CN111337753A - Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition - Google Patents

Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition Download PDF

Info

Publication number
CN111337753A
CN111337753A CN202010180116.3A CN202010180116A CN111337753A CN 111337753 A CN111337753 A CN 111337753A CN 202010180116 A CN202010180116 A CN 202010180116A CN 111337753 A CN111337753 A CN 111337753A
Authority
CN
China
Prior art keywords
titanium concentrate
calcium magnesium
magnesium titanium
water content
calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202010180116.3A
Other languages
Chinese (zh)
Other versions
CN111337753B (en
Inventor
杨彪
郭祥
代忠仿
成宬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunming University of Science and Technology
Original Assignee
Kunming University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunming University of Science and Technology filed Critical Kunming University of Science and Technology
Priority to CN202010180116.3A priority Critical patent/CN111337753B/en
Publication of CN111337753A publication Critical patent/CN111337753A/en
Application granted granted Critical
Publication of CN111337753B publication Critical patent/CN111337753B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R27/00Arrangements for measuring resistance, reactance, impedance, or electric characteristics derived therefrom
    • G01R27/02Measuring real or complex resistance, reactance, impedance, or other two-pole characteristics derived therefrom, e.g. time constant
    • G01R27/26Measuring inductance or capacitance; Measuring quality factor, e.g. by using the resonance method; Measuring loss factor; Measuring dielectric constants ; Measuring impedance or related variables
    • G01R27/2617Measuring dielectric properties, e.g. constants
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K11/00Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00
    • G01K11/32Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using changes in transmittance, scattering or luminescence in optical fibres
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/28Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/44Sample treatment involving radiation, e.g. heat
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3554Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for determining moisture content

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention relates to a method for adjusting the dielectric constant of high-calcium magnesium titanium concentrate under the microwave heating condition, belonging to the technical field of microwave heating devices. According to the measured local water content and temperature, calculating dielectric coefficient values of different temperature measurement points of the heated high-calcium-magnesium-titanium concentrate, and combining a balanced water content model and an expected dielectric coefficient to further obtain water required by the high-calcium-magnesium-titanium concentrate to reach the expected dielectric coefficient value; the moisture of different parts of the high-calcium magnesium titanium concentrate is regulated, so that the aim of uniformly distributing the dielectric properties of the high-calcium magnesium titanium concentrate in the microwave heating process is fulfilled, and the temperature distribution uniformity is improved; meanwhile, the method can be used for improving the heating efficiency of the high-calcium magnesium titanium concentrate.

Description

Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition
Technical Field
The invention relates to a method for adjusting the dielectric constant of high-calcium magnesium titanium concentrate under the microwave heating condition, belonging to the technical field of microwave heating devices.
Background
In the microwave heating process, the temperature control of the heated material is very important, and the essential problem of controlling the temperature change of the material in a microwave field is to control the dielectric coefficient change of the material. Due to the fact that the distribution of the electromagnetic field in the microwave cavity is not uniform, the dielectric property of the material is anisotropic, and the temperature and the water content of the heated material are in a non-uniform distribution state.
Disclosure of Invention
The invention provides a method for adjusting the dielectric constant of high-calcium magnesium titanium concentrate under the microwave heating condition.
The technical scheme of the invention is as follows: a method for adjusting the dielectric constant of high-calcium magnesium titanium concentrate under the microwave heating condition comprises the following steps:
determining the initial water content of the high-calcium magnesium titanium concentrate;
calculating the water loss of the high-calcium magnesium titanium concentrate in real time in the microwave heating process;
calculating the dielectric coefficients of the heated high-calcium magnesium titanium concentrate at different temperature measuring points in real time according to the measured current water content and temperature of the high-calcium magnesium titanium concentrate and the relational expression between the dielectric coefficient of the high-calcium magnesium titanium concentrate and the temperature and the water content;
obtaining water required for the high-calcium magnesium titanium concentrate to reach the expected dielectric coefficient according to the balanced water content model and the expected dielectric coefficient of the high-calcium magnesium titanium concentrate;
and regulating the moisture of different parts of the high-calcium magnesium titanium concentrate according to the required moisture, so that the aim of uniformly distributing the dielectric properties of the high-calcium magnesium titanium concentrate in the microwave heating process is fulfilled, the temperature distribution uniformity is improved, and meanwhile, the method can be used for improving the heating efficiency of the high-calcium magnesium titanium concentrate.
Further, the initial water content of the high-calcium-magnesium titanium concentrate is determined by a weighing method, and the method comprises the following steps:
1.1, putting a certain mass of high-calcium magnesium titanium concentrate sample into a container with mass m, and weighing the sample to obtain the total weight mt
1.2, putting the container containing the sample into a microwave drying device for drying until the weight is constant, and recording the total weight of the container and the sample as m1
1.3 obtaining the initial water content of the sample
Figure BDA0002412218040000021
Further, during the microwave heating process, the water loss of the high-calcium magnesium titanium concentrate due to evaporation is as follows:
Figure BDA0002412218040000022
wherein: d represents the moisture diffusion rate; u. ofaIs the air humidity; u. ofcThe surface water content of the high calcium magnesium titanium concentrate is obtained; h ismThe mass transfer coefficient of the surface of the high-calcium magnesium titanium concentrate is obtained; n represents a unit vector vertical to the surface, u is the current water content of the high-calcium magnesium titanium concentrate, and the current water content u of the high-calcium magnesium titanium concentrate is the initial water content u at the initial stage1
Further, the surface quality transmission coefficient h of the high-calcium-magnesium titanium concentratemThe calculation formula is related to the evaporation rate of the surface moisture:
hm=mv/A×VH
wherein: a is the surface area of the high-calcium magnesium titanium concentrate; m isvDenotes the evaporation rate, mv=104s-1;VHIs the volume of water in the high calcium magnesium titanium concentrate.
Further, the relational expression between the dielectric coefficient of the high-calcium magnesium titanium concentrate, the temperature T and the water content u can be obtained by measuring the dielectric coefficient epsilon '-j epsilon' and the water content u in real time in an experiment of heating the high-calcium magnesium titanium concentrate at constant temperature under different temperatures T through multiple linear regression, and the form is as follows:
ε″=a1+a2u+a3T+a4u2+a5T2+a6uT
ε′=b1+b2u+b3T+b4u2+b5T2+b6T
wherein: u and T are the current water content and the temperature of the high-calcium magnesium titanium concentrate respectively, and the current water content u of the high-calcium magnesium titanium concentrate is the initial water content u at the initial stage1;a1…a6And b1…b6For the parameters obtained from the multiple linear regression experiment, j is the imaginary sign.
Further, according to the equilibrium water content model and the expected dielectric coefficient of the high-calcium-magnesium-titanium concentrate, the specific steps of obtaining the water required by the high-calcium-magnesium-titanium concentrate to reach the expected dielectric coefficient are as follows:
4.1, firstly obtaining a balanced moisture content model of the high-calcium-magnesium titanium concentrate, and setting an expected dielectric coefficient;
4.2, deducing the water content of the high-calcium magnesium titanium concentrate under a certain temperature condition when the dielectric coefficient is expected according to a relational expression between the expected dielectric coefficient of the high-calcium magnesium titanium concentrate and the temperature T and the water content u by combining the temperature of the current temperature measuring point and the expected dielectric coefficient;
4.3, obtaining the equilibrium moisture content by utilizing a equilibrium moisture content model according to the temperature, the air humidity and the water activity of the current temperature measuring point;
4.4, measuring the current water content, and comparing the current water content of the measuring point with the water content when the expected dielectric coefficient is reached to obtain a water content value to be added;
if the current water content is smaller than the equilibrium water content, indicating that the high-calcium magnesium titanium concentrate is in an outward adsorption state, adding the required water to a measured point of the high-calcium magnesium titanium concentrate;
and if the current water content is greater than the equilibrium water content, indicating that the high-calcium magnesium titanium concentrate is in an outward desorption state, adding more water than required to be added to a measured point of the high-calcium magnesium titanium concentrate.
Further, the equilibrium moisture content model of the high-calcium-magnesium titanium concentrate is obtained by experiments and comprises the following steps:
1) dividing a certain amount of high-calcium magnesium titanium concentrate experimental sample into N parts;
2) adding distilled water into the N parts of the high-calcium magnesium titanium concentrate to prepare an experimental sample with the water content gradient of 2%;
3) respectively putting N parts of high-calcium magnesium titanium concentrate into constant-temperature incubators at different temperatures for balancing for a period of time, and recording the air humidity in the incubators;
4) and when the recorded air humidity reaches the balance and does not change any more, measuring the water content of the high-calcium magnesium titanium concentrate at the moment to obtain the balance water content u of the high-calcium magnesium titanium concentratebMeasuring the water activity a by means of a water activity meterwAdopting SAS software to make nonlinear regression to obtain the equilibrium water content u of high-calcium magnesium titanium concentratebWith temperature T, air humidity uaWater activity awThe relationship of three parameters, in the form of
Figure BDA0002412218040000031
Wherein: c. C1,c2,c3,c4Is a dimensionless parameter obtained by nonlinear regression experiments.
Fig. 1 can be a device for measuring some parameters in a required method, wherein the device comprises an optical fiber radiation thermometer 1, an infrared moisture meter 2, a positive pressure gas flow nozzle 3, a heated medium high calcium magnesium titanium concentrate 4 and a microwave generating device 5; the microwave generating device 5 is provided with a fiber radiation thermodetector 1, an infrared moisture meter 2 and a positive pressure airflow nozzle 3;
the current water content u of the high-calcium magnesium titanium concentrate can be measured by an infrared moisture meter 2 arranged on a microwave generating device 5; the current temperature of the high-calcium magnesium titanium concentrate can be measured by the optical fiber radiation temperature measuring instrument 1, and the water content of different parts of the high-calcium magnesium titanium concentrate can be adjusted by the positive pressure airflow nozzle 3 according to the required water content.
The invention has the beneficial effects that:
the method calculates the water loss of the high-calcium magnesium titanium concentrate in real time in the microwave heating process; calculating the dielectric coefficient values of different temperature measurement points of the heated high-calcium-magnesium titanium concentrate according to the measured local water content and temperature, and further obtaining the water required by the high-calcium-magnesium titanium concentrate to reach the expected dielectric coefficient value by combining a balanced water content model and the expected dielectric coefficient;
the moisture of different parts of the high-calcium magnesium titanium concentrate is regulated, so that the aim of uniformly distributing the dielectric properties of the high-calcium magnesium titanium concentrate in the microwave heating process is fulfilled, and the temperature distribution uniformity is improved; meanwhile, the method can be used for improving the heating efficiency of the high-calcium magnesium titanium concentrate.
Drawings
Fig. 1 is a schematic perspective view of the present invention.
1. The device comprises an optical fiber radiation temperature measuring instrument, 2, an infrared moisture meter, 3, a positive pressure airflow nozzle, 4, high-calcium magnesium titanium concentrate 5 and a microwave generating device.
Detailed Description
Example 1: as shown in fig. 1, a method for adjusting the dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition includes:
determining the initial water content of the high-calcium magnesium titanium concentrate;
calculating the water loss of the high-calcium magnesium titanium concentrate in real time in the microwave heating process;
calculating the dielectric coefficients of the heated high-calcium magnesium titanium concentrate at different temperature measuring points in real time according to the measured current water content and temperature of the high-calcium magnesium titanium concentrate and the relational expression between the dielectric coefficient of the high-calcium magnesium titanium concentrate and the temperature and the water content;
obtaining water required for the high-calcium magnesium titanium concentrate to reach the expected dielectric coefficient according to the balanced water content model and the expected dielectric coefficient of the high-calcium magnesium titanium concentrate;
and regulating the moisture of different parts of the high-calcium magnesium titanium concentrate according to the required moisture, so that the aim of uniformly distributing the dielectric properties of the high-calcium magnesium titanium concentrate in the microwave heating process is fulfilled, the temperature distribution uniformity is improved, and meanwhile, the method can be used for improving the heating efficiency of the high-calcium magnesium titanium concentrate.
Further, the initial water content of the high-calcium-magnesium titanium concentrate is determined by a weighing method, and the method comprises the following steps:
1.1, putting a certain mass of high-calcium magnesium titanium concentrate sample into a container with mass m, and weighing the total weightmt
1.2, putting the container containing the sample into a microwave drying device for drying until the weight is constant, and recording the total weight of the container and the sample as m1
1.3 obtaining the initial water content of the sample
Figure BDA0002412218040000041
Further, during the microwave heating process, the water loss of the high-calcium magnesium titanium concentrate due to evaporation is as follows:
Figure BDA0002412218040000042
wherein: d represents the moisture diffusion rate; u. ofaIs the air humidity; u. ofcThe surface water content of the high calcium magnesium titanium concentrate is obtained; h ismThe mass transfer coefficient of the surface of the high-calcium magnesium titanium concentrate is obtained; n represents a unit vector vertical to the surface, u is the current water content of the high-calcium magnesium titanium concentrate, and the current water content u of the high-calcium magnesium titanium concentrate is the initial water content u at the initial stage1
Further, the surface quality transmission coefficient h of the high-calcium-magnesium titanium concentratemThe calculation formula is related to the evaporation rate of the surface moisture:
hm=mv/A×VH
wherein: a is the surface area of the high-calcium magnesium titanium concentrate; m isvDenotes the evaporation rate, mv=104s-1;VHIs the volume of water in the high calcium magnesium titanium concentrate.
Further, the relational expression between the dielectric coefficient of the high-calcium magnesium titanium concentrate, the temperature T and the water content u can be obtained by measuring the dielectric coefficient epsilon '-j epsilon' and the water content u in real time in an experiment of heating the high-calcium magnesium titanium concentrate at constant temperature under different temperatures T through multiple linear regression, and the form is as follows:
ε″=a1+a2u+a3T+a4u2+a5T2+a6uT
ε′=b1+b2u+b3T+b4u2+b5T2+b6T
wherein: u and T are the current water content and the temperature of the high-calcium magnesium titanium concentrate respectively, and the current water content u of the high-calcium magnesium titanium concentrate is the initial water content u at the initial stage1;a1…a6And b1…b6For the parameters obtained from the multiple linear regression experiment, j is the imaginary sign.
Further, according to the equilibrium water content model and the expected dielectric coefficient of the high-calcium-magnesium-titanium concentrate, the specific steps of obtaining the water required by the high-calcium-magnesium-titanium concentrate to reach the expected dielectric coefficient are as follows:
4.1, firstly obtaining a balanced moisture content model of the high-calcium-magnesium titanium concentrate, and setting an expected dielectric coefficient;
4.2, deducing the water content of the high-calcium magnesium titanium concentrate under a certain temperature condition when the dielectric coefficient is expected according to a relational expression between the expected dielectric coefficient of the high-calcium magnesium titanium concentrate and the temperature T and the water content u by combining the temperature of the current temperature measuring point and the expected dielectric coefficient;
4.3, obtaining the equilibrium moisture content by utilizing a equilibrium moisture content model according to the temperature, the air humidity and the water activity of the current temperature measuring point;
4.4, measuring the current water content, and comparing the current water content of the measuring point with the water content when the expected dielectric coefficient is reached to obtain a water content value to be added;
if the current water content is smaller than the equilibrium water content, indicating that the high-calcium magnesium titanium concentrate is in an outward adsorption state, adding the required water to a measured point of the high-calcium magnesium titanium concentrate;
and if the current water content is greater than the equilibrium water content, indicating that the high-calcium magnesium titanium concentrate is in an outward desorption state, adding more water than required to be added to a measured point of the high-calcium magnesium titanium concentrate.
Further, the equilibrium moisture content model of the high-calcium-magnesium titanium concentrate is obtained by experiments and comprises the following steps:
1) dividing a certain amount of high-calcium magnesium titanium concentrate experimental sample into N parts;
2) adding distilled water into the N parts of the high-calcium magnesium titanium concentrate to prepare an experimental sample with the water content gradient of 2%;
3) respectively putting N parts of high-calcium magnesium titanium concentrate into constant-temperature incubators at different temperatures for balancing for a period of time, and recording the air humidity in the incubators;
4) and when the recorded air humidity reaches the balance and does not change any more, measuring the water content of the high-calcium magnesium titanium concentrate at the moment to obtain the balance water content u of the high-calcium magnesium titanium concentratebMeasuring the water activity a by means of a water activity meterwAdopting SAS software to make nonlinear regression to obtain the equilibrium water content u of high-calcium magnesium titanium concentratebWith temperature T, air humidity uaWater activity awThe relationship of three parameters, in the form of
Figure BDA0002412218040000061
Wherein: c. C1,c2,c3,c4Is a dimensionless parameter obtained by nonlinear regression experiments.
As a further illustration of the present invention, fig. 1 may be a device for measuring some parameters in a required method, wherein the device includes an optical fiber radiation thermometer 1, an infrared moisture meter 2, a positive pressure gas flow nozzle 3, a heated medium high calcium magnesium titanium concentrate 4, and a microwave generating device 5; the microwave generating device 5 is provided with a fiber radiation thermodetector 1, an infrared moisture meter 2 and a positive pressure airflow nozzle 3;
the current water content u of the high-calcium magnesium titanium concentrate can be measured by an infrared moisture meter 2 arranged on a microwave generating device 5; the current temperature of the high-calcium magnesium titanium concentrate can be measured by the optical fiber radiation temperature measuring instrument 1, and the water content of different parts of the high-calcium magnesium titanium concentrate can be adjusted by the positive pressure airflow nozzle 3 according to the required water content.
The structure of the device can comprise a microwave oven, wherein 5 optical fiber radiation temperature measuring probes, 5 infrared moisture meters and 5 positive pressure airflow nozzles are respectively arranged in the microwave oven.
In the microwave heating process, the problems of uneven electric field distribution and uneven material temperature distribution caused by anisotropic dielectric properties of the high-calcium magnesium titanium concentrate are solved.
According to the method, the water loss of the high-calcium-magnesium-titanium concentrate is calculated in real time, the dielectric coefficient values of the heated high-calcium-magnesium-titanium concentrate at different temperature measuring points are further calculated according to the local water content measured by the 5 infrared moisture meters and the temperature measured by the optical fiber radiation temperature measuring meter, and the water required by the high-calcium-magnesium-titanium concentrate to reach the expected dielectric coefficient value is obtained by combining the equilibrium water content model and the expected dielectric coefficient. 5 positive pressure airflow nozzles are adopted to adjust the moisture of different parts of the high-calcium magnesium titanium concentrate, so that the aim of uniformly distributing the dielectric coefficients of the high-calcium magnesium titanium concentrate in the microwave heating process is fulfilled, and the uniformity of temperature distribution is improved. Meanwhile, the method can be used for improving the heating efficiency of the high-calcium magnesium titanium concentrate.
While the present invention has been described in detail with reference to the embodiments shown in the drawings, the present invention is not limited to the embodiments, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art.

Claims (7)

1. A method for adjusting the dielectric constant of high-calcium magnesium titanium concentrate under the microwave heating condition is characterized by comprising the following steps:
determining the initial water content of the high-calcium magnesium titanium concentrate;
calculating the water loss of the high-calcium magnesium titanium concentrate in real time in the microwave heating process;
calculating the dielectric coefficients of the heated high-calcium magnesium titanium concentrate at different temperature measuring points in real time according to the measured current water content and temperature of the high-calcium magnesium titanium concentrate and the relational expression between the dielectric coefficient of the high-calcium magnesium titanium concentrate and the temperature and the water content;
obtaining water required for the high-calcium magnesium titanium concentrate to reach the expected dielectric coefficient according to the balanced water content model and the expected dielectric coefficient of the high-calcium magnesium titanium concentrate;
and regulating the moisture of different parts of the high-calcium magnesium titanium concentrate according to the required moisture, thereby achieving the purpose that the dielectric properties of the high-calcium magnesium titanium concentrate are uniformly distributed in the microwave heating process and further improving the temperature distribution uniformity.
2. The method for adjusting the dielectric constant of the high-calcium magnesium titanium concentrate under the microwave heating condition according to claim 1, wherein the method comprises the following steps: the initial water content of the high-calcium-magnesium titanium concentrate is determined by a weighing method, and the method comprises the following steps:
1.1, putting a certain mass of high-calcium magnesium titanium concentrate sample into a container with mass m, and weighing the sample to obtain the total weight mt
1.2, putting the container containing the sample into a microwave drying device for drying until the weight is constant, and recording the total weight of the container and the sample as m1
1.3 obtaining the initial water content of the sample
Figure FDA0002412218030000011
3. The method for adjusting the dielectric constant of the high-calcium magnesium titanium concentrate under the microwave heating condition according to claim 1, wherein the method comprises the following steps: in the microwave heating process, the water loss of the high-calcium magnesium titanium concentrate due to evaporation is as follows:
Figure FDA0002412218030000012
wherein: d represents the moisture diffusion rate; u. ofaIs the air humidity; u. ofcThe surface water content of the high calcium magnesium titanium concentrate is obtained; h ismThe mass transfer coefficient of the surface of the high-calcium magnesium titanium concentrate is obtained; n represents a unit vector vertical to the surface, u is the current water content of the high-calcium magnesium titanium concentrate, and the current water content u of the high-calcium magnesium titanium concentrate is the initial water content u at the initial stage1
4. The method for adjusting the dielectric constant of the high-calcium magnesium titanium concentrate under the microwave heating condition according to claim 3, wherein the method comprises the following steps: the surface quality transmission coefficient h of the high-calcium magnesium titanium concentratemThe calculation formula is related to the evaporation rate of the surface moisture:
hm=mv/A×VH
wherein: a is the surface area of the high-calcium magnesium titanium concentrate; m isvDenotes the evaporation rate, mv=104s-1;VHIs the volume of water in the high calcium magnesium titanium concentrate.
5. The method for adjusting the dielectric constant of the high-calcium magnesium titanium concentrate under the microwave heating condition according to claim 1, wherein the method comprises the following steps: the relational expression between the dielectric coefficient of the high-calcium magnesium titanium concentrate, the temperature T and the water content u can be obtained by measuring the dielectric coefficient epsilon ∈' -j ∈ ″ and the water content u in real time in a constant-temperature heating experiment of the high-calcium magnesium titanium concentrate at different temperatures T through multiple linear regression, and the form is as follows:
ε″=a1+a2u+a3T+a4u2+a5T2+a6uT
ε′=b1+b2u+b3T+b4u2+b5T2+b6T
wherein: u and T are the current water content and the temperature of the high-calcium magnesium titanium concentrate respectively, and the current water content u of the high-calcium magnesium titanium concentrate is the initial water content u at the initial stage1;a1…a6And b1…b6For the parameters obtained from the multiple linear regression experiment, j is the imaginary sign.
6. The method for adjusting the dielectric constant of the high-calcium magnesium titanium concentrate under the microwave heating condition according to claim 1, wherein the method comprises the following steps: the specific steps of obtaining the water required for the high-calcium-magnesium titanium concentrate to reach the expected dielectric coefficient according to the equilibrium water content model and the expected dielectric coefficient of the high-calcium-magnesium titanium concentrate are as follows:
4.1, firstly obtaining a balanced moisture content model of the high-calcium-magnesium titanium concentrate, and setting an expected dielectric coefficient;
4.2, deducing the water content of the high-calcium magnesium titanium concentrate under a certain temperature condition when the dielectric coefficient is expected according to a relational expression between the expected dielectric coefficient of the high-calcium magnesium titanium concentrate and the temperature T and the water content u by combining the temperature of the current temperature measuring point and the expected dielectric coefficient;
4.3, obtaining the equilibrium moisture content by utilizing a equilibrium moisture content model according to the temperature, the air humidity and the water activity of the current temperature measuring point;
4.4, measuring the current water content, and comparing the current water content of the measuring point with the water content when the expected dielectric coefficient is reached to obtain a water content value to be added;
if the current water content is smaller than the equilibrium water content, indicating that the high-calcium magnesium titanium concentrate is in an outward adsorption state, adding the required water to a measured point of the high-calcium magnesium titanium concentrate;
and if the current water content is greater than the equilibrium water content, indicating that the high-calcium magnesium titanium concentrate is in an outward desorption state, adding more water than required to be added to a measured point of the high-calcium magnesium titanium concentrate.
7. The method for adjusting the dielectric constant of the high-calcium magnesium titanium concentrate under the microwave heating condition according to claim 1 or 6, wherein: the equilibrium moisture content model of the high-calcium magnesium titanium concentrate is obtained by experiments and comprises the following steps:
1) dividing a certain amount of high-calcium magnesium titanium concentrate experimental sample into N parts;
2) adding distilled water into the N parts of the high-calcium magnesium titanium concentrate to prepare an experimental sample with the water content gradient of 2%;
3) respectively putting N parts of high-calcium magnesium titanium concentrate into constant-temperature incubators at different temperatures for balancing for a period of time, and recording the air humidity in the incubators;
4) and when the recorded air humidity reaches the balance and does not change any more, measuring the water content of the high-calcium magnesium titanium concentrate at the moment to obtain the balance water content u of the high-calcium magnesium titanium concentratebMeasuring the water activity a by means of a water activity meterwAdopting SAS software to make nonlinear regression to obtain the equilibrium water content u of high-calcium magnesium titanium concentratebWith temperature T, air humidity uaWater activity awThe relationship of three parameters, in the form of
Figure FDA0002412218030000031
Wherein: c. C1,c2,c3,c4Is a dimensionless parameter obtained by nonlinear regression experiments.
CN202010180116.3A 2020-03-16 2020-03-16 Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition Expired - Fee Related CN111337753B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010180116.3A CN111337753B (en) 2020-03-16 2020-03-16 Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010180116.3A CN111337753B (en) 2020-03-16 2020-03-16 Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition

Publications (2)

Publication Number Publication Date
CN111337753A true CN111337753A (en) 2020-06-26
CN111337753B CN111337753B (en) 2021-07-30

Family

ID=71182379

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010180116.3A Expired - Fee Related CN111337753B (en) 2020-03-16 2020-03-16 Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition

Country Status (1)

Country Link
CN (1) CN111337753B (en)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4566804A (en) * 1982-12-16 1986-01-28 Cem Corporation Apparatuses, processes and articles for controllably heating and drying materials by microwave radiation
CN87101733A (en) * 1986-03-03 1987-09-30 阿尔法斯塔公司 A kind of method of stability heating
EP0466362A1 (en) * 1990-06-29 1992-01-15 Matsui Manufacturing Co., Ltd. Method and apparatus for drying powdered or granular materials
CN102338547A (en) * 2010-07-23 2012-02-01 林国辉 Microwave drier and microwave drying method
US20120088950A1 (en) * 2008-12-18 2012-04-12 University Of Nottingham Microwave processing of feedstock, such as exfoliating vermiculite and other minerals, and treating contaminated materials
CN103234339A (en) * 2013-05-02 2013-08-07 昆明理工大学 Device for ilmenite concentrate microwave drying and application method thereof
CN106839751A (en) * 2017-03-29 2017-06-13 江南大学 A kind of microwave drying control system based on dielectric property dynamic change
CN106947588A (en) * 2017-04-10 2017-07-14 金太阳粮油股份有限公司 A kind of method that dielectric drying processing improves cold press vegetable seed oil yield and its oil quality
CN109926037A (en) * 2017-12-15 2019-06-25 中国科学院大连化学物理研究所 One kind preparing TiO by titanium-based binder2The method of preformed catalyst carrier
CN209139469U (en) * 2018-09-20 2019-07-23 杭州臻尚环境科技有限公司 A kind of screening of soil and microwave heating appts
CN110609045A (en) * 2019-10-26 2019-12-24 河南极速环保有限公司 Medical waste water content detection device and method by utilizing microwave heating technology

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4566804A (en) * 1982-12-16 1986-01-28 Cem Corporation Apparatuses, processes and articles for controllably heating and drying materials by microwave radiation
CN87101733A (en) * 1986-03-03 1987-09-30 阿尔法斯塔公司 A kind of method of stability heating
EP0466362A1 (en) * 1990-06-29 1992-01-15 Matsui Manufacturing Co., Ltd. Method and apparatus for drying powdered or granular materials
US20120088950A1 (en) * 2008-12-18 2012-04-12 University Of Nottingham Microwave processing of feedstock, such as exfoliating vermiculite and other minerals, and treating contaminated materials
CN102338547A (en) * 2010-07-23 2012-02-01 林国辉 Microwave drier and microwave drying method
CN103234339A (en) * 2013-05-02 2013-08-07 昆明理工大学 Device for ilmenite concentrate microwave drying and application method thereof
CN106839751A (en) * 2017-03-29 2017-06-13 江南大学 A kind of microwave drying control system based on dielectric property dynamic change
CN106947588A (en) * 2017-04-10 2017-07-14 金太阳粮油股份有限公司 A kind of method that dielectric drying processing improves cold press vegetable seed oil yield and its oil quality
CN109926037A (en) * 2017-12-15 2019-06-25 中国科学院大连化学物理研究所 One kind preparing TiO by titanium-based binder2The method of preformed catalyst carrier
CN209139469U (en) * 2018-09-20 2019-07-23 杭州臻尚环境科技有限公司 A kind of screening of soil and microwave heating appts
CN110609045A (en) * 2019-10-26 2019-12-24 河南极速环保有限公司 Medical waste water content detection device and method by utilizing microwave heating technology

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEN-HUI LIU 等: "Effect of temperature on dielectric property and microwave heating behavior of low grade Panzhihua ilmenite ore", 《SCIENCE DIRECT》 *
孙俊 等: "基于介电特性与回归算法的玉米叶片含水率无损检测", 《农业机械学报》 *
杜婉: "微波加热铁精矿试验建模及温度控制器设计", 《自动化仪表》 *

Also Published As

Publication number Publication date
CN111337753B (en) 2021-07-30

Similar Documents

Publication Publication Date Title
Ferrari et al. Drying kinetics for a single droplet of skim-milk
CN102439414A (en) Condensation testing device and condensation testing method
Courtois et al. Modelling of drying in order to improve processing quality of maize
CN111337753B (en) Method for adjusting dielectric constant of high-calcium magnesium titanium concentrate under microwave heating condition
Culpin The viscosity of liquid indium and liquid tin
CN108050773A (en) A kind of drying device that can measure material color and luster and metamorphosis in real time
CN108917309A (en) A kind of multifunctional electro-heating circulation convection oven
CN108917310A (en) A kind of use for laboratory Multifunctional oven
CN209327257U (en) A kind of peanut pod water transport variation test device
CN110180058A (en) A kind of method and its system that Breathing Suppotion device temperature is adjusted
CN108889344A (en) A kind of multifunctional electro-heating convection oven
CN108518972A (en) A kind of baking room dry materials course control method for use calculated based on accumulated temperature
Bulgakov et al. Intensification of rapeseed drying process through the use of infrared emitters.
RU2352934C2 (en) Method for definition of thermal characteristics of dispersed food materials
CN110096083B (en) Temperature and humidity precise control device
JP2009092446A (en) Method and device for adjusting temperature/humidity in humidity conditioning performance measuring device
Abdiche et al. Humidity control tool for neonatal incubator
Swinbank A sensitive vapour pressure recorder
Can An analytical method for determining the temperature dependent moisture diffusivities of pumpkin seeds during drying process
CN102072921B (en) Method for detecting condensation status of coating
AU766454B2 (en) Humidity probe
Edney The construction and calibration of an electrical hygrometer suitable for microclimatic measurements
Swann VI. On the specific heats of air and carbon dioxide at atmospheric pressure by the continuous electric method at 20˚ C. and 100˚ C
CN216350222U (en) A ageing oven and system for determining natural rubber plasticity retention rate
CN109433294A (en) A kind of small-size multifunction experiment porch

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20210730

CF01 Termination of patent right due to non-payment of annual fee