Gaseous pollutant measuring device capable of avoiding pollution of window sheet
Technical Field
The invention relates to a gaseous pollutant measuring device capable of avoiding pollution of a window sheet, and belongs to the technical field of gaseous pollutant monitoring instruments.
Background
For the existing gaseous pollutant measuring device, when high-concentration polluted gas is measured, sulfur-containing gaseous molecules can generate chemical reaction under the irradiation of ultraviolet rays, and mist is generated on the surface of the light-transmitting window sheet (namely, mist solid matters can be slowly deposited on the light-transmitting window sheet), so that the ultraviolet transmittance of the window sheet is greatly reduced, and the test result is seriously influenced.
Disclosure of Invention
The purpose of the invention is as follows: in order to solve the problems in the prior art, the invention provides a gaseous pollutant measuring device capable of avoiding window piece pollution, wherein a heating device is arranged on the outer side of a light-transmitting window piece at one end or two ends of a measuring cavity of the gaseous pollutant measuring device, so that the light-transmitting window piece can be heated, the problem that mist is slowly deposited on the light-transmitting window piece when sulfur-containing gaseous molecules in polluted gas at normal temperature are irradiated by ultraviolet rays is effectively avoided, and the long-term stability of the measuring effect of the measuring device is further ensured.
In order to solve the problems, the technical scheme adopted by the invention is as follows:
the utility model provides a can avoid gaseous pollutant measuring device of window piece pollution, is including the measurement chamber that is used for filling the gas that awaits measuring, the outside of the transmission end light-transmitting window piece and/or the receiving terminal light-transmitting window piece of measuring the chamber is equipped with heating device.
Wherein, a light-transmitting through hole is arranged on the heating device.
The heating device is of an annular structure, so that the light-transmitting window piece can be fully heated, and ultraviolet light can pass through the heating device.
The heating device is a heating sheet with a built-in heating wire, the heating sheet is a ceramic heating sheet, a temperature sensor is welded on the ceramic heating sheet, and the heating wire and the temperature sensor are respectively connected with an external temperature controller through wires.
The device also comprises a transmitting end sealing ring, a transmitting end gland, a receiving end sealing ring and a receiving end gland; the transmitting end sealing ring, the transmitting end light-transmitting window sheet and the transmitting end heating device are tightly pressed and installed at the transmitting end of the measuring cavity through the transmitting end pressing cover, and the receiving end sealing ring, the receiving end light-transmitting window sheet and the receiving end heating device are tightly pressed and installed at the receiving end of the measuring cavity through the receiving end pressing cover. The transmitting end heating device is tightly attached to the transmitting end light-transmitting window piece, and the receiving end heating device is tightly attached to the receiving end light-transmitting window piece, so that the transmitting end light-transmitting window piece and the receiving end light-transmitting window piece are heated to fixed temperatures.
The spectrometer comprises a measuring cavity, an ultraviolet source, a spectrometer and a spectrometer support, wherein the ultraviolet source, the ultraviolet source support, the spectrometer and the spectrometer support are further included, the ultraviolet source is arranged at the transmitting end of the measuring cavity through the ultraviolet source support, and the spectrometer is arranged at the receiving end of the measuring cavity through the spectrometer support. The ultraviolet light source emits ultraviolet light, the ultraviolet light passes through the transmitting end light-transmitting window sheet and the measuring gas in the measuring cavity, after a part of the ultraviolet light is absorbed, the ultraviolet light passes through the receiving end light-transmitting window sheet again and irradiates on the spectrograph, and the spectrograph analyzes the absorbed spectrum and outputs data.
The measuring cavity is provided with an air inlet and an air outlet, the air inlet and the air outlet on the measuring cavity are respectively connected with an external air chamber through air pipes, and measuring gas is introduced into the cavity from the air inlet of the measuring cavity and is discharged out of the cavity from the air outlet.
The window sheet bracket comprises a mounting block, a first positioning plate and a second positioning plate, wherein the first positioning plate and the second positioning plate are positioned on two sides of the mounting block; the transmitting end light-transmitting window piece with the sealing ring is embedded into a positioning hole of the mounting block and is fixed on the mounting block through a first positioning plate, and the heating device and a circuit board electrically connected with the heating device are also embedded into the positioning hole of the mounting block and are fixed on the mounting block through a second positioning plate; the emission end gland tightly presses the window sheet bracket to the emission end of the measurement cavity. The circuit board is provided with a temperature sensor and is connected with an external temperature controller through a joint lead.
The window sheet support is embedded into a positioning hole of the window sheet support, and the window sheet support is tightly pressed and installed at the receiving end of the measuring cavity by the receiving end gland.
The working process of the gaseous pollutant measuring device comprises the following steps: when the device works normally, the transmitting end heating device and/or the receiving end heating device are electrified to operate, and the transmitting end light-transmitting window sheet and the receiving end light-transmitting window sheet are respectively heated to a certain fixed temperature and then kept at constant temperature; then the measurement gas is introduced into the measurement cavity from a gas inlet on the measurement cavity and is discharged out of the measurement cavity from a gas outlet (the measurement cavity is communicated with an external gas chamber for circulation); then the ultraviolet light source emits ultraviolet light, the ultraviolet light passes through the transmitting end light-transmitting window sheet and the measuring gas in the measuring cavity, and after a part of the ultraviolet light is absorbed, the ultraviolet light passes through the receiving end light-transmitting window sheet again and irradiates the spectrometer. At this time, because the transmitting end light-transmitting window piece and the receiving end light-transmitting window piece are always kept at high temperature, even if sulfur-containing gaseous molecules in the measurement gas are irradiated by ultraviolet rays, mist cannot be generated on the transmitting end light-transmitting window piece or the receiving end light-transmitting window piece, and therefore the continuous stability of the measurement effect is guaranteed.
Has the advantages that: according to the gaseous pollutant measuring device, the heating device is arranged on the outer side of the light-transmitting window piece at one end or two ends of the measuring cavity to heat the light-transmitting window piece, so that the problem that mist is slowly deposited on the light-transmitting window piece when sulfur-containing gaseous molecules in polluted gas are irradiated by ultraviolet rays at normal temperature is effectively avoided, and the long-term stability of the measuring effect of the measuring device is further ensured.
Drawings
FIG. 1 is an exploded view of a gaseous pollutant measuring device according to example 1;
FIG. 2 is a schematic view showing the structure of a gaseous pollutant measuring apparatus according to embodiment 1;
FIG. 3 is an exploded view of the gaseous pollutant measuring device of example 2;
FIG. 4 is a schematic view showing the structure of a gaseous pollutant measuring apparatus according to embodiment 2;
FIG. 5 shows the measurement of sulfur dioxide (SO) in a gaseous contaminant without a heating device at the window piece2) The result of the transmittance measurement;
FIG. 6 shows the measurement of sulfur dioxide (SO) by the device for measuring gaseous pollutants according to the present invention2) The result of transmittance measurement of (2).
Detailed Description
The technical scheme of the invention is further explained by combining the drawings and the specific embodiment.
Example 1
As shown in fig. 1-2, the gaseous pollutant measuring device capable of avoiding the pollution of the window sheet comprises a measuring cavity 1 for filling gas to be measured, wherein heating devices (6, 7) are arranged on the outer sides of light-transmitting window sheets (2, 3) at two ends of the measuring cavity 1; the heating devices (6, 7) are provided with light-transmitting through holes 16, and the heating devices (6, 7) can be in an annular structure, so that the light-transmitting window sheets (2, 3) can be fully heated, and ultraviolet light can pass through the light-transmitting window sheets; the heating devices (6, 7) can also be in other shapes with light-transmitting gaps. The heating devices (6 and 7) are heating sheets with built-in heating wires, the heating sheets are ceramic heating sheets, temperature sensors (the temperature sensors can be Pt type thermal resistors or other temperature sensors such as K type thermocouples) are welded on the ceramic heating sheets, and the heating wires and the temperature sensors are respectively connected with an external temperature controller through wires.
The device for measuring the gaseous pollutants also comprises a transmitting end sealing ring 4, a transmitting end gland 8, a receiving end sealing ring 5 and a receiving end gland 9; the transmitting end sealing ring 4, the transmitting end light-transmitting window sheet 2, the transmitting end heating device 6 are tightly pressed and installed at the transmitting end of the measuring cavity 1 through the transmitting end gland 8 (the transmitting end gland 8 is fixedly connected with the transmitting end of the measuring cavity 1 through screws), the receiving end sealing ring 5, the receiving end light-transmitting window sheet 3 and the receiving end heating device 7 are tightly pressed and installed at the receiving end of the measuring cavity 1 through the receiving end gland 9 (the receiving end gland 9 is fixedly connected with the receiving end of the measuring cavity 1 through screws). The transmitting end heating device 6 is tightly attached to the transmitting end light-transmitting window piece 2, and the receiving end heating device 7 is tightly attached to the receiving end light-transmitting window piece 3, so that the transmitting end light-transmitting window piece 2 and the receiving end light-transmitting window piece 3 are heated to a fixed temperature. The transmitting end sealing ring 4 and the receiving end sealing ring 5 ensure the sealing performance of the measuring cavity 1.
The device for measuring the gaseous pollutants further comprises an ultraviolet light source 11, an ultraviolet light source support 10, a spectrometer 13 and a spectrometer support 12, wherein the ultraviolet light source support 10 and the spectrometer support 12 are respectively fixed at two ends of the measuring cavity 1, the ultraviolet light source 11 is installed at the transmitting end of the measuring cavity 1 through the ultraviolet light source support 10, and the spectrometer 13 is installed at the receiving end of the measuring cavity 1 through the spectrometer support 12. The emission end gland 8 is fixed on the ultraviolet light source support 10, and the receiving end gland 9 is fixed on the spectrometer support 12. The ultraviolet light source 11 emits ultraviolet light, which passes through the transmitting end light-transmitting window sheet 2 and the measurement gas in the measurement cavity 1, and after being absorbed, passes through the receiving end light-transmitting window sheet 3 again, and irradiates on the spectrometer 13, and the spectrometer 13 analyzes the absorbed spectrum and outputs data.
The measuring cavity 1 of the gaseous pollutant measuring device is provided with an air inlet 14 and an air outlet 15, the air inlet 14 and the air outlet 15 on the measuring cavity 1 are respectively connected with an external air chamber through air pipes, and measuring gas is introduced into the cavity from the air inlet 14 of the measuring cavity 1 and is discharged out of the cavity from the air outlet 15.
The heating devices (6, 7) of the gaseous pollutant measuring device of the invention are composed of a heating sheet with a built-in heating wire and a temperature sensor, lead wires 26 of the heating sheet and the temperature sensor are connected with an external temperature control circuit, and the temperature control circuit controls heating to keep the temperature of the heating devices (6, 7) at 125 +/-5 ℃ all the time (namely the working temperature of the heating devices is 125 +/-5 ℃). The heating devices (6, 7) used by the gaseous pollutant measuring device are ceramic heating sheets, and the ceramic heating sheets are heating elements which are manufactured by printing resistance slurry on an alumina ceramic green body, then baking the alumina ceramic green body at high temperature, and then installing electrodes and leads.
Example 2
As shown in fig. 3 to 4, the device for measuring gaseous pollutants capable of avoiding the pollution of the window sheet of the present invention includes a measurement cavity 1 for filling the gas to be measured, wherein the measurement cavity 1 is provided with a heating device 6 only at the outer side of the light-transmitting window sheet 2 at the emission end; wherein, the heating device 6 is provided with a light-transmitting through hole 16, and the heating device 6 can be in an annular structure, thus not only fully heating the light-transmitting window sheet 2, but also enabling ultraviolet light to pass through; the heating device 6 can also be in other shapes with light transmission gaps, the heating device 6 is a ceramic heating sheet, the ceramic heating sheet is electrically connected with a heating sheet circuit board 17, a temperature sensor is arranged on the heating sheet circuit board 17, and the heating sheet circuit board 17 is connected with an external temperature control circuit 32 through a connector lead 30.
The gaseous pollutant measuring device capable of avoiding window sheet pollution further comprises an emission end gland 8 and a window sheet support 18 embedded in the emission end gland 8, wherein the window sheet support 18 comprises a mounting block 19, a first positioning plate 20 and a second positioning plate 21 which are positioned on two sides of the mounting block 19, and a fastening bolt 22 sequentially penetrates through the first positioning plate 20, the mounting block 19 and a through hole in the circuit board 17 and is mutually matched and fixedly connected with a threaded hole in the second positioning plate 21 through internal and external threads; the transmitting end light-transmitting window piece 2 with the sealing ring 4 is embedded into a positioning hole 23 of the mounting block 19 and is fixed on the mounting block 19 through a first positioning plate 20, and the heating device 6 and the circuit board 17 electrically connected with the heating device 6 are also embedded into the positioning hole 23 of the mounting block 19 and are fixed on the mounting block 19 through a second positioning plate 21; the emission end gland 8 compresses tightly the window sheet support 19 and installs the emission end in the measurement cavity 1 (the emission end gland 8 and the emission end in the measurement cavity 1 are fixedly connected through a screw), and when the emission end light-transmitting window sheet 2 needs to be cleaned, the window sheet support 18 is pulled out from the groove of the emission end gland 8. The gaseous pollutant measuring device capable of avoiding the pollution of the window sheet further comprises a receiving end gland 9 and a window sheet support 24 embedded in the receiving end gland 9, wherein the receiving end light-transmitting window sheet 3 with the sealing ring 5 is embedded in a positioning hole 25 of the window sheet support 24, and the window sheet support 24 is tightly pressed and installed at the receiving end of the measuring cavity 1 by the receiving end gland 9 (the receiving end gland 9 is fixedly connected with the receiving end of the measuring cavity 1 through a screw). When the receiving end light-transmitting window piece 3 needs to be cleaned, the window piece bracket 24 is pulled out from the groove of the receiving end gland 9.
The device for measuring the gaseous pollutants further comprises an ultraviolet light source 11, an ultraviolet light source support 10, a spectrometer 13 and a spectrometer support 12, wherein the ultraviolet light source support 10 and the spectrometer support 12 are respectively fixed at two ends of the measuring cavity 1, the ultraviolet light source 11 is installed at the transmitting end of the measuring cavity 1 through the ultraviolet light source support 10, and the spectrometer 13 is installed at the receiving end of the measuring cavity 1 through the spectrometer support 12. The emission end gland 8 is fixed on the ultraviolet light source support 10, and the receiving end gland 9 is fixed on the spectrometer support 12.
FIG. 5 shows the measurement of sulfur dioxide (SO) in a gaseous contaminant without a heating device at the window piece2) Transmittance measurement result (abscissa: time, ordinate: (ii) spectral intensity; the curve: normal temperature transmittance, high temperature transmittance); FIG. 6 shows the measurement of sulfur dioxide (SO) by the device for measuring gaseous pollutants according to the present invention2) Transmittance measurement result (abscissa: time, ordinate: (ii) spectral intensity; three curves: temperature, normal temperature transmittance, high temperature transmittance). As can be seen from the graphs of FIGS. 5 to 6, after the heating device is added at the light-transmitting window sheet of the gaseous pollutant measuring device, the long-term stability of the measuring effect of the measuring device is effectively ensured. Therefore, the gaseous pollutant measuring device solves the problem that when the traditional ultraviolet gaseous pollutant measuring device is used for measuring gaseous sulfide pollutants, the polluted gas is transmitted to the light-transmitting window sheet 2 and the receiving window sheet 2 under the action of ultraviolet raysThe opaque mist is deposited on the end light-transmitting window sheet 3, which affects the measurement effect.