CN111357969A - Potassium chloride for food and preparation method thereof - Google Patents

Potassium chloride for food and preparation method thereof Download PDF

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Publication number
CN111357969A
CN111357969A CN201811605872.5A CN201811605872A CN111357969A CN 111357969 A CN111357969 A CN 111357969A CN 201811605872 A CN201811605872 A CN 201811605872A CN 111357969 A CN111357969 A CN 111357969A
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Prior art keywords
chloride
potassium chloride
salt
potassium
magnesium
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CN201811605872.5A
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李国强
张金浩
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Tianjin Luhe Food Additives Co ltd
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Tianjin Luhe Food Additives Co ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/40Table salts; Dietetic salt substitutes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Seasonings (AREA)

Abstract

The potassium chloride for the food has a dry content of more than 99.5 percent, a sodium content of less than 0.5 percent and an average particle size of 90 percent potassium chloride particles of more than 0.4 mm. The invention also discloses a preparation method of the potassium chloride. The invention has the advantages that the potassium chloride is especially suitable for salt, and the content of sodium in the salt is effectively reduced. The preparation method provided by the invention is simple to operate, the prepared potassium chloride is high in purity, and the potassium chloride is fully dissolved and filtered at 40 ℃ before being dissolved in water in the last step of filtering, so that the impurity removal effect is better.

Description

Potassium chloride for food and preparation method thereof
Technical Field
The invention relates to the technical field of food, in particular to potassium chloride for food and a preparation method thereof.
Background
KCl is a colorless elongated rhombohedral or cubic crystal or white crystalline small granular powder with the appearance like common salt, no odor and salty taste. Is commonly used as additive for low sodium salt and mineral water. The potassium chloride is a clinically common electrolyte balance regulating medicine, has definite clinical curative effect and is widely applied to various clinical departments.
According to the research of people, many diseases are related to a large amount of edible salt, the salt contains sodium ions which are main cations of extracellular fluid and play an important role in maintaining the osmotic pressure of extracellular fluid crystals, and the sodium ions are combined with water molecules to form hydrated ions, so that water is preserved and is prevented from losing. Sodium ions play an important role in maintaining nerve, muscle excitability and cell membrane permeability.
The main component of common salt is sodium, so if the sodium salt is accumulated too much in vivo, the cell osmotic pressure is changed, a human body can absorb a large amount of water in order to maintain a certain osmotic pressure, the capacity of the whole blood is increased, the heart is overloaded, the symptoms of heart failure are induced or aggravated, the blood pressure is increased due to the excessive sodium, the renal arteriosclerotic process is accelerated, and therefore, the amount of the common salt in the diet is required to be controlled in spite of hypertension and heart diseases, and the potassium has the function of reducing the blood pressure when the high sodium is taken to cause the hypertension. In normal human body, sodium ion accounts for 92% of total cation content in extracellular fluid, and potassium ion accounts for about 98% of total cation content in intracellular fluid. Potassium also helps to lower blood pressure.
Meanwhile, potassium is a nutrient necessary for the growth of human bodies. It accounts for 5% of inorganic salts in human body and is very important for maintaining healthy nervous system and regulating heart rhythm. It can prevent stroke, maintain normal muscle contraction, and maintain fluid balance with sodium.
Therefore, some potassium chloride is added into the common salt at present, but the granularity of the potassium chloride is too low at present, so that the mixing is not uniform, the problem of non-uniformity is easy to occur during use, and the common salt is eaten more or less sometimes.
Disclosure of Invention
In view of the above, the present invention aims to provide a potassium chloride for food as a food additive, and also discloses a preparation method of the potassium chloride.
In order to achieve the purpose, the technical scheme of the invention is realized as follows:
potassium chloride for food use, the potassium chloride being present in an amount of more than 99.5% on a dry basis, the sodium being present in an amount of less than 0.5%, the particles of 90% potassium chloride having an average particle size of more than 0.4 mm.
A preparation method of potassium chloride for food comprises the following steps:
(1) mixing bittern obtained after seawater is exposed to the sun to separate out sodium chloride and old bittern obtained after separation of potassium chloride and magnesium double salt according to the volume ratio of 2:1, so that the molar ratio of magnesium sulfate to magnesium chloride in the mixed bittern is below 0.08, and the molar ratio of magnesium chloride to potassium chloride is 9-10;
(2) fully separating out bitter salt from the mixed halogen obtained in the step (1) in a halogen adding tank, removing the bitter salt, evaporating and concentrating the mixed halogen to 140 ℃, putting the concentrated mixed halogen into a heat-preservation settler, and separating out high-temperature salt at 120 ℃; separating out low-temperature salt at 85 ℃ and separating;
(3) cooling the filtrate to separate out a potassium-magnesium chloride compound salt, dissolving the potassium-magnesium chloride compound salt in water, wherein the volume ratio of the potassium-magnesium chloride compound salt to the water is 1:20, and dissolving magnesium chloride to obtain crude potassium chloride;
(4) dissolving the potassium chloride obtained in the step (3) in water, wherein the mass ratio of the potassium chloride to the water is 1:20, and introducing chlorine gas to saturation after filtering; boiling for 30 min to remove excessive chlorine, and introducing hydrogen chloride to separate out potassium chloride;
(5) and after separation, washing with water, dissolving in water, heating to 40 ℃ for full dissolution, filtering, cooling to about-5 ℃ to obtain crystals, and drying at 100-120 ℃ to obtain the finished product.
Preferably, the bitter salt of step 2 contains 85% sodium chloride, 23% magnesium chloride, 0.5% magnesium sulfate and 0.2% potassium chloride.
Preferably, the high temperature salt in step 2 contains 35% of sodium chloride, 12% of magnesium chloride, 10% of magnesium sulfate and 1% of potassium chloride.
Preferably, the low-temperature salt in the step 2 contains 15% of sodium chloride, 14% of magnesium chloride, 20% of magnesium sulfate and 1% of potassium chloride.
The molar ratio of magnesium sulfate to magnesium chloride in the mixed halogen is below 0.08, and the molar ratio of magnesium chloride to potassium chloride is 9-10, so that the purity of the potassium chloride obtained in the subsequent reaction of the mixed halogen is the highest.
The final potassium chloride has a dry content of more than 99.5%, a sodium content of less than 0.5%, and 90% potassium chloride particles having an average particle size of more than 0.4 mm. If the particle size of potassium chloride is too small, the potassium chloride is likely to be unevenly mixed when mixed with salt, which may affect the absorption of potassium chloride. The average particle size of 90% potassium chloride in the invention is larger than 0.4mm, so that the potassium chloride is easier to mix when in use.
The low-sodium salt is a healthy salt, and a certain amount of potassium chloride is added on the basis of common sodium salt, so that the balance of sodium and potassium of a human body is facilitated, and the risk of hypertension and cardiovascular diseases is reduced. In addition, because the salt causes salty taste and is chloride ions, the low sodium salt can better realize the purposes of reducing sodium and supplementing potassium without reducing the taste. However, potassium ions are not easily discharged out of the body, so that the human body is not benefited by too much eating.
The invention has the advantages that the potassium chloride is especially suitable for salt, and the content of sodium in the salt is effectively reduced. The preparation method provided by the invention is simple to operate, the prepared potassium chloride is high in purity, and the potassium chloride is fully dissolved and filtered at 40 ℃ before being dissolved in water in the last step of filtering, so that the impurity removal effect is better.
Detailed Description
Example 1
A preparation method of potassium chloride for food comprises the following steps:
(1) mixing bittern obtained after seawater is exposed to the sun to separate out sodium chloride and old bittern obtained after separation of potassium chloride and magnesium double salt according to the volume ratio of 2:1, so that the molar ratio of magnesium sulfate to magnesium chloride in the mixed bittern is below 0.08, and the molar ratio of magnesium chloride to potassium chloride is 9-10;
(2) fully separating out bitter salt from the mixed halogen obtained in the step (1) in a halogen adding tank, wherein the bitter salt contains 85% of sodium chloride, 23% of magnesium chloride, 0.5% of magnesium sulfate and 0.2% of potassium chloride. And removing, evaporating and concentrating the mixed halogen to 140 ℃, putting into a heat-preservation settler, and separating out high-temperature salt at 120 ℃, wherein the high-temperature salt contains 35% of sodium chloride, 12% of magnesium chloride, 10% of magnesium sulfate and 1% of potassium chloride. (ii) a After separating low-temperature salt separated at 85 ℃, the low-temperature salt contains 15% of sodium chloride, 14% of magnesium chloride, 20% of magnesium sulfate and 1% of potassium chloride.
(3) Cooling the filtrate to separate out a potassium-magnesium chloride compound salt, dissolving the potassium-magnesium chloride compound salt in water, wherein the volume ratio of the potassium-magnesium chloride compound salt to the water is 1:20, and dissolving magnesium chloride to obtain crude potassium chloride;
(4) dissolving the potassium chloride obtained in the step (3) in water, wherein the mass ratio of the potassium chloride to the water is 1:20, and introducing chlorine gas to saturation after filtering; boiling for 30 min to remove excessive chlorine, and introducing hydrogen chloride to separate out potassium chloride;
(5) and after separation, washing with water, dissolving in water, heating to 40 ℃ for full dissolution, filtering, cooling to about-5 ℃ to obtain crystals, and drying at 100-120 ℃ to obtain the finished product.
The dry content of the prepared potassium chloride is more than 99.5 percent, the content of sodium is less than 0.5 percent, and the average particle size of particles of 90 percent of potassium chloride is more than 0.4 mm.
Example 2
To the salt was added 10% of the potassium chloride obtained in example 1.
10 hypertensive patients were selected for comparative tests in two groups, wherein the total amount of common salt consumed by the first group of five hypertensive patients per day was not more than 3g, and the total amount of potassium chloride salt consumed by the second group of five hypertensive patients per day was not more than 3g, and blood pressure was measured after 1 month of use.
TABLE 1 Effect of edible Potassium chloride salt and common salt on hypertensive patients
Numbering Blood pressure before experiment Blood pressure after experiment
First group number one 150/95 150/95
First group of two numbers 140/100 140/100
First group of three numbers 150/95 150/95
First group of four numbers 180/100 180/100
Group five of the first 160/100 160/100
Second group number one 150/95 140/90
Second group number two 140/100 140/90
Second group III 150/95 145/92
Second group of four numbers 180/100 160/96
Second group of five numbers 160/100 140/95
It is seen from the above table that the consumption of salt with 10% potassium chloride is beneficial to the patients with hypertension because of the low consumption of sodium ions.
Example 3
To the salt was added 20% of the potassium chloride obtained in example 1.
10 hypertensive patients were selected for comparative tests in two groups, wherein the total amount of common salt consumed by the first group of five hypertensive patients per day was not more than 3g, and the total amount of potassium chloride salt consumed by the second group of five hypertensive patients per day was not more than 3g, and blood pressure was measured after 1 month of use.
TABLE 1 Effect of edible Potassium chloride salt and common salt on hypertensive patients
Figure BDA0001922400680000041
Figure BDA0001922400680000051
It is seen from the above table that the benefits of eating salt with 20% potassium chloride added are better for the hypertensive than with 10% salt, because less sodium ions are available.
Example 3
To the salt was added 30% of the potassium chloride obtained in example 1.
10 hypertensive patients were selected for comparative tests in two groups, wherein the total amount of common salt consumed by the first group of five hypertensive patients per day was not more than 3g, and the total amount of potassium chloride salt consumed by the second group of five hypertensive patients per day was not more than 3g, and blood pressure was measured after 1 month of use.
TABLE 1 Effect of edible Potassium chloride salt and common salt on hypertensive patients
Numbering Blood pressure before experiment Blood pressure after experiment
First group number one 150/95 150/95
First group of two numbers 140/100 140/100
First group of three numbers 150/95 150/95
First group of four numbers 180/100 180/100
Group five of the first 160/100 160/100
Second group number one 150/95 130/86
Second group number two 140/100 132/88
Second group III 150/95 142/90
Second group of four numbers 180/100 148/93
Second group of five numbers 160/100 144/90
It is seen from the above table that the edible salt added with 30% of potassium chloride is more beneficial to the hypertensive than the edible salt added with 10%, but the ratio of the edible salt to the edible salt added with 20% is not much different, and the edible salt added with 20% of potassium chloride is the most suitable dosage in consideration of the problem that potassium ions are not easy to be excreted.

Claims (6)

1. Potassium chloride for food use, characterized in that it has a dry content of more than 99.5% and a sodium content of less than 0.5%, the particles of 90% potassium chloride having an average size of more than 0.4 mm.
2. The method for preparing potassium chloride for food according to claim 1, comprising the steps of:
(1) mixing bittern obtained after seawater is exposed to the sun to separate out sodium chloride and old bittern obtained after separation of potassium chloride and magnesium double salt according to the volume ratio of 2:1, so that the molar ratio of magnesium sulfate to magnesium chloride in the mixed bittern is below 0.08, and the molar ratio of magnesium chloride to potassium chloride is 9-10;
(2) fully separating out bitter salt from the mixed halogen obtained in the step (1) in a halogen adding tank, removing the bitter salt, evaporating and concentrating the mixed halogen to 140 ℃, putting the concentrated mixed halogen into a heat-preservation settler, and separating out high-temperature salt at 120 ℃; separating out low-temperature salt at 85 ℃ and separating;
(3) cooling the filtrate to separate out a potassium-magnesium chloride compound salt, dissolving the potassium-magnesium chloride compound salt in water, wherein the volume ratio of the potassium-magnesium chloride compound salt to the water is 1:20, and dissolving magnesium chloride to obtain crude potassium chloride;
(4) dissolving the potassium chloride obtained in the step (3) in water, wherein the mass ratio of the potassium chloride to the water is 1:20, and introducing chlorine gas to saturation after filtering; boiling for 30 min to remove excessive chlorine, and introducing hydrogen chloride to separate out potassium chloride;
(5) and after separation, washing with water, dissolving in water, heating to 40 ℃ for full dissolution, filtering, cooling to about-5 ℃ to obtain crystals, and drying at 100-120 ℃ to obtain the finished product.
3. The method for preparing potassium chloride for food according to claim 2, wherein the bitter salt of step 2 contains 85% of sodium chloride, 23% of magnesium chloride, 0.5% of magnesium sulfate and 0.2% of potassium chloride.
4. The method for preparing potassium chloride for food according to claim 2, wherein the high temperature salt in step 2 comprises 35% sodium chloride, 12% magnesium chloride, 10% magnesium sulfate and 1% potassium chloride.
5. The method for preparing potassium chloride for food according to claim 2, wherein the low-temperature salt in step 2 contains 15% of sodium chloride, 14% of magnesium chloride, 20% of magnesium sulfate and 1% of potassium chloride.
6. A potassium chloride for food use as common salt according to claim 1.
CN201811605872.5A 2018-12-26 2018-12-26 Potassium chloride for food and preparation method thereof Pending CN111357969A (en)

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Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
CN111357969A true CN111357969A (en) 2020-07-03

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