CN111233517A - Ground anti-skid maintenance material and preparation method thereof - Google Patents
Ground anti-skid maintenance material and preparation method thereof Download PDFInfo
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- CN111233517A CN111233517A CN202010053930.9A CN202010053930A CN111233517A CN 111233517 A CN111233517 A CN 111233517A CN 202010053930 A CN202010053930 A CN 202010053930A CN 111233517 A CN111233517 A CN 111233517A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Floor Finish (AREA)
Abstract
The invention discloses a ground anti-skid maintenance material and a preparation method thereof, and relates to the field of anti-skid materials, wherein the ground anti-skid maintenance material comprises a permeable layer and an anti-skid layer, the permeable layer is coated on the surface of a ceramic tile, and the anti-skid layer is coated on the surface of the permeable layer; the permeable layer comprises the following raw materials in parts by weight: 15-30 parts of nano calcium carbonate, 10-15 parts of glass fiber, 20-50 parts of polyethylene terephthalate and 20-50 parts of octadecanol polyoxyethylene ether. The anti-skid layer comprises the following raw materials in parts by weight: 10-20 parts of inorganic auxiliary agent, 5-10 parts of fatty alcohol-polyoxyethylene ether, 3-15 parts of ammonium oxide, 10-20 parts of fruit acid, 15-30 parts of butyl acetate and 30-40 parts of deionized water. According to the invention, the nano calcium carbonate can form a tiny uneven plane on the surface of the ceramic tile, so that the anti-skid layer can better permeate into the surface of the ceramic tile, and meanwhile, the uneven plane can increase the friction force on the surface of the ceramic tile.
Description
Technical Field
The invention relates to the field of anti-skid materials, in particular to a ground anti-skid maintenance material and a preparation method thereof.
Background
The skid resistance of the ceramic tile refers to the property of the ceramic tile to overcome the slipping in a special environment. At present, the anti-skid property of the ceramic tile is mainly formed by increasing the friction of a contact surface, and the surface of the ceramic tile is generally processed into a pattern or a concave-convex shape so as to increase the surface friction force. But not only can increase the processing procedure in the production process of the ceramic tile and reduce the smoothness and the aesthetic degree of the ceramic tile by processing the surface of the ceramic tile into a pattern or a concave-convex shape. The prior commonly used anti-slip agent usually adopts an acidic material with higher concentration and stronger corrosivity to corrode the surface of the ceramic tile, and easily influences the glossiness of the ceramic tile.
Disclosure of Invention
The invention aims to provide a ground anti-skid maintenance material and a preparation method thereof, and solves the problem that the existing anti-skid agent is easy to damage the surface glossiness of a ceramic tile.
In order to solve the technical problems, the technical scheme of the invention is as follows:
the ground anti-skid maintenance material comprises a permeable layer and an anti-skid layer, wherein the permeable layer is coated on the surface of a ceramic tile, and the anti-skid layer is coated on the surface of the permeable layer; the permeable layer comprises the following raw materials in parts by weight:
15-30 parts of nano calcium carbonate, 10-15 parts of glass fiber, 20-50 parts of polyethylene terephthalate and 20-50 parts of octadecanol polyoxyethylene ether;
the anti-skid layer comprises the following raw materials in parts by weight:
10-20 parts of inorganic auxiliary agent, 5-10 parts of fatty alcohol-polyoxyethylene ether, 3-15 parts of ammonium oxide, 10-20 parts of fruit acid, 15-30 parts of butyl acetate and 30-40 parts of deionized water.
Preferably, the particle size of the nano calcium carbonate is 50-80 nm.
Preferably, the fruit acid is tartaric acid or citric acid.
Preferably, the inorganic auxiliary agent is wood fiber.
The preparation method of the ground anti-skid maintenance material comprises the following steps:
(1) preparation of the permeation layer:
(1-1) adding glass fibers into a mixed solution of polyethylene terephthalate and polyoxyethylene octadecanol, and uniformly mixing by ultrasonic waves to obtain a first mixture;
(1-2) adding nano calcium carbonate into the first mixture, and uniformly stirring to obtain a permeation layer mixed solution;
(2) preparing an anti-slip layer:
(2-1) adding the inorganic auxiliary agent into butyl acetate, and uniformly mixing to obtain a second mixture for later use;
(2-2) adding the ammonium oxide into deionized water, and uniformly stirring to obtain a third mixture;
(2-3) sequentially adding fruit acid and fatty alcohol-polyoxyethylene ether into the third mixture, and uniformly stirring to obtain a fourth mixture;
(2-4) adding the second mixture and the third mixture into the fourth mixture, and uniformly stirring to obtain an anti-skid layer mixed solution;
(3) spraying the permeation layer mixed solution on the surface of a clean and dry ceramic tile, and performing permeation reaction for 10-30min to obtain a permeation layer;
(4) and (3) coating a layer of antiskid layer mixed solution on the surface of the permeable layer by using sponge, and carrying out osmotic reaction for 20-40min to obtain the required ground antiskid maintenance material.
By adopting the technical scheme, the nano calcium carbonate can form a tiny uneven plane on the surface of the ceramic tile, so that the anti-skid layer can better permeate the surface of the ceramic tile, and meanwhile, the uneven plane can increase the friction force on the surface of the ceramic tile; the nano calcium carbonate can be distributed more uniformly through the glass fiber, and the glass fiber has good optical transmittance and cannot influence the attractiveness of the surface of the ceramic tile; the fatty alcohol-polyoxyethylene ether is used as a penetrating agent, and can help the anti-skid layer to penetrate into the permeable layer; butyl acetate can play good dissolving effect to inorganic auxiliary agent, can further promote the frictional force on skid resistant course and then promote anti-skidding effect through inorganic auxiliary agent.
Drawings
FIG. 1 shows the performance test results of the anti-slip floor care material of the present invention.
Detailed Description
The following further describes embodiments of the present invention with reference to the drawings. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
Example 1
The ground anti-skid maintenance material comprises a permeable layer and an anti-skid layer, wherein the permeable layer is coated on the surface of a ceramic tile, and the anti-skid layer is coated on the surface of the permeable layer; the permeable layer comprises the following raw materials in parts by weight:
20 parts of calcium carbonate with the particle size of 60nm, 13 parts of glass fiber, 35 parts of polyethylene terephthalate and 35 parts of octadecanol polyoxyethylene ether;
the anti-skid layer comprises the following raw materials in parts by weight:
15 parts of wood fiber, 8 parts of fatty alcohol-polyoxyethylene ether, 10 parts of ammonium oxide, 15 parts of tartaric acid, 20 parts of butyl acetate and 35 parts of deionized water.
The preparation method of the ground anti-skid maintenance material comprises the following steps:
(1) preparation of the permeation layer:
(1-1) adding glass fibers into a mixed solution of polyethylene terephthalate and polyoxyethylene octadecanol, and uniformly mixing by ultrasonic waves to obtain a first mixture;
(1-2) adding nano calcium carbonate into the first mixture, and uniformly stirring to obtain a permeation layer mixed solution;
(2) preparing an anti-slip layer:
(2-1) adding the wood fiber into butyl acetate, and uniformly mixing to obtain a second mixture for later use;
(2-2) adding the ammonium oxide into deionized water, and uniformly stirring to obtain a third mixture;
(2-3) sequentially adding tartaric acid and fatty alcohol-polyoxyethylene ether into the third mixture, and uniformly stirring to obtain a fourth mixture;
(2-4) adding the second mixture and the third mixture into the fourth mixture, and uniformly stirring to obtain an anti-skid layer mixed solution;
(3) spraying the permeation layer mixed solution on the surface of a clean and dry ceramic tile, and performing permeation reaction for 20min to obtain a permeation layer;
(4) and (3) coating a layer of antiskid layer mixed solution on the surface of the permeable layer by using sponge, and carrying out osmotic reaction for 30min to obtain the required ground antiskid maintenance material.
According to the invention, the nano calcium carbonate can form a tiny uneven plane on the surface of the ceramic tile, so that the anti-skid layer can better permeate into the surface of the ceramic tile, and meanwhile, the uneven plane can increase the friction force on the surface of the ceramic tile; the nano calcium carbonate can be distributed more uniformly through the glass fiber, and the glass fiber has good optical transmittance and cannot influence the attractiveness of the surface of the ceramic tile; the fatty alcohol-polyoxyethylene ether is used as a penetrating agent, and can help the anti-skid layer to penetrate into the permeable layer; butyl acetate can play good dissolving effect to inorganic auxiliary agent, can further promote the frictional force on skid resistant course and then promote anti-skidding effect through inorganic auxiliary agent.
Example 2
The ground anti-skid maintenance material comprises a permeable layer and an anti-skid layer, wherein the permeable layer is coated on the surface of a ceramic tile, and the anti-skid layer is coated on the surface of the permeable layer; the permeable layer comprises the following raw materials in parts by weight:
15 parts of nano calcium carbonate with the particle size of 50nm, 10 parts of glass fiber, 20 parts of polyethylene terephthalate and 20 parts of octadecanol polyoxyethylene ether;
the anti-skid layer comprises the following raw materials in parts by weight:
10 parts of wood fiber, 5 parts of fatty alcohol-polyoxyethylene ether, 3 parts of ammonium oxide, 10 parts of citric acid, 15 parts of butyl acetate and 30 parts of deionized water.
The preparation method of the ground anti-skid maintenance material comprises the following steps:
(1) preparation of the permeation layer:
(1-1) adding glass fibers into a mixed solution of polyethylene terephthalate and polyoxyethylene octadecanol, and uniformly mixing by ultrasonic waves to obtain a first mixture;
(1-2) adding nano calcium carbonate into the first mixture, and uniformly stirring to obtain a permeation layer mixed solution;
(2) preparing an anti-slip layer:
(2-1) adding the wood fiber into butyl acetate, and uniformly mixing to obtain a second mixture for later use;
(2-2) adding the ammonium oxide into deionized water, and uniformly stirring to obtain a third mixture;
(2-3) sequentially adding citric acid and fatty alcohol-polyoxyethylene ether into the third mixture, and uniformly stirring to obtain a fourth mixture;
(2-4) adding the second mixture and the third mixture into the fourth mixture, and uniformly stirring to obtain an anti-skid layer mixed solution;
(3) spraying the permeation layer mixed solution on the surface of a clean and dry ceramic tile, and performing permeation reaction for 10min to obtain a permeation layer;
(4) and (3) coating a layer of antiskid layer mixed solution on the surface of the permeable layer by using sponge, and carrying out osmotic reaction for 20min to obtain the required ground antiskid maintenance material.
Example 3
The ground anti-skid maintenance material comprises a permeable layer and an anti-skid layer, wherein the permeable layer is coated on the surface of a ceramic tile, and the anti-skid layer is coated on the surface of the permeable layer; the permeable layer comprises the following raw materials in parts by weight:
30 parts of nano calcium carbonate with the particle size of 80nm, 15 parts of glass fiber, 50 parts of polyethylene terephthalate and 50 parts of octadecanol polyoxyethylene ether;
the anti-skid layer comprises the following raw materials in parts by weight:
20 parts of wood fiber, 10 parts of fatty alcohol-polyoxyethylene ether, 15 parts of ammonium oxide, 20 parts of tartaric acid and citric acid, 30 parts of butyl acetate and 40 parts of deionized water.
The preparation method of the ground anti-skid maintenance material comprises the following steps:
(1) preparation of the permeation layer:
(1-1) adding glass fibers into a mixed solution of polyethylene terephthalate and polyoxyethylene octadecanol, and uniformly mixing by ultrasonic waves to obtain a first mixture;
(1-2) adding nano calcium carbonate into the first mixture, and uniformly stirring to obtain a permeation layer mixed solution;
(2) preparing an anti-slip layer:
(2-1) adding the wood fiber into butyl acetate, and uniformly mixing to obtain a second mixture for later use;
(2-2) adding the ammonium oxide into deionized water, and uniformly stirring to obtain a third mixture;
(2-3) sequentially adding tartaric acid, citric acid and fatty alcohol-polyoxyethylene ether into the third mixture, and uniformly stirring to obtain a fourth mixture;
(2-4) adding the second mixture and the third mixture into the fourth mixture, and uniformly stirring to obtain an anti-skid layer mixed solution;
(3) spraying the permeation layer mixed solution on the surface of a clean and dry ceramic tile, and performing permeation reaction for 30min to obtain a permeation layer;
(4) and (3) coating a layer of antiskid layer mixed solution on the surface of the permeable layer by using sponge, and carrying out osmotic reaction for 40min to obtain the required ground antiskid maintenance material.
The physical indexes before and after the ceramic tile is treated are tested, the test standard is executed according to GB/T4100-.
Although the present invention has been described with reference to a preferred embodiment, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (5)
1. A ground antiskid maintenance material is characterized in that: the ceramic tile comprises a permeable layer and an anti-skid layer, wherein the permeable layer is coated on the surface of the ceramic tile, and the anti-skid layer is coated on the surface of the permeable layer; the permeable layer comprises the following raw materials in parts by weight:
15-30 parts of nano calcium carbonate, 10-15 parts of glass fiber, 20-50 parts of polyethylene terephthalate and 20-50 parts of octadecanol polyoxyethylene ether;
the anti-skid layer comprises the following raw materials in parts by weight:
10-20 parts of inorganic auxiliary agent, 5-10 parts of fatty alcohol-polyoxyethylene ether, 3-15 parts of ammonium oxide, 10-20 parts of fruit acid, 15-30 parts of butyl acetate and 30-40 parts of deionized water.
2. The non-slip floor care material as set forth in claim 1, wherein: the particle size of the nano calcium carbonate is 50-80 nm.
3. The non-slip floor care material as set forth in claim 1, wherein: the fruit acid is tartaric acid or citric acid.
4. The non-slip floor care material as set forth in claim 1, wherein: the inorganic auxiliary agent is wood fiber.
5. A method for preparing the anti-skid floor care material as claimed in any one of claims 1 to 4, wherein: the method comprises the following steps:
(1) preparation of the permeation layer:
(1-1) adding glass fibers into a mixed solution of polyethylene terephthalate and polyoxyethylene octadecanol, and uniformly mixing by ultrasonic waves to obtain a first mixture;
(1-2) adding nano calcium carbonate into the first mixture, and uniformly stirring to obtain a permeation layer mixed solution;
(2) preparing an anti-slip layer:
(2-1) adding the inorganic auxiliary agent into butyl acetate, and uniformly mixing to obtain a second mixture for later use;
(2-2) adding the ammonium oxide into deionized water, and uniformly stirring to obtain a third mixture;
(2-3) sequentially adding fruit acid and fatty alcohol-polyoxyethylene ether into the third mixture, and uniformly stirring to obtain a fourth mixture;
(2-4) adding the second mixture and the third mixture into the fourth mixture, and uniformly stirring to obtain an anti-skid layer mixed solution;
(3) spraying the permeation layer mixed solution on the surface of a clean and dry ceramic tile, and performing permeation reaction for 10-30min to obtain a permeation layer;
(4) and (3) coating a layer of antiskid layer mixed solution on the surface of the permeable layer by using sponge, and carrying out osmotic reaction for 20-40min to obtain the required ground antiskid maintenance material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010053930.9A CN111233517A (en) | 2020-01-17 | 2020-01-17 | Ground anti-skid maintenance material and preparation method thereof |
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| CN202010053930.9A CN111233517A (en) | 2020-01-17 | 2020-01-17 | Ground anti-skid maintenance material and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050274283A1 (en) * | 2004-06-10 | 2005-12-15 | Esselman Scott P | Method and composition for increasing slip resistance of a substrate surface |
| CN107325790A (en) * | 2017-07-28 | 2017-11-07 | 河北畅步地面防滑工程技术有限公司 | A kind of anti-skidding agent prescription of floor tile and preparation method |
| CN107418182A (en) * | 2017-08-25 | 2017-12-01 | 苏州群力防滑材料有限公司 | A kind of Antiskid ceramic tile with very strong security |
| CN110129004A (en) * | 2019-05-17 | 2019-08-16 | 广东极米新材料科技有限公司 | A kind of processing method that ground is anti-skidding |
| CN110527394A (en) * | 2019-08-14 | 2019-12-03 | 九月防滑科技(苏州)有限公司 | A kind of anti-skidding auxiliary agent for natatorium ceramic tile |
-
2020
- 2020-01-17 CN CN202010053930.9A patent/CN111233517A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050274283A1 (en) * | 2004-06-10 | 2005-12-15 | Esselman Scott P | Method and composition for increasing slip resistance of a substrate surface |
| CN107325790A (en) * | 2017-07-28 | 2017-11-07 | 河北畅步地面防滑工程技术有限公司 | A kind of anti-skidding agent prescription of floor tile and preparation method |
| CN107418182A (en) * | 2017-08-25 | 2017-12-01 | 苏州群力防滑材料有限公司 | A kind of Antiskid ceramic tile with very strong security |
| CN110129004A (en) * | 2019-05-17 | 2019-08-16 | 广东极米新材料科技有限公司 | A kind of processing method that ground is anti-skidding |
| CN110527394A (en) * | 2019-08-14 | 2019-12-03 | 九月防滑科技(苏州)有限公司 | A kind of anti-skidding auxiliary agent for natatorium ceramic tile |
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Application publication date: 20200605 |