CN111234675A - Reflective heat insulation type heat preservation stone-like coating base material - Google Patents
Reflective heat insulation type heat preservation stone-like coating base material Download PDFInfo
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- CN111234675A CN111234675A CN202010253555.2A CN202010253555A CN111234675A CN 111234675 A CN111234675 A CN 111234675A CN 202010253555 A CN202010253555 A CN 202010253555A CN 111234675 A CN111234675 A CN 111234675A
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- base material
- stone
- potassium hexatitanate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A reflective heat insulation type heat preservation stone-like coating base material is prepared from the following raw materials in parts by weight: 10-20 parts of emulsion; 10-20 parts of potassium hexatitanate whisker powder; 30-50 parts of potassium hexatitanate whisker sand; 10-20 parts of modified ultra-white silicon dioxide powder, taking the base material prepared by the invention as a stone-like coating base material, adding a protective agent and an auxiliary agent by a conventional stone-like coating preparation method, and carrying out mixing, stirring, toning, granulating and other process flows to obtain the stone-like coating with heat preservation and insulation effects. The used potassium hexatitanate whisker sand and powder are dispersed in the coating, so that the coating has extremely high infrared reflection and diffuse reflection rate, and the silica powder used as the filler has small expansion coefficient, high hardness, good acid-base resistance and weather resistance, and can improve the tensile strength of the coating, so that the prepared coating has good heat insulation effect, high strength and good elasticity, and is not easy to generate cracks due to expansion with heat and contraction with cold.
Description
Technical Field
The invention relates to the field of building coatings, in particular to a reflective heat-insulation stone-like coating base material.
Background
The stone-like coating is a new product type which is very popular in the building coating industry in recent years, and the product takes a physical and chemical colloid technology and a surface treatment technology as theoretical bases; various colloidal stone-like particles with different sizes and colors are uniformly and stably suspended and dispersed in the water-based emulsion coating, and the pattern effect of the finished granite-like stone can reach the extent of being fake and unreal through one-step construction and forming.
For example, Chinese patent publication No. CN103849280A discloses 'a preparation method of an ultra-stable high weather-resistant water-in-water granite imitation multicolor paint'; chinese patent publication No. CN103319969A discloses an environment-friendly water-in-water multicolor paint and a preparation method thereof. The technical development and application of the stone-like coating are mature day by day, but the stone-like coating is still like common latex in the aspect of energy saving and has no reflective heat insulation function.
At present, porous low-barrier heat insulation materials such as asbestos cloth, glass wool, foam plastics and the like are adopted for partial heat insulation, and the materials can only slow down but cannot block the transfer of heat energy. In daytime, solar energy continuously enters the space and the structure in a room or a container through a roof, a wall or a container wall, and once heat energy is transmitted, the heat energy is trapped in the space and the structure even if the outdoor temperature is reduced.
The heat insulation coating is typically used on the outer wall surface of a building and an outdoor large storage tank, and the common wall surface heat insulation technologies at home and abroad are as follows: the external-hanging external heat-insulation polystyrene board and the wall body are formed by one-step pouring and the polystyrene particle heat-insulation mortar external wall is heat-insulation, and the heat resistance is used as a heat-insulation means, so that the effect is good, the influence on the load bearing, the external decoration and the like of the building is large, and the construction cost is greatly increased.
The existing popular heat insulation coating is different from a porous low-barrier heat insulation material, and usually adopts a reflective heat insulation material, namely absorbed heat can be radiated in a heat radiation mode to cool the indoor space, and meanwhile, the reflective heat insulation material can reduce the influence of heat radiation on the outer wall of a building or the outer wall of a container, so that the method is a method for fundamentally solving the heat insulation and heat preservation of the wall or the container. However, the existing reflective heat-insulating material has poor stability, insufficient construction performance and heat-insulating effect and no elasticity, cannot adapt to the change of thermal expansion and cold contraction of a wall body or a container wall, and is easy to crack.
Disclosure of Invention
The invention aims to solve the technical problems of overcoming the defects of the prior art and providing a reflective heat-insulation stone-like coating base material which has good stability, good construction performance and heat insulation effect, good elasticity and waterproof effect, is not easy to crack and has little environmental pollution.
The purpose of the invention is realized as follows: a reflective heat insulation type heat preservation stone-like coating base material is prepared from the following raw materials in parts by weight:
in one embodiment, the emulsion is an aqueous polyurethane emulsion.
In one embodiment, the feed additive is prepared from the following raw materials in parts by weight:
in one embodiment, the feed additive is prepared from the following raw materials in parts by weight:
in one embodiment, the feed additive is prepared from the following raw materials in parts by weight:
the base material prepared by the invention is used as the base material of the stone-like coating, the protective agent and the auxiliary agent are added by the conventional preparation method of the stone-like coating, and the stone-like coating with the heat preservation and insulation effects can be prepared by the process flows of mixing, stirring, toning, granulating and the like. The potassium hexatitanate whisker powder and the potassium hexatitanate whisker sand are dispersed in the coating, have extremely high infrared reflection and diffuse reflection, and meanwhile, the modified ultra-white silica powder serving as the filler also has high reflection, small expansion coefficient, high hardness, good acid-base resistance and weather resistance, and can improve the tensile strength of the coating, so that the prepared coating has good heat insulation effect, high strength and good elasticity, and is not easy to generate cracks due to thermal expansion and cold contraction.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more clear, the present invention is further described in detail below with reference to examples. It should be understood that the specific embodiments described herein are only for better understanding of the technical solutions of the present invention, and are not intended to limit the present invention.
A reflective heat insulation type heat preservation stone-like coating base material is prepared from the following raw materials in parts by weight:
the base material prepared by the invention is used as the base material of the stone-like coating, the protective agent and the auxiliary agent are added by the conventional preparation method of the stone-like coating, and the stone-like coating with the heat preservation and insulation effects can be prepared by the process flows of mixing, stirring, toning, granulating and the like. The potassium hexatitanate whisker powder and the potassium hexatitanate whisker sand are dispersed in the coating, have extremely high infrared reflection and diffuse reflection, and meanwhile, the modified ultra-white silica powder serving as the filler also has high reflection, small expansion coefficient, high hardness, good acid-base resistance and weather resistance, and can improve the tensile strength of the coating, so that the prepared coating has good heat insulation effect, high strength and good elasticity, and is not easy to generate cracks due to thermal expansion and cold contraction.
The potassium hexatitanate whisker sand is particles formed by grinding potassium hexatitanate whiskers, the potassium hexatitanate whiskers are K2Ti6O13, the structure is a chain tunnel type structure, and K + ions are arranged in the middle of a tunnel. The direct result of the structure is that K + ions have high stability, and the potassium hexatitanate crystal whisker has excellent mechanical property and physical property, stable chemical property, low heat conductivity coefficient and large heat capacity at high temperature, excellent corrosion resistance, heat resistance and heat insulation, wear resistance, lubricity and extremely high infrared reflection and diffuse reflection rate due to the structure, and the potassium hexatitanate crystal whisker as a heat insulation material mainly has the advantages of material structure based on the heat insulation material, extremely low heat conductivity coefficient, large heat capacity and high infrared reflection rate, can bear the high temperature of 1200 ℃, is more typical of heat insulation materials or coatings in the fields of space launching frames, military machinery, automobile exhaust pipes, dryers, petrochemical engineering pipelines and high specific required temperature, and is an ideal asbestos substitute material.
The potassium hexatitanate whisker powder is whisker powder made of potassium hexatitanate whiskers and is matched with potassium hexatitanate whisker sand to form a stone-like coating particle modeling main body.
In one embodiment, the emulsion is an aqueous polyurethane emulsion. The waterborne polyurethane emulsion has the advantages of good permeability and strong bonding force, has good bonding integrity with silicon dioxide powder and sand, and provides the bonding strength of the stone-like coating. And the surface of the waterborne polyurethane emulsion has strong anti-fouling capability, so that the surface of the coating is easier to clean.
In one embodiment, the feed additive is prepared from the following raw materials in parts by weight:
in one embodiment, the feed additive is prepared from the following raw materials in parts by weight:
in one embodiment, the feed additive is prepared from the following raw materials in parts by weight:
the above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (5)
1. The reflective heat-insulation type heat-preservation stone-like coating base material is characterized by being prepared from the following raw materials in parts by weight:
10-20 parts of emulsion;
10-20 parts of potassium hexatitanate whisker powder;
30-50 parts of potassium hexatitanate whisker sand
10-20 parts of modified ultra-white silicon dioxide powder.
2. The reflective insulation type heat preservation stone-like coating base material according to claim 1, characterized in that the emulsion is an aqueous polyurethane emulsion.
3. The reflective insulation type heat preservation stone-like coating base material according to claim 2, characterized by being prepared from the following raw materials in parts by weight:
10-13 parts of a water-based polyurethane emulsion;
17-20 parts of potassium hexatitanate whisker powder;
30-35 parts of potassium hexatitanate whisker sand
17-20 parts of modified ultra-white silicon dioxide powder.
4. The reflective insulation type heat preservation stone-like coating base material according to claim 2, characterized by being prepared from the following raw materials in parts by weight:
13-16 parts of a water-based polyurethane emulsion;
14-17 parts of potassium hexatitanate whisker powder;
35-45 parts of potassium hexatitanate whisker sand
14-17 parts of modified ultra-white silicon dioxide powder.
5. The reflective heat insulation type heat preservation stone-like coating base material according to claim 2 is characterized by being prepared from the following raw materials in parts by weight:
16-20 parts of a water-based polyurethane emulsion;
10-14 parts of potassium hexatitanate whisker powder;
45-50 parts of potassium hexatitanate whisker sand
10-14 parts of modified ultra-white silicon dioxide powder.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104231917A (en) * | 2014-10-13 | 2014-12-24 | 北京国泰瑞华精藻硅特种材料有限公司 | Nanometer high temperature resistant thermal insulation and prevention coating |
CN105400342A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Functional really stone paint and preparation method thereof |
CN106830753A (en) * | 2017-01-05 | 2017-06-13 | 安徽柏瑞特家居装饰品有限公司 | A kind of true mineral varnish of high-quality and preparation method thereof |
-
2020
- 2020-04-02 CN CN202010253555.2A patent/CN111234675A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104231917A (en) * | 2014-10-13 | 2014-12-24 | 北京国泰瑞华精藻硅特种材料有限公司 | Nanometer high temperature resistant thermal insulation and prevention coating |
CN105400342A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Functional really stone paint and preparation method thereof |
CN106830753A (en) * | 2017-01-05 | 2017-06-13 | 安徽柏瑞特家居装饰品有限公司 | A kind of true mineral varnish of high-quality and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
朱洪法: "《精细化工产品配方与制造 第5册》", 31 December 2000, 金盾出版社 * |
李肇强: "《现代涂料的生产及应用 第2版》", 31 March 2017, 上海科学技术文献出版社 * |
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Application publication date: 20200605 |