CN111318677B - Stainless steel mold casting covering slag - Google Patents

Stainless steel mold casting covering slag Download PDF

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CN111318677B
CN111318677B CN201811521731.5A CN201811521731A CN111318677B CN 111318677 B CN111318677 B CN 111318677B CN 201811521731 A CN201811521731 A CN 201811521731A CN 111318677 B CN111318677 B CN 111318677B
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parts
fly ash
stainless steel
oxide
slag
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CN111318677A (en
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曾辉
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Hongjiang Sanxing Metallurgical Charge Co ltd
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Hongjiang Sanxing Metallurgical Charge Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/18Measures for using chemical processes for influencing the surface composition of castings, e.g. for increasing resistance to acid attack

Abstract

The invention provides stainless steel die casting covering slag, and belongs to the technical field of metallurgy. The stainless steel die-casting covering slag is prepared from the following raw materials: fly ash, argil, borax, glass slag, hollow ceramic microspheres, pitchstone, perlite, basalt, iron oxide, aluminum oxide and hydrated lime. The stainless steel die casting protective slag prepared by the invention does not need to add a heating agent and a heat preservation agent, can improve the surface quality of steel ingots and the feeding quality of ingot heads, thereby reducing the head cutting rate and improving the yield.

Description

Stainless steel mold casting covering slag
Technical Field
The invention relates to the technical field of metallurgy, in particular to stainless steel die-casting covering slag.
Background
Because the stainless steel contains chromium, titanium and other easily-oxidized elements, the molten stainless steel has the characteristics of easy oxidation, high viscosity, poor fluidity, low melting point and the like, and is the most difficult steel to cast in the die casting, the heating agent and the heat insulating agent are required to be separately added when the common stainless steel die casting covering slag is used at present, so that the processing technology is complex, the cost is high, the practical performance of the covering slag is single, and if the covering slag, the heating agent and the heat insulating agent are not uniformly mixed, the protection effect is easily caused, and the use effect is poor.
Disclosure of Invention
In order to solve the technical problems, the invention provides the stainless steel die-casting covering slag, which is prepared by taking fly ash as a main raw material, enabling the fly ash to be in a spherical shape and a spongy shape, shrinking into liquid drops under the action of surface tension after melting, cooling to form beads, and improving the heat insulation performance and the spreadability of the covering slag, wherein the fly ash is good in fluidity and provided with a plurality of air holes inside, and meanwhile, the stainless steel die-casting covering slag is beneficial to changing factory wastes into valuables and protecting the environment.
The invention provides stainless steel die casting covering slag which is prepared from the following raw materials: fly ash, argil, borax, glass slag, hollow ceramic microspheres, pitchstone, perlite, basalt, iron oxide, aluminum oxide and hydrated lime.
As a further improvement of the invention, the health-care food is prepared from the following raw materials in parts by weight: 60-80 parts of fly ash, 12-20 parts of argil, 15-25 parts of borax, 10-16 parts of glass slag, 5-13 parts of hollow ceramic microspheres, 12-18 parts of pitchstone, 10-16 parts of perlite, 7-14 parts of basalt, 5-12 parts of iron oxide, 10-15 parts of aluminum oxide and 5-10 parts of slaked lime.
As a further improvement of the invention, the health-care food is prepared from the following raw materials in parts by weight: 65-75 parts of fly ash, 15-18 parts of argil, 17-23 parts of borax, 12-15 parts of glass slag, 7-11 parts of hollow ceramic microspheres, 13-16 parts of pitchstone, 12-15 parts of perlite, 8-12 parts of basalt, 6-10 parts of iron oxide, 11-14 parts of aluminum oxide and 6-8 parts of slaked lime.
As a further improvement of the invention, the health-care food is prepared from the following raw materials in parts by weight: 70 parts of fly ash, 16 parts of argil, 20 parts of borax, 14 parts of glass slag, 9 parts of hollow ceramic microspheres, 14 parts of pitchstone, 13 parts of perlite, 10 parts of basalt, 8 parts of ferric oxide, 12 parts of aluminum oxide and 7 parts of hydrated lime.
As a further improvement of the invention, the health-care food is prepared from the following raw materials in parts by weight: 72 parts of fly ash, 17 parts of argil, 21 parts of borax, 13 parts of glass slag, 10 parts of hollow ceramic microspheres, 15 parts of pitchstone, 14 parts of perlite, 11 parts of basalt, 9 parts of ferric oxide, 13 parts of aluminum oxide and 7 parts of hydrated lime.
As a further improvement of the invention, the fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
As a further improvement of the invention, the density of the fly ash is 1520-1980g/cm3The bulk volume weight is 475-3
As a further improvement of the invention, expanded graphite is also added.
As a further improvement of the invention, the content of the expanded graphite is 12.5-15.7% by mass.
The invention has the following beneficial effects:
1. the main raw material of the invention is that the fly ash particles are more spherical and spongy, and after being melted, the fly ash particles are contracted into liquid drops under the action of surface tension, and the liquid drops are cooled to form beads, so that the fluidity is good, and a plurality of air holes are formed in the fly ash particles, thereby improving the heat insulation performance and the spreadability of the casting powder, and being beneficial to changing factory wastes into valuables and protecting the environment;
2. the added hollow ceramic microspheres have excellent fluidity, can reduce the viscosity of the casting powder, increase the fluidity and the heat-insulating property, have stable chemical properties and are not easy to decompose at high temperature;
3. the pitchstone, the perlite and the basalt added in the invention have the excellent performances of light weight, heat preservation, heat insulation and fire prevention, and also have the advantages of no combustion, high strength, low water absorption, good blending property and long service life, the carbon content is low, the density is low, the additive floats on the top of a liquid slag layer, does not directly contact molten steel, and does not cause recarburization of the molten steel;
4. the added expanded graphite is expanded at high temperature, so that the spreadability and heat preservation of the covering slag are improved;
5. the stainless steel die casting protective slag prepared by the invention does not need to add a heating agent and a heat preservation agent, can improve the surface quality of steel ingots and the feeding quality of ingot heads, thereby reducing the head cutting rate and improving the yield.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is obvious that the embodiments described are only some representative embodiments of the present invention, rather than all embodiments, and all other embodiments obtained by a person skilled in the art without creative efforts belong to the protection scope of the present invention.
Example 1
The raw materials comprise the following components in parts by weight: 60 parts of fly ash, 12 parts of argil, 15 parts of borax, 10 parts of glass slag, 5 parts of hollow ceramic microspheres, 12 parts of pitchstone, 10 parts of perlite, 7 parts of basalt, 5 parts of iron oxide, 10 parts of aluminum oxide and 5 parts of hydrated lime.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1520g/cm3Bulk volume weight of 475g/cm3
Example 2
The raw materials comprise the following components in parts by weight: 80 parts of fly ash, 20 parts of argil, 25 parts of borax, 16 parts of glass slag, 13 parts of hollow ceramic microspheres, 18 parts of pitchstone, 16 parts of perlite, 14 parts of basalt, 12 parts of ferric oxide, 15 parts of aluminum oxide and 10 parts of hydrated lime.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1980g/cm3The bulk volume weight is 985g/cm3
Example 3
The raw materials comprise the following components in parts by weight: 65 parts of fly ash, 15 parts of argil, 17 parts of borax, 12 parts of glass slag, 7 parts of hollow ceramic microspheres, 13 parts of pitchstone, 12 parts of perlite, 8 parts of basalt, 6 parts of iron oxide, 11 parts of aluminum oxide and 6 parts of hydrated lime.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1630g/cm3The bulk volume weight is 543g/cm3
Example 4
The raw materials comprise the following components in parts by weight: 75 parts of fly ash, 18 parts of argil, 23 parts of borax, 15 parts of glass slag, 11 parts of hollow ceramic microspheres, 16 parts of pitchstone, 15 parts of perlite, 12 parts of basalt, 10 parts of iron oxide, 14 parts of aluminum oxide and 8 parts of hydrated lime.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1850g/cm3Bulk volume weight of 894g/cm3
Example 5
The raw materials comprise the following components in parts by weight: 70 parts of fly ash, 16 parts of argil, 20 parts of borax, 14 parts of glass slag, 9 parts of hollow ceramic microspheres, 14 parts of pitchstone, 13 parts of perlite, 10 parts of basalt, 8 parts of ferric oxide, 12 parts of aluminum oxide and 7 parts of hydrated lime.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1670g/cm3Bulk volume weight of 652g/cm3
Example 6
The raw materials comprise the following components in parts by weight: 72 parts of fly ash, 17 parts of argil, 21 parts of borax, 13 parts of glass slag, 10 parts of hollow ceramic microspheres, 15 parts of pitchstone, 14 parts of perlite, 11 parts of basalt, 9 parts of ferric oxide, 13 parts of aluminum oxide and 7 parts of hydrated lime.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1775g/cm3Bulk volume weight of 751g/cm3
Example 7
The raw materials comprise the following components in parts by weight: 72 parts of fly ash, 17 parts of argil, 21 parts of borax, 13 parts of glass slag, 10 parts of hollow ceramic microspheres, 15 parts of pitchstone, 14 parts of perlite, 11 parts of basalt, 9 parts of ferric oxide, 13 parts of aluminum oxide and 7 parts of hydrated lime.
Expanded graphite is also added, and the mass percent of the expanded graphite is 12.5%.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1702g/cm3The bulk volume weight is 795g/cm3
Example 8
The raw materials comprise the following components in parts by weight: 72 parts of fly ash, 17 parts of argil, 21 parts of borax, 13 parts of glass slag, 10 parts of hollow ceramic microspheres, 15 parts of pitchstone, 14 parts of perlite, 11 parts of basalt, 9 parts of ferric oxide, 13 parts of aluminum oxide and 7 parts of hydrated lime.
And expanded graphite is also added, and the mass percent of the expanded graphite is 15.7%.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1836g/cm3Bulk volume weight of 824g/cm3
Example 9
The raw materials comprise the following components in parts by weight: 70 parts of fly ash, 16 parts of argil, 20 parts of borax, 14 parts of glass slag, 9 parts of hollow ceramic microspheres, 14 parts of pitchstone, 13 parts of perlite, 10 parts of basalt, 8 parts of ferric oxide, 12 parts of aluminum oxide and 7 parts of hydrated lime.
Expanded graphite is also added, and the mass percent of the expanded graphite is 13.6%.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1744g/cm3Root of Chinese pineThe bulk density is 769g/cm3
Example 10
The raw materials comprise the following components in parts by weight: 70 parts of fly ash, 16 parts of argil, 20 parts of borax, 14 parts of glass slag, 9 parts of hollow ceramic microspheres, 14 parts of pitchstone, 13 parts of perlite, 10 parts of basalt, 8 parts of ferric oxide, 12 parts of aluminum oxide and 7 parts of hydrated lime.
Expanded graphite is also added, and the mass percent of the expanded graphite is 14.1%.
The fly ash comprises silicate, quartz sand, sulfate, calcium oxide, magnesium oxide, iron oxide and aluminum oxide.
The density of the fly ash is 1805g/cm3Bulk volume weight of 801g/cm3
Test example 1
The stainless steel mold casting powder of examples 1 to 10 of the present invention was subjected to physical property tests, and the results are shown in Table 1.
TABLE 1
Figure BDA0001903372800000041
Figure BDA0001903372800000051
Compared with the prior art, the main raw material of the invention is the fly ash particles which are mostly spherical and spongy, and the fly ash particles are contracted into liquid drops under the action of surface tension after being melted and cooled to form beads, so that the fluidity is good, a plurality of air holes are formed in the fly ash particles, the heat insulation performance and the spreadability of the casting powder are improved, and the fly ash protective agent is beneficial to changing factory wastes into valuables and protecting the environment; the added hollow ceramic microspheres have excellent fluidity, can reduce the viscosity of the casting powder, increase the fluidity and the heat-insulating property, have stable chemical properties and are not easy to decompose at high temperature; the pitchstone, the perlite and the basalt added in the invention have the excellent performances of light weight, heat preservation, heat insulation and fire prevention, and also have the advantages of no combustion, high strength, low water absorption, good blending property and long service life, the carbon content is low, the density is low, the additive floats on the top of a liquid slag layer, does not directly contact molten steel, and does not cause recarburization of the molten steel; the added expanded graphite is expanded at high temperature, so that the spreadability and heat preservation of the covering slag are improved; the stainless steel die casting protective slag prepared by the invention does not need to add a heating agent and a heat preservation agent, can improve the surface quality of steel ingots and the feeding quality of ingot heads, thereby reducing the head cutting rate and improving the yield.
Various modifications may be made to the above without departing from the spirit and scope of the invention as defined by the appended claims. The scope of the invention is therefore intended to be limited not by the above description, but rather by the scope of the appended claims.

Claims (7)

1. The stainless steel die-casting covering slag is characterized by being prepared from the following raw materials: fly ash, argil, borax, glass slag, hollow ceramic microbeads, pitchstone, perlite, basalt, iron oxide, aluminum oxide and hydrated lime;
the weight portions of the raw materials are as follows: 60-80 parts of fly ash, 12-20 parts of argil, 15-25 parts of borax, 10-16 parts of glass slag, 5-13 parts of hollow ceramic microspheres, 12-18 parts of pitchstone, 10-16 parts of perlite, 7-14 parts of basalt, 5-12 parts of iron oxide, 10-15 parts of aluminum oxide and 5-10 parts of slaked lime;
the density of the fly ash is 1520-1980g/cm3, and the bulk volume weight is 475-985g/cm3
2. The stainless steel die-casting covering slag according to claim 1, which is prepared from the following raw materials in parts by weight: 65-75 parts of fly ash, 15-18 parts of argil, 17-23 parts of borax, 12-15 parts of glass slag, 7-11 parts of hollow ceramic microspheres, 13-16 parts of pitchstone, 12-15 parts of perlite, 8-12 parts of basalt, 6-10 parts of iron oxide, 11-14 parts of aluminum oxide and 6-8 parts of slaked lime.
3. The stainless steel die-casting covering slag according to claim 2, which is prepared from the following raw materials in parts by weight: 70 parts of fly ash, 16 parts of argil, 20 parts of borax, 14 parts of glass slag, 9 parts of hollow ceramic microspheres, 14 parts of pitchstone, 13 parts of perlite, 10 parts of basalt, 8 parts of ferric oxide, 12 parts of aluminum oxide and 7 parts of hydrated lime.
4. The stainless steel die-casting covering slag according to claim 2, which is prepared from the following raw materials in parts by weight: 72 parts of fly ash, 17 parts of argil, 21 parts of borax, 13 parts of glass slag, 10 parts of hollow ceramic microspheres, 15 parts of pitchstone, 14 parts of perlite, 11 parts of basalt, 9 parts of ferric oxide, 13 parts of aluminum oxide and 7 parts of hydrated lime.
5. The stainless steel mold casting powder of claim 1, wherein the fly ash comprises silicates, quartz sand, sulfates, calcium oxide, magnesium oxide, iron oxide, and aluminum oxide.
6. The stainless steel mold casting powder according to claim 1, wherein expanded graphite is further added.
7. The stainless steel mold casting powder according to claim 6, wherein the expanded graphite is contained in an amount of 12.5 to 15.7% by mass.
CN201811521731.5A 2018-12-13 2018-12-13 Stainless steel mold casting covering slag Active CN111318677B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1122734A (en) * 1994-11-11 1996-05-22 伍本华 Composition bentonite protection slag
JP2003334640A (en) * 2002-05-17 2003-11-25 Shinagawa Refract Co Ltd Mold powder for continuous steel casting
CN101116906A (en) * 2006-07-31 2008-02-06 宝山钢铁股份有限公司 Carbon-free casting powder for casting steel making die
CN102825246A (en) * 2012-07-31 2012-12-19 马鞍山科润冶金材料有限公司 Covering slag for steelmaking die casting by using fly ash

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1122734A (en) * 1994-11-11 1996-05-22 伍本华 Composition bentonite protection slag
JP2003334640A (en) * 2002-05-17 2003-11-25 Shinagawa Refract Co Ltd Mold powder for continuous steel casting
CN101116906A (en) * 2006-07-31 2008-02-06 宝山钢铁股份有限公司 Carbon-free casting powder for casting steel making die
CN102825246A (en) * 2012-07-31 2012-12-19 马鞍山科润冶金材料有限公司 Covering slag for steelmaking die casting by using fly ash

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Denomination of invention: A type of stainless steel mold casting protective slag

Effective date of registration: 20231110

Granted publication date: 20210727

Pledgee: Industrial and Commercial Bank of China Limited Hongjiang City Branch

Pledgor: Hongjiang Sanxing metallurgical charge Co.,Ltd.

Registration number: Y2023980065135