CN111362505A - A process for treating pig farm wastewater - Google Patents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
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- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
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Abstract
本发明涉及一种养猪场废水的处理工艺,它属于废水处理技术领域。本发明工艺包括如下步骤:(1)养猪废水先经过固液分离装置;(2)固液分离装置出水进入调节池;(3)调节池出水进入混凝沉淀池;(4)混凝沉淀池出水进入厌氧池;(5)厌氧池出水进入好氧池;(6)好氧池出水进入FSMBR装置;(7)FSMBR装置出水进入分子膜装置;(8)分子膜装置出水进入消毒池。本发明处理工艺中将无机平板膜代替传统MBR膜的FSMBR技术与分子膜处理技术相结合用于养猪场废水处理,使得MBR膜污染问题有效改善的同时,将处理后的废水出水可回用,减少养猪废水排放带来的环境污染,提高资源利用率,降低给环境带来的危害。
The invention relates to a process for treating pig farm wastewater, which belongs to the technical field of wastewater treatment. The process of the invention comprises the following steps: (1) pig-raising wastewater first passes through a solid-liquid separation device; (2) the effluent from the solid-liquid separation device enters a regulating tank; (3) the effluent from the regulating tank enters a coagulation and sedimentation tank; (4) coagulation and sedimentation The effluent of the pool enters the anaerobic tank; (5) the effluent of the anaerobic tank enters the aerobic tank; (6) the effluent of the aerobic tank enters the FSMBR device; (7) the effluent of the FSMBR device enters the molecular membrane device; (8) the effluent of the molecular membrane device enters the disinfection pool. In the treatment process of the invention, the FSMBR technology in which the inorganic flat membrane replaces the traditional MBR membrane is combined with the molecular membrane treatment technology for the treatment of pig farm wastewater, so that the pollution problem of the MBR membrane is effectively improved, and the treated wastewater effluent can be reused , reduce the environmental pollution caused by the discharge of pig-raising wastewater, improve the utilization rate of resources, and reduce the harm to the environment.
Description
技术领域technical field
本发明涉及一种工艺,尤其是涉及一种养猪场废水的处理工艺吗,它属于废水处理技术领域。The invention relates to a process, in particular to a process for treating pig farm wastewater, which belongs to the technical field of wastewater treatment.
背景技术Background technique
随着工农业的发展,养殖业朝着集约化和工厂化的方向发展。在养殖业中,养猪业占有很大的比重,生猪规模化养殖比例不断增加,养猪场废水排放量占畜禽养殖场废水排放总量的一半以上,养殖过程中产生的废水对水体污染的问题也日益严重,已成为我国农村污染的主要来源。养猪废水不仅排放量巨大,而且具有悬浮物多、有机物和氨氮浓度高、臭味大而且富含某些重金属等污染特性,同时具有水质复杂、排放点分散、难收集处理等特点。养猪废水的污染物浓度高,其中 BOD 高达2000-8000 mg/L,COD 高达5000- 20000 mg/L,氨氮高达800-1500mg/L,还具有抗生素和病原体残留等特点。未得到妥善处理便直接排放的养猪废水进入外界环境后,对土壤、水体、大气环境都会造成严重危害。因此,在强调绿色可持续发展的环境背景下,积极寻求一条既经济又环保的养猪废水处理工艺是养猪产业健康发展的关键。With the development of industry and agriculture, the breeding industry is developing in the direction of intensification and industrialization. In the breeding industry, pig breeding occupies a large proportion, and the proportion of large-scale pig breeding continues to increase. The discharge of wastewater from pig farms accounts for more than half of the total discharge of wastewater from livestock and poultry farms. The wastewater generated in the breeding process pollutes water bodies. The problem of pollution has become increasingly serious and has become the main source of rural pollution in my country. Pig-raising wastewater not only discharges a huge amount, but also has pollution characteristics such as a large amount of suspended solids, high concentration of organic matter and ammonia nitrogen, strong odor and rich in certain heavy metals. The concentration of pollutants in pig-raising wastewater is high, including BOD as high as 2000-8000 mg/L, COD as high as 5000-20000 mg/L, and ammonia nitrogen as high as 800-1500 mg/L. It also has the characteristics of antibiotics and pathogen residues. The directly discharged pig waste water will cause serious harm to the soil, water and atmospheric environment after entering the external environment without proper treatment. Therefore, under the environmental background of emphasizing green and sustainable development, it is the key to the healthy development of the pig industry to actively seek an economical and environmentally friendly pig wastewater treatment process.
目前,规模化养猪废水处理模式主要有三种:还田模式、自然处理模式和工业化处理模式。其中,工业处理模式因人为控制操作条件,处理能力及效果可控,对养猪场的废水处理更为实用,是当前国内外普遍采用的养猪废水处理模式。目前,运用最多的工业处理模式有厌氧好氧工艺法和MBR法。常规厌氧好氧工艺法能满足出水COD的达标,但是占地面积大,出水氨氮超标,其他水质指标不稳定,且出水无法回收利用。MBR法处理效果好,污泥产量少,但单独处理效果无法稳定满足排放标准,且传统MBR膜污染问题严重,导致膜组件频繁清洗更换、使用寿命降低。针对现有处理技术的不足,寻求更加高效稳定的养猪废水处理工艺,进行污染物的减量化、无害化、资源化处理与合理利用,才是治理养殖业污染的最佳途径。At present, there are three main modes of large-scale pig breeding wastewater treatment: returning to the field, natural treatment and industrial treatment. Among them, the industrial treatment mode is more practical for the wastewater treatment of pig farms because of the artificial control of operating conditions, the treatment capacity and the effect are controllable, and it is the most widely used pig wastewater treatment mode at home and abroad. At present, the most widely used industrial treatment modes are anaerobic aerobic process method and MBR method. The conventional anaerobic aerobic process method can meet the effluent COD standard, but it covers a large area, the effluent ammonia nitrogen exceeds the standard, other water quality indicators are unstable, and the effluent cannot be recycled. The MBR method has good treatment effect and low sludge output, but the effect of single treatment cannot stably meet the emission standards, and the traditional MBR membrane has serious pollution problems, resulting in frequent cleaning and replacement of membrane modules and reduced service life. In view of the deficiencies of the existing treatment technologies, seeking a more efficient and stable treatment process for pig-raising wastewater, reducing, harmless, resource-based and rational utilization of pollutants is the best way to control pollution in the breeding industry.
公开日为2016年08月10日,公开号为CN105836969A的中国专利中,公开了一种名称为“一种养猪场废水处理方法”的发明专利。该专利养猪场废水经管道收集,进入格栅池,去除粪类物料后的废水进入水质调节装置,除磷、均匀水质、初步水解酸化;厌氧处理:经过所述水质调节装置处理后的废水进入沼气池进行厌氧处理,再进入水解酸化池,将不溶性有机物水解成可溶性有机物;好氧处理:所述水解酸化池处理后的废水进行好氧处理;深度处理:好氧处理后的废水进入深度降解设备,采用好氧颗粒污泥进行深度处理。虽然该处理方法,易于实施,但是占地面积大,水质指标不稳定,且出水无法回收利用。故其还是存在上述缺陷。The publication date is August 10, 2016, and in the Chinese patent with the publication number CN105836969A, an invention patent named "a method for treating wastewater from a pig farm" is disclosed. The patented pig farm wastewater is collected through pipelines and enters the grid tank, and the wastewater after removing fecal materials enters the water quality adjustment device for phosphorus removal, uniform water quality, preliminary hydrolysis and acidification; anaerobic treatment: after the treatment by the water quality adjustment device The wastewater enters the biogas tank for anaerobic treatment, and then enters the hydrolysis and acidification tank to hydrolyze the insoluble organic matter into soluble organic matter; aerobic treatment: the wastewater treated in the hydrolysis and acidification tank undergoes aerobic treatment; advanced treatment: the wastewater after aerobic treatment Enter the deep degradation equipment, and use aerobic granular sludge for advanced treatment. Although this treatment method is easy to implement, it occupies a large area, the water quality index is unstable, and the effluent cannot be recycled. Therefore, it still has the above-mentioned defects.
因此,提供一种工艺合理,环保节能,废水出水可回用,提高资源利用率的养猪场废水处理工艺,显得尤为必要。Therefore, it is particularly necessary to provide a pig farm wastewater treatment process with reasonable process, environmental protection and energy saving, reusable wastewater effluent, and improved resource utilization rate.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于克服现有技术中存在的上述不足,而提供一种工艺合理,有效改善MBR膜污染,环保节能,废水出水可回用,提高资源利用率,采用无机平板膜代替传统MBR膜的FSMBR技术与分子膜处理技术相结合的养猪场废水处理工艺。The purpose of the present invention is to overcome the above-mentioned deficiencies in the prior art, and to provide a reasonable process, effectively improve MBR membrane pollution, environmental protection and energy saving, waste water effluent can be reused, improve resource utilization, and use inorganic flat membranes to replace traditional MBR membranes The pig farm wastewater treatment process combines the FSMBR technology with the molecular membrane treatment technology.
本发明解决上述问题所采用的技术方案是:该The technical solution adopted by the present invention to solve the above problems is: the
本发明与现有技术相比,具有以下优点和效果:1、整体工艺合理,环保节能,养猪废水出水可回用,减少养猪废水排放带来的环境污染,提高资源利用率,降低给环境带来的危害;2、该工艺将无机平板膜片代替传统MBR膜的FSMBR技术与分子膜处理技术相结合用于处理养猪废水;在改善传统MBR膜污染问题的同时,FSMBR工艺作为分子膜处理的前期工艺,能够给分子膜处理系统提供更加优质和稳定的供水水质;分子膜作为养猪废水的深度处理,出水水质可达到COD≤50mg/L,氨氮≤8mg/L,满足GB18918《城镇污水处理厂污染物排放标准》一级A标准,能够作为一般回用水利用,在减少给环境带来的危害的同时,还节约了水资源;3、该工艺对污泥进行集中收集和处理,进一步资源化利用。Compared with the prior art, the present invention has the following advantages and effects: 1. The overall process is reasonable, environmental protection and energy saving, the effluent of pig-raising wastewater can be reused, the environmental pollution caused by the discharge of pig-raising wastewater is reduced, the utilization rate of resources is improved, and the energy consumption is reduced. 2. This process combines the FSMBR technology of the inorganic flat membrane instead of the traditional MBR membrane with the molecular membrane treatment technology to treat pig wastewater; while improving the pollution problem of the traditional MBR membrane, the FSMBR process acts as a molecular The pre-process of membrane treatment can provide the molecular membrane treatment system with more high-quality and stable water supply quality; as the advanced treatment of pig wastewater, the effluent quality of molecular membrane can reach COD≤50mg/L, ammonia nitrogen≤8mg/L, which meets GB18918 " Urban Sewage Treatment Plant Pollutant Discharge Standard "Class A Standard", which can be used as general reuse water, which saves water resources while reducing harm to the environment; 3. This process collects and treats sludge centrally , further resource utilization.
附图说明Description of drawings
图1是本发明实施例的养猪场废水处理工艺的流程简图。FIG. 1 is a schematic flow chart of a pig farm wastewater treatment process according to an embodiment of the present invention.
图中:固液分离装置1,调节池2,混凝沉淀池3,厌氧池4,好氧池5,FSMBR装置6,分子膜装置7,消毒池8,污泥池9。In the figure: solid-liquid separation device 1, regulating
具体实施方式Detailed ways
下面结合附图并通过实施例对本发明作进一步的详细说明,以下实施例是对本发明的解释而本发明并不局限于以下实施例。The present invention will be further described in detail below in conjunction with the accompanying drawings and through the examples. The following examples are to explain the present invention and the present invention is not limited to the following examples.
实施例。Example.
参见图1,本实施例养猪场废水的处理工艺,包括如下步骤:Referring to Fig. 1, the treatment process of pig farm wastewater in the present embodiment includes the following steps:
S1)将养猪场废水收集引入固液分离装置1,分离出的固态猪粪便残渣进行统一收集,后续用作堆肥利用。S1) The pig farm wastewater is collected and introduced into the solid-liquid separation device 1, and the separated solid pig manure residues are collected uniformly, and subsequently used for composting.
S2)将通过固液分离装置的废水引入调节池2,在调节池2内充分调节水质水量,用氢氧化钠溶液作为调节剂,调节废水的pH值在6.5-7.5。S2) Introduce the wastewater passing through the solid-liquid separation device into the regulating
S3)将通过调节池2的废水引入混凝沉淀池3,向混凝沉淀池3内添加硫酸铝作为絮凝剂,PAM作为助凝剂,硫酸铝投加量控制在8g/L左右,PAM投加量控制在0.1g/L,混凝沉淀过程产生的沉淀物引入污泥池9。S3) Introduce the wastewater passing through the
S4)将通过混凝沉淀池3的废水引入厌氧池4,在厌氧池4内通过厌氧微生物的新陈代谢作用去除废水中难降解的有机污染物,池内温度控制在30-35℃,处理时间为24h,厌氧生物处理产生的气体抽送至沼气罐进行沼气利用,产生的污泥排至污泥池。S4) Introducing the wastewater passing through the coagulation sedimentation tank 3 into the anaerobic tank 4, and removing the refractory organic pollutants in the wastewater through the metabolism of anaerobic microorganisms in the anaerobic tank 4, the temperature in the tank is controlled at 30-35 ° C, and the treatment The time is 24h, the gas produced by the anaerobic biological treatment is pumped to the biogas tank for biogas utilization, and the produced sludge is discharged to the sludge tank.
S5) 本实施例的好氧池5选用生物接触氧化池,将通过厌氧池4的废水引入生物接触氧化池进行好氧生化处理,通过微生物的自身代谢去除大部分有机污染物,池内设有辫带式填料及曝气系统,底部设有排泥装置,好氧生化处理过程产生的污泥排至污泥池。S5) the
S6)将通过生物接触氧化池的废水引入FSMBR装置6,FSMBR装置6的膜组件材料选用平板陶瓷膜片,机架材料选用304不锈钢。S6) Introduce the wastewater passing through the biological contact oxidation tank into the FSMBR device 6, the membrane module material of the FSMBR device 6 is selected from flat ceramic diaphragm, and the frame material is selected from 304 stainless steel.
S7)将FSMBR装置6出水引入分子膜装置7进行深度处理,分子膜材料选用四氟乙烯,分子膜垂直设置,流动液体全部垂直地透过膜孔。S7) The effluent of the FSMBR device 6 is introduced into the molecular membrane device 7 for advanced treatment. The molecular membrane material is selected from tetrafluoroethylene, the molecular membrane is arranged vertically, and the flowing liquid all vertically passes through the membrane pores.
S8)将分子膜装置7出水引入消毒池8进行消毒处理,杀灭废水中的细菌病毒等有害微生物,使出水符合排放标准的同时还满足一般回用水的水质标准。S8) The effluent of the molecular membrane device 7 is introduced into the
S9)将污泥池9中收集的污泥进行脱水、干化后再利用。S9) The sludge collected in the sludge tank 9 is dewatered and dried before being reused.
采用本申请用于某养猪场300t/d废水的处理,各检测项进出水水质试验结果如下表所示。The application is used for the treatment of 300t/d wastewater in a pig farm. The test results of the influent and effluent water quality of each test item are shown in the following table.
从表格可知,出水水质满足GB18918《城镇污水处理厂污染物排放标准》一级A标准,说明该养猪场废水处理工艺切实可行。It can be seen from the table that the effluent quality meets the Grade A standard of GB18918 "Pollutant Discharge Standard for Urban Sewage Treatment Plants", indicating that the wastewater treatment process of the pig farm is feasible.
通过上述阐述,本领域的技术人员已能实施。Through the above description, those skilled in the art have been able to implement.
此外,需要说明的是,本说明书中所描述的具体实施例,其零、部件的形状、所取名称等可以不同,本说明书中所描述的以上内容仅仅是对本发明结构所作的举例说明。凡依据本发明专利构思所述的构造、特征及原理所做的等效变化或者简单变化,均包括于本发明专利的保护范围内。本发明所属技术领域的技术人员可以对所描述的具体实施例做各种各样的修改或补充或采用类似的方式替代,只要不偏离本发明的结构或者超越本权利要求书所定义的范围,均应属于本发明的保护范围。In addition, it should be noted that the specific embodiments described in this specification may have different shapes and names of parts and components, and the above content described in this specification is only an illustration of the structure of the present invention. All equivalent changes or simple changes made according to the structure, features and principles described in the patent concept of the present invention are included in the protection scope of the patent of the present invention. Those skilled in the art to which the present invention pertains can make various modifications or supplements to the described specific embodiments or substitute in similar manners, as long as they do not deviate from the structure of the present invention or go beyond the scope defined by the claims, All should belong to the protection scope of the present invention.
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