CN1112524A - Vitrification and power generation system - Google Patents

Vitrification and power generation system Download PDF

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Publication number
CN1112524A
CN1112524A CN94113710A CN94113710A CN1112524A CN 1112524 A CN1112524 A CN 1112524A CN 94113710 A CN94113710 A CN 94113710A CN 94113710 A CN94113710 A CN 94113710A CN 1112524 A CN1112524 A CN 1112524A
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CN
China
Prior art keywords
boiler
gas
kiln
outlet
flue
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Pending
Application number
CN94113710A
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Chinese (zh)
Inventor
K·R·麦克尼尔
B·J·博兰
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Vert Investments Ltd
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Vert Investments Ltd
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Publication of CN1112524A publication Critical patent/CN1112524A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/235Heating the glass
    • C03B5/237Regenerators or recuperators specially adapted for glass-melting furnaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/06Reclamation of contaminated soil thermally
    • B09C1/067Reclamation of contaminated soil thermally by vitrification
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Soil Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Air Supply (AREA)
  • Other Liquid Machine Or Engine Such As Wave Power Use (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)

Abstract

A vitrification and power generation apparatus comprises a glass-forming furnace including inlets for feedstock and inlet gas including fuel gases or oil and pre-heated air, and a gas outlet from which furnace flue gases are fed; heat recovery means through which furnace flue gases are fed to reduce their temperature, the heat recovery means also pre-heating the air fed to the furnace; and a boiler coupled to the heat recovery means including a gas inlet through which the furnace flue gases are fed to the boiler, a steam outlet and a gas outlet through which boiler flue gases are fed, the boiler flue gases for feeding to a gas treatment system in which the boiler flue outlet is coupled to two outlet paths and means for splitting the flow such that one outlet path is for feeding boiler flue gases to a gas treatment system and the other outlet path leads to the furnace inlet, to the furnace outlet or to the boiler inlet, whereby part of the flow of boiler flue gas is recirculated.

Description

Vitrification and power generation system
The present invention relates to a kind of vitrifying and power generation system of being used for.The present invention particularly advantageously is applicable to vitreous toxic waste and the system that uses waste oil to act as a fuel.When furnace charge not with waste material during as its raw material, the present invention is equally applicable to the general gas furnace operating.
Various glass melting furnaces are arranged, and many kinds wherein all are applicable to the poisonous widely feedstock production glass of employing.In order when keeping the glass work output, to be suitable for raw material widely, offer the amount of the fuel gas or the oil of stove by change, will change condition in the stove.
Be shaped and fusion cast glass, need make glass reach 1350 ℃ temperature range.In order to realize this temperature, effluent gas temperature must be in about 1550 ℃ of temperature.Because temperature is high like this, the energy when stack gas is left stove is very high.Therefore, glass industry is being repaid examination always and is being come the recovery part heat by using accumulation of heat or heat exchange air preheating system.In this case, stack gas will be passed through a regenerator, and general regenerator comprises two chambers that are made of refractory brick, the air that the chamber heating is sent here, and it will be admitted in the stove, and the hot flue gases of stove is left in another chamber cooling.Because flowing through this chamber, stack gas can make the brick heating, so periodically open these chambers.When in a single day the temperature of brick reaches predetermined temperature, will change through the flow of this regenerator, make be input to this chamber be used for incendiary gas by hot brick preheating.When this process was carried out, second regenerator was used for removing heat from stove discharge gas.Passage by these two regenerator replaces continuously.Generally, the air preheating temperature value and is in 1450-1550 ℃ in the temperature of the stack gas on the top of regenerator between 1200-1300 ℃.Even air preheating temperature is so high, the temperature of leaving the stack gas of regenerator also is in the 450-600 ℃ of scope.This is equivalent to about 25% of the input of fuel energy in the stack gas.Why such reason be the thermal capacitance flux of fuel gas and this air under these temperature ratio more than 1.2: 1, this efficient that limits any regenerator is about 70 or 80%.
The interchanger that number of different types is arranged.Wherein a kind of interchanger is a metal construction, and it also can be built with refractory materials.In this interchanger, the waste gas of heat by flue, is equipped with metal or fire resisting material tube continuously in this flue.Air and waste gas adverse current are passed through this pipe continuously, thereby make its preheating.
Preheating 650-700 ℃ technological specification is that the temperature of combustion gas is 950-1050 ℃.So can see that this interchanger is effective not as regenerator.Therefore, they can not be widely used for the recovery of heat in the glass industry.
In order to guarantee that this heat do not lose, the energy in flue gases of furnace can be used for heating raw, heating boiler or is used for other Waste Heat Recovery System (WHRS), and this system is not connected with glass furnace.
Unfortunately, stack gas is used for the preheating furnace charge, normally stack gas is directly contacted with raw material, make that the water in raw material is discharged to chimney with hot flue gases along its passage.Yet when containing foxic waste in raw material, organic toxin also can be discharged with water.And international law stipulates any poisonous gas and all will it be disappeared destroys being exposed under the high temperature (its temperature is at least 1200 ℃) the one given period (this time was greater than for 2 seconds) under the excess of oxygen existence condition, and this just means that this selection was unacceptable when foxic waste was a part of in the furnace charge.
One of method of utilizing this energy is to come heating boiler with it.This boiler can be used to produce steam, generates electricity with driving steam turbine.Although the multipotency of common glass furnace produces the power of 1.5MW, it can prove and be difficult to use a common glass furnace that the output of one constant power is provided probably.If this energy will be effectively utilized, the power that produces by this equipment need be constant and predictable so.
Problem has occurred in the time will increasing the output of this boiler.The temperature that can raise in its kiln is conditional, because the refractory lining of the too high kiln of temperature can be damaged.The stack gas of similarly, discharging from stove is as if can not directly sending into boiler in the operating temperature range that is not reduced to the boiler permission.For example, for some stack gas, boiler can not be operated being higher than under 1200 ℃ the temperature.Then all the more so when containing volatile heavy metal and sour gas in the gas.If more gas is provided, promptly offer the gas of fuel by increase, then reduced the temperature in the kiln thus, this means from the gas gross of boiler output to increase equally.Yet, importantly will keep minimum from the gas volume of boiler feeding, because all such gases must be handled, to remove any remaining toxin, this toxin is not removed in vitreous.
Related equipment and technology is very expensive when handling such gas, is very important so handle the gas of minimum.
Up to now, proved that it is impossible wanting these three prerequisites of balance, that is:
(ⅰ) to from kiln, prepare the glass of maximum production;
(ⅱ) to from boiler, produce the power of predetermined constant amount; And
(ⅲ) to from boiler, produce the stack gas of minimum.
According to the present invention, a kind of vitreous and power generation equipment are provided, comprising:
One forming of glass kiln, comprising material inlet and gas feed, this gas comprises fuel gas or oil and preheated air and is used for feeding the kiln flue gas outlet;
Heat reclamation device, furnace flue gas install its temperature through this to be reduced, and this heat reclamation device also preheating is sent into the air of kiln; With
A boiler that links to each other with heat reclamation device comprising gas feed, is admitted to boiler by its furnace flue gas, and vapour outlet and pneumatic outlet are sent by this exhaust pass gas, and the stack gas of boiler is sent to a gas treating system;
Wherein boiler flue outlet and two outlet streams link to each other with the device that is used to be divided into two streams, make a stream that boiler flue is delivered to gas treating system, import, the outlet of kiln or the import of boiler of second stream guiding kiln, thus make the part of the stack gas of boiler form recirculation.
According to method of the present invention, its step comprises: feeding glass forms furnace charge, fuel gas or oil and preheating gas; Through heat reclamation device furnace flue gas (temperature of stack gas reduces in this device) is sent in the boiler, produce steam herein and export boiler flue, this vaporizer stack gas is sent to an air treatment system, thus, the recirculation of part boiler flue is entered the import of kiln import, kiln outlet or this boiler.
Take a part of boiler flue from the exit away, can reduce total volume of air of sending into gas treating system like this, and can reduce the cost of final gas processing thus.
If stack gas is sent into the kiln import, then increased the volume of air of sending into by kiln, this means that the air capacity that needs to add in the fuel gas may reduce.So just reduced the total air of sending in the system.
On the other hand, the stack gas of boiler is recycled to the kiln outlet, so that it can mix with the furnace flue gas phase before entering regenerator.In addition, also can when leaving regenerator, the boiler inlet place be admitted to furnace flue gas at it.
Separate a part of air-flow from boiler export and leave air handling feeding stream, thereby reduce the amount that to handle air.
Though first and second aspects of the present invention can independently be used, such system is dumb, and can not use kiln raw material widely.
The 3rd aspect of the present invention is that first and second aspects of the present invention are combined, wherein that part of in the glass handling will be sent in the stack gas of boiler, separated into two parts, a part is directly delivered to the import of kiln, and second section is delivered to the import of boiler.This system can be used for the part air-flow is introduced the kiln import, will partly introduce boiler inlet simultaneously.Yet, an on-off mechanism is preferably arranged, it is arranged at carries out switch between these streams.An efficient system so just is provided, thereby for example, in 1000 tons of glass of preparation, has produced the power of 36MW, and do not produce too much waste gas.
Boiler can be the water pipe type, also can be fire-tube type, and this depends on the size and the power of system.
Heat reclamation device can be common regenerator or interchanger, but preferably regenerator is uncurrent, and brick that need not effective volume in this regenerator seals, and would rather only use a spot of brick, so that a spot of heat of recovery from the stack gas of kiln only.Have additional benefit like this, guaranteed in all time waste gas is required regulation in 2 seconds of temperature maintenance more than 1200 ℃ without the regenerator of brick sealing.
Should be noted that usually the most effective heat exchange is to be that 3.3 times of kiln transverse section are realized by the volume that brick is provided.Yet for efficient system so too, brick will be drawn too many heat, and this will make the air themperature Tai Gao of preheating-too high for kiln.Therefore, be that this regenerator will be less than preferably effective volume with the meaning of the brick of " on a small quantity ".
According to all four aspects of the present invention, the example of vitreous and generation power system describes with reference now to accompanying drawing:
Fig. 1 is an outline flowchart of introducing kiln and boiler according to prior art;
Fig. 2 is according to system's outline flowchart of the present invention;
Fig. 3 is the fragmentary cross sectional view of an employed regenerator in native system.
Fig. 1 introduction be the kiln and the boiler systems of a general type.Kiln (1) is common forming of glass kiln, and it comprises material inlet (3) and gas feed (5), and this gas comprises fuel gas or oil.When glass formed, glass was sent by glass outlet (7).The stack gas of kiln is discharged by outlet (9), delivers to boiler (11) by regenerator (25) subsequently, and this boiler produces steam from vapour outlet (13).Boiler flue is sent by outlet (15), then, it is sent in the gas processing device shown in the sketch.
With carrying air as 24 air generator as described in sketch illustrates, one of them chamber 25A of regenerator 25 carries out preheating at this with wherein brick.The air flow air intlet 3 of preheating then, simultaneously, the outside cabin 25B that furnace flue gas is admitted to regenerator heats brick.Periodically chamber 25A and 25B are imported in exchange.
Raw material can be the mixture of sand, Wingdale, corundum, toxic materials and water.The example of toxic material is to contain radioactive substance, spent catalyst, filter cake, river sludge, dirt and dirty soil, oil refining residue in asbestos, incinerator resistates, the mining.Usually in order to realize output 527GJ from boiler (11), the hot-fluid that enters kiln must be 1072GJ.Thermal losses usually (A) is that 24GJ and the heat in glass output will be 218GJ, takes away 830GJ in stack gas.The stack gas that this means boiler is 303GJ.
Fig. 2 introduction be according to system of the present invention.Native system has made referrals to common ground and has used same label in Fig. 1, because these parts are identical.Below introduce the other part of native system.
The flue gas outlet of boiler (15) and branch's stream (19) and (21) link to each other with the device that is used to tell tributary (20).Selection for switch that adapts or valve is easily for those skilled in the art.First stream (19) is directly guided gas processing device (17) into.Second stream (21) is introduced recirculation with the part air-flow of boiler flue.Second stream (21) guides to two switches (26,28) that are used for the shunting and carry out switch between three streams (27,29 and 31), one of them (27) guide kiln import (5) into, another (29) guide kiln outlet (9) into, and the 3rd (31) guide boiler inlet (10) into.Provide air from air generator (24), process condenser (23) and regenerator (25) flow to the gas feed (5) of kiln (1).Vapour outlet (13) driving turbine with boiler produces power.This steam is discharged through condenser (23), and coagulum turns back to boiler (11).Coagulation generation heat by steam in condenser is used to heat the air that is provided.This air further carries out preheating by the chamber (25A) of regenerator.Regenerator (25B) obtains heat by the stack gas (9) of kiln.Boiler flue reduces the gas volume that will handle by recirculation.Whether recycle gas depends on the humidity that employed raw material and gas produces through path 27,29 or 31.Thermal losses when gas processing has also reduced.Numerical value in Fig. 2 is to be that unit shows heat flux with GJ per hour.Because per hour provide 47GJ in kiln, so the amount of per hour sending into GJ by fuel gas (5) can be reduced to 1025, and produce glass equally on request, and produce steam and drive turbine by boiler flue.Calculate by producing 1000 tons of glass every day, can produce the power of 36MW simultaneously.In Fig. 3, introduced a chamber in the regenerator 25, can see that therefrom this chamber comprises a spot of brick, but be not to seal with brick in the mode of sketch.Can carry out heat exchange like this, but not be effectively heat exchange.

Claims (8)

1, vitrifying and dynamogenic equipment, comprising:
Forming of glass kiln (1), it comprises the import (3,5) that is used for raw material, feeding gas and preheated air, this feeding gas comprises fuel gas or oil, and the flue gas outlet (9) of kiln;
Heat reclamation device (25), furnace flue gas install its temperature through this to be reduced, and this heat reclamation device also preheating is sent into the air of kiln; And
Boiler (11), link to each other with heat reclamation device (25), comprising a gas feed by its furnace flue pneumatic transmission go in the boiler (11), a vapour outlet (13) and air (15), stack gas through this outlet boiler is sent, boiler flue is delivered in the gas treating system (17), wherein:
On the flue outlet (5) of boiler, be connected with two devices that export streams (19,21) and be used for the branch stream, make a stream (19) be used for boiler flue is delivered to gas treating system (17), another stream (21) is used for guiding it into the import (5) of kiln, the outlet (9) or the boiler inlet (10) of kiln, thereby makes the part of boiler flue form recirculation.
2, according to the equipment of claim 1, wherein this kiln comprises that stack gas import and another outlet stream (21) guide to the stack gas import (5) of kiln, thereby, make the part of boiler flue air-flow enter kiln and carry out recirculation.
3, according to the equipment of claim 1, wherein another outlet stream (21) is guided kiln outlet (9) into, thereby the recirculation of part boiler flue air-flow is entered in the furnace flue gas that is fed to heat reclamation device (25).
4, according to the equipment of claim 1, wherein another outlet stream is guided boiler inlet (10) into, thereby makes a part of air-flow recirculation of boiler flue enter boiler inlet (10).
5, according to the equipment of claim 1, wherein another outlet stream (21) is drawn two streams, and one passes to the kiln import, and another passes to boiler inlet, thereby make a part of air-flow of boiler flue recirculation advance the kiln import, and the part air-flow is to boiler inlet.
6, according to the equipment of claim 5, its middle outlet stream (21) comprises switching arrangement, be used at the stream of introducing kiln import (5) and be introduced between the stream of boiler inlet (10) carrying out the switch of boiler flue air-flow, also can be recycled to boiler inlet (10) thereby make this boiler flue promptly can be recycled to kiln import (5).
7, require according to aforesaid right in any one desired equipment, wherein heat reclamation device comprises regenerator, comprising the volume of brick to be less than the volume of preferred kiln.
8, a kind of vitrifying and dynamogenic method, its step comprises: feeding forming of glass kiln raw material, fuel gas or oil and preheating gas; Furnace flue gas is delivered to the boiler from kiln through heat reclamation device (temperature of stack gas reduces in this device), this boiler produces steam and exports boiler flue, this boiler flue is delivered in the gas treating system, thus, the part of boiler flue is recirculated into the import of kiln import, kiln outlet or this vaporizer.
CN94113710A 1993-09-18 1994-09-17 Vitrification and power generation system Pending CN1112524A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB939319365A GB9319365D0 (en) 1993-09-18 1993-09-18 Vitrification & power generation system
GB9319365.4 1993-09-18

Publications (1)

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CN1112524A true CN1112524A (en) 1995-11-29

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CN94113710A Pending CN1112524A (en) 1993-09-18 1994-09-17 Vitrification and power generation system

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EP (1) EP0739314A1 (en)
JP (1) JPH09503738A (en)
CN (1) CN1112524A (en)
AU (1) AU7646194A (en)
BR (1) BR9407554A (en)
CA (1) CA2171427A1 (en)
GB (1) GB9319365D0 (en)
TW (1) TW294646B (en)
WO (1) WO1995008514A1 (en)
ZA (1) ZA947172B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102213541A (en) * 2011-05-26 2011-10-12 天津华能北方热力设备有限公司 Coal hot air furnace capable of simultaneously generating steam
CN103249999A (en) * 2010-12-27 2013-08-14 三菱重工业株式会社 Heat recovery and utilization system

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10359191B2 (en) * 2013-06-26 2019-07-23 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Direct-fired heating method and facility for implementing same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH248745A (en) * 1944-05-22 1947-05-31 Electroverre Romont Sa Process for using the heat contained in the fumes as they exit from at least one furnace.

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103249999A (en) * 2010-12-27 2013-08-14 三菱重工业株式会社 Heat recovery and utilization system
CN103249999B (en) * 2010-12-27 2015-08-05 三菱日立电力系统株式会社 Recuperation of heat utilizes system
US9803853B2 (en) 2010-12-27 2017-10-31 Mitsubishi Hitachi Powers Systems, Ltd. Heat recovery and utilization system
CN102213541A (en) * 2011-05-26 2011-10-12 天津华能北方热力设备有限公司 Coal hot air furnace capable of simultaneously generating steam

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Publication number Publication date
AU7646194A (en) 1995-04-10
JPH09503738A (en) 1997-04-15
BR9407554A (en) 1996-12-31
WO1995008514A1 (en) 1995-03-30
GB9319365D0 (en) 1993-11-03
TW294646B (en) 1997-01-01
EP0739314A1 (en) 1996-10-30
CA2171427A1 (en) 1995-03-30
ZA947172B (en) 1995-05-08

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