethylbenzene and propylene glycol monomethyl ether into a stirring kettle, adding rosin modified castor oil phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding titanium dioxide, permanent violet RL pigment, a polymer dispersant, fumed silica and methacryloxypropyl triethoxysilane, fully mixing, and uniformly dispersing to obtain the rubber ink composition which is marked as C-2.
Example 3
According to the formula: 10 parts of rosin modified castor oil phenolic resin, 2 parts of castor oil mercaptopropionate, 9.5 parts of titanium dioxide, 0.7 part of benzidine yellow G pigment, 1 part of polymeric dispersant, 1 part of modified hydrogenated castor oil, 3 parts of vinyl triethoxysilane, 20 parts of butanone and 50 parts of DMF.
Adding butanone and DMF into a stirring kettle, adding rosin modified castor oil phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding titanium dioxide and benzidine yellow G pigment, benzidine yellow G dispersing agent, modified hydrogenated castor oil and vinyl triethoxysilane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, which is marked as C-3.
Example 4
According to the formula: 12 parts of rosin modified castor oil phenolic resin, 1.3 parts of castor oil mercaptopropionate, 14 parts of titanium dioxide, 1 part of C.I. pigment blue 17 pigment, 1.3 parts of polymeric dispersant, 1.2 parts of organic bentonite, 2.5 parts of methacryloxypropyltrimethoxysilane, 15 parts of butyl acetate and 58 parts of dipropylene glycol monomethyl ether.
Adding butyl acetate and dipropylene glycol monomethyl ether into a stirring kettle, adding rosin modified castor oil phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding titanium dioxide, a C.I. pigment blue 17 pigment, a polymer type dispersing agent, organic bentonite and methacryloxypropyl trimethoxy silane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, which is marked as C-4.
Example 5
According to the formula: 8 parts of rosin modified castor oil phenolic resin, 1.6 parts of castor oil mercaptopropionate, 7 parts of titanium dioxide, 0.6 part of phthalocyanine violet pigment, 1.3 parts of polymeric dispersant, 1.2 parts of polyamide wax, 4 parts of methacryloxypropyl methyldimethoxysilane and 65 parts of ethylene glycol monomethyl ether.
Adding ethylene glycol monomethyl ether into a stirring kettle, adding rosin modified castor oil phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding titanium dioxide, phthalocyanine violet pigment, a polymer dispersant, polyamide wax and methacryloxypropyl methyldimethoxysilane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, which is marked as C-5.
Example 6
According to the formula: 12 parts of rosin modified castor oil phenolic resin, 2.5 parts of castor oil mercaptopropionate, 3.2 parts of permanent orange RN pigment, 1 part of polymeric dispersant, 1.1 parts of castor oil derivative anti-settling agent, 2.5 parts of vinyl methyl dimethoxysilane and 65 parts of cyclohexanone, and mixing.
Adding cyclohexanone into a stirring kettle, adding rosin modified castor oil phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding the permanent orange RN pigment, the polymeric dispersant, the castor oil derivative anti-settling agent and the vinyl methyl dimethoxyl silane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, which is marked as C-6.
Comparative example 1
According to the formula: 12 parts of rosin modified castor oil phenolic resin, 3.2 parts of permanent orange RN pigment, 1 part of polymeric dispersant, 1.1 parts of castor oil derivative anti-settling agent, 2.5 parts of vinyl methyl dimethoxy silane and 65 parts of cyclohexanone.
Adding cyclohexanone into a stirring kettle, adding rosin modified castor oil phenolic resin, stirring for dissolving, adding permanent orange RN pigment, a polymer type dispersing agent, a castor oil derivative anti-settling agent and vinyl methyl dimethoxy silane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, wherein the mark is C-7.
Comparative example 2
According to the formula: 12 parts of rosin modified phenolic resin, 2.5 parts of castor oil mercaptopropionate, 3.2 parts of permanent orange RN pigment, 1 part of polymeric dispersant, 1.1 parts of castor oil derivative anti-settling agent, 2.5 parts of vinyl methyl dimethoxysilane and 65 parts of cyclohexanone, and mixing.
Adding cyclohexanone into a stirring kettle, adding rosin modified phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding the permanent orange RN pigment, the polymeric dispersant, the castor oil derivative anti-settling agent and the vinyl methyl dimethoxyl silane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, wherein the mark is C-8.
Comparative example 3
According to the formula: 12 parts of castor oil modified phenolic resin, 2.5 parts of castor oil mercaptopropionate, 3.2 parts of permanent orange RN pigment, 1 part of polymeric dispersant, 1.1 parts of castor oil derivative anti-settling agent, 2.5 parts of vinyl methyl dimethoxysilane and 65 parts of cyclohexanone.
Adding cyclohexanone into a stirring kettle, adding castor oil modified phenolic resin and castor oil mercaptopropionate, stirring for dissolving, adding permanent orange RN pigment, a polymer type dispersing agent, a castor oil derivative anti-settling agent and vinyl methyl dimethoxyl silane, fully mixing, and uniformly dispersing to obtain the rubber ink composition, wherein the mark is C-9.
The properties of the rubber ink compositions C-1 to C-9 are shown in Table 1.
The rubber ink compositions C-1 to C-9 were sprayed on a tire at normal temperature and cured at 160 ℃ for 40 minutes, and the properties are shown in Table 1.
The rubber ink compositions C-1 to C-9 were sprayed on a tire at 110 ℃ and cured at 160 ℃ for 40 minutes, the properties of which are shown in Table 1.
TABLE 1
Therefore, the rubber ink composition has better adhesive force and temperature resistance after being sprayed on the surface of rubber and cured.
The foregoing has shown and described the fundamental principles, principal features and advantages of the invention. It should be understood by those skilled in the art that the present invention is not limited by the foregoing embodiments, which are merely preferred embodiments of the present invention, and the scope of the present invention should not be limited thereby, and that equivalent changes and modifications made within the scope of the present invention and the specification should be covered thereby. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. The rubber ink composition is characterized by comprising, by weight, 5-15 parts of rosin modified castor oil phenolic resin, 1-3 parts of castor oil mercaptopropionate, 3-20 parts of pigment, 0.5-2 parts of a dispersing agent, 0.5-1.5 parts of an anti-settling agent, 1-5 parts of an adhesion promoter and 60-80 parts of an organic solvent.
2. The rubber ink composition according to claim 1, wherein the viscosity (35 ℃) of the rosin-modified castor oil phenol resin is 2000 to 4000 cP.
3. The rubber ink composition of claim 1, wherein the castor oil mercaptopropionate is obtained from an esterification reaction of castor oil and mercaptopropionic acid.
4. The rubber ink composition according to claim 1, wherein the pigment is one or more selected from inorganic pigments and organic pigments.
5. The rubber ink composition of claim 1, the dispersant being selected from polymeric dispersants.
6. The rubber ink composition according to claim 1, wherein the anti-settling agent is one or more selected from the group consisting of organobentonite, fumed silica, castor oil derivatives, polyamide wax, and modified hydrogenated castor oil.
7. The rubber ink composition of claim 1, the adhesion promoter being selected from silane coupling agents.
8. The rubber ink composition according to claim 1, wherein the organic solvent is one or more selected from the group consisting of methyl ethyl ketone, cyclohexanone, butyl acetate, N-butanol, propylene glycol monomethyl ether, ethylene glycol monomethyl ether, dipropylene glycol monomethyl ether, diethylene glycol monomethyl ether, N-dimethylformamide, N-dimethylacetamide, 1,2, 4-trimethylbenzene and 1,3, 5-trimethylbenzene.
9. A method for preparing the rubber ink composition as described in any one of claims 1 to 8, wherein the rubber ink composition is obtained by accurately weighing each raw material component according to a formula, adding the organic solvent into a stirring tank, adding the rosin-modified castor oil phenolic resin and the castor oil mercaptopropionate, stirring for dissolution, adding the pigment, the dispersant, the anti-settling agent, and the adhesion promoter, mixing thoroughly, and dispersing uniformly.
10. A method of using the rubber ink composition of any one of claims 1 to 8, wherein the composition is directly sprayed on the rubber at 80 to 130 ℃ and cured at 150 to 180 ℃ for 20 to 50 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN202010392470.2A CN111363411B (en) | 2020-05-11 | 2020-05-11 | Rubber ink composition, preparation method and application method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010392470.2A CN111363411B (en) | 2020-05-11 | 2020-05-11 | Rubber ink composition, preparation method and application method |
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| CN111363411A true CN111363411A (en) | 2020-07-03 |
| CN111363411B CN111363411B (en) | 2022-06-07 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114752253A (en) * | 2020-12-29 | 2022-07-15 | 苏州圣瑞赛标识科技有限公司 | Complete water-based code-spraying ink for tires and preparation method and application thereof |
| CN116676015A (en) * | 2023-07-10 | 2023-09-01 | 徐工集团工程机械股份有限公司 | Printing ink composition and preparation method and application thereof |
| WO2024027463A1 (en) * | 2023-07-10 | 2024-02-08 | 徐工集团工程机械股份有限公司 | Ink composition, and preparation method and use thereof |
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| CN102911330A (en) * | 2012-10-16 | 2013-02-06 | 山西省应用化学研究所 | Vegetable oil modified rosin phenolic resin and preparation method thereof |
| CN104086728A (en) * | 2014-07-25 | 2014-10-08 | 广西众昌树脂有限公司 | Preparation method of modified phenolic resin |
| CN107936696A (en) * | 2017-12-27 | 2018-04-20 | 明光瑞泰工业有限公司 | A kind of automobile tire coding ink and preparation method thereof |
| CN108431154A (en) * | 2015-12-22 | 2018-08-21 | 株式会社普利司通 | Application composition, cured film, laminated body and tire |
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2020
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911330A (en) * | 2012-10-16 | 2013-02-06 | 山西省应用化学研究所 | Vegetable oil modified rosin phenolic resin and preparation method thereof |
| CN104086728A (en) * | 2014-07-25 | 2014-10-08 | 广西众昌树脂有限公司 | Preparation method of modified phenolic resin |
| CN108431154A (en) * | 2015-12-22 | 2018-08-21 | 株式会社普利司通 | Application composition, cured film, laminated body and tire |
| CN107936696A (en) * | 2017-12-27 | 2018-04-20 | 明光瑞泰工业有限公司 | A kind of automobile tire coding ink and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114752253A (en) * | 2020-12-29 | 2022-07-15 | 苏州圣瑞赛标识科技有限公司 | Complete water-based code-spraying ink for tires and preparation method and application thereof |
| CN116676015A (en) * | 2023-07-10 | 2023-09-01 | 徐工集团工程机械股份有限公司 | Printing ink composition and preparation method and application thereof |
| WO2024027463A1 (en) * | 2023-07-10 | 2024-02-08 | 徐工集团工程机械股份有限公司 | Ink composition, and preparation method and use thereof |
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| CN111363411B (en) | 2022-06-07 |
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