CN111359650B - Preparation method, product and application of iron, nickel and palladium co-doped graphite-phase carbon nitride composite catalyst - Google Patents
Preparation method, product and application of iron, nickel and palladium co-doped graphite-phase carbon nitride composite catalyst Download PDFInfo
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- CN111359650B CN111359650B CN202010331486.2A CN202010331486A CN111359650B CN 111359650 B CN111359650 B CN 111359650B CN 202010331486 A CN202010331486 A CN 202010331486A CN 111359650 B CN111359650 B CN 111359650B
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- nickel
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- carbon nitride
- phase carbon
- palladium
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- 239000003054 catalyst Substances 0.000 title claims abstract description 114
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 99
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 93
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title claims abstract description 85
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 52
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 49
- 239000002131 composite material Substances 0.000 title claims abstract description 42
- 229910052763 palladium Inorganic materials 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000010439 graphite Substances 0.000 claims abstract description 29
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 29
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 17
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- 239000002243 precursor Substances 0.000 claims abstract description 16
- 238000001354 calcination Methods 0.000 claims abstract description 13
- 150000002815 nickel Chemical class 0.000 claims abstract description 13
- -1 carbon nitride compound Chemical class 0.000 claims abstract description 12
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- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 claims abstract description 6
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- XMEVHPAGJVLHIG-FMZCEJRJSA-N chembl454950 Chemical compound [Cl-].C1=CC=C2[C@](O)(C)[C@H]3C[C@H]4[C@H]([NH+](C)C)C(O)=C(C(N)=O)C(=O)[C@@]4(O)C(O)=C3C(=O)C2=C1O XMEVHPAGJVLHIG-FMZCEJRJSA-N 0.000 claims description 14
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- 238000004519 manufacturing process Methods 0.000 description 7
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- 239000000356 contaminant Substances 0.000 description 6
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 5
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- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 4
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- 229940044631 ferric chloride hexahydrate Drugs 0.000 description 4
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 4
- LAIZPRYFQUWUBN-UHFFFAOYSA-L nickel chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Ni+2] LAIZPRYFQUWUBN-UHFFFAOYSA-L 0.000 description 4
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- VCUVETGKTILCLC-UHFFFAOYSA-N 5,5-dimethyl-1-pyrroline N-oxide Chemical compound CC1(C)CCC=[N+]1[O-] VCUVETGKTILCLC-UHFFFAOYSA-N 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910017135 Fe—O Inorganic materials 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
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- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Abstract
Description
Sample (I) | Specific surface area (m) 2 /g) |
Comparative example 1 | 14.40155 |
Example 1 | 9.18082 |
Comparative example 2 | 11.26370 |
Catalyst and process for preparing same | AR-73 removal Rate (%) | TC removal rate (%) |
Example 1 | 91.9 | 93.2 |
Example 2 | - | 35.8 |
Example 3- | 85.5 | |
Example 4 | - | 92.1 |
Comparative example 1 | 75.2 | 88.3 |
Comparative example 2 | 75.9 | 40.7 |
Claims (10)
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CN202010331486.2A CN111359650B (en) | 2020-04-24 | 2020-04-24 | Preparation method, product and application of iron, nickel and palladium co-doped graphite-phase carbon nitride composite catalyst |
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CN202010331486.2A CN111359650B (en) | 2020-04-24 | 2020-04-24 | Preparation method, product and application of iron, nickel and palladium co-doped graphite-phase carbon nitride composite catalyst |
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Publication Number | Publication Date |
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CN111359650A CN111359650A (en) | 2020-07-03 |
CN111359650B true CN111359650B (en) | 2022-09-20 |
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CN110482504B (en) * | 2019-08-28 | 2021-04-13 | 清华大学 | Preparation method and application of iron-sulfur co-modified graphite-phase carbon nitride compound |
CN112259751B (en) * | 2020-10-27 | 2022-06-14 | 广东工业大学 | ORR and OER bifunctional catalyst, and preparation method and application thereof |
CN112593254B (en) * | 2020-11-27 | 2021-11-09 | 浙江大学衢州研究院 | Nitrogen/sulfur co-doped carbon-supported iron monatomic catalyst and preparation method and application thereof |
CN113042085B (en) * | 2021-03-26 | 2022-04-08 | 河北工业大学 | Preparation method and application of nitrogen-phosphorus double-doped graphene-supported nickel-cobalt-palladium nano catalyst |
CN115283003B (en) * | 2022-10-10 | 2023-03-24 | 河北海鹰环境安全科技股份有限公司 | Method for preparing ozone catalyst by microwave method |
CN116577309A (en) * | 2023-02-22 | 2023-08-11 | 咸阳师范学院 | Pyridine axial coordination modified porphyrin-like Ni-N-C composite material and preparation method and application thereof |
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