CN111303497A - Temperature-sensing reversible color-changing condom and preparation method thereof - Google Patents

Temperature-sensing reversible color-changing condom and preparation method thereof Download PDF

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Publication number
CN111303497A
CN111303497A CN201811529067.9A CN201811529067A CN111303497A CN 111303497 A CN111303497 A CN 111303497A CN 201811529067 A CN201811529067 A CN 201811529067A CN 111303497 A CN111303497 A CN 111303497A
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CN
China
Prior art keywords
temperature
condom
latex
changing
color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811529067.9A
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Chinese (zh)
Other versions
CN111303497A8 (en
Inventor
李华智
岑安宁
卢智俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Wanfangjian Pharmaceutical Co ltd
Original Assignee
Guangzhou Wanfangjian Pharmaceutical Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Wanfangjian Pharmaceutical Co ltd filed Critical Guangzhou Wanfangjian Pharmaceutical Co ltd
Priority to CN201811529067.9A priority Critical patent/CN111303497A/en
Publication of CN111303497A publication Critical patent/CN111303497A/en
Publication of CN111303497A8 publication Critical patent/CN111303497A8/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F6/00Contraceptive devices; Pessaries; Applicators therefor
    • A61F6/02Contraceptive devices; Pessaries; Applicators therefor for use by males
    • A61F6/04Condoms, sheaths or the like, e.g. combined with devices protecting against contagion
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02Organic tenebrescent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00Characterised by the use of natural rubber
    • C08J2307/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00Characterised by the use of unspecified rubbers
    • C08J2321/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2407/00Characterised by the use of natural rubber
    • C08J2407/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2421/00Characterised by the use of unspecified rubbers
    • C08J2421/02Latex

Abstract

The invention discloses a temperature-sensing reversible color-changing condom and a preparation method thereof, wherein the color of the condom can change along with the change of temperature, specifically comprises the change of hue, lightness and saturation, the change processes can reflect the ambient temperature or the contacted body surface temperature of a human body to a certain degree, and the experience pleasure of a user is increased while the user feels fresh.

Description

Temperature-sensing reversible color-changing condom and preparation method thereof
Technical Field
The invention belongs to the technical field of condoms, and particularly relates to a temperature-sensing reversible color-changing condom and a preparation method thereof.
Background
Condoms are widely used in human life, but lack innovation. Specifically, condoms on the market are all fixed in color, and are either the color of latex itself or the color of pigment which appears after the addition of pigment, which is very old. There is currently no condom which can be changed with temperature changes.
Disclosure of Invention
The invention aims to provide a novel temperature-sensing reversible color-changing condom and a preparation method thereof, which can increase the use interest of the condom, improve the use willingness of the condom and reduce accidental pregnancy.
The invention innovatively designs a novel temperature-sensing reversible color-changing condom, namely the color of the condom can change along with the change of temperature. The color change of the temperature-sensing reversible color-changing condom comprises the changes of hue, lightness and saturation, and the change processes can reflect the ambient temperature or the body surface temperature of a contacted human body to a certain extent, so that the experience pleasure of a user is increased while the freshness of consumers is provided.
The color of the condom of the invention can change within a certain critical temperature range, and the change can be the change of hue, lightness or saturation. The color change of the condom may be from colorless to colored, from colored to colorless, from one color to another, or multiple color changes at different temperature stages. The critical temperature range of the change is 0-80 ℃, preferably 30-40 ℃, and most preferably 35 ℃. The condom may also contain one or more pigments.
One method of implementing the condom of the invention is to include one or more temperature-sensitive reversible toner.
The raw materials for the condom according to the invention are preferably natural latex, synthetic latex, a mixture of natural latex and synthetic latex, and modified latexes of the above latexes.
The invention can be prepared by a preparation method comprising the following steps:
preparing temperature-sensitive reversible color liquid: adding one or more temperature-sensitive reversible toner(s) into water to prepare temperature-sensitive reversible toner(s) with the mass fraction of 5-20%;
preparing a pigment mother solution: adding common pigment powder into the prepared temperature-sensitive reversible color-changing liquid according to 0-10% of the mass fraction of the temperature-sensitive reversible color-changing liquid, and mixing and dispersing to prepare a pigment mother liquid;
latex prevulcanization and centrifugation treatment: sequentially putting the latex into a pre-vulcanizing tank and a centrifugal machine for processing to obtain pre-vulcanized and centrifugally processed latex;
preparing temperature-sensitive reversible color-changing latex: adding the prepared pigment mother solution according to 0.01-40% of the mass fraction of the latex subjected to prevulcanization and centrifugation treatment, and fully mixing and stirring uniformly to prepare the temperature-sensitive reversible color-changing latex;
preparing and drying an adhesive film: immersing the condom mold into the temperature-sensing reversible color latex, placing for a moment, then taking out, and then drying the mold to obtain a dried adhesive film.
Curling, demoulding and shaping: and curling, demolding and shaping the dried adhesive film to obtain the temperature-sensitive reversible color-changing condom.
Wherein, the steps of preparing the adhesive film and drying can be repeated for 1-5 times, so that the thickness of the dried adhesive film is 20-100 um.
Detailed Description
The technical solution of the present invention is further described in detail by the following embodiments. It should be understood that the scope of the present invention is not limited to the following examples. Various substitutions and alterations according to the general knowledge and conventional practice in the art are intended to be included within the scope of the present invention without departing from the technical spirit of the present invention as described above.
Example 1
A temperature-sensing reversible color-changing condom is characterized in that the color of the temperature-sensing reversible color-changing condom is bluish purple at normal room temperature or at the temperature of 35 ℃ or below, the color is darker as the temperature is lower, and the color of the temperature-sensing reversible color-changing condom is gradually changed from bluish purple to pink when the temperature is raised to above 35 ℃. The preparation steps of the novel temperature-sensing reversible color-changing condom capable of changing from bluish purple to pink along with the temperature change are as follows:
1) preparing temperature-sensitive reversible color liquid: adding a blue temperature-sensitive reversible toner capable of decoloring at 35 ℃ into water to prepare a temperature-sensitive reversible color liquid with the mass fraction of 10%;
2) preparing a pigment mother solution: adding common fluorescent red pigment powder into the prepared temperature-sensitive reversible color-changing liquid according to 1% of the mass fraction of the temperature-sensitive reversible color-changing liquid, and mixing and dispersing to prepare a pigment mother liquid;
3) latex prevulcanization and centrifugation treatment: sequentially putting the latex into a pre-vulcanizing tank and a centrifugal machine for processing to obtain pre-vulcanized and centrifugally processed latex;
4) preparing temperature-sensitive reversible color-changing latex: adding the prepared pigment mother solution according to 0.5 percent of the mass of the latex subjected to pre-vulcanization and centrifugal treatment, fully mixing and uniformly stirring to prepare the temperature-sensitive reversible color-changing latex;
5) preparing and drying an adhesive film: immersing the condom mold into the temperature-sensing reversible color latex, placing for a moment, then taking out, and then drying the mold to obtain a dried adhesive film. Repeating the steps for 3 times, wherein the thickness of the dried adhesive film is 35 um.
6) Curling, demoulding and shaping: and curling, demolding and shaping the dried adhesive film to obtain the temperature-sensitive reversible color-changing condom.
Example 2
The temperature sensing reversible color-changing condom has a color of blue when the temperature is generally room temperature or below 30 ℃, the color of the temperature sensing reversible color-changing condom is darker when the temperature is lower, and the color of the temperature sensing reversible color-changing condom is gradually changed from blue to colorless when the temperature is raised to be above 30 ℃. The preparation steps of the novel temperature-sensing reversible color-changing condom capable of changing from blue to colorless with the temperature change are as follows:
1) preparing temperature-sensitive reversible color liquid: adding a blue temperature-sensitive reversible toner capable of decoloring at 30 ℃ into water to prepare a temperature-sensitive reversible color liquid with the mass fraction of 15%, and using the temperature-sensitive reversible color liquid as a pigment mother liquid;
2) latex prevulcanization and centrifugation treatment: sequentially putting the latex into a pre-vulcanizing tank and a centrifugal machine for processing to obtain pre-vulcanized and centrifugally processed latex;
3) preparing temperature-sensitive reversible color-changing latex: adding prepared pigment mother liquor according to 1% of the mass of the latex subjected to prevulcanization and centrifugation treatment, fully mixing and uniformly stirring to prepare temperature-sensitive reversible color-changing latex;
4) preparing and drying an adhesive film: immersing the condom mold into the temperature-sensing reversible color latex, placing for a moment, then taking out, and then drying the mold to obtain a dried adhesive film. Repeating the steps for 3 times, wherein the thickness of the dried adhesive film is 35 um.
5) Curling, demoulding and shaping: and curling, demolding and shaping the dried adhesive film to obtain the temperature-sensitive reversible color-changing condom.

Claims (7)

1. A temperature-sensing reversible color-changing condom is characterized in that the color of the condom can be reversibly changed along with the change of temperature.
2. The condom of claim 1 wherein the condom contains one or more temperature-sensitive reversible toners.
3. The condom of claim 1 wherein the critical temperature range for the color change of the condom is 0-80 ℃.
4. A condom according to claim 3, in which the critical temperature range for the colour change of the condom is preferably 30 to 40 ℃.
5. The temperature-sensitive reversible color-changing condom of any one of claims 1-5, wherein the condom contains one or more pigments.
6. The condom of claim 6 wherein the starting materials used in the condom are natural latex, synthetic latex, mixtures of natural and synthetic latex, and modified latexes of the above.
7. The method of making a condom of claim 7, comprising the steps of:
preparing temperature-sensitive reversible color liquid: adding one or more temperature-sensitive reversible toner(s) into water to prepare temperature-sensitive reversible toner(s) with the mass fraction of 5-20%;
preparing a pigment mother solution: adding common pigment powder into the prepared temperature-sensitive reversible color-changing liquid according to 0-10% of the mass fraction of the temperature-sensitive reversible color-changing liquid, and mixing and dispersing to prepare a pigment mother liquid;
latex prevulcanization and centrifugation treatment: sequentially putting the latex into a pre-vulcanizing tank and a centrifugal machine for processing to obtain pre-vulcanized and centrifugally processed latex;
preparing temperature-sensitive reversible color-changing latex: adding the prepared pigment mother solution according to 0.01-40% of the mass fraction of the latex subjected to prevulcanization and centrifugation treatment, and fully mixing and stirring uniformly to prepare the temperature-sensitive reversible color-changing latex;
preparing and drying an adhesive film: immersing the condom mold into the temperature-sensing reversible color latex, placing for a moment, then taking out, and then drying the mold to obtain a dried adhesive film.
Curling, demoulding and shaping: and curling, demolding and shaping the dried adhesive film to obtain the temperature-sensitive reversible color-changing condom.
Wherein, the steps of preparing the adhesive film and drying can be repeated for 1-5 times, so that the thickness of the dried adhesive film is 20-100 um.
CN201811529067.9A 2018-12-12 2018-12-12 Temperature-sensing reversible color-changing condom and preparation method thereof Pending CN111303497A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811529067.9A CN111303497A (en) 2018-12-12 2018-12-12 Temperature-sensing reversible color-changing condom and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811529067.9A CN111303497A (en) 2018-12-12 2018-12-12 Temperature-sensing reversible color-changing condom and preparation method thereof

Publications (2)

Publication Number Publication Date
CN111303497A true CN111303497A (en) 2020-06-19
CN111303497A8 CN111303497A8 (en) 2022-03-25

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2316934Y (en) * 1997-12-18 1999-05-05 钱志友 Health-care prewarning condom
CN1900147A (en) * 2006-07-13 2007-01-24 张家港宏裕乳胶手套有限公司 Recipe and producing method of temperature sensing color changing gloves
CN101194866A (en) * 2007-06-08 2008-06-11 桂林乳胶厂 Golden condom
CN101851359A (en) * 2010-06-04 2010-10-06 中国化工橡胶株洲研究设计院 Antibacterial latex prophylactic and production method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2316934Y (en) * 1997-12-18 1999-05-05 钱志友 Health-care prewarning condom
CN1900147A (en) * 2006-07-13 2007-01-24 张家港宏裕乳胶手套有限公司 Recipe and producing method of temperature sensing color changing gloves
CN101194866A (en) * 2007-06-08 2008-06-11 桂林乳胶厂 Golden condom
CN101851359A (en) * 2010-06-04 2010-10-06 中国化工橡胶株洲研究设计院 Antibacterial latex prophylactic and production method thereof

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PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CI02 Correction of invention patent application

Correction item: Applicant

Correct: GUANGZHOU WANFANGJIAN MEDICINE Co.,Ltd.

False: Guangzhou wanfangjian Pharmaceutical Co.,Ltd.

Number: 25-02

Page: The title page

Volume: 36

Correction item: Applicant

Correct: GUANGZHOU WANFANGJIAN MEDICINE Co.,Ltd.

False: Guangzhou wanfangjian Pharmaceutical Co.,Ltd.

Number: 25-02

Volume: 36

CI02 Correction of invention patent application
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20200619

WD01 Invention patent application deemed withdrawn after publication