CN111360052A - Multi-layer circulating well system for soil and underground water remediation - Google Patents
Multi-layer circulating well system for soil and underground water remediation Download PDFInfo
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- CN111360052A CN111360052A CN202010286741.6A CN202010286741A CN111360052A CN 111360052 A CN111360052 A CN 111360052A CN 202010286741 A CN202010286741 A CN 202010286741A CN 111360052 A CN111360052 A CN 111360052A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/002—Reclamation of contaminated soil involving in-situ ground water treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C2101/00—In situ
Abstract
The invention discloses a multilayer circulating well system for soil and underground water remediation, which comprises one or more injection wells; a plurality of packers which are arranged along the vertical direction are arranged in the injection well to divide the injection well into a packing section, a hole sealing section, an injection layer and a pumping layer; each packer is fixed through a middle casing vertically arranged in the center of the injection well; each packer is connected with external hydraulic control equipment through a control inner pipe; the circulation mode is controlled by the electric valve, circulation disturbance is enhanced, various underground water circulation modes are formed, multi-dimensional circulation disturbance is realized, and the well walls of the pumping layer and each injection layer are sieve tube structures comprising filter layers; a submersible pump is arranged in the pumping layer; the injection pipe injects water and a repair agent into each injection layer. The invention can repair a plurality of pollutants by injecting chemical agents such as chemical oxidation, chemical reduction, chemical leaching and the like, and is particularly suitable for places with non-aqueous phase fluid pollutants.
Description
Technical Field
The invention relates to the technical field of environmental pollution remediation, in particular to a multilayer circulating well system for soil and underground water remediation.
Background
In recent years, major environmental pollution events caused by soil and underground water pollution are frequent, and with the progress of urbanization, the acceleration of industrial structure adjustment and the improvement of ecological civilization construction requirements, the treatment of soil and underground water pollution becomes an important content of current urban double-repair and ecological civilization construction. The main sources of soil and underground water pollution are leakage, accidents, illegal pollution discharge and the like in the long-term production process of chemical industry related enterprises such as chemical industry, smelting, textile printing and dyeing, electroplating and the like. According to the type of pollutants, soil and underground water pollution can be mainly divided into heavy metal and organic pollution, the existing soil and underground water remediation technology mainly comprises solidification and stabilization, soil leaching, chemical oxidation/reduction, thermal desorption, bioremediation and the like, and the corresponding modes can be divided into an in-situ mode and an ex-situ mode.
In-situ soil and groundwater remediation technologies have become increasingly popular in recent years for their advantages of no excavation, low environmental disturbance, low risk of secondary pollution, etc. In-situ soil and underground water remediation can be divided into in-situ chemical oxidation, in-situ chemical reduction, in-situ leaching, in-situ bioremediation and other technologies according to different remediation technologies, and remediation agents are generally required to be injected into soil and underground water, wherein the injection modes comprise high-pressure rotary spraying, fixed injection wells, direct-push injection and the like. The shallow stratum in southern China generally takes cohesive soil-sand-inclusion silt as a main material, a horizontal interlayer often exists in a stratum structure, the heterogeneous characteristic of a water-bearing stratum is obvious, the vertical permeability condition is relatively poor, the diffusion time of a medicament is long, and the construction progress is often influenced. Meanwhile, the groundwater aquifer has the capillary action of a pore cavity, an advantageous channel, a water level amplitude-changing zone and the like, so that the restoration effect rebounds and the trailing phenomenon commonly exist in groundwater in-situ restoration. In-situ soil and groundwater remediation currently has many problems in remediation due to differences and complexity of hydrogeological conditions. For example:
1) due to the existence of the repair blind area, the preferential pore canal and the low permeability area, the contact between the medicament and the pollutant is insufficient, and the repair efficiency is reduced.
2) The pollutants are often attached to the soil medium, and the medicinal preparation is difficult to contact or needs long reaction time, so that the repairing effect is unbalanced, and rebound is often generated after the detection and repair reach the standard, particularly under the condition that non-aqueous phase fluid exists.
3) Due to the poor repairing efficiency and repairing effect, and the decomposition of the repairing agent in the soil medium transmission process or the reaction loss of the repairing agent and soil components, the problems of great agent loss, repeated dosing repairing and the like exist in-situ repairing, so that great agent waste and repairing cost are caused.
Therefore, how to improve the repair efficiency, enhance the repair effect and reduce the repair cost becomes a technical problem which needs to be solved by those skilled in the art.
Disclosure of Invention
In view of the above defects in the prior art, the invention provides a multilayer circulating well system for soil and groundwater remediation, which aims to solve the problems of uneven transmission and large loss of remediation agents in soil media, improve the in-situ remediation efficiency of polluted soil and groundwater, strengthen the remediation effect, avoid rebound and reduce the remediation cost.
In order to achieve the aim, the invention discloses a multilayer circulating well system for soil and underground water remediation, which comprises one or more injection wells; a plurality of packers arranged along the vertical direction are arranged in the injection well to divide the injection well into a multilayer structure;
in the injection well, the part covered by each packer is a packer section, the part between the uppermost packer section and the surface cap seal is a hole sealing section, the part between every two packers is an injection layer, and the part between the lowermost packer section and the bottom of the injection well is a pumping layer;
the well wall of the pumping layer and each injection layer is of a sieve tube structure comprising a filter layer, the sieve opening rate is 20-30%, and the water seepage requirement is met;
a submersible pump is arranged in the pumping layer; the submersible pump pumps out the water accumulated in the pumping layer through a pumping pipe;
the injection pipe injects water or repairing medicament into each injection layer; the repair agent comprises a chemical oxidizing agent, a chemical reducing agent, an eluting agent and/or a biological repair agent;
each packer is fixed through an intermediate casing vertically arranged in the center of the injection well; each packer is connected with external hydraulic control equipment through a control inner pipe;
and a liquid level meter is arranged on the outer side of the injection well and used for acquiring the height of the underground water level.
Preferably, the upper end of the extraction pipe extends out of the ground and then is divided into a first shunt pipe and a second shunt pipe, the first shunt pipe is connected with a water treatment and dispensing system, and the second shunt pipe is respectively connected with the injection pipe and the horizontal leaching pipe; the injection pipe is vertically arranged in the injection well and communicated with each injection layer;
the water outlet of the water treatment and dispensing system is respectively connected with the second shunt pipe and the horizontal leaching pipe through return pipes;
the injection pipe is at each the delivery port on injection layer, first shunt tubes, the second shunt tubes, and the back flow with the second shunt tubes with the branch pipeline that the level drench washing union coupling all is equipped with the automatically controlled valve, each the automatically controlled valve all opens, closes and the aperture through external PLC switch board control.
Preferably, the well wall of the injection layer is filled with quartz sand or gravel, so that the requirements of water and repairing agent permeation are met;
the well wall of the hole sealing section and the well wall of each sealing section are filled with clay, bentonite and/or concrete, and the sealing and water stopping requirements are met.
Preferably, a sealing structure is arranged between the well cover of the injection well and the well wall.
Preferably, the injection well extends a minimum of 2 meters into the impermeable barrier;
preferably, when the contaminated site includes non-aqueous phase fluid NAPL, the draw-off layer is positioned at a depth of the heavy non-aqueous phase fluid DNAPL for targeted draw-off and the uppermost injection layer is positioned at a depth of the light non-aqueous phase fluid LNAPL for targeted treatment of the light non-aqueous phase fluid LNAPL.
Preferably, the control inner pipe is vertically arranged, penetrates through each packer in the injection well, is connected with each packer and is communicated with the inner cavity of each packer;
and the external hydraulic control equipment props each packer to be tightly attached to the well wall of the corresponding packer section in a manner of injecting a liquid medium into each packer for pressurization so as to form sealing.
Preferably, the middle sleeve is made of stainless steel materials, and the extraction pipe is arranged in the middle sleeve.
Preferably, the horizontal leaching pipe is arranged in a trench with the depth of 0.2 to 0.5 meter below the ground surface of the polluted area, and comprises a main pipe and a plurality of branch pipes;
the width of the groove is 0.1 to 0.2 meters;
each branch pipe is a perforated pipe; the aperture of the open pore on the open pore pipe is 0.5 mm to 1 mm, and the opening rate is 20 percent to 40 percent; and a filter screen is wound outside each branch pipe, and quartz sand is used for backfill protection.
Preferably, the surface cap seal is a concrete cap seal.
The invention has the beneficial effects that:
the application of the invention changes the local groundwater flow field, strengthens the disturbance to the polluted soil and groundwater, avoids the influence of the factors of geological conditions (pore cavities, dominant channels, capillary action, low permeability zones and the like) on the restoration effect, and can realize the restoration of the aeration zone and the saturation zone at the same time.
The invention can repair a plurality of pollutants by injecting chemical agents such as chemical oxidation, chemical reduction, chemical leaching and the like, and is particularly suitable for places with non-aqueous phase fluid pollutants.
The application of the invention can obviously enhance the contact effect of the medicament and the pollutants, reduce the influence of the geological structure on medicament transmission and improve the repairing efficiency of the pollutants.
The invention can obviously reduce the medicament loss and reduce the repair cost. The system is controlled by a water level monitoring and PLC control system, is simple to operate and runs stably.
The conception, the specific structure and the technical effects of the present invention will be further described with reference to the accompanying drawings to fully understand the objects, the features and the effects of the present invention.
Drawings
Fig. 1 shows a schematic structural diagram of an embodiment of the present invention.
Fig. 2 is a schematic diagram showing the flow conditions of a water body using a single well cycle according to an embodiment of the present invention.
FIG. 3 is a schematic diagram illustrating the flow conditions of a body of water using interwell circulation in accordance with an embodiment of the present invention.
FIG. 4 is a schematic diagram illustrating the flow conditions of a body of water using another interwell circulation in accordance with an embodiment of the present invention.
FIG. 5 is a schematic view showing the flow conditions of a body of water using a third interwell circulation according to an embodiment of the present invention.
Fig. 6 is a schematic view showing a water flow state in which horizontal leaching is adopted according to an embodiment of the present invention.
Detailed Description
Examples
As shown in fig. 1, the multi-well circulation system for soil and groundwater remediation includes one or more injection wells 1; a plurality of packers 2 arranged along the vertical direction are arranged in the injection well 1 to divide the injection well 1 into a multilayer structure;
in the injection well 1, the part covered by each packer 2 is a packer section 3, the part between the uppermost packer section 3 and a surface cap seal 4 is a hole sealing section 5, the part between every two packers 2 is an injection layer 6, and the part between the lowermost packer section 3 and the bottom of the injection well 1 is a pumping layer 7;
the well wall of the pumping layer 7 and each injection layer 6 is of a sieve tube structure comprising a filter layer, the sieve opening rate is 20-30%, and the water seepage requirement is met;
a submersible pump 8 is arranged in the pumping layer 7; the submersible pump 8 pumps out the water accumulated in the pumping layer 7 through the pumping pipe 9;
the injection pipe 13 injects water or a repairing agent into each injection layer 6; the repairing agent comprises a chemical oxidizing agent, a chemical reducing agent, an eluting agent and/or a biological repairing agent;
each packer 2 is fixed by an intermediate casing 17 vertically arranged in the central position of the injection well 1; and each packer 2 is connected with an external hydraulic control device 19 through a control inner pipe 18;
a liquid level meter 21 is arranged outside the injection well 1, and the liquid level meter 21 is used for acquiring the height of underground water level 22.
The invention can effectively disturb and treat (oxidize, reduce, leach and the like) the upper light pollutant and extract the lower heavy pollutant through layered injection and extraction.
The polluted underground water can be used as medicament water distribution to be recharged to the underground soil layer after being pumped out and treated, and compared with an exhaust mode after being pumped out and treated, the method can reduce the underground water loss and control the sewage treatment amount. The recharging mode comprises two modes of injection and horizontal leaching, the pollutant in the aeration zone can be effectively repaired, the integral repair of the whole soil from a saturated zone to the aeration zone is achieved, and the removal of the pollutant in a capillary zone is particularly facilitated.
According to the pollution characteristics, different remediation agents can be selected in a targeted mode, for example, heavy metal pollutants, leaching agents can be adopted, and oxidizing agents, reducing agents and the like can be selected for organic pollutants.
In some embodiments, the upper end of the extraction pipe 9 extends out of the ground and then is divided into a first shunt pipe 10 and a second shunt pipe 11, the first shunt pipe 10 is connected with a water treatment and dispensing system 12, and the second shunt pipe 11 is respectively connected with an injection pipe 13 and a horizontal shower pipe 14; the injection pipe 13 is vertically arranged in the injection well 1 and is communicated with each injection layer 6;
the water outlet of the water treatment and dispensing system 12 is respectively connected with the second shunt pipe 11 and the horizontal shower pipe 14 through a return pipe 15;
the injection pipe 13 is provided with an electric control valve 16 at the water outlet 20 of each injection layer 6, the first shunt pipe 10, the second shunt pipe 11 and branch pipelines of the return pipe 15 connected with the second shunt pipe 11 and the horizontal shower pipe 14, and each electric control valve 16 is controlled to open, close and open by an external PLC control cabinet.
Through measures such as layering injection and electric control valve regulation, can effectively improve the accuracy and the pertinence that the medicament injected into, for example according to the degree of depth design circulation injection well degree of depth and packer position of pollutant, open and close through the control governing valve, can carry out the medicament to different depths and inject into, compare with conventional single layer injection, increased the selectivity of injection depth, improved the precision of medicament.
As shown in fig. 2 to 6, there are various modes that can be switched such as single well circulation, inter-well circulation, horizontal leaching, etc., the single well circulation, i.e., pumping groundwater is controlled by a pipeline and a control valve, and soil is re-injected through an injection pipe of the well itself, thereby realizing the single well circulation.
There are two types of inter-well circulation, one of which is that, as shown in fig. 3 and 4, pumped underground water is conveyed to an injection pipe of an adjacent well through a pipeline to be injected to form inter-well disturbance; secondly, as shown in fig. 5, the pumped-out groundwater is transported to a water treatment facility, and then transported to injection pipes of a plurality of wells at the same time via recharge pipes, and injected into an aquifer. The horizontal leaching mode is that the treated underground water is arranged in a horizontal leaching pipeline near the ground surface and is injected into the soil, and the horizontal leaching pipeline can be used for repairing the polluted soil of the aeration zone, so that the method can realize the synchronous repair of the saturation zone and the aeration zone.
Different groundwater flow fields can be formed through switching of the circulation modes, groundwater disturbance, particularly interaction between wells is strengthened, effective contact of the medicament and pollutants is effectively promoted, influence of repair blind areas and preferential holes on medicament adding effect is avoided, the medicament application rate is improved, the 'rebound' effect is reduced, and repair cost is saved; the pumping and injecting mode, namely the flow regulation, is realized through the liquid level meter, the electric control valve and the PLC, and the cost is low.
In some embodiments, the well wall of the injection layer 6 is filled with quartz sand or gravel to meet the requirements of water and repairing agent penetration;
the well wall of the hole sealing section 5 and the well wall of each sealing section 3 are filled with clay, bentonite and/or concrete, and the sealing and water stopping requirements are met.
In some embodiments, the well lid 23 of the injection well 1 is sealed from the well wall.
In certain embodiments, injection well 1 extends a minimum of 2 meters into the impermeable barrier;
in certain embodiments, when the contaminated site includes non-aqueous phase fluid NAPL, draw-off layer 7 is positioned at the depth of heavy non-aqueous phase fluid DNAPL24, which is a targeted draw-off of heavy non-aqueous phase fluid DNAPL24, and uppermost injection layer 6 is positioned at the depth of light non-aqueous phase fluid LNAPL25, which is a targeted treatment for light non-aqueous phase fluid LNAPL 25.
In some embodiments, control inner tube 18 is vertically disposed through each packer 2 in injection well 1, connected to each packer 2, and communicates with the inner cavity of each packer 2;
the external hydraulic control device 19 is used for expanding each packer 2 to be tightly attached to the well wall of the corresponding packer section 3 to form sealing in a mode of injecting a liquid medium into each packer 2 for pressurization.
In certain embodiments, the intermediate sleeve 17 is made of stainless steel material and the extraction tube 9 is arranged inside the intermediate sleeve 17.
In certain embodiments, the horizontal shower pipe 14 is disposed in a trench 0.2 to 0.5 meters deep below the surface of the contaminated site, including a main pipe and a number of branch pipes 26;
the width of the groove is 0.1 to 0.2 meters;
each branch pipe 26 is a perforated pipe; the aperture of the open pore on the open pore pipe is 0.5 mm to 1 mm, and the opening rate is 20 percent to 40 percent; a layer of filter screen is wound outside each branch pipe 26, and quartz sand is used for backfill protection.
In certain embodiments, the surface cap seal 4 is a concrete cap seal.
In a certain practical application, the diameter of an injection well 1 is 200mm, the depth is 7.5m, and the underground 0-1.5m is a clay hole sealing section; from top to bottom, 1.5-2.5m is the first injection layer 6; 3.0-4.5m is the second injection layer 6; 5.0-6.0 is the third injection layer 6; the extraction layer 7 is 6.5-7.5 m; the injection layer 6 comprises a filtering layer, and the well wall of the filtering layer is filled with 2-4mm graded quartz sand.
The well wall of each injection layer 6 is made of stainless steel materials into a sieve tube structure, and the opening rate is generally 27%.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.
Claims (10)
1. A multi-layer circulating well system for soil and groundwater remediation, comprising one or more injection wells (1); the method is characterized in that: a plurality of packers (2) arranged along the vertical direction are arranged in the injection well (1) to divide the injection well (1) into a multilayer structure;
in the injection well (1), the part covered by each packer (2) is a packer section (3), the part between the uppermost packer section (3) and a surface cap seal (4) is a hole sealing section (5), the part between every two packers (2) is an injection layer (6), and the part between the lowermost packer section (3) and the bottom of the injection well (1) is a withdrawal layer (7);
the well wall of the pumping layer (7) and the well wall of each injection layer (6) are both sieve tube structures comprising filter layers, the sieve opening rate is 20-30%, and the water seepage requirement is met;
a submersible pump (8) is arranged in the pumping layer (7); the submersible pump (8) pumps out the water accumulated in the pumping layer (7) through a pumping-out pipe (9);
the injection pipe (13) injects water or repairing medicament into each injection layer (6); the repair agent comprises a chemical oxidizing agent, a chemical reducing agent, an eluting agent and/or a biological repair agent;
each packer (2) is fixed through an intermediate casing (17) vertically arranged at the central position of the injection well (1); each packer (2) is connected with external hydraulic control equipment (19) through a control inner pipe (18);
the injection well (1) outside is equipped with level gauge (21), level gauge (21) are used for gathering the height of ground water level (22).
2. The system of the multi-layer circulating well for soil and groundwater remediation according to claim 1, wherein the upper end of the extraction pipe (9) is divided into a first shunt pipe (10) and a second shunt pipe (11) after extending out of the ground, the first shunt pipe (10) is connected with a water treatment and dispensing system (12), and the second shunt pipe (11) is connected with an injection pipe (13) and a horizontal leaching pipe (14) respectively; the injection pipe (13) is vertically arranged in the injection well (1) and is communicated with each injection layer (6);
a water outlet of the water treatment and dispensing system (12) is respectively connected with the second shunt pipe (11) and the horizontal shower pipe (14) through a return pipe (15);
the injection pipe (13) is at each delivery port (20) of injection layer (6), first shunt tube (10), second shunt tube (11), and return pipe (15) with second shunt tube (11) with the branch pipeline that horizontal shower pipe (14) are connected all is equipped with automatically controlled valve (16), each automatically controlled valve (16) all open through external PLC switch board control, close and the aperture, can form multiple circulation mode.
3. The multi-layer circulating well system for soil and groundwater remediation as claimed in claim 1, wherein the well wall of the injection layer (6) is filled with quartz sand or gravel to meet the requirement of water and remediation agent infiltration;
the well wall of the hole sealing section (5) and the well wall of each sealing section (3) are filled with clay, bentonite and/or concrete, and the sealing and water stopping requirements are met.
4. The multi-layer circulating well system for soil and groundwater remediation according to claim 1, wherein a sealing structure is provided between the well lid (23) of the injection well (1) and the well wall.
5. A multi-layer circulating well system for soil and groundwater remediation according to claim 1, wherein the injection well (1) penetrates into the impermeable bed by a minimum of 2 meters.
6. The multi-layer circulating well system for soil and groundwater remediation according to claim 1, wherein when the contaminated site includes the non-aqueous phase fluid NAPL, the pumping out layer (7) is disposed at a depth of a heavy non-aqueous phase fluid DNAPL (24), the heavy non-aqueous phase fluid DNAPL (24) is subjected to the targeted pumping out, and the uppermost injection layer (6) is disposed at a depth of a light non-aqueous phase fluid LNAPL (25), the light non-aqueous phase fluid LNAPL (25) is subjected to the targeted treatment.
7. A multi-layer circulating well system for soil and groundwater remediation according to claim 1, wherein the control inner pipe (18) is vertically arranged to pass through each of the packers (2) in the injection well (1), to be connected to each of the packers (2), to communicate with the inner cavity of each of the packers (2);
and the external hydraulic control equipment (19) is used for propping each packer (2) to be tightly attached to the well wall of the corresponding packer section (3) in a manner of injecting a liquid medium into each packer (2) for pressurization so as to form sealing.
8. A multi-layer circulating well system for soil and groundwater remediation according to claim 1, wherein the intermediate casing (17) is made of stainless steel material, and the extraction pipe (9) is disposed within the intermediate casing (17).
9. The multi-layer circulating well system for soil and groundwater remediation according to claim 1, wherein the horizontal shower pipe (14) is disposed in a trench 0.2 to 0.5 meters deep below the surface of the contaminated area, comprising a main pipe and a plurality of branch pipes (26);
the width of the groove is 0.1 to 0.2 meters;
each branch pipe (26) is an open pore pipe; the aperture of the open pore on the open pore pipe is 0.5 mm to 1 mm, and the opening rate is 20 percent to 40 percent; and a layer of filter screen is wound outside each branch pipe (26), and quartz sand is used for backfilling protection.
10. A multi-layer circulating well system for soil and groundwater remediation according to claim 1, wherein the surface cap seal (4) is a concrete cap seal.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010286741.6A CN111360052A (en) | 2020-04-13 | 2020-04-13 | Multi-layer circulating well system for soil and underground water remediation |
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| CN202010286741.6A CN111360052A (en) | 2020-04-13 | 2020-04-13 | Multi-layer circulating well system for soil and underground water remediation |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111960484A (en) * | 2020-08-07 | 2020-11-20 | 宝航环境修复有限公司 | Multidirectional three-dimensional circulation in-situ remediation system |
| CN113800657A (en) * | 2021-10-12 | 2021-12-17 | 中国石油化工股份有限公司 | In-situ treatment method and treatment device for underground water DNAPLS |
| CN114278271A (en) * | 2021-11-22 | 2022-04-05 | 中国地质大学（北京） | Composite circulation well system and use method |
| CN114320263A (en) * | 2021-11-22 | 2022-04-12 | 中国地质大学（北京） | Multi-filter-layer circulating well system and working mode |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111960484A (en) * | 2020-08-07 | 2020-11-20 | 宝航环境修复有限公司 | Multidirectional three-dimensional circulation in-situ remediation system |
| CN113800657A (en) * | 2021-10-12 | 2021-12-17 | 中国石油化工股份有限公司 | In-situ treatment method and treatment device for underground water DNAPLS |
| CN114278271A (en) * | 2021-11-22 | 2022-04-05 | 中国地质大学（北京） | Composite circulation well system and use method |
| CN114320263A (en) * | 2021-11-22 | 2022-04-12 | 中国地质大学（北京） | Multi-filter-layer circulating well system and working mode |
| CN114320263B (en) * | 2021-11-22 | 2023-01-17 | 中国地质大学（北京） | Multi-filter-layer circulating well system and working mode |
| CN114278271B (en) * | 2021-11-22 | 2022-10-04 | 中国地质大学（北京） | Composite circulating well system and using method |
| CN115093009A (en) * | 2022-01-24 | 2022-09-23 | 成都理工大学 | Photocatalysis microbial fuel cell treatment assembly for underground water circulating well |
| CN114833184A (en) * | 2022-05-09 | 2022-08-02 | 常州大学 | Soil pit pickled Chinese cabbage soil repairing device and repairing method thereof |
| CN114833184B (en) * | 2022-05-09 | 2024-04-30 | 常州大学 | Soil restoration device and restoration method for pickled Chinese cabbage in soil pit |
| CN115026124A (en) * | 2022-06-22 | 2022-09-09 | 上海城建市政工程（集团）有限公司 | Multi-depth in-situ infiltration injection method for soil and underground water remediation |
| CN115026124B (en) * | 2022-06-22 | 2023-10-20 | 上海城建市政工程（集团）有限公司 | Multi-depth in-situ infiltration injection method for soil and groundwater remediation |
| CN115710039A (en) * | 2022-11-25 | 2023-02-24 | 吉林大学 | Circulating well repairing system and method |
| CN115724498A (en) * | 2022-11-25 | 2023-03-03 | 吉林大学 | Underground pollution remediation device, system and method |
| CN115710039B (en) * | 2022-11-25 | 2024-03-19 | 吉林大学 | Circulating well repairing system and method |
| CN115724498B (en) * | 2022-11-25 | 2024-03-19 | 吉林大学 | Underground pollution restoration device and method |
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