CN111233397B - Concrete tunnel lining material and preparation method thereof - Google Patents
Concrete tunnel lining material and preparation method thereof Download PDFInfo
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- 239000004567 concrete Substances 0.000 title claims abstract description 34
- 239000000463 material Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 239000000835 fiber Substances 0.000 claims abstract description 125
- -1 polyethylene Polymers 0.000 claims abstract description 74
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000006185 dispersion Substances 0.000 claims abstract description 46
- 239000004698 Polyethylene Substances 0.000 claims abstract description 42
- 229920000573 polyethylene Polymers 0.000 claims abstract description 42
- 239000010881 fly ash Substances 0.000 claims abstract description 39
- 239000004568 cement Substances 0.000 claims abstract description 37
- 239000004743 Polypropylene Substances 0.000 claims abstract description 32
- 229920001155 polypropylene Polymers 0.000 claims abstract description 32
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 28
- 230000036571 hydration Effects 0.000 claims abstract description 28
- 238000006703 hydration reaction Methods 0.000 claims abstract description 28
- 239000004576 sand Substances 0.000 claims abstract description 28
- 238000010146 3D printing Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 34
- 238000003756 stirring Methods 0.000 claims description 27
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 17
- 235000002906 tartaric acid Nutrition 0.000 claims description 17
- 239000011975 tartaric acid Substances 0.000 claims description 17
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 15
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 14
- 238000009210 therapy by ultrasound Methods 0.000 claims description 14
- 229910021536 Zeolite Inorganic materials 0.000 claims description 13
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 13
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 13
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 13
- 239000010457 zeolite Substances 0.000 claims description 13
- 239000000725 suspension Substances 0.000 claims description 10
- 239000005457 ice water Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000011398 Portland cement Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims 6
- 230000003014 reinforcing effect Effects 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 229920005646 polycarboxylate Polymers 0.000 abstract description 30
- 238000010276 construction Methods 0.000 abstract description 17
- 238000009412 basement excavation Methods 0.000 abstract description 7
- 239000011435 rock Substances 0.000 abstract description 7
- 230000002787 reinforcement Effects 0.000 abstract description 4
- 230000007774 longterm Effects 0.000 abstract description 3
- 239000011229 interlayer Substances 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract 2
- 230000000052 comparative effect Effects 0.000 description 11
- 238000007639 printing Methods 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 239000011378 shotcrete Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000011150 reinforced concrete Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000008030 superplasticizer Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00181—Mixtures specially adapted for three-dimensional printing (3DP), stereo-lithography or prototyping
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
- C04B2111/343—Crack resistant materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
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- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开了一种的混凝土隧道衬砌材料,该材料由水泥、粉煤灰、聚乙烯短切纤维、聚丙烯异型纤维、纤维分散粘结助剂、水化调节剂、聚羧酸减水剂、水和砂制备而成,且无配筋并可借助3D打印设备进行施工。本发明还公开了上述材料的制备方法。该材料可借助3D打印设备在隧道开挖后迅速完成初次衬砌的施工,衬砌混凝土具有无配筋、超薄且韧性抗裂等特征,施工自动化程度高、材料变异性小、内轮廓面平整光滑,与隧道原始开挖面接触紧密、无空隙,Ⅱ级(含)以上围岩中可直接作为永久衬砌,Ⅱ级以下围岩中可与防水夹层及二次衬砌共同形成复合衬砌,从而为隧道运营空间的长期安全性和舒适性提供保障。The invention discloses a concrete tunnel lining material, which is composed of cement, fly ash, polyethylene chopped fiber, polypropylene special-shaped fiber, fiber dispersion and bonding assistant, hydration regulator and polycarboxylate water reducer. It is prepared from , water and sand without reinforcement and can be constructed with the help of 3D printing equipment. The invention also discloses a preparation method of the above material. The material can quickly complete the initial lining construction after tunnel excavation with the help of 3D printing equipment. The lining concrete has the characteristics of no reinforcement, ultra-thin, toughness and crack resistance, high degree of construction automation, small material variability, and smooth inner contour surface. It is in close contact with the original excavation surface of the tunnel and has no voids. The surrounding rock above grade II (inclusive) can be directly used as a permanent lining, and the surrounding rock below grade II can form a composite lining with the waterproof interlayer and secondary lining, so as to form a composite lining for the tunnel. Long-term safety and comfort of the operating space is guaranteed.
Description
技术领域technical field
本发明涉及隧道衬砌结构和材料领域,特别涉及一种混凝土隧道衬砌材料及其制备方法。The invention relates to the field of tunnel lining structures and materials, in particular to a concrete tunnel lining material and a preparation method thereof.
背景技术Background technique
随着铁路和公路的发展,隧道的数量和长度均在快速增加。同时,由于铁路和公路隧道的技术要求逐渐变高、隧道修建逐步向西部复杂地质环境中延伸等客观现实,现代隧道运营环境面临的挑战也越来越大。因此,作为开挖后支持和维护隧道长期稳定的永久结构物,隧道衬砌的质量要求也不断提高。然而,受地质环境的复杂性和不确定性、隧道施工人员的素质不一、隧道衬砌施工工艺水平参差不齐、施工设备差异较大等因素影响,隧道衬砌的施工质量难以始终保持高水平,从而影响后期运营安全和维护周期,甚至缩短隧道的使用寿命。With the development of railways and highways, the number and length of tunnels are increasing rapidly. At the same time, due to the objective reality of the increasingly high technical requirements of railway and highway tunnels and the gradual extension of tunnel construction to the complex geological environment in the west, the challenges faced by the modern tunnel operation environment are also increasing. Therefore, as a permanent structure to support and maintain the long-term stability of the tunnel after excavation, the quality requirements of the tunnel lining are also constantly increasing. However, due to the complexity and uncertainty of the geological environment, the different quality of tunnel construction personnel, the uneven construction technology level of tunnel lining, and the large difference in construction equipment, it is difficult to maintain a high level of construction quality of tunnel lining. This will affect the later operation safety and maintenance cycle, and even shorten the service life of the tunnel.
目前,国内外常用的隧道衬砌材料有:混凝土及钢筋混凝土、片石混凝土、料石或混凝土预制块,以及喷射混凝土等。上述各种衬砌材料均具有明显的优缺点,例如混凝土及钢筋混凝土衬砌的强度高、整体性强,但需要提前架设模板,因此存在支护不及时的弊端,不能在隧道开挖后迅速制止围岩变形的发展。另外,采用片石混凝土、料石或混凝土预制块修建的隧道衬砌虽然技术难度较低,对施工人员技术水平和施工设备的要求不高,但衬砌与开挖面间可能存在较多的空隙,为围岩进一步松动变形提供了空间,容易出现应力集中现象,进而引起开裂、渗水等问题。喷射混凝土衬砌有效改善了支护不及时的问题,但衬砌施工时不能控制衬砌外表面轮廓线,大多数情况下只能根据经验目测操作,因此,喷射混凝土衬砌与二次衬砌间的接触面容易出现不平整的现象;同时,受材料和设备水平等限制,目前喷射混凝土层的厚度十分有限,而且喷射混凝土质量可控性较差。At present, the commonly used tunnel lining materials at home and abroad are: concrete and reinforced concrete, rubble concrete, stone or concrete prefabricated blocks, and shotcrete. The above-mentioned various lining materials have obvious advantages and disadvantages. For example, concrete and reinforced concrete linings have high strength and strong integrity, but need to erect formwork in advance, so there is the disadvantage of untimely support, and can not be quickly stopped after tunnel excavation. The development of rock deformation. In addition, although the tunnel lining built with rubble concrete, aggregated stone or concrete prefabricated blocks is less technically difficult, and does not require high technical level of construction personnel and construction equipment, there may be many gaps between the lining and the excavation surface, which is a The further loosening and deformation of the surrounding rock provides space, which is prone to stress concentration, which in turn causes problems such as cracking and water seepage. Shotcrete lining can effectively improve the problem of untimely support, but the outline of the outer surface of the lining cannot be controlled during lining construction. At the same time, limited by the level of materials and equipment, the thickness of the current shotcrete layer is very limited, and the controllability of the shotcrete quality is poor.
发明内容SUMMARY OF THE INVENTION
针对目前常规隧道衬砌材料存在的弊端,本发明所要解决的技术问题为提供一种具有韧性抗裂特征且施工质量一致性较高的无配筋混凝土隧道衬砌材料。Aiming at the drawbacks of the current conventional tunnel lining materials, the technical problem to be solved by the present invention is to provide an unreinforced concrete tunnel lining material with toughness and crack resistance and high consistency of construction quality.
为解决上述技术问题,本发明所设计的技术方案为:For solving the above-mentioned technical problems, the technical scheme designed by the present invention is:
一种混凝土隧道衬砌材料,该混凝土隧道衬砌材料由水泥、粉煤灰、聚乙烯短切纤维、聚丙烯异型纤维、纤维分散粘结助剂、水化调节剂、聚羧酸减水剂、水和砂按如下比例制备而成:水泥21.8~30.9重量份、粉煤灰10.5~19.2重量份、聚乙烯短切纤维0.03~0.05重量份、聚丙烯异型纤维0.02~0.04重量份、纤维分散粘结助剂0.5~1.1重量份、水化调节剂0.22~0.41重量份、聚羧酸减水剂0.1~0.3重量份、水10.3~18.5重量份、砂40.2~65.9重量份,且各组分之和为100重量份;所述混凝土隧道衬砌材料无配筋且可借助3D打印设备进行施工。A concrete tunnel lining material, the concrete tunnel lining material is composed of cement, fly ash, polyethylene chopped fiber, polypropylene special-shaped fiber, fiber dispersion and bonding assistant, hydration regulator, polycarboxylate water reducer, water The mixed sand is prepared in the following proportions: 21.8-30.9 parts by weight of cement, 10.5-19.2 parts by weight of fly ash, 0.03-0.05 parts by weight of polyethylene chopped fibers, 0.02-0.04 parts by weight of polypropylene special-shaped fibers, and fibers dispersed and bonded 0.5-1.1 parts by weight of auxiliary, 0.22-0.41 parts by weight of hydration regulator, 0.1-0.3 parts by weight of polycarboxylate water reducing agent, 10.3-18.5 parts by weight of water, 40.2-65.9 parts by weight of sand, and the sum of each component is 100 parts by weight; the concrete tunnel lining material has no reinforcement and can be constructed by means of 3D printing equipment.
所述水泥为强度等级为52.5MPa的普通52.5硅酸盐水泥,粉煤灰为一级粉煤灰。The cement is ordinary 52.5 Portland cement with a strength grade of 52.5 MPa, and the fly ash is first-grade fly ash.
所述聚乙烯短切纤维的长度为1.5~2.5cm,直径为25~35μm,抗拉强度为2800~3000MPa,密度为0.98g/cm3。所述聚丙烯异型纤维的长度为4~6cm,直径为0.8~1.2mm,抗拉强度为550~650MPa,密度为0.90g/cm3。The polyethylene chopped fibers have a length of 1.5-2.5 cm, a diameter of 25-35 μm, a tensile strength of 2800-3000 MPa, and a density of 0.98 g/cm 3 . The polypropylene special-shaped fibers have a length of 4-6 cm, a diameter of 0.8-1.2 mm, a tensile strength of 550-650 MPa, and a density of 0.90 g/cm 3 .
所述纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比配制而成。其中,聚乙烯吡咯烷酮粉状颗粒物的固含量大于96%,超细沸石粉的细度为200~400目。The fiber dispersion and bonding assistant is prepared from polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10. Wherein, the solid content of the polyvinylpyrrolidone powder particles is greater than 96%, and the fineness of the ultrafine zeolite powder is 200-400 meshes.
所述水化调节剂由三乙醇胺和酒石酸按照1:(2.1~3.7)的重量比混合而成。The hydration regulator is prepared by mixing triethanolamine and tartaric acid in a weight ratio of 1:(2.1-3.7).
所述三乙醇胺、酒石酸和聚羧酸减水剂均为商品添加剂。The triethanolamine, tartaric acid and polycarboxylate water reducer are all commercial additives.
本发明还提供了上述混凝土隧道衬砌材料的制备方法,该方法包括如下步骤:The present invention also provides a method for preparing the above-mentioned concrete tunnel lining material, which comprises the following steps:
1)按材料组成比例计算称取水泥、粉煤灰、聚乙烯短切纤维、聚丙烯异型纤维、纤维分散粘结助剂、水化调节剂、聚羧酸减水剂、水和砂,备用;1) Calculate and weigh cement, fly ash, polyethylene chopped fibers, polypropylene special-shaped fibers, fiber dispersing and bonding aids, hydration regulators, polycarboxylate water reducers, water and sand according to the material composition ratio. ;
2)取水量15%~25%的水并将纤维分散粘结助剂加入其中,置于冰水浴中采用超声波处理30~60min得到纤维分散粘结助剂悬浮液;然后加入聚乙烯短切纤维并继续使用超声波处理10~30min得到稳定的聚乙烯短切纤维分散体A,待用;2) Take 15% to 25% of water and add fiber dispersing and bonding aid into it, place it in an ice-water bath and use ultrasonic treatment for 30 to 60 minutes to obtain fiber dispersion and bonding aid suspension; then add polyethylene chopped fibers And continue to use ultrasonic treatment for 10-30min to obtain stable polyethylene chopped fiber dispersion A, ready for use;
3)将称量好的水泥、粉煤灰与砂拌合均匀得到混合物B;3) evenly mixing the weighed cement, fly ash and sand to obtain mixture B;
4)将聚丙烯异型纤维、水化调节剂和聚羧酸减水剂加入剩余水中并搅拌均匀后,与A一起加入混合物B中,慢速搅拌10~30s,再快速搅拌1~5min,最后慢速搅拌30~60s即可。4) After adding polypropylene special-shaped fiber, hydration regulator and polycarboxylate water reducing agent to the remaining water and stirring evenly, add it to mixture B together with A, stir at a slow speed for 10-30s, then quickly stir for 1-5min, and finally Stir at slow speed for 30 to 60 s.
本发明通过添加较大比例的粉煤灰、利用水化调节剂来控制混凝土凝结时间并改善其流动性,从而在隧道开挖后可借助3D打印设备迅速完成初次衬砌的施工,保证初次衬砌与开挖面接触紧密、无空隙;而且,3D打印混凝土衬砌的内轮廓面平整光滑,可直接作为Ⅱ级(含)以上围岩中的永久衬砌,或者与后续防水夹层(隔离层)及二次衬砌共同形成Ⅱ级以下围岩中的永久衬砌,从而为隧道运营空间的长期安全性和舒适性提供保障基础。The invention controls the setting time of concrete and improves its fluidity by adding a relatively large proportion of fly ash and using hydration regulator, so that the construction of the primary lining can be quickly completed with the help of 3D printing equipment after tunnel excavation, so as to ensure that the primary lining and the The excavation surface is in close contact and has no voids; moreover, the inner contour surface of the 3D printed concrete lining is flat and smooth, which can be directly used as a permanent lining in the surrounding rock above Grade II (inclusive), or with the subsequent waterproof interlayer (isolation layer) and secondary The lining together forms a permanent lining in the surrounding rock below Grade II, thereby providing a guarantee basis for the long-term safety and comfort of the tunnel operating space.
特别需要说明的是水化调节剂和纤维分散粘结助剂的配合使用,一方面能够使掺入两种纤维的混凝土具备良好流动性和可挤出性,保证混凝土材料可快速均质地通过3D打印施工设备进行打印施工,且打印施工过程中粗细纤维不结团、不分层。另一方面,打印施工完毕后混凝土迅速凝结硬化,利于粗细纤维之间相互搭接且与混凝土间紧密粘结,形成稳定的空间网络结构,从而有效替代普通衬砌混凝土中的钢筋,使隧道衬砌混凝土具备无筋化、超薄化及韧性抗裂的特征。In particular, it should be noted that the combined use of hydration regulator and fiber dispersion and bonding agent can make the concrete mixed with the two fibers have good fluidity and extrudability, and ensure that the concrete material can pass through 3D homogeneously quickly and homogeneously. The printing construction equipment is used for printing construction, and the thick and thin fibers are not agglomerated or delaminated during the printing construction process. On the other hand, after the printing construction is completed, the concrete quickly solidifies and hardens, which is conducive to the overlapping between the thick and thin fibers and the close bonding with the concrete, forming a stable spatial network structure, which effectively replaces the steel bars in the ordinary lining concrete and makes the tunnel lining concrete. It has the characteristics of no reinforcement, ultra-thinning and toughness and crack resistance.
此外,聚乙烯短切纤维为和聚丙烯异型纤维的粗细、长短以及抗拉强度高低的搭配使用,可以在保证在不使用钢筋且降低衬砌厚度的前提下衬砌混凝土具仍有足够的强度,同时还具有优异的韧性,为其韧性变形能力和抗裂能力提供保障,使得围岩发生松动变形时衬砌混凝土可允许并控制其变形。In addition, the polyethylene chopped fiber is used in combination with the thickness, length and tensile strength of the polypropylene special-shaped fiber, which can ensure that the lining concrete still has sufficient strength without using steel bars and reducing the thickness of the lining, and at the same time It also has excellent toughness, which guarantees its tough deformation ability and crack resistance, so that the lining concrete can allow and control its deformation when the surrounding rock is loose and deformed.
具体实施方式Detailed ways
为了更好地阐述本发明,下面结合具体实施例进一步叙述本发明的内容,但本发明并不仅仅局限于下面的实施例。In order to better illustrate the present invention, the content of the present invention is further described below in conjunction with specific embodiments, but the present invention is not limited to the following embodiments.
对照例A0:Comparative example A 0 :
水泥:粉煤灰:聚羧酸减水剂:水:砂=25份:10份:0.25份:12.5份:52.25份。Cement: fly ash: polycarboxylate water reducing agent: water: sand = 25 parts: 10 parts: 0.25 parts: 12.5 parts: 52.25 parts.
首先,按配料比例称取水泥、粉煤灰、聚羧酸减水剂、水和砂,备用。然后,采用搅拌机将水泥、粉煤灰和砂搅拌均匀,得到混合物A;同时,将称量好聚羧酸减水剂加入水中并搅拌均匀,得到溶液B;然后,将B加入混合物A中,慢速搅拌30s,再快速搅拌3min,最后慢速搅拌60s即可。First, weigh cement, fly ash, polycarboxylate water-reducing agent, water and sand according to the proportion of ingredients, and set aside. Then, use a mixer to stir the cement, fly ash and sand evenly to obtain mixture A; at the same time, add the weighed polycarboxylate water reducing agent into water and stir to obtain solution B; then, add B into mixture A, Stir at slow speed for 30 s, then quickly stir for 3 min, and finally stir at slow speed for 60 s.
对照例A1:Comparative Example A 1 :
水泥:粉煤灰:聚乙烯短切纤维:纤维分散粘结助剂:水化调节剂:聚羧酸减水剂:水:砂=22.5份:12.6份:0.04份:0.5份:0.22份:0.1份:10.8份:53.24份。纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比混合而成而成。水化调节剂由三乙醇胺和酒石酸按照1:3的重量比混合而成。Cement: Fly Ash: Polyethylene Chopped Fiber: Fiber Dispersion Bonding Auxiliary: Hydration Regulator: Polycarboxylate 0.1 servings: 10.8 servings: 53.24 servings. The fiber dispersing and bonding aid is prepared by mixing polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10. The hydration regulator is prepared by mixing triethanolamine and tartaric acid in a weight ratio of 1:3.
取水量20%的水(即10.8*20%=2.16份)并将纤维分散粘结助剂加入其中,置于冰水浴中采用超声波处理45min得到纤维分散粘结助剂悬浮液;然后加入聚乙烯短切纤维并继续使用超声波处理20min得到稳定的聚乙烯短切纤维分散体C,待用;将称量好的水泥、粉煤灰与砂拌合均匀得到混合物D;将三乙醇胺、酒石酸和聚羧酸减水剂加入剩余水(即10.8*80%=8.64份)中并搅拌均匀后,与C一起加入到混合物D中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Take 20% of water (i.e. 10.8*20%=2.16 parts) and add the fiber dispersion bonding aid to it, place it in an ice-water bath and use ultrasonic treatment for 45min to obtain the fiber dispersion bonding aid suspension; then add polyethylene The chopped fibers are continuously treated with ultrasonic waves for 20 min to obtain a stable polyethylene chopped fiber dispersion C, which is ready for use; the weighed cement, fly ash and sand are mixed uniformly to obtain a mixture D; triethanolamine, tartaric acid and polyethylene are mixed. Carboxylic acid water reducing agent is added to the remaining water (ie 10.8*80%=8.64 parts) and stirred evenly, then added to mixture D together with C, stirred at a slow speed for 10s, then quickly stirred for 3 minutes, and finally stirred at a slow speed for 30s. .
对照例A2:Comparative Example A 2 :
水泥:粉煤灰:聚丙烯异型纤维:纤维分散粘结助剂:水化调节剂:聚羧酸减水剂:水:砂=22.5份:12.6份:0.03份:0.5份:0.22份:0.1份:10.8份:53.25份。纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比混合而成而成。水化调节剂由三乙醇胺和酒石酸按照1:3的重量比混合而成。Cement: Fly Ash: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Hydration Regulator: Polycarboxylate Servings: 10.8 Servings: 53.25 Servings. The fiber dispersing and bonding aid is prepared by mixing polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10. The hydration regulator is prepared by mixing triethanolamine and tartaric acid in a weight ratio of 1:3.
取水量20%的水(即10.8*20%=2.16份)并将纤维分散粘结助剂加入其中,置于冰水浴中采用超声波处理45min得到纤维分散粘结助剂悬浮液;将称量好的水泥、粉煤灰与砂拌合均匀得到混合物E;将聚丙烯异型纤维、三乙醇胺、酒石酸和聚羧酸减水剂加入剩余水(即10.8*80%=8.64份)中并搅拌均匀后,与纤维分散粘结助剂悬浮液一起加入到混合物E中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Take 20% water (i.e. 10.8*20%=2.16 parts) and add the fiber dispersion and bonding aid to it, place it in an ice-water bath and use ultrasonic treatment for 45min to obtain the fiber dispersion bonding aid suspension; Mix the cement, fly ash and sand evenly to obtain mixture E; add polypropylene special-shaped fiber, triethanolamine, tartaric acid and polycarboxylate water reducer to the remaining water (ie 10.8*80%=8.64 parts) and stir evenly , together with the fiber dispersion and bonding aid suspension, add it to the mixture E, stir at a slow speed for 10 s, then quickly stir for 3 min, and finally stir at a slow speed for 30 s.
对照例A3:Comparative Example A3 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:水化调节剂:聚羧酸减水剂:水:砂=22.5份:13.1份:0.04份:0.03份:0.22份:0.1份:10.8份:53.21份。水化调节剂由三乙醇胺和酒石酸按照1:3的重量比混合而成。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Hydration Regulator: Polycarboxylate : 10.8 servings: 53.21 servings. The hydration regulator is prepared by mixing triethanolamine and tartaric acid in a weight ratio of 1:3.
将称量好的水泥、粉煤灰与砂拌合均匀得到混合物F;将聚乙烯短切纤维、聚丙烯异型纤维、三乙醇胺、酒石酸和聚羧酸减水剂加入水中并搅拌均匀后加入到混合物F中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Mix the weighed cement, fly ash and sand evenly to obtain mixture F; add polyethylene chopped fibers, polypropylene special-shaped fibers, triethanolamine, tartaric acid and polycarboxylate water reducer into water and stir evenly and then add to the mixture. In mixture F, stir at slow speed for 10 s, then quickly stir for 3 min, and finally stir at slow speed for 30 s.
对照例A4:Comparative Example A4 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:碳酸钠:聚羧酸减水剂:水:砂=22.5份:12.6份:0.04份:0.03份:0.5份:0.22份:0.1份:10.8份:53.21份。纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比混合而成而成。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Aid: Sodium Carbonate: Polycarboxylate Water Reducer: Water: Sand=22.5 parts: 12.6 parts: 0.04 parts: 0.03 parts: 0.5 servings: 0.22 servings: 0.1 servings: 10.8 servings: 53.21 servings. The fiber dispersing and bonding aid is prepared by mixing polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10.
取水量20%的水(即10.8*20%=2.16份)并将纤维分散粘结助剂加入其中,置于冰水浴中采用超声波处理45min得到纤维分散粘结助剂悬浮液;然后加入聚乙烯短切纤维并继续使用超声波处理20min得到稳定的聚乙烯短切纤维分散体G,待用;将称量好的水泥、粉煤灰与砂拌合均匀得到混合物H;将聚丙烯异型纤维、硫酸钠和聚羧酸减水剂加入剩余水(即10.8*80%=8.64份)中并搅拌均匀后,与G一起加入到混合物H中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Take 20% of water (i.e. 10.8*20%=2.16 parts) and add the fiber dispersion bonding aid to it, place it in an ice-water bath and use ultrasonic treatment for 45min to obtain the fiber dispersion bonding aid suspension; then add polyethylene chopped fibers and continue to use ultrasonic treatment for 20min to obtain stable polyethylene chopped fiber dispersion G, which is ready for use; mix the weighed cement, fly ash and sand evenly to obtain mixture H; mix polypropylene special-shaped fibers, sulfuric acid Sodium and polycarboxylate superplasticizer were added to the remaining water (ie 10.8*80%=8.64 parts) and stirred evenly, then added to the mixture H together with G, stirred at a slow speed for 10s, then quickly stirred for 3 minutes, and finally stirred at a slow speed 30s is enough.
对照例A5:Comparative Example A5 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:三乙醇胺:聚羧酸减水剂:水:砂=22.5份:12.6份:0.04份:0.03份:0.5份:0.075份:0.1份:10.8份:53.355份。纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比混合而成而成。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Triethanolamine: Polycarboxylate Superplasticizer: Water: Sand=22.5 parts: 12.6 parts: 0.04 parts: 0.03 parts 0.5 part: 0.075 part: 0.1 part: 10.8 part: 53.355 part. The fiber dispersing and bonding aid is prepared by mixing polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10.
取水量20%的水(即10.8*20%=2.16份)并将纤维分散粘结助剂加入其中,置于冰水浴中采用超声波处理45min得到纤维分散粘结助剂悬浮液;然后加入聚乙烯短切纤维并继续使用超声波处理20min得到稳定的聚乙烯短切纤维分散体I,待用;将称量好的水泥、粉煤灰与砂拌合均匀得到混合物J;将聚丙烯异型纤维、三乙醇胺和聚羧酸减水剂加入剩余水(即10.8*80%=8.64份)中并搅拌均匀后,与I一起加入到混合物J中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Take 20% of water (i.e. 10.8*20%=2.16 parts) and add the fiber dispersion bonding aid to it, place it in an ice-water bath and use ultrasonic treatment for 45min to obtain the fiber dispersion bonding aid suspension; then add polyethylene Chopped fibers and continue to use ultrasonic treatment for 20min to obtain stable polyethylene chopped fiber dispersion I, set aside; the weighed cement, fly ash and sand are evenly mixed to obtain mixture J; polypropylene special-shaped fibers, three Ethanolamine and polycarboxylate water reducer are added to the remaining water (i.e. 10.8*80%=8.64 parts) and stirred evenly, then added to mixture J together with I, stirred at a slow speed for 10s, then quickly stirred for 3min, and finally stirred at a slow speed 30s is enough.
对照例A6:Comparative Example A6 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:酒石酸:聚羧酸减水剂:水:砂=22.5份:12.6份:0.04份:0.03份:0.5份:0.225份:0.1份:10.8份:53.205份。纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比混合而成而成。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Tartaric Acid: Polycarboxylate Servings: 0.225 Servings: 0.1 Servings: 10.8 Servings: 53.205 Servings. The fiber dispersing and bonding aid is prepared by mixing polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10.
取水量20%的水(即10.8*20%=2.16份)并将纤维分散粘结助剂加入其中,置于冰水浴中采用超声波处理45min得到纤维分散粘结助剂悬浮液;然后加入聚乙烯短切纤维并继续使用超声波处理20min得到稳定的聚乙烯短切纤维分散体K,待用;将称量好的水泥、粉煤灰与砂拌合均匀得到混合物L;将聚丙烯异型纤维、酒石酸和聚羧酸减水剂加入剩余水(即10.8*80%=8.64份)中并搅拌均匀后,与K一起加入到混合物L中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Take 20% of water (i.e. 10.8*20%=2.16 parts) and add the fiber dispersion bonding aid to it, place it in an ice-water bath and use ultrasonic treatment for 45min to obtain the fiber dispersion bonding aid suspension; then add polyethylene chopped fibers and continue to use ultrasonic treatment for 20min to obtain a stable polyethylene chopped fiber dispersion K, which is ready for use; mix the weighed cement, fly ash and sand evenly to obtain a mixture L; mix polypropylene special-shaped fibers, tartaric acid Add polycarboxylate water reducing agent and polycarboxylate to the remaining water (ie 10.8*80%=8.64 parts) and stir evenly, add to mixture L together with K, stir at slow speed for 10s, then quickly stir for 3min, and finally stir at slow speed for 30s That's it.
对照例A7:Comparative Example A7 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:水化调节剂:聚羧酸减水剂:水:砂=22.5份:12.6份:0.04份:0.03份:0.5份:0.3份:0.1份:10.8份:53.13份。纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比混合而成而成。水化调节剂由三乙醇胺和酒石酸按照2:1的重量比混合而成。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Hydration Regulator: Polycarboxylate Water Reducer: Water: Sand = 22.5 parts: 12.6 parts: 0.04 parts: 0.03 Servings: 0.5 Servings: 0.3 Servings: 0.1 Servings: 10.8 Servings: 53.13 Servings. The fiber dispersing and bonding aid is prepared by mixing polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10. The hydration regulator is prepared by mixing triethanolamine and tartaric acid in a weight ratio of 2:1.
取水量20%的水(即10.8*20%=2.16份)并将纤维分散粘结助剂加入其中,置于冰水浴中采用超声波处理45min得到纤维分散粘结助剂悬浮液;然后加入聚乙烯短切纤维并继续使用超声波处理20min得到稳定的聚乙烯短切纤维分散体M,待用;将称量好的水泥、粉煤灰与砂拌合均匀得到混合物N;将聚丙烯异型纤维、三乙醇胺、酒石酸和聚羧酸减水剂加入剩余水(即10.8*80%=8.64份)中并搅拌均匀后,与N一起加入到混合物N中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Take 20% of water (i.e. 10.8*20%=2.16 parts) and add the fiber dispersion bonding aid to it, place it in an ice-water bath and use ultrasonic treatment for 45min to obtain the fiber dispersion bonding aid suspension; then add polyethylene The chopped fibers are continuously treated with ultrasonic waves for 20 minutes to obtain a stable polyethylene chopped fiber dispersion M, which is ready for use; the weighed cement, fly ash and sand are mixed uniformly to obtain a mixture N; polypropylene special-shaped fibers, three Ethanolamine, tartaric acid and polycarboxylate water reducer were added to the remaining water (ie 10.8*80%=8.64 parts) and stirred evenly, then added to the mixture N together with N, stirred at a slow speed for 10s, then quickly stirred for 3 minutes, and finally slowly Stir at high speed for 30s.
实施例B1:Example B 1 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:水化调节剂:聚羧酸减水剂:水:砂=22.5份:12.6份:0.04份:0.03份:0.5份:0.22份:0.1份:10.8份:53.21份。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Hydration Regulator: Polycarboxylate Water Reducer: Water: Sand = 22.5 parts: 12.6 parts: 0.04 parts: 0.03 Servings: 0.5 Servings: 0.22 Servings: 0.1 Servings: 10.8 Servings: 53.21 Servings.
实施例B2:Example B2 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:水化调节剂:聚羧酸减水剂:水:砂=30.5份:11份:0.04份:0.03份:0.5份:0.4份:0.2份:15.25份:42.08份。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Hydration Regulator: Polycarboxylate Water Reducer: Water: Sand=30.5 parts: 11 parts: 0.04 parts: 0.03 Servings: 0.5 Servings: 0.4 Servings: 0.2 Servings: 15.25 Servings: 42.08 Servings.
实施例B3:Example B3 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:水化调节剂:聚羧酸减水剂:水:砂=26.3份:15.8份:0.05份:0.02份:0.8份:0.31份:0.2份:11.5份:45.02份。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Hydration Regulator: Polycarboxylate Water Reducer: Water: Sand = 26.3 parts: 15.8 parts: 0.05 parts: 0.02 Servings: 0.8 Servings: 0.31 Servings: 0.2 Servings: 11.5 Servings: 45.02 Servings.
实施例B4:Example B4 :
水泥:粉煤灰:聚乙烯短切纤维:聚丙烯异型纤维:纤维分散粘结助剂:水化调节剂:聚羧酸减水剂:水:砂=30.3份:15.53份:0.03份:0.04份:1份:0.4份:0.28份:12.2份:40.22份。Cement: Fly Ash: Polyethylene Chopped Fiber: Polypropylene Shaped Fiber: Fiber Dispersion Bonding Auxiliary: Hydration Regulator: Polycarboxylate Water Reducer: Water: Sand=30.3 parts: 15.53 parts: 0.03 parts: 0.04 Servings: 1 Serving: 0.4 Servings: 0.28 Servings: 12.2 Servings: 40.22 Servings.
实施例B1~B4的混凝土隧道衬砌材料制备方法中:In the preparation method of concrete tunnel lining material of embodiment B1~B4:
首先,按材料组成比例计算称取水泥、粉煤灰、聚乙烯短切纤维、聚丙烯异型纤维、纤维分散粘结助剂、水化调节剂、聚羧酸减水剂、水和砂,备用。First, calculate and weigh cement, fly ash, polyethylene chopped fibers, polypropylene special-shaped fibers, fiber dispersing and bonding aids, hydration regulators, polycarboxylate water reducers, water and sand according to the material composition ratio. .
其中:in:
所述水泥为强度等级为52.5MPa的普通52.5硅酸盐水泥,粉煤灰为一级粉煤灰。The cement is ordinary 52.5 Portland cement with a strength grade of 52.5 MPa, and the fly ash is first-grade fly ash.
所述聚乙烯短切纤维的长度为1.5~2.5cm,直径为25~35μm,抗拉强度为2800~3000MPa,密度为0.98g/cm3。所述聚丙烯异型纤维的长度为4~6cm,直径为0.8~1.2mm,抗拉强度为550~650MPa,密度为0.90g/cm3。The polyethylene chopped fibers have a length of 1.5-2.5 cm, a diameter of 25-35 μm, a tensile strength of 2800-3000 MPa, and a density of 0.98 g/cm 3 . The polypropylene special-shaped fibers have a length of 4-6 cm, a diameter of 0.8-1.2 mm, a tensile strength of 550-650 MPa, and a density of 0.90 g/cm 3 .
所述纤维分散粘结助剂由聚乙烯吡咯烷酮和超细沸石粉按照1:10的重量比混合而成而成。其中,聚乙烯吡咯烷酮粉状颗粒物的固含量大于96%,超细沸石粉的细度为200~400目。The fiber dispersion and bonding assistant is prepared by mixing polyvinylpyrrolidone and ultrafine zeolite powder in a weight ratio of 1:10. Wherein, the solid content of the polyvinylpyrrolidone powder particles is greater than 96%, and the fineness of the ultrafine zeolite powder is 200-400 meshes.
所述水化调节剂由三乙醇胺和酒石酸按照1:3的重量比混合而成。The hydration regulator is prepared by mixing triethanolamine and tartaric acid in a weight ratio of 1:3.
所述三乙醇胺、酒石酸、聚羧酸减水剂均为商品添加剂。The triethanolamine, tartaric acid and polycarboxylate water reducer are all commercial additives.
其次,取水量20%的水并将聚乙烯吡咯烷酮和超细沸石粉加入其中,置于冰水浴中采用超声波处理45min得到纤维分散粘结助剂悬浮液;然后加入聚乙烯短切纤维并继续使用超声波处理20min得到稳定的聚乙烯短切纤维分散体O,待用;将称量好的水泥、粉煤灰与砂拌合均匀得到混合物P;将聚丙烯异型纤维、三乙醇胺、酒石酸和聚羧酸减水剂加入剩余水中并搅拌均匀后,与O一起加入到混合物P中,慢速搅拌10s,再快速搅拌3min,最后慢速搅拌30s即可。Next, take 20% of water and add polyvinylpyrrolidone and ultrafine zeolite powder into it, place it in an ice-water bath and use ultrasonic treatment for 45min to obtain a suspension of fiber dispersion and bonding aid; then add polyethylene chopped fibers and continue to use Ultrasonic treatment for 20min obtains stable polyethylene chopped fiber dispersion O, which is ready for use; the weighed cement, fly ash and sand are evenly mixed to obtain mixture P; polypropylene special-shaped fibers, triethanolamine, tartaric acid and polycarboxylate are mixed After adding the acid water reducing agent to the remaining water and stirring evenly, it is added to the mixture P together with O, stirred at a slow speed for 10 s, then quickly stirred for 3 min, and finally stirred at a slow speed for 30 s.
按照《公路工程水泥及水泥混凝土试验规程JTG E30-2005》,测试本发明实施例与对照例的流动度、6h和28d抗压强度、抗折强度以及28d抗弯极限跨中挠度,结果汇总于表1。由表中各项指标测试结果可知,对照例A0和A6在6h时强度还未形成,对照例A1~A4中虽然添加了水化调节剂或其它常规速凝剂,但本发明实施例B1~B4的6h和28d抗压强度、抗折抗压强度以及韧性(即极限跨中挠度)均显著大于对照例,表明本发明实施例所列混凝土隧道衬砌材料具有早期强度发展速度快的优势。本发明实施例的流动度适中,有利于控制混凝土隧道衬砌材料的打印施工。与对照例A1和A2相比,聚乙烯短切纤维和聚丙烯异型纤维的搭配使用在强度和韧性方面均显著优于单独使用其中一种纤维。与对照例A3相比,本发明实施例中采用纤维分散粘结助剂后使得纤维的协同作用更为显著,表现为强度和韧性更优异。与对照例A4、A5和A7相比,采用其它速凝剂或仅使用三乙醇胺作为促凝剂或三乙醇胺/酒石酸配比不当时,虽然衬砌材料也具备快凝早强的特征,但28d强度和韧性均明显低于本发明的实施例。According to the "Highway Engineering Cement and Cement Concrete Test Regulations JTG E30-2005", the fluidity, 6h and 28d compressive strength, flexural strength and 28d flexural limit mid-span deflection of the embodiment of the present invention and the control example were tested. The results are summarized in Table 1. It can be seen from the test results of the indicators in the table that the strength of the comparative examples A 0 and A 6 has not yet formed at 6h. Although the comparative examples A 1 to A 4 have added hydration regulators or other conventional accelerators, the present invention The 6h and 28d compressive strengths, flexural compressive strengths and toughness (i.e. ultimate mid-span deflection) of Examples B1 to B4 are significantly greater than those of the control example, indicating that the concrete tunnel lining materials listed in the examples of the present invention have early strength development Speed advantage. The fluidity of the embodiment of the present invention is moderate, which is beneficial to control the printing construction of the concrete tunnel lining material. Compared with the control examples A 1 and A 2 , the combined use of polyethylene chopped fibers and polypropylene profiled fibers is significantly better than the use of either fiber alone in terms of strength and toughness. Compared with the control example A 3 , the fibers in the examples of the present invention have a more significant synergistic effect after using the fiber dispersion and bonding assistant, which is manifested as better strength and toughness. Compared with the control examples A 4 , A 5 and A 7 , when other accelerators are used or only triethanolamine is used as the accelerator or the ratio of triethanolamine/tartaric acid is not appropriate, although the lining material also has the characteristics of fast setting and early strength, However, the strength and toughness of 28d are significantly lower than those of the examples of the present invention.
表1本发明中的实施例与对照例性能测试结果Table 1 Embodiment in the present invention and comparative example performance test result
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