CN111215097A - MoS2/Sb2S3Preparation method of composite photocatalyst - Google Patents
MoS2/Sb2S3Preparation method of composite photocatalyst Download PDFInfo
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- 239000011941 photocatalyst Substances 0.000 title claims abstract description 34
- 229910052961 molybdenite Inorganic materials 0.000 title claims abstract description 30
- 229910052982 molybdenum disulfide Inorganic materials 0.000 title claims abstract description 30
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 11
- 229910052959 stibnite Inorganic materials 0.000 claims abstract description 32
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 19
- 239000002243 precursor Substances 0.000 claims abstract description 17
- 238000001816 cooling Methods 0.000 claims abstract description 12
- 239000011259 mixed solution Substances 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000007789 sealing Methods 0.000 claims abstract description 7
- 239000012299 nitrogen atmosphere Substances 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 6
- 238000000926 separation method Methods 0.000 claims description 7
- 238000001291 vacuum drying Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000012298 atmosphere Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000002045 lasting effect Effects 0.000 claims 1
- 230000001699 photocatalysis Effects 0.000 abstract description 11
- 238000001179 sorption measurement Methods 0.000 abstract description 5
- 238000013033 photocatalytic degradation reaction Methods 0.000 abstract description 4
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 abstract description 3
- 229940043267 rhodamine b Drugs 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 6
- 238000007146 photocatalysis Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000004770 chalcogenides Chemical group 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000000593 degrading effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- -1 transition metal disulfide Chemical class 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 229910052699 polonium Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
- B01J27/051—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0218—Compounds of Cr, Mo, W
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0285—Sulfides of compounds other than those provided for in B01J20/045
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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Abstract
The invention discloses a MoS2/Sb2S3The preparation method of the composite photocatalyst comprises the following steps: reacting SbCl3And CH3CSNH2Dissolving in anhydrous ethanol, stirring under nitrogen atmosphere for 25-35min, and centrifuging to obtain bright orange precursor; dissolving the prepared precursor in deionized water, and magnetically stirring to obtain Sb2S3Precursor solution, adding H32Mo7N6O28And CH4N2S, stirring to obtain a mixed solution; transferring the mixed solution into a reaction kettle, placing into a muffle furnace, sealing, heating to 165-175 deg.C for 25-27h, and coolingAnd after the temperature is reduced to room temperature, centrifugally separating, washing, drying and cooling to obtain the catalyst. The method is simple, convenient, rapid and easy to operate, and the prepared MoS2/Sb2S3The composite photocatalyst has higher efficiency on photocatalytic degradation of rhodamine B, shows excellent adsorption performance and photocatalytic performance, and has certain application value.
Description
Technical Field
The invention relates to a MoS2/Sb2S3A preparation method of a composite photocatalyst.
Background
In recent years, the nano semiconductor photocatalysis technology has attracted wide attention due to the great advantages of the nano semiconductor photocatalysis technology in the aspects of alternative energy and environmental remediation, and is also applied to industrial production. A wide variety of semiconductor photocatalytic materials such as TiO2CdS, ZnO and different morphological structures such as flower-like (SnWO)4) Rod-like (ZnO), sheet-like (BiVO)4) The binary metal oxide of (A) has a certain application in the field of photocatalysis. However, TiO2The photocatalyst such as ZnO has a wider band gap structure, has stronger response to ultraviolet light only and lower utilization rate to natural light, so that the special properties of other materials and TiO are utilized2The photocatalyst is compounded, so that the improvement of the photocatalytic performance becomes a new research hotspot.
At present, metal sulfides such as Sb2S3、Bi2S3Due to the narrow band gap structure, it has attracted a wide attention to have a strong response in the visible region. Among numerous binary metal sulfides, the direct band gap semiconductor material Sb belonging to the orthorhombic system2S3Due to strong spectral response, higher thermal band energy and excellent photoelectric property, the photocatalyst is widely applied to the fields of solar energy conversion, photocatalysis, thermoelectric cooling and the like, and simultaneously is used as a photocatalyst together with TiO2Compared with ZnO, the photocatalyst has higher photocatalytic degradation efficiency in a visible light region. Sb2S3The main disadvantages of (1) are that photogenerated electron-hole pairs are easy to recombine and the electron migration rate is slow. Increase of Sb2S3The improvement of the separation efficiency by utilizing the oxidation mechanism of electron hole pairs in water is considered as the key for effectively degrading organic pollutants, so that the design of the composite material for effectively reducing the recombination rate of photo-generated electron holes becomes a research hotspot. To promote Sb2S3Efficient separation of photogenerated carriers, some semiconductor materials (TiO)2ZnO) or conductor materials (rGO, carbon nanotube CNT) and Sb2S3Composite, as an electron transfer acceptor, greatly improves Sb2S3The photon-generated carrier migration rate and the separation efficiency.
The latest research found that MoS2As a two-dimensional (2D) layered material similar to graphene, attention is paid to its layered structure, in which each layer is formed of two hexagonal close-packed S atoms and one Mo atom in between to form a sandwich structure, adjacent layers are bonded together by weak van der waals force, MoS2The layered structure shows huge specific surface area and more active sites, so that the layered structure has certain adsorption performance and also provides rapid migration of electronsIt is possible. As a member of a transition metal disulfide (MX)2M represents transition metal, X represents chalcogenide metal such as S, Se, Te and Po), the band gap of the chalcogenide metal is 1.23-1.69 eV, the solar light utilization rate is high, and the band gap is related to factors such as layer thickness, nanometer size and doping. MoS2The crystal phase of (A) is mainly hexagonal phase 2H-MoS2Orthorhombic 3R-MoS phase2Tetragonal phase 1T-MoS2。MoS2The properties of the catalyst can be widely applied to a plurality of aspects such as sensors, super capacitors, solar panels, catalytic hydrogen production and the like, and can be used as a cocatalyst for degrading organic wastewater. Mixing MoS2And Sb2S3The composite photocatalyst is prepared by compounding, and not only can exert Sb2S3Can exert strong absorption effect on visible light and strong photocatalytic activity thereof, and can also exert MoS2The function of (1): (1) as an excellent electron transporter, the photocatalyst can efficiently prevent the self-phase recombination of electron hole pairs in the photocatalysis process so as to improve the catalytic performance of the photocatalyst; (2) mixing MoS2The photocatalyst is compounded with the photocatalyst, so that the light absorption intensity of the photocatalyst can be improved, and the absorption wavelength range of sunlight is expanded, so that the solar energy utilization rate is improved; (3) MoS with huge specific surface area2The photocatalyst carrier can increase the specific surface area of a semiconductor, so that the adsorption sites and the catalytic sites of the composite material are increased, and finally, the catalytic performance of the photocatalyst is enhanced. Simultaneously, MoS2And Sb2S3Compounding also helps to reduce MoS2The self-phase stacking phenomenon is more beneficial to the dispersion of the photocatalyst. Thus, Sb2S3And MoS2The composite photocatalyst has wide research prospect.
Disclosure of Invention
The invention aims to provide a MoS2/Sb2S3A preparation method of a composite photocatalyst.
The invention is realized by the following technical scheme:
MoS2/Sb2S3Preparation method of composite photocatalyst and packageThe method comprises the following steps: 5-7 parts of SbCl3And 8-10 parts of CH3CSNH2Dissolving in 55-65 parts of absolute ethyl alcohol, magnetically stirring for 25-35min under the atmosphere of nitrogen, and performing centrifugal separation to obtain a bright orange precursor; the prepared SbCl3Dissolving the bright orange precursor in 50-60 parts of deionized water, and magnetically stirring to obtain Sb2S3Adding 2-4 parts of H into the precursor solution32Mo7N6O28And 5-7 parts of CH4N2S, magnetically stirring to obtain a mixed solution; finally transferring the mixed solution into a reaction kettle, putting the reaction kettle into a muffle furnace, sealing and heating the reaction kettle to 165-175 ℃, keeping the temperature for 25-27h, cooling the reaction kettle to room temperature, and then, adding MoS2/Sb2S3Centrifugally separating the composite photocatalyst, washing with anhydrous ethanol and deionized water for 4-6 times, drying in a vacuum drying oven at 45-55 deg.C for 13-15h, and cooling; the raw materials are in parts by weight.
Preferably, in the preparation method, the magnetic stirring is carried out for 30min under the nitrogen atmosphere.
Preferably, in the preparation method, the mixture is placed into a muffle furnace to be hermetically heated to 170 ℃.
Preferably, the preparation method lasts for 26 h.
Preferably, in the preparation method, the mixture is dried for 14 hours in a vacuum drying oven at 50 ℃.
The invention has the technical effects that:
the method is simple, convenient, rapid and easy to operate, and the prepared MoS2/Sb2S3The composite photocatalyst has higher efficiency on photocatalytic degradation of rhodamine B, shows excellent adsorption performance and photocatalytic performance, and has certain application value.
Detailed Description
The following describes the substance of the present invention with reference to the examples.
Example 1
MoS2/Sb2S3The preparation method of the composite photocatalyst comprises the following steps: 6 parts of SbCl3And 9 parts of CH3CSNH2Dissolved in 60 parts of absolute ethyl alcoholMagnetically stirring for 30min under nitrogen atmosphere, and performing centrifugal separation to obtain a bright orange precursor; the prepared SbCl3Dissolving the bright orange precursor in 55 parts of deionized water, and magnetically stirring to obtain Sb2S3Precursor solution, 3 parts of H are added32Mo7N6O28And 6 parts of CH4N2S, magnetically stirring to obtain a mixed solution; finally transferring the mixed solution into a reaction kettle, putting the reaction kettle into a muffle furnace, sealing and heating the reaction kettle to 170 ℃, continuing for 26 hours, cooling the reaction kettle to room temperature, and then, adding MoS2/Sb2S3Centrifugally separating the composite photocatalyst, washing with anhydrous ethanol and deionized water for 5 times, drying in a vacuum drying oven at 50 deg.C for 14h, and cooling to obtain the final product; the raw materials are in parts by weight.
Example 2
MoS2/Sb2S3The preparation method of the composite photocatalyst comprises the following steps: 5 parts of SbCl3And 8 parts of CH3CSNH2Dissolving in 55 parts of absolute ethyl alcohol, magnetically stirring for 25min under the nitrogen atmosphere, and performing centrifugal separation to obtain a bright orange precursor; the prepared SbCl3Dissolving the bright orange precursor in 50 parts of deionized water, and magnetically stirring to obtain Sb2S3Precursor solution, 2 parts of H are added32Mo7N6O28And 5 parts of CH4N2S, magnetically stirring to obtain a mixed solution; finally transferring the mixed solution into a reaction kettle, putting the reaction kettle into a muffle furnace, sealing and heating the reaction kettle to 165 ℃ for 25 hours, cooling the reaction kettle to room temperature, and then, adding MoS2/Sb2S3Centrifugally separating the composite photocatalyst, washing with anhydrous ethanol and deionized water for 4 times, drying in a vacuum drying oven at 45 deg.C for 13h, and cooling to obtain the final product; the raw materials are in parts by weight.
Example 3
MoS2/Sb2S3The preparation method of the composite photocatalyst comprises the following steps: 7 parts of SbCl3And 10 parts of CH3CSNH2Dissolving in 65 parts of anhydrous ethanol, magnetically stirring under nitrogen atmosphere for 35min, and centrifuging to obtain bright orange extractDriving a body; the prepared SbCl3Dissolving the bright orange precursor in 60 parts of deionized water, and magnetically stirring to obtain Sb2S3Precursor solution, 4 parts of H are added32Mo7N6O28And 7 parts of CH4N2S, magnetically stirring to obtain a mixed solution; finally transferring the mixed solution into a reaction kettle, putting the reaction kettle into a muffle furnace, sealing and heating the reaction kettle to 175 ℃, keeping the temperature for 27 hours, cooling the reaction kettle to room temperature, and then, adding MoS2/Sb2S3Centrifugally separating the composite photocatalyst, washing with absolute ethyl alcohol and deionized water for 6 times, drying in a vacuum drying oven at 55 ℃ for 15h, and cooling to obtain the photocatalyst; the raw materials are in parts by weight.
The method is simple, convenient, rapid and easy to operate, and the prepared MoS2/Sb2S3The composite photocatalyst has higher efficiency on photocatalytic degradation of rhodamine B, shows excellent adsorption performance and photocatalytic performance, and has certain application value.
Claims (5)
1. MoS2/Sb2S3The preparation method of the composite photocatalyst is characterized by comprising the following steps: 5-7 parts of SbCl3And 8-10 parts of CH3CSNH2Dissolving in 55-65 parts of absolute ethyl alcohol, magnetically stirring for 25-35min under the atmosphere of nitrogen, and performing centrifugal separation to obtain a bright orange precursor; the prepared SbCl3Dissolving the bright orange precursor in 50-60 parts of deionized water, and magnetically stirring to obtain Sb2S3Adding 2-4 parts of H into the precursor solution32Mo7N6O28And 5-7 parts of CH4N2S, magnetically stirring to obtain a mixed solution; finally transferring the mixed solution into a reaction kettle, putting the reaction kettle into a muffle furnace, sealing and heating the reaction kettle to 165-175 ℃, keeping the temperature for 25-27h, cooling the reaction kettle to room temperature, and then, adding MoS2/Sb2S3Centrifugally separating the composite photocatalyst, washing with anhydrous ethanol and deionized water for 4-6 times, drying in a vacuum drying oven at 45-55 deg.C for 13-15h, and cooling; the raw materials are in parts by weight.
2. The method of claim 1, wherein: magnetically stir for 30min under nitrogen atmosphere.
3. The method of claim 1, wherein: putting the mixture into a muffle furnace, sealing and heating the mixture to 170 ℃.
4. The method of claim 1, wherein: lasting for 26 h.
5. The method of claim 1, wherein: drying in a vacuum drying oven at 50 deg.C for 14 h.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112023985A (en) * | 2020-09-28 | 2020-12-04 | 长春工业大学 | Preparation method of composite nano photocatalytic material |
| CN112121826A (en) * | 2020-10-16 | 2020-12-25 | 安徽理工大学 | 1T @2H-MoS2/SnS2Preparation method, product and application of visible light response photocatalyst |
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2018
- 2018-11-24 CN CN201811410612.2A patent/CN111215097A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112023985A (en) * | 2020-09-28 | 2020-12-04 | 长春工业大学 | Preparation method of composite nano photocatalytic material |
| CN112121826A (en) * | 2020-10-16 | 2020-12-25 | 安徽理工大学 | 1T @2H-MoS2/SnS2Preparation method, product and application of visible light response photocatalyst |
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