CN111304959B - Preparation method of pulp-coated paper for leak-proof mercury-free battery - Google Patents
Preparation method of pulp-coated paper for leak-proof mercury-free battery Download PDFInfo
- Publication number
- CN111304959B CN111304959B CN202010119120.9A CN202010119120A CN111304959B CN 111304959 B CN111304959 B CN 111304959B CN 202010119120 A CN202010119120 A CN 202010119120A CN 111304959 B CN111304959 B CN 111304959B
- Authority
- CN
- China
- Prior art keywords
- solution
- coated paper
- slurry
- mercury
- corrosion inhibitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cell Separators (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention relates to a preparation method of coated paper for a leak-proof mercury-free battery, which comprises the following steps: (a) Adding a PAM solution, a mixed solution of PVA and zinc chloride, an acidic catalyst solution, a modified starch solution, an emulsifier solution and a corrosion inhibitor into a reaction vessel in sequence, stirring and mixing to obtain slurry, and adjusting the pH value of the slurry to 2.0-2.2; the chemical structural general formula of the corrosion inhibitor is
(b) Coating the slurry; (c) Preheating the slurry coated in the step (b) at 60-80 ℃, drying at 95-100 ℃, and ironing at 50-55 ℃ to obtain a semi-finished coated paper; (d) And cutting and rewinding the pulp layer paper semi-finished product. Can obtain the pulp layer paper with large liquid absorption amount and high liquid absorption speed.
Description
Technical Field
The invention relates to the technical field of dry battery manufacturing, in particular to a preparation method of coated paper for a leakage-proof mercury-free battery.
Background
The negative electrode of the acid zinc-manganese dry battery is a zinc cylinder which is amalgamated to ensure that the surface property is more uniform, reduce the corrosion of zinc and improve the storage performance of the battery; the positive electrode material is a mixed paste composed of manganese dioxide powder, ammonium chloride and carbon black.
Since the hydrogen evolution overpotential of the zinc amalgam alloy formed by mercury and zinc in water environment is high, people always adopt mercury as a corrosion inhibitor to slow down the self-corrosion rate of a zinc electrode and obviously improve the storage period of the battery for a long time. In addition, the added metal mercury enables the anode to be in better contact, reduces the internal resistance of the battery and can also improve the anti-seismic performance of the battery. However, mercury is extremely toxic and volatile, strict protection measures must be taken in the production process, the post-treatment process of waste batteries and the like, otherwise mercury leaks into water and soil, enters organisms by virtue of food chains, and finally flows into human bodies to cause mercury poisoning, for example, chronic poisoning often causes obvious neurasthenia, sensory disturbance and mental disturbance, severe poisoning encephalopathy and hepatopathy and has obvious embryotoxicity.
In addition, whether the battery performance of the zinc-manganese dry battery can meet the standard requirements depends not only on the corrosion inhibition performance of the selected corrosion inhibitor, but also has a direct relation with the performance of the used coated paper. The pulp paper is used as a diaphragm for separating the positive electrode and the negative electrode in the battery, and the addition of the pulp paper ensures that materials of the two electrodes cannot be in direct contact with each other and that electrolyte can smoothly pass through the pulp paper to absorb certain electrolyte when the battery works normally, so that the current amount in the period is kept smooth. The manufactured coated paper meets the following technical requirements: the isolation is good, the positive electrode and the negative electrode can be well separated, and the passing of the electric core particles is prevented; the ion permeability is good, and conductive ions can pass through the battery smoothly when the battery works; the chemical stability is good, side reactions such as hydrolysis, segregation and degradation do not occur in the acid electrolyte, and the storage is easy; good liquid absorption and retention, can absorb more electrolyte and prolong the service life of the battery. The existing coated paper generally consists of base paper, an adhesive, a liquid retention agent, a paste material, an auxiliary additive and the like, generally has the problems of low liquid absorption speed, small liquid absorption amount, poor isolation performance, poor electrical performance and the like, and has great significance in researching green, environment-friendly, corrosion-inhibition and leakage-proof zinc-manganese battery coated paper in order to eliminate the ecological damage problem caused by mercury pollution and slow down the self-corrosion rate of a zinc electrode.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a preparation method of a leak-proof mercury-free battery coated paper.
In order to achieve the purpose, the invention adopts the technical scheme that: a preparation method of a leak-proof mercury-free battery pulp-layer paper comprises the following steps:
(a) Adding a PAM solution, a mixed solution of PVA and zinc chloride, an acidic catalyst solution, a modified starch solution, an emulsifier solution and a corrosion inhibitor into a reaction vessel in sequence, stirring and mixing to obtain slurry, and adjusting the pH value of the slurry to 2.0-2.2; the chemical structural general formula of the corrosion inhibitor is
(b) Coating the slurry;
(c) Preheating the slurry coated in the step (b) at 60-80 ℃, drying at 95-100 ℃, and ironing at 50-55 ℃ to obtain a semi-finished coated paper;
(d) And cutting and rewinding the semi-finished pulp paper.
Preferably, in step (a), the acidic catalyst solution is Bi 2 O 3 Of HCl (g).
Optimally, in the step (a), the modified starch is etherified starch and cross-linked starch in a mass ratio of 0.5-2: 1.
preferably, in step (a), the emulsifier is TX-10 emulsifier.
Further, in the step (a), the mass ratio of the PAM, the PVA, the zinc chloride, the catalyst, the modified starch, the emulsifier and the corrosion inhibitor is 10-15: 1:0.6 to 0.7:0.15 to 0.2:12 to 18: 0.4-0.6: 1.8 to 2.2.
Further, in the step (a), the mass ratio of the PAM, the PVA, the zinc chloride, the catalyst, the modified starch, the emulsifier and the corrosion inhibitor is 12:1:0.66:0.16:15:0.5:2.
furthermore, in the step (a), the mixed solution of PVA and zinc chloride is prepared by mixing a PVA solution and a zinc chloride solution, and the mass concentration of the zinc chloride solution is 25-35%.
Optimally, in step (a), the viscosity of the slurry is also adjusted to 175-219mm 2 /s。
Optimally, in the step (b), coating is carried out by a coating machine, and the coating weight is controlled to be 28-36 g/m 2 。
Optimally, in the step (c), the water content of the pulp layer paper semi-finished product is 8-12%.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages: according to the preparation method of the leakproof mercury-free battery pulp-layer paper, the corrosion inhibitor with a specific structure, a PAM solution, a mixed solution of PVA and zinc chloride, an acid catalyst solution, a modified starch solution and the like are added into a reaction container to be mixed, and then preheating, drying and ironing are carried out, so that the pulp-layer paper with a large liquid absorption amount (the liquid absorption rate can reach as high as 180%, while the liquid absorption rate of the conventional pulp-layer paper is only about 80%), a high liquid absorption speed (the liquid absorption speed is only 18s/ul, while the liquid absorption speed of the conventional pulp-layer paper is only 30 s/ul) can be obtained, and the preparation method has the advantages of strong corrosion resistance, improvement of the discharge utilization rate of active substances and the like; when the zinc electrode inhibitor is applied to an acid zinc-manganese dry battery, the zinc electrode inhibitor has an obvious inhibition effect on corrosion of the zinc electrode, so that the hydrogen evolution amount of the zinc electrode is effectively reduced, the conductivity of the zinc electrode and the utilization rate of active substances are improved, the storage life of the zinc electrode is prolonged, and the zinc electrode inhibitor can replace mercury to be used as a corrosion inhibitor.
Drawings
FIG. 1 is a nuclear magnetic spectrum of a corrosion inhibitor in the preparation method of the coated paper for the leak-proof mercury-free battery.
Detailed Description
The invention relates to a preparation method of pulp paper for a leak-proof mercury-free battery, which comprises the following steps: (a) Adding a PAM solution, a mixed solution of PVA and zinc chloride, an acidic catalyst solution, a modified starch solution, an emulsifier solution and a corrosion inhibitor into a reaction vessel in sequence, stirring and mixing to obtain a slurry, and adjusting the pH value of the slurry to 2.0-2.2; the chemical structural general formula of the corrosion inhibitor is
(b) Coating the slurry; (c) Preheating the slurry coated in the step (b) at 60-80 ℃, drying at 95-100 ℃, and ironing at 50-55 ℃ to obtain a semi-finished coated paper; (d) And cutting and rewinding the semi-finished pulp paper. By adding the corrosion inhibitor with a specific structure into the reaction container, mixing the corrosion inhibitor with the PAM solution, the mixed solution of PVA and zinc chloride, the acidic catalyst solution, the modified starch solution and the like, and then preheating, drying and ironing, the coated paper with a large liquid absorption amount and a high liquid absorption speed can be obtained, and the coated paper has the advantages of strong corrosion resistance, improvement on the discharge utilization rate of active substances and the like; when the corrosion inhibitor is applied to an acid zinc-manganese dry battery, the corrosion inhibitor has an obvious inhibiting effect on the corrosion of a zinc electrode, effectively reduces the hydrogen evolution quantity of the zinc electrode, improves the conductivity of the zinc electrode and the utilization rate of active substances, prolongs the storage life of the zinc electrode, and can replace mercury as a corrosion inhibitor.
In the step (a), the acidic catalyst solution is Bi 2 O 3 The HCl solution of (1); the modified starch is etherified starch and cross-linked starch in a mass ratio of 0.5-2: 1; the emulsifier is TX-10 emulsifier; the mass ratio of the PAM to the PVA to the zinc chloride to the catalyst to the modified starch to the emulsifier to the corrosion inhibitor is 10-15: 1:0.6 to 0.7:0.15 to 0.2:12 to 18: 0.4-0.6: 1.8 to 2.2; the mass ratio of the PAM to the PVA to the zinc chloride to the catalyst to the modified starch to the emulsifier to the corrosion inhibitor is 12:1:0.66:0.16:15:0.5:2; in the step (a), the mixed solution of PVA and zinc chloride is prepared by mixing a PVA solution and a zinc chloride solution, and the mass concentration of the zinc chloride solution is 25-35%;in the step (a), the viscosity of the slurry is also adjusted to 175-219mm 2 And s. In the step (b), coating is carried out by a coating machine, and the coating weight is controlled to be 28-36 g/m 2 . In the step (c), the water content of the pulp layer paper semi-finished product is 8-12%; this can further improve the electrochemical performance of dry batteries using the pulp-coated paper, and the dry batteries are free from leakage.
The corrosion inhibitor is prepared by the following method: adding 0.1mol of KOH and 30mL of acetonitrile into a 250mL three-neck flask, fully dissolving at room temperature, adding 0.12mol of imidazole in batches, and continuously stirring until no gas is generated; slowly dripping 0.05mol of 1, 6-dibromohexane into a three-necked bottle under the protection of nitrogen, and refluxing and stirring for 12 hours at 65 ℃; after the reaction is finished, filtering NaBr while the reaction is hot, and washing the NaBr with acetonitrile; removing acetonitrile from the filtrate by rotary evaporation, and drying to obtain a white solid 1, 6-diimidazole hexane with the yield of 90.7 percent; dissolving 0.05mol of the product (namely 1, 6-diimidazole hexane) in 50mL of ethyl acetate, slowly and dropwise adding 0.05mol of methyl iodide into an isopropanol solution in an ice water bath, and continuously reacting for 6 hours at room temperature; after the reaction is finished, white solid is obtained and is washed by ethyl acetate and ether for 2 times respectively, and the target product of the corrosion inhibitor (2, 3-dimethyl-1- (6- (2-methylimidazole) hexyl imidazole iodide) is obtained, and the nuclear magnetic spectrum of the product is shown in figure 1.
The present invention will be described in further detail with reference to specific examples, but the present invention is not limited to the following examples. The implementation conditions adopted in the embodiments can be further adjusted according to different requirements of specific use, and the implementation conditions not mentioned are conventional conditions in the industry.
Example 1
The embodiment provides a preparation method of coated paper for a leakage-proof mercury-free battery, which comprises the following steps:
(a) Taking 1000ml of deionized water by using a beaker, boiling, adding 600g of PAM (polyacrylamide), stirring to dissolve the PAM, and adding the PAM into a mixing tank; weighing 50g of PVA (polyvinyl alcohol) and adding the PVA into a 1000ml beaker, then adding 110g of 30 percent (mass concentration) zinc chloride solution, heating the mixture in an electric furnace at the temperature of between 95 and 100 ℃ until the PVA is completely melted, and adding the mixture into a material mixing tank; balance with scale9g of Bi are taken 2 O 3 2mol/L HCl solution (12 ml) is used for melting and then is dripped into a batching tank; weighing 375g of etherified starch and crosslinked starch respectively, adding 1000ml of deionized water, stirring uniformly, and adding into a batching tank; weighing 25g of TX-10, adding 50ml of deionized water, stirring uniformly, and adding into a batching tank; weighing 100g of corrosion inhibitor
Directly adding into a batching tank; stirring evenly to obtain slurry, measuring the pH value of the slurry to be 2.0-2.2 and adjusting the viscosity to be 175-219mm 2 /s；
(b) Adding the slurry into a coating machine for coating test, and controlling the coating weight within a standard range of 32 +/-4 g/m 2 ；
(c) Steam drying is used, low-temperature (60-80 ℃) preheating is carried out, high-temperature (95-100 ℃) drying is carried out, and then low-temperature (50-55 ℃) ironing is carried out to obtain a pulp-coated paper semi-finished product (the water content of the pulp-coated paper semi-finished product is about 10 percent;
(d) Cutting, rewinding and packaging the pulp layer paper semi-finished product for later use; the surface of the coated paper is required to be uniformly and flatly coated during slitting, and the phenomena of no de-coating, no deep printing, shallow printing, no wrinkle and the like are avoided; when rewinding, the side surface of the disc is smooth, the tightness is proper, and the phenomenon of burr and disjointing does not exist.
Example 2
This example provides a method of making a coated paper for a leak-proof mercury-free battery, which is substantially the same as in example 1, except that: in step (a), 90g of corrosion inhibitor was used.
Example 3
This example provides a method of making a coated paper for a leak-proof mercury-free battery, which is substantially the same as in example 1, except that: in step (a), 111g of corrosion inhibitor was used.
Example 4
This example provides a method of making a coated paper for a leak-proof mercury-free battery, which is substantially the same as in example 1, except that: in step (a), 500g of PAM was used.
Example 5
This example provides a method of making a coated paper for a leak-proof mercury-free battery, which is substantially the same as in example 1, except that: in step (a), 750g of PAM was used.
Example 6
This example provides a method of making a coated paper for a leak-proof mercury-free battery, which is substantially the same as in example 1, except that: in step (a), 20g of emulsifier was used.
Example 7
This example provides a method of making a coated paper for a leak-proof mercury-free battery, which is substantially the same as in example 1, except that: in step (a), 30g of emulsifier was used.
Comparative example 1
This example provides a method of making a battery coated paper substantially as in example 1, except that: in step (a), no zinc chloride solution was added.
Comparative example 2
This example provides a method of making a battery coated paper substantially as in example 1, except that: in step (a), no PAM was added.
Comparative example 3
This example provides a method of making a battery coated paper substantially as in example 1, except that: in step (a), no PVA was added.
Comparative example 4
This example provides a method of making a battery-use coated paper, which is substantially the same as that of example 1, except that: in step (a), bi is not added 2 O 3 。
Comparative example 5
This example provides a method of making a battery-use coated paper, which is substantially the same as that of example 1, except that: in step (a), no etherified starch is added.
Comparative example 6
This example provides a method of making a battery-use coated paper, which is substantially the same as that of example 1, except that: in step (a), no cross-linked starch is added.
Comparative example 7
This example provides a method of making a battery coated paper substantially as in example 1, except that: in step (a), no TX-10 was added.
Comparative example 8
This example provides a method of making a battery-use coated paper, which is substantially the same as that of example 1, except that: in step (a), no corrosion inhibitor is added.
Comparative example 9
This example provides a method of making a battery-use coated paper, which is substantially the same as that of example 1, except that: in step (a), the corrosion inhibitor used is
Comparative example 10
This example provides a method of making a battery coated paper substantially as in example 1, except that: in step (a), the corrosion inhibitor used is
The coated papers prepared in examples 1 to 7 and comparative examples 1 to 10 were subjected to the liquid absorption rate and liquid absorption speed tests, and the results thereof are shown in table 1.
TABLE 1 table for testing the properties of coated papers prepared in examples 1 to 7 and comparative examples 1 to 10
Measurement of liquid absorption Rate: taking coated paper (coated paper with medium mass in examples 1-7 and comparative examples 1-10), weighing, and recording the mass m1; soaking the paper in a beaker filled with standard electrolyte for 10min, taking out the pulp layer paper, suspending the paper until the pulp layer paper does not drip (about 3 min), and weighing again to record the mass m2; liquid absorption rate = (m 2-m 1)/m 1 × 100%.
Measurement of imbibition speed: 3 pieces of coated paper samples with the area of 3cm multiplied by 3cm are intercepted and put on a clean glass slide; 0.05mL of distilled water was dropped onto the center of the coated paper sample at a height of 15mm with a 50. Mu.L pipette; the time taken from the water drop onto the sample until the water is completely absorbed by the sample is measured once per sample, and the average of the three permeation rates is calculated as the liquid absorption rate.
The coated papers prepared in examples 1 to 7 and comparative examples 1 to 10 were assembled into a battery (R6S) according to the battery standard GB 8897-2008-T, and the battery performance was measured, and the results thereof are shown in table 2. It can be seen that compared with the coated paper added with the corrosion inhibitor listed in the present application, the mercury-free battery assembled by the coated paper without the corrosion inhibitor listed in the present application has no obvious reduction in the performances such as open-circuit voltage, load voltage, discharge capacity and the like, but the battery assembled by the coated paper added with the corrosion inhibitor listed in the present application has obvious improvement in the leakage-proof performance and the corrosion inhibition performance, so that the use of the coated paper can greatly improve the service performance and the service life of the battery.
TABLE 2 Dry cell Performance Table Using the coated papers prepared in examples 1 to 7 and comparative examples 1 to 10
The above embodiments are merely illustrative of the technical concept and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the content of the present invention and implement the invention, and not to limit the scope of the invention, and all equivalent changes or modifications made according to the spirit of the present invention should be covered by the scope of the present invention.
Claims (6)
1. A preparation method of a leak-proof mercury-free battery pulp-layer paper is characterized by comprising the following steps:
(a) Adding PAM solution, PVA and zinc chloride mixed solution, acid catalyst solution and the like into a reaction vessel in sequenceStirring and mixing a starch solution, an emulsifier solution and a corrosion inhibitor to obtain a slurry, and adjusting the pH value of the slurry to 2.0-2.2; the chemical structural general formula of the corrosion inhibitor is
(ii) a The acid catalyst solution is Bi 2 O 3 The HCl solution of (1); the modified starch is prepared from etherified starch and cross-linked starch according to a mass ratio of 0.5 to 2:1; the emulsifier is TX-10 emulsifier; the mass ratio of the PAM to the PVA to the zinc chloride to the catalyst to the modified starch to the emulsifier to the corrosion inhibitor is 10 to 15:1:0.6 to 0.7:0.15 to 0.2:12 to 18:0.4 to 0.6:1.8 to 2.2;
(b) Coating the slurry;
(c) Preheating the slurry coated in the step (b) at 60-80 ℃, drying at 95-100 ℃, and ironing at 50-55 ℃ to obtain a semi-finished coated paper;
(d) And cutting and rewinding the semi-finished pulp paper.
2. The method for preparing the coated paper for the leak-proof mercury-free battery according to claim 1, wherein the method comprises the following steps: in the step (a), the mass ratio of the PAM, the PVA, the zinc chloride, the catalyst, the modified starch, the emulsifier and the corrosion inhibitor is 12:1:0.66:0.16:15:0.5:2.
3. the method for preparing the coated paper for the leakproof mercury-free battery according to claim 1, wherein the method comprises the following steps: in the step (a), the mixed solution of PVA and zinc chloride is prepared by mixing a PVA solution and a zinc chloride solution, and the mass concentration of the zinc chloride solution is 25-35%.
4. The method for preparing the coated paper for the leak-proof mercury-free battery according to claim 1, wherein the method comprises the following steps: in step (a), the viscosity of the slurry is also adjusted to be 175 to 219mm/s.
5. The method for preparing the coated paper for the leakproof mercury-free battery according to claim 1The preparation method is characterized by comprising the following steps: in the step (b), coating is carried out by a coating machine, and the coating weight is controlled to be 28 to 36g/m 2 。
6. The method for preparing the coated paper for the leakproof mercury-free battery according to claim 1, wherein the method comprises the following steps: in the step (c), the water content of the semi-finished coated paper is 8 to 12 percent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010119120.9A CN111304959B (en) | 2020-02-26 | 2020-02-26 | Preparation method of pulp-coated paper for leak-proof mercury-free battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010119120.9A CN111304959B (en) | 2020-02-26 | 2020-02-26 | Preparation method of pulp-coated paper for leak-proof mercury-free battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111304959A CN111304959A (en) | 2020-06-19 |
| CN111304959B true CN111304959B (en) | 2021-11-19 |
Family
ID=71157094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010119120.9A Active CN111304959B (en) | 2020-02-26 | 2020-02-26 | Preparation method of pulp-coated paper for leak-proof mercury-free battery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111304959B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3120744B1 (en) | 2021-03-12 | 2023-05-12 | Accumulateurs Fixes | Negative electrode comprising an electrochemically active zinc material |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1556278A (en) * | 2004-01-08 | 2004-12-22 | 佘志明 | Sizing layer paper for paper board battery and its manufacturing method |
| CN1700492A (en) * | 2005-03-29 | 2005-11-23 | 嘉善宇河特种纸品有限公司 | Mercury-free zinc-manganese battery slurry layer paper |
| CN101271968A (en) * | 2008-05-16 | 2008-09-24 | 辽源市鸿图纸业有限公司 | Mercury-free diaphragm paper for laminated cell |
| CN101798778A (en) * | 2010-03-09 | 2010-08-11 | 肖勇 | Coated paper of mercury-free zinc manganese dry cell for high-speed battery production line and preparation method thereof |
| CN103789773A (en) * | 2014-01-16 | 2014-05-14 | 河北科技大学 | Organic composite corrosion inhibitor for coated paper and slurry thereof |
| CN103891035A (en) * | 2011-10-28 | 2014-06-25 | 富士胶片株式会社 | Electrolyte solution for non-aqueous secondary battery, and secondary battery |
| CN104904034A (en) * | 2012-10-10 | 2015-09-09 | 无限科技全球公司 | Printed energy storage device |
| CN108221489A (en) * | 2018-01-10 | 2018-06-29 | 广东肇庆明珠纸业有限公司 | Coated paper for producing mercury-free zinc-manganese dioxide dry battery and preparation method thereof |
| CN109701465A (en) * | 2019-01-22 | 2019-05-03 | 四川轻化工大学 | Preparation of oil-soluble corrosion inhibitor microcapsule for anticorrosive paint |
-
2020
- 2020-02-26 CN CN202010119120.9A patent/CN111304959B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1556278A (en) * | 2004-01-08 | 2004-12-22 | 佘志明 | Sizing layer paper for paper board battery and its manufacturing method |
| CN1700492A (en) * | 2005-03-29 | 2005-11-23 | 嘉善宇河特种纸品有限公司 | Mercury-free zinc-manganese battery slurry layer paper |
| CN101271968A (en) * | 2008-05-16 | 2008-09-24 | 辽源市鸿图纸业有限公司 | Mercury-free diaphragm paper for laminated cell |
| CN101798778A (en) * | 2010-03-09 | 2010-08-11 | 肖勇 | Coated paper of mercury-free zinc manganese dry cell for high-speed battery production line and preparation method thereof |
| CN103891035A (en) * | 2011-10-28 | 2014-06-25 | 富士胶片株式会社 | Electrolyte solution for non-aqueous secondary battery, and secondary battery |
| CN104904034A (en) * | 2012-10-10 | 2015-09-09 | 无限科技全球公司 | Printed energy storage device |
| CN103789773A (en) * | 2014-01-16 | 2014-05-14 | 河北科技大学 | Organic composite corrosion inhibitor for coated paper and slurry thereof |
| CN108221489A (en) * | 2018-01-10 | 2018-06-29 | 广东肇庆明珠纸业有限公司 | Coated paper for producing mercury-free zinc-manganese dioxide dry battery and preparation method thereof |
| CN109701465A (en) * | 2019-01-22 | 2019-05-03 | 四川轻化工大学 | Preparation of oil-soluble corrosion inhibitor microcapsule for anticorrosive paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111304959A (en) | 2020-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103547584B (en) | Synthesis of hetero ionic compounds using dialkylcarbonate quaternization | |
| CN103594738B (en) | A kind of high temperature valve controlled sealed lead-acid accumulator | |
| CN103972466B (en) | Positive pole of a kind of high-temperature lithium thionyl chloride battery and preparation method thereof | |
| CN107565134A (en) | Water system Zinc ion battery based on the tetrone positive pole of pyrene 4,5,9,10 and zinc load | |
| Yuan et al. | Influence of surface modification with Sn6O4 (OH) 4 on electrochemical performance of ZnO in Zn/Ni secondary cells | |
| CN106229498A (en) | A kind of negative material being applicable to Water based metal ion battery and preparation method thereof | |
| CN108598516A (en) | Alkaline zinc-manganese battery | |
| Dönmez et al. | A performance comparison of protective silicate-coated lead and non-coated lead electrodes in various kind electrolytes of gel valve-regulated lead-acid battery | |
| CN109273699A (en) | A kind of positive pole material for high-performance lithium-sulfur battery and preparation method thereof | |
| CN104078680B (en) | A kind of carbon sulphur anode composite and secondary aluminium-sulfur battery | |
| CN111304959B (en) | Preparation method of pulp-coated paper for leak-proof mercury-free battery | |
| CN106571248A (en) | Preparation method for electrode material of Se-doped ZnO-SnO2 supercapacitor taking foamed nickel as substrate | |
| CN110729528A (en) | Solar-assisted rechargeable zinc-air battery with low charging potential | |
| Huang et al. | Evaluation of tetraphenylporphyrin modified ZnO as anode material for Ni-Zn rechargeable battery | |
| CN110783560B (en) | Alkaline zinc-manganese battery containing modified nano zinc powder and preparation method thereof | |
| CN102117938B (en) | Energy-saving environmentally-friendly high-temperature valve-regulated sealed lead acid storage battery | |
| CN108221489B (en) | Coated paper for producing mercury-free zinc-manganese dioxide dry battery and preparation method thereof | |
| CN104362313A (en) | Polypyrrole, mesoporous carbon and sulfur composite electrode material and secondary cell | |
| CN103789773A (en) | Organic composite corrosion inhibitor for coated paper and slurry thereof | |
| CN111446509B (en) | Electrolyte and gel electrolyte for secondary zinc ion battery and preparation method thereof | |
| CN101271968A (en) | Mercury-free diaphragm paper for laminated cell | |
| CN116730408A (en) | Preparation method and application of modified sodium ion positive electrode material | |
| CN101555559B (en) | Aluminum alloy and applications and production method of aluminum alloy | |
| CN108063231B (en) | Preparation method of hydrogen storage alloy/graphene composite material for nickel-metal hydride battery cathode | |
| CN100589262C (en) | Nickel positive pole and preparation method thereof and comprise the Ni-metal hydride accumulator that this is anodal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20210903 Address after: 213164 21 Gehu Middle Road, HUTANG Town, Wujin District, Changzhou City, Jiangsu Province Applicant after: CHANGZHOU University Applicant after: Shandong Huatai New Energy Battery Co.,Ltd. Address before: 213164 21 Gehu Middle Road, HUTANG Town, Wujin District, Changzhou City, Jiangsu Province Applicant before: CHANGZHOU University Applicant before: LINYI HUATAI BATTERY Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |