CN111345313A - Fly-killing composition for controlling fly breeding place and application thereof - Google Patents
Fly-killing composition for controlling fly breeding place and application thereof Download PDFInfo
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- CN111345313A CN111345313A CN201811578949.4A CN201811578949A CN111345313A CN 111345313 A CN111345313 A CN 111345313A CN 201811578949 A CN201811578949 A CN 201811578949A CN 111345313 A CN111345313 A CN 111345313A
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- methyl
- fly
- pirimiphos
- polyoxyethylene ether
- chlorfluazuron
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a fly-killing composition with strong permeability for controlling breeding places of flies, which comprises active ingredients of pirimiphos-methyl and chlorfluazuron or hexaflumuron, wherein the weight ratio of the pirimiphos-methyl to the chlorfluazuron is 1: 15-15: 1, preferably 1: 5-10: 1; the weight ratio of the pirimiphos-methyl to the hexaflumuron is 1: 15-15: 1, preferably 1: 10-15: 1. the invention also provides missible oil for killing flies, which comprises 10-50 percent of active ingredients, 1-15 percent of emulsifier, 1-10 percent of penetrant and the balance of solvent according to the percentage of the total weight of the missible oil. The insecticide is used for controlling flies bred by the flies by compounding the pirimiphos-methyl and the chlorfluazuron or the hexaflumuron. The composition has good permeability, good lethal effect, long persistent period, high emergence inhibition rate and reduced labor cost; the insecticidal composition is widely applied to places such as garbage piles, manure pits, farms and the like, has special effects on controlling bred ground fly larvae, and simultaneously kills adults.
Description
Technical Field
The invention relates to a sanitary insecticide, in particular to a compound sanitary insecticide containing pirimiphos-methyl and chlorfluazuron or hexaflumuron.
Background
Flies are the most familiar and major sanitary pests, and there are many kinds of flies, among which the species of housekeeping and semi-housekeeping are closely related to human and livestock. Mainly causing harm such as mechanical transmission disease, harassment blood absorption and the like. Fly breeding habit not only relates to the self factors of spawning habit of the species group and feeding property of larvae, but also has great difference due to different regions, seasons, places and states of breeding substances. The breeding substances are the basic condition for breeding flies. The breeding material is not exactly equal to the food of the fly larvae, which are often a mixture of food and other materials, and is also a habitat for the fly larvae. The place where the breeding materials are present is called breeding place. A great deal of waste such as food residue, excrement, production leftovers, animal carcasses and the like generated in the daily life and production process of human beings can be used as a living substrate for breeding the fly larvae.
For the flies whose breeding can not be cleared temporarily, the chemical treatment is generally carried out. When chemical drugs are used to kill fly maggots, attention should be paid to the influence of the age and the character of the breeding ground of the maggots on the drugs. It is further noted that resistance development is also induced when larvae are exposed to low doses of drugs, especially when the same class of chemical drugs is used to control larvae and adult flies. Meanwhile, the fly larvae are loved to be hidden in the deep parts of the breeding ground, and how to make the medicament go deep into the breeding ground is also one of the influencing factors for controlling the fly larvae of the breeding ground. At present, most of fly breeding ground larvae are controlled by granules, aqueous emulsion and microemulsion, and the dosage forms have not good effect on controlling fly larvae in the deep part of breeding ground.
The pirimiphos-methyl is an organophosphorus insecticide and has the characteristics of contact poisoning, stomach poisoning and quick effect. When the pests contact the liquid medicine, the activity of cholinesterase in the bodies of the pests is inhibited, and the nervous system is paralyzed, poisoned and stopped to feed, so that the pests die.
The chlorfluazuron is a novel pesticide of phenylformyl urea, mainly takes stomach toxicity as a main part, has an action mechanism mainly inhibiting chitin synthesis, prevents normal molting of insects, and prevents hatching of eggs, larval molting and pupal development deformity, and eclosion of adults to play a role in killing insects; fluoruride is a novel acyl urea insecticide that kills pests by inhibiting molting.
The action mechanisms of the pirimiphos-methyl, the chlorfluazuron and the fluroin are different, the pirimiphos-methyl has good quick action but poor persistence, and the drug resistance of pests is easy to occur when one drug is singly used, so that the drug application cost is increased, and hidden danger is brought to the living environment; in contrast, chlorfluazuron and fluorouril are chitin synthesis inhibitors, which have poor quick-acting property and long-lasting property.
Disclosure of Invention
One of the objects of the present invention is: provides a compound fly-killing composition containing pirimiphos-methyl and chlorfluazuron or flurourea, which has good insecticidal effect, double mechanisms are compounded to enhance the effect and is not easy to generate drug resistance. Wherein the weight ratio of the pirimiphos-methyl to the chlorfluazuron is 1: 15-15: 1, preferably 1: 5-10: 1, the weight ratio of the pirimiphos-methyl to the hexaflumuron is 1: 20-20: 1, preferably 1: 10-15: 1.
another object of the present invention is to: provides a preparation capable of reaching deep breeding places to kill fly larvae, wherein the weight ratio of the pirimiphos-methyl to the chlorfluazuron is 1: 15-15: 1, preferably 1: 5-10: 1, the weight ratio of the pirimiphos-methyl to the hexaflumuron is 1: 20-20: 1, preferably 1: 10-15: 1.
yet another object of the present invention is to: provides the application of the insecticidal composition and the preparation in breeding places of flies.
The invention is realized by the following modes: the preparation is missible oil, and comprises 10-50% of effective components, 1-15% of emulsifier, 1-10% of penetrating agent and the balance of solvent according to the percentage of the total weight of the missible oil, wherein the effective components are prepared by compounding the pirimiphos-methyl and the chlorfluazuron or the hexaflumuron, the weight ratio of the pirimiphos-methyl to the chlorfluazuron is 1: 15-15: 1, preferably 1: 5-10: 1, the weight ratio of the pirimiphos-methyl to the hexaflumuron is 1: 20-20: 1, preferably 1: 10-15: 1.
the emulsifier is selected from: two or three of styryl phenol polyoxyethylene ether, phenyl phenol polyoxyethylene ether phosphate, castor oil polyoxyethylene ether phosphate, calcium alkyl benzene sulfonate, alkylphenol polyoxyethylene ether, phenethyl phenol formaldehyde resin polyoxyethylene ether, nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, alkylaryl polyoxypropylene polyoxyethylene ether, alkylaryl polyoxyethylene ether, tween series and span series.
The penetrant is selected from: one of sulfonated dioctyl sodium sulfosuccinate, sulfonated di-sec-octyl succinate sodium salt, ricinoleic acid sodium sulfate, octanol polyoxyethylene ether and sodium alkyl benzene sulfonate.
The solvent is selected from: one or two of dimethyl sulfoxide, N-dimethylformamide, N-dimethylacetamide, N-methylpyrrolidone, cyclohexanone, benzyl alcohol and N-butanol.
The invention also provides application of the fly killing composition in controlling flies in fly breeding places.
The flies are breeding ground fly larvae and/or adults.
The breeding places comprise garbage piles, manure pits, farms and the like.
Detailed Description
The present invention will be further described with reference to examples. The percentages in the following examples are by weight unless otherwise indicated.
Formulation example 1: 32% methyl pyrimidyl phosphorus chlorfluazuron missible oil
The formula materials are mixed evenly to prepare 32 percent methyl pyrimidine phosphorus chlorfluazuron missible oil. Formulation example 2: 22% methyl pyrimidyl phosphorus chlorfluazuron missible oil
The formula materials are mixed evenly to prepare 22 percent methyl pyrimidine phosphorus chlorfluazuron missible oil. Formulation example 3: 30% methyl pyrimidyl phosphorus chlorfluazuron missible oil
The formula materials are mixed evenly to prepare the 30 percent methyl pyrimidine phosphorus chlorfluazuron missible oil. Formulation example 4: 20% methyl pyrimidyl phosphorus chlorfluazuron missible oil
The formula materials are mixed evenly to prepare 20 percent methyl pyrimidine phosphorus chlorfluazuron missible oil. Formulation example 5: 36% methyl pyrimidyl phosphorus chlorfluazuron missible oil
The formula materials are mixed evenly to prepare the 36 percent methyl pyrimidine phosphorus chlorfluazuron missible oil. Formulation example 6: 44% methyl pyrimidyl phosphorus chlorfluazuron missible oil
The formula materials are mixed evenly to prepare the 44 percent methyl pyrimidine phosphorus chlorfluazuron missible oil. Formulation example 7: 48% methyl pyrimidyl phosphorus chlorfluazuron emulsifiable concentrate
The formula materials are mixed evenly to prepare the 48 percent methyl pyrimidine phosphorus chlorfluazuron missible oil. Formulation example 8: 42% methyl pyrimidyl phosphorus hexaflumuron emulsifiable concentrate
The formula materials are mixed evenly to prepare the 42 percent methyl pyrimidine phosphorus hexaflumuron missible oil. Formulation example 9: 22% methyl pyrimidyl phosphorus hexaflumuron emulsifiable concentrate
The formula materials are mixed evenly to prepare 22 percent methyl pyrimidine phosphorus hexaflumuron missible oil. Formulation example 10: 30% methyl pyrimidyl phosphorus hexaflumuron emulsifiable concentrate
The formula materials are mixed evenly to prepare the 30 percent methyl pyrimidine phosphorus hexaflumuron missible oil. Formulation example 11: 40% methyl pyrimidyl phosphorus hexaflumuron emulsifiable concentrate
The formula materials are mixed evenly to prepare the 40 percent methyl pyrimidine phosphorus hexaflumuron missible oil. Formulation example 12: 42% methyl pyrimidyl phosphorus hexaflumuron emulsifiable concentrate
The formula materials are mixed evenly to prepare the 42 percent methyl pyrimidine phosphorus hexaflumuron missible oil. Formulation example 13: 55% methyl pyrimidyl phosphorus hexaflumuron emulsifiable concentrate
The formula materials are mixed evenly to prepare 55 percent of methyl pyrimidine phosphorus hexaflumuron missible oil. Formulation example 14: 42% methyl pyrimidyl phosphorus hexaflumuron emulsifiable concentrate
The formula materials are mixed evenly to prepare the 42 percent methyl pyrimidine phosphorus hexaflumuron missible oil.
Application example 1: drug effect test for controlling fly larvae
Test targets: larva of 3-instar housefly
The test method comprises spreading housefly larva fodder of 5cm thickness in a wooden case of 20cm × 50cm × 10cm, placing 100 housefly larvae, applying the medicinal preparation on the fodder surface, spraying 50g of medicinal liquid, covering the case with gauze, standing for 10 days, observing survival adult number, calculating emergence rate, and setting blank control group;
and (3) test treatment: preparation examples 1-3,8-10 total concentration of active ingredients were diluted to 500 mg/l;
control 1: diluting 5% chlorfluazuron missible oil to 500 mg/l;
control 2: diluting 5% fluazuron missible oil to 500 mg/l;
control 3: diluting 20% methyl pyrimidine phosphorus missible oil to 500 mg/l;
blank control: distilled water
And (3) test results:
the test result shows that: the control 1-3 are single-agent emulsifiable concentrates, the feathering inhibition rate of the fly larvae is lower than that of the preparation of the invention, and the preparation examples 1-3,8-10 of the invention have good lethal effect and high feathering inhibition rate (see Table 1)
TABLE 1 formulation examples 1-3,8-10 efficacy tests for fly larvae control
Further, the same efficacy tests are carried out on the preparation examples 4-7 and 11-14, the lethal effect is good, the emergence rate is very high, and the persistence is good.
Application example 2: simulated field test for fly larvae control
Test targets: larva of 3-instar housefly
The test method comprises spreading 20cm thick housefly larva fodder in 20cm × 50cm × 30cm wooden case, applying the medicine on the fodder surface, spraying 50g of medicinal liquid, placing 100 pieces of 3-year-old housefly larva in the wooden case on the day, 2 weeks, 4 weeks, covering the case with gauze, observing survival imago number after 10 days, calculating emergence inhibition rate, and spraying water properly to keep the fodder moist after 2 weeks, 4 weeks of the test;
and (3) test treatment: preparation examples 4-5,11-12 total concentration of active ingredients were diluted to 500 mg/l;
control 1: diluting 5% chlorfluazuron missible oil to 500 mg/l;
control 2: diluting 5% fluazuron missible oil to 500 mg/l;
control 3: diluting 20% methyl pyrimidine phosphorus missible oil to 500 mg/l;
and (3) test results:
the test result shows that: the comparison samples 1-3 are single-agent missible oil, the feathering inhibition rate of the preparation is lower than that of the preparation, and the persistence is lower than that of the preparation. In the preparation examples 4-5 and 11-12 of the present invention, not only the lethal effect is good, but also the emergence retarding rate is high, and the persistence is good (see Table 2)
Table 2 formulation examples 4-5,11-12 simulated field trials for fly larvae control
Further, the same efficacy tests are carried out on the preparation examples 1-3,6-10 and 13-14, the lethal effect is good, the eclosion inhibition rate is high, and the persistence is good.
Application example 3: permeability test of larvae of Drosophila infestans
Test targets: larva of 3-instar housefly
The test method comprises spreading housefly larva fodder of 10cm, 20cm and 30cm thickness in a wooden case of 20cm × 50cm, 50cm × 30cm, applying the agent on the fodder surface, spraying 50g of medicinal liquid, placing 100 housefly larvae of 3 years old in the wooden case, covering the case with gauze, observing the number of survival adults after 10 days, and calculating the emergence inhibition rate;
and (3) test treatment: formulation examples 6 and 13 the total concentration of active ingredient was diluted to 500 mg/l;
control 1: the penetrant is removed following the formulation example 6;
control 2: removal of penetrants following the formulation example 13;
and (3) test results:
the test results showed that the control samples 1 and 2, to which no penetrant was added, had decreasing rates of emergence inhibition for fly larvae with increasing feed thickness, and had lower rates of emergence inhibition than those of the formulation examples 6 and 13, and had poorer permeability than those of the formulation examples 6 and 13, the formulation examples 6 and 13 of the present invention had both good penetration effects and high rates of emergence inhibition for feeds of different thicknesses (see Table 3)
TABLE 3 Drosophila larvae Permeability pharmacodynamic test
Application example 4: drug effect test of different formulations on bred ground fly larvae
Test targets: larva of 3-instar housefly
The test method comprises spreading 20cm thick housefly larva fodder in 20cm × 50cm × 30cm wooden case, applying the medicine on the fodder surface, spraying 50g of medicinal liquid, placing 100 pieces of 3-year-old housefly larva in the wooden case, covering the case with gauze, observing the number of survival imagoes after 10 days, and calculating the eclosion inhibition rate;
and (3) test treatment: formulation examples 7 and 14 the total concentration of active ingredient was diluted to 500 mg/l;
control 1: diluting the pirimiphos-methyl and chlorfluazuron microemulsion to 500 mg/l;
control 2: diluting the aqueous emulsion of pirimiphos-methyl and chlorfluazuron to 500 mg/l;
control 3: diluting the pirimiphos-methyl and hexaflumuron microemulsion to 500 mg/l;
control 4: diluting the pirimiphos-methyl and hexaflumuron water emulsion to 500 mg/l;
and (3) test results:
the test results showed that the control samples 1-2 had a lower feathering inhibition ratio for fly larvae than that of formulation example 7, and had poorer penetration properties than that of formulation example 7, and the control samples 3-4 had a lower feathering inhibition ratio for fly larvae than that of formulation example 14, and had poorer penetration properties than that of formulation example 14. The formulations of examples 7 and 14 according to the invention have good penetration and a high emergence inhibition (see Table 4)
TABLE 4 drug effect test of different formulations on bred Dilophaga terrestris
Application example 5: outdoor efficacy test of adult ground flies bred
Test targets: adult fly
The test method comprises the following steps: spraying or scattering a medicament on the surface of a breeding ground in a garbage field subarea, and recording the density reduction rate of the fly imagoes for 24 hours;
and (3) test treatment: preparation example 5, preparation example 12 total concentration of active ingredients is diluted to 500 mg/l;
and (3) test results:
the test result shows that the preparation of the invention has the effect of killing imagoes and high fly density reduction rate (see table 5)
TABLE 5 outdoor efficacy test of adult ground flies bred
| Treatment of | Density decrease ratio (%) |
| Formulation example 5 | 96.7 |
| Formulation example 12 | 96.3 |
Application example 6: determination of cotoxicity coefficient of compound pyrithion and chlorfluazuron or fluorosyringa
Test targets: larva of 3-instar housefly
The test method comprises the following steps: the method comprises the steps of filling 30g of fly feed in a white enamel bowl with the volume of 300mL, preparing solutions with different concentrations, sucking 40mL of the fly feed, mixing the fly feed with the solutions, standing for several minutes, putting 50 housefly larvae of 3 years old into the bowl, observing the number of the housefly larvae which survive for 10 days, considering all pupae which cannot be eclosized as dead, and calculating the death rate;
the data calculates half lethal concentration value and virulence regression equation according to linear weighted regression method, and calculates cotoxicity coefficient by referring to Sun cloud Pepper method.
The test results show that the insecticidal composition has good synergistic effect on the feathering inhibition rate of the fly larvae after being compounded through indoor pesticide effect tests and calculation, and the specific results are shown in tables 6 and 7:
TABLE 6 Co-toxicity assay of pirimiphos-methyl and chlorfluazuron (for housefly larvae)
As shown in table 6, the compounding ratio of pirimiphos-methyl to chlorfluazuron is 1: 15-15: 1, the co-toxicity coefficient for fly larvae is more than 100, and particularly, when the compounding ratio is 1: 5-10: when 1, the co-toxicity coefficient exceeds 120, and the synergistic effect is obvious.
TABLE 7 Co-toxicity assay of pirimiphos-methyl and hexaflumuron (for housefly larvae)
As shown in table 7, the compounding ratio of pirimiphos-methyl to hexaflumuron was 1: 20-20: 1, the co-toxicity coefficient for fly larvae is more than 100, and particularly, when the compounding ratio is 1: 10-15: when 1, the co-toxicity coefficient exceeds 120, and the synergistic effect is obvious.
Claims (6)
1. A compound fly-killing composition is characterized in that: the composition contains a compound component of pirimiphos-methyl and chlorfluazuron or hexaflumuron, wherein the weight ratio of the pirimiphos-methyl to the chlorfluazuron is 1: 15-15: 1; the weight ratio of the pirimiphos-methyl to the hexaflumuron is 1: 20-20: 1.
2. the built fly-killing composition of claim 1, wherein: the weight ratio of the pirimiphos-methyl to the chlorfluazuron is 1: 5-10: 1; the weight ratio of the pirimiphos-methyl to the hexaflumuron is 1: 10-15: 1.
3. the built fly-killing composition of claim 1 or 2, characterized in that: the composition comprises, by weight, 10-50% of pirimiphos-methyl and chlorfluazuron or hexaflumuron, 1-15% of an emulsifier, 1-10% of a penetrant and the balance of a solvent.
4. The built fly-killing composition of claim 3, wherein: the emulsifier is selected from two or three of styryl phenol polyoxyethylene ether, phenyl phenol polyoxyethylene ether phosphate, castor oil polyoxyethylene ether phosphate, calcium alkyl benzene sulfonate, alkylphenol polyoxyethylene ether, phenethyl phenol formaldehyde resin polyoxyethylene ether, nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, alkylaryl polyoxypropylene polyoxyethylene ether, alkylaryl polyoxyethylene ether, tween series and span series; the penetrant is selected from: one or two of sulfonated dioctyl sodium sulfosuccinate, sulfonated di-sec-octyl succinate sodium salt, ricinoleic acid sodium sulfate, octanol polyoxyethylene ether and sodium alkyl benzene sulfonate; the solvent is selected from: one or two of dimethyl sulfoxide, N-dimethylformamide, N-dimethylacetamide, N-methylpyrrolidone, cyclohexanone, benzyl alcohol and N-butanol.
5. The use of the built fly-killing composition according to any one of claims 1 to 4 for controlling flies in breeding places of flies.
6. Use according to claim 5, characterized in that the breeding ground comprises a garbage heap, a manure pit or a farm, and the flies comprise fly larvae and/or adults.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811578949.4A CN111345313A (en) | 2018-12-24 | 2018-12-24 | Fly-killing composition for controlling fly breeding place and application thereof |
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| CN201811578949.4A CN111345313A (en) | 2018-12-24 | 2018-12-24 | Fly-killing composition for controlling fly breeding place and application thereof |
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| CN201811578949.4A Pending CN111345313A (en) | 2018-12-24 | 2018-12-24 | Fly-killing composition for controlling fly breeding place and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115211434A (en) * | 2021-04-19 | 2022-10-21 | 江苏扬农化工股份有限公司 | Fly killing composition containing lufenuron and trifluoropyrimidine and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5823871B2 (en) * | 1978-02-06 | 1983-05-18 | 石原産業株式会社 | N↓-pyridyloxyphenylurea compounds and insecticides containing them |
| US4780457A (en) * | 1985-09-05 | 1988-10-25 | Nihon Tokushi Noyaku Seizo K.K. | Insecticidal composition for agricultural and horticultural use |
| CN101018482A (en) * | 2004-07-20 | 2007-08-15 | 拜尔农作物科学股份公司 | Insecticidal agents based on selected insecticides and safeners |
| CN103798282A (en) * | 2014-03-07 | 2014-05-21 | 南通联农农药制剂研究开发有限公司 | Insecticide composition containing pirimiphos-methyl and micro-capsule suspending agent thereof |
-
2018
- 2018-12-24 CN CN201811578949.4A patent/CN111345313A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5823871B2 (en) * | 1978-02-06 | 1983-05-18 | 石原産業株式会社 | N↓-pyridyloxyphenylurea compounds and insecticides containing them |
| US4780457A (en) * | 1985-09-05 | 1988-10-25 | Nihon Tokushi Noyaku Seizo K.K. | Insecticidal composition for agricultural and horticultural use |
| CN101018482A (en) * | 2004-07-20 | 2007-08-15 | 拜尔农作物科学股份公司 | Insecticidal agents based on selected insecticides and safeners |
| CN103798282A (en) * | 2014-03-07 | 2014-05-21 | 南通联农农药制剂研究开发有限公司 | Insecticide composition containing pirimiphos-methyl and micro-capsule suspending agent thereof |
Non-Patent Citations (1)
| Title |
|---|
| 丁金凤等: "双委夜蛾幼虫对不同类别杀虫剂的敏感性及中毒症状 ", 《农药学学报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115211434A (en) * | 2021-04-19 | 2022-10-21 | 江苏扬农化工股份有限公司 | Fly killing composition containing lufenuron and trifluoropyrimidine and application thereof |
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Effective date of registration: 20201125 Address after: 225009 No. 39, Wenfeng Road, Yangzhou, Jiangsu Applicant after: JIANGSU YANGNONG CHEMICAL Co.,Ltd. Applicant after: JIANGSU YOUJIA PLANT PROTECTION Co.,Ltd. Address before: 225009 No. 39, Wenfeng Road, Yangzhou, Jiangsu Applicant before: JIANGSU YANGNONG CHEMICAL Co.,Ltd. |
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Application publication date: 20200630 |